JP5480904B2 - 弱相互作用性ポリマーを用いる繊維紡糸法 - Google Patents
弱相互作用性ポリマーを用いる繊維紡糸法 Download PDFInfo
- Publication number
- JP5480904B2 JP5480904B2 JP2011526261A JP2011526261A JP5480904B2 JP 5480904 B2 JP5480904 B2 JP 5480904B2 JP 2011526261 A JP2011526261 A JP 2011526261A JP 2011526261 A JP2011526261 A JP 2011526261A JP 5480904 B2 JP5480904 B2 JP 5480904B2
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- JP
- Japan
- Prior art keywords
- fibers
- polymer
- spinning
- solution
- fiber
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000835 fiber Substances 0.000 title claims description 66
- 229920000642 polymer Polymers 0.000 title claims description 55
- 238000009987 spinning Methods 0.000 title claims description 43
- 238000000034 method Methods 0.000 claims description 34
- 239000002904 solvent Substances 0.000 claims description 27
- 230000005684 electric field Effects 0.000 claims description 12
- 238000007664 blowing Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- 230000002452 interceptive effect Effects 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 150000002430 hydrocarbons Chemical class 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 150000008282 halocarbons Chemical class 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 6
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 6
- 238000001523 electrospinning Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- 239000003570 air Substances 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000001307 helium Substances 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000012456 homogeneous solution Substances 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000306 polymethylpentene Polymers 0.000 description 3
- 239000011116 polymethylpentene Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004750 melt-blown nonwoven Substances 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/20—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of cyclic compounds with one carbon-to-carbon double bond in the side chain
- D01F6/22—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of cyclic compounds with one carbon-to-carbon double bond in the side chain from polystyrene
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Dispersion Chemistry (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US19110308P | 2008-09-05 | 2008-09-05 | |
| US61/191,103 | 2008-09-05 | ||
| PCT/US2009/056181 WO2010028339A1 (en) | 2008-09-05 | 2009-09-08 | Fiber spinning process using a weakly interacting polymer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012502198A JP2012502198A (ja) | 2012-01-26 |
| JP2012502198A5 JP2012502198A5 (enExample) | 2012-10-18 |
| JP5480904B2 true JP5480904B2 (ja) | 2014-04-23 |
Family
ID=41228573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011526261A Active JP5480904B2 (ja) | 2008-09-05 | 2009-09-08 | 弱相互作用性ポリマーを用いる繊維紡糸法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8211353B2 (enExample) |
| EP (1) | EP2318576B1 (enExample) |
| JP (1) | JP5480904B2 (enExample) |
| KR (1) | KR101693390B1 (enExample) |
| CN (1) | CN102144055B (enExample) |
| BR (1) | BRPI0913520A2 (enExample) |
| WO (1) | WO2010028339A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100059906A1 (en) * | 2008-09-05 | 2010-03-11 | E. I. Du Pont De Nemours And Company | High throughput electroblowing process |
| US9487886B1 (en) | 2010-05-26 | 2016-11-08 | The Boeing Company | Indium tin oxide nanotubes and method of manufacture |
| KR20130125287A (ko) | 2010-05-29 | 2013-11-18 | 애쉴리 에스. 스코트 | 정전기 유도 용매 분출 또는 입자 형성을 위한 장치, 방법 및 유체 조성물 |
| CN102071542B (zh) * | 2011-02-22 | 2012-08-29 | 天津工业大学 | 一种聚合物纳微纤维非织造布的制备方法 |
| CN102121173B (zh) * | 2011-02-22 | 2012-05-30 | 天津工业大学 | 一种超细纤维非织造布吸音隔热材料的制备方法 |
| CN102505357A (zh) * | 2011-09-22 | 2012-06-20 | 东华大学 | 一种血液过滤用静电纺熔喷复合非织造材料及其制备方法 |
| CN104099674A (zh) * | 2014-05-19 | 2014-10-15 | 浙江大东南集团有限公司 | 一种气流助力式连续纳米纤维膜静电纺丝装置 |
| WO2017123293A2 (en) * | 2015-10-09 | 2017-07-20 | Massachusetts Institute Of Technology | Gel-electrospinning process for preparing high performance polymer nanofibers |
| US10895028B2 (en) | 2015-12-14 | 2021-01-19 | Dupont Industrial Biosciences Usa, Llc | Nonwoven glucan webs |
| CN107142534B (zh) * | 2017-05-25 | 2019-05-03 | 天津工业大学 | 一种溶液喷射纺丝设备 |
| KR102080990B1 (ko) | 2018-06-05 | 2020-02-24 | 서정옥 | 차량용 홀더형 음료용기 보관용구 |
| EP3747855B1 (de) | 2019-06-04 | 2024-01-10 | OQ Chemicals GmbH | Verfahren zur kontinuierlichen herstellung von diolen aus aldehyden mittels raney-cobalt katalyse |
| EP3954811A1 (en) * | 2020-08-13 | 2022-02-16 | Gelatex Technologies OÜ | Device and method for producing polymer fibers and its uses thereof |
| WO2024031105A1 (en) * | 2022-08-05 | 2024-02-08 | Matregenix, Inc. | Electrospinning systems for mass production of nanofibers |
| WO2025171011A1 (en) * | 2024-02-09 | 2025-08-14 | Moleaer, Inc. | Nanobubbles for preparation of spun fibrous materials |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100549140B1 (ko) | 2002-03-26 | 2006-02-03 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 일렉트로-브로운 방사법에 의한 초극세 나노섬유 웹제조방법 |
| US20050187605A1 (en) * | 2002-04-11 | 2005-08-25 | Greenhalgh Skott E. | Electrospun skin capable of controlling drug release rates and method |
| EP1709219A4 (en) * | 2003-09-05 | 2008-03-05 | Univ Louisiana State | NANOFIBRES AND DEVICE FOR MANUFACTURING NANOFIBRES BY REACTIVE ELECTROLYZATION |
| JP4351094B2 (ja) * | 2004-03-22 | 2009-10-28 | 日本バイリーン株式会社 | 繊維の製造方法及び製造装置 |
| US20060012084A1 (en) * | 2004-07-13 | 2006-01-19 | Armantrout Jack E | Electroblowing web formation process |
| US7887311B2 (en) * | 2004-09-09 | 2011-02-15 | The Research Foundation Of State University Of New York | Apparatus and method for electro-blowing or blowing-assisted electro-spinning technology |
| US7846374B2 (en) * | 2004-11-05 | 2010-12-07 | E. I. Du Pont De Nemours And Company | Blowing gases in electroblowing process |
| US20060135020A1 (en) * | 2004-12-17 | 2006-06-22 | Weinberg Mark G | Flash spun web containing sub-micron filaments and process for forming same |
| US7582247B2 (en) * | 2005-08-17 | 2009-09-01 | E. I. Du Pont De Nemours And Company | Electroblowing fiber spinning process |
| DE602006019774D1 (de) | 2005-11-28 | 2011-03-03 | Univ Delaware | Verfahren zur lösung eines präparats aus polymeren der polyolefinklasse zur elektrospinning-verarbeitung |
-
2009
- 2009-09-03 US US12/553,578 patent/US8211353B2/en active Active
- 2009-09-08 EP EP09792303A patent/EP2318576B1/en active Active
- 2009-09-08 WO PCT/US2009/056181 patent/WO2010028339A1/en not_active Ceased
- 2009-09-08 KR KR1020117007757A patent/KR101693390B1/ko active Active
- 2009-09-08 BR BRPI0913520A patent/BRPI0913520A2/pt not_active IP Right Cessation
- 2009-09-08 CN CN200980134778.9A patent/CN102144055B/zh active Active
- 2009-09-08 JP JP2011526261A patent/JP5480904B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2318576B1 (en) | 2013-03-27 |
| US20100059907A1 (en) | 2010-03-11 |
| KR20110055714A (ko) | 2011-05-25 |
| US8211353B2 (en) | 2012-07-03 |
| EP2318576A1 (en) | 2011-05-11 |
| BRPI0913520A2 (pt) | 2019-04-30 |
| KR101693390B1 (ko) | 2017-01-06 |
| WO2010028339A1 (en) | 2010-03-11 |
| CN102144055A (zh) | 2011-08-03 |
| CN102144055B (zh) | 2014-03-05 |
| JP2012502198A (ja) | 2012-01-26 |
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