JP5465433B2 - 生地含浸用の水性ポリオレフィン分散物 - Google Patents
生地含浸用の水性ポリオレフィン分散物 Download PDFInfo
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- JP5465433B2 JP5465433B2 JP2008545645A JP2008545645A JP5465433B2 JP 5465433 B2 JP5465433 B2 JP 5465433B2 JP 2008545645 A JP2008545645 A JP 2008545645A JP 2008545645 A JP2008545645 A JP 2008545645A JP 5465433 B2 JP5465433 B2 JP 5465433B2
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- polymer
- aqueous dispersion
- impregnated
- dispersion
- ethylene
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/08—Heel stiffeners; Toe stiffeners
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/08—Heel stiffeners; Toe stiffeners
- A43B23/081—Toe stiffeners
- A43B23/086—Toe stiffeners made of impregnated fabrics, plastics or the like
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/08—Heel stiffeners; Toe stiffeners
- A43B23/16—Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/04—Processes in which the treating agent is applied in the form of a foam
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/183—Synthetic polymeric fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2361—Coating or impregnation improves stiffness of the fabric other than specified as a size
Description
本出願は、2005年12月15日に出願された発明の名称「AQUEOUS POLYOLEFIN DISPERSIONS FOR TEXTILE IMPREGNATION」の米国特許出願第11/3300,993号の優先権を主張する通常出願であり、その開示は全て、以下に再現されるように、参照により本明細書に組み込まれる。
(a)約1.7〜約3.5のMw/Mn、少なくとも1つの融点Tm(℃)、および密度d(g/cm3)を有し、ここで、Tmおよびdの数値が以下の関係式に対応する。
Tm>−2002.9+4538.5(d)−2422.2(d)2;または
(b)約1.7〜約3.5のMw/Mnを有し、融解熱ΔH(J/g)、およびデルタ量ΔT(最高DSCピークと最高CRYSTAFピークとの温度差として定義される℃)を特徴とし、ここで、ΔTおよびΔHの数値が以下の関係を有する。
0より大きく、および130J/gまでのΔHに関して、ΔT>−0.1299(ΔH)+62.81
130J/gより大きいΔHに関して、ΔT>48℃
ここで、CRYSTAFピークは累積ポリマーの少なくとも5%を使用して測定され、ポリマーの5%未満が同定可能なCRYSTAFピークを有する場合、CRYSTAF温度は30℃である;または
(c) エチレン/α−オレフィンインターポリマーの圧縮成形フィルムを用いて測定される300%歪および1サイクルにおける弾性回復率Re(%)を特徴とし、密度d(g/cm3)を有し、ここで、Reおよびdの数値は、エチレン/α−オレフィンインターポリマーが架橋相を実質的に有さない場合に、下記の関係式を満たす。
Re>1481−1629(d);または
(d) TREFを使用して分別した場合に、40℃〜130℃で溶離する分子画分を有し、該画分が、同じ温度範囲で溶離する比較可能なランダムエチレンインターポリマー画分より少なくとも5%高いモルコモノマー量(molar comonomer content)を有することを特徴とし、該比較可能なランダムエチレンインターポリマーは、同じコモノマーを有し、エチレン/α−オレフィンインターポリマーの10%以内の、メルトインデックス、密度およびモルコモノマー量(全ポリマーに基づく)を有する;または
(e) 25℃における貯蔵弾性率G’(25℃)、および100℃における貯蔵弾性率G’(100℃)を有し、G’(25℃)/G’(100℃)の比率が約1:1〜約9:1である。
エチレン/α−オレフィンインターポリマーは、下記であってもよい。
(a) TREFを使用して分別した場合に、40℃〜130℃で溶離する分子画分を有し、該画分が、少なくとも0.5〜約1までのブロックインデックスを有し、約1.3より大きい分子量分布Mw/Mnを有することを特徴とする;または
(b) 0より大きい、および約1.0までの平均ブロックインデックス、および約1.3より大きい分子量分布Mw/Mnを有する。
2つのポリオレフィン分散物を、以下の実施例全体を通して使用し、該分散物は、基剤ポリマー/安定剤混合物を含んでいた。第一分散物は、VERSIFY(商標)DP4200/PRIMACOR(商標)5980I混合物を使用して形成し、第二分散物は、ENGAGE(商標)8200/PRIMACOR(商標)5980I混合物を使用して形成し、それらは、それぞれ、Dow Chemical Company(Midland, MI)から入手可能である。PRIMACOR(商標)5980Iは、エチレンアクリル酸コポリマーであり(20.5wt%アクリル酸;13.8のMFR、125℃で2.16kg重量を使用;0.958g/cc);VERSIFY(商標)DP4200は、プロピレン基剤エラストマーであり(9mol%エチレン;25 MFR、230℃で2.16kg重量を使用);ENGAGE(商標)8200は、エチレン基剤エラストマーである(エチレン−オクテンコポリマー;5 MI;0.870g/cc)。
ASR=100(H1/H2)2
ここで、図5に示されるように、H1は、関連成形用具(金型のドーム)の高さであり、H2は、第1または第10回目のへこみ後の成形ドームの内部高さである。補強剤が硬いほど、靴の変形を防ぐ保形性がより優れている。
Mホ゜リエチレン=0.431(Mホ゜リスチレン)
Claims (22)
- 含浸生地の形成法であって、下記の工程:
水性分散物を含む化合物を形成する工程であって、前記水性分散物が下記の物質を含む工程、
(a)エチレン基剤熱可塑性ポリマー、プロピレン基剤熱可塑性ポリマー、およびそれらの混合物からなる群より選択される少なくとも1つのポリマー、ここで該少なくとも1つのポリマーが、前記水性分散物の35〜55容積%を占める;
(b)少なくとも1つの高分子量安定剤;および、
(c)水;
生地に前記化合物を含浸させる工程;
エチレン基剤熱可塑性ポリマー、プロピレン基剤熱可塑性ポリマー、およびそれらの混合物からなる群より選択される前記ポリマーの融点またはそれ以上の範囲の温度のもとで、前記含浸生地から少なくとも一部の水を除去する工程;および
それによって連続基剤ポリマー相および該連続基剤ポリマー相に分散した不連続安定剤相を含むフィルムを形成する工程;を有し、
前記含浸生地が、前記少なくとも1つのポリマーおよび前記高分子量安定剤の合計量を、前記含浸生地100重量部につき15〜75重量部の範囲で有し、
前記化合物が、少なくとも1つの充填剤をさらに含み、前記含浸生地が、前記充填剤、前記少なくとも1つのポリマーおよび前記高分子量安定剤の合計量を、前記含浸生地100重量部につき10〜300重量部の範囲で有し、
前記含浸が、前記水性分散物中の前記少なくとも1つのポリマーを、前記水性分散物の35〜55wt%の範囲に調節することによって、及び、前記化合物の粘度を、20〜3000cPの範囲に調節することによって維持される、形成法。 - 前記化合物の粘度、前記水性分散物中の組み合わされたポリマーおよび安定剤の濃度、または前記水性分散物の極性の少なくとも1つを調節することをさらに含む、請求項1に記載の方法。
- 前記少なくとも1つのポリマーが、前記水性分散物の40〜50容量%の範囲に調節される、請求項2に記載の方法。
- 前記化合物の粘度が、20〜3000cPの範囲に調節される、請求項3に記載の方法。
- 前記含浸生地を高温に暴露することによって一部の水を除去することをさらに含む、請求項1に記載の方法。
- 温度が70℃〜120℃である、請求項5に記載の方法。
- 前記エチレン基剤ポリマーが、エチレン−α−オレフィンインターポリマーである、請求項1に記載の方法。
- 前記プロピレン基剤ポリマーが、プロピレン−α−オレフィンインターポリマーである、請求項1に記載の方法。
- 前記少なくとも1つの高分子量安定剤が、少なくとも1つの極性ポリマーを含む、請求項1に記載の方法。
- 前記極性ポリマーが極性ポリオレフィンを含む、請求項9に記載の方法。
- 前記極性ポリオレフィンが、部分的または完全に中和されたエチレン−酸コポリマーを含む、請求項10に記載の方法。
- 前記極性ポリオレフィンが、エチレン−アクリル酸ポリマー、エチレン−メタクリル酸ポリマーおよびそれらの組合せからなる群より選択される少なくとも1つを含む、請求項11に記載の方法。
- 前記少なくとも1つのポリマーおよび前記少なくとも1つの高分子量安定剤の合計量が、前記水性分散物の25〜74容積%である、請求項1に記載の方法。
- 前記水性分散物が、pH6〜14を有する、請求項1に記載の方法。
- 前記水性分散物が、pH9〜12を有する、請求項14に記載の方法。
- 前記水性分散物が、平均粒度0.3〜3.0ミクロンを有する、請求項1に記載の方法。
- 前記水性分散物が、平均粒度0.5〜2.7ミクロンを有する、請求項16に記載の方法。
- 前記含浸生地が、織物、編物および不織布から選択される少なくとも1つを含む繊維構造物を含有する、請求項1に記載の方法。
- 前記含浸生地が、亜麻、麻、セルロース、パルプおよび木材からなる群より選択される天然繊維を含む繊維構造物を含有する、請求項1に記載の方法。
- 前記含浸生地が、綿、ウール、合成ウール、セルロース系材料;ポリアミド、ポリアクリロニトリル、ポリビニルクロライド、ポリビニリデンクロライド、ポリプロピレン、ポリエステルの合成繊維、およびそれらの組合せの少なくとも1つを含む繊維構造物を含有する、請求項1に記載の方法。
- 前記化合物が、湿潤剤、界面活性剤、帯電防止剤、顔料、中和剤、増粘剤、流動調節剤、殺生物剤、殺真菌剤およびそれらの組合せから選択される少なくとも1つをさらに含む、請求項1に記載の方法。
- 前記含浸生地を他の支持体に結合させるか、貼り合わせるかまたはコーティングすることをさらに含む、請求項1に記載の方法。
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US11/300,993 US7528080B2 (en) | 2005-12-15 | 2005-12-15 | Aqueous polyolefin dispersions for textile impregnation |
US11/300,993 | 2005-12-15 | ||
PCT/US2006/046494 WO2007078536A1 (en) | 2005-12-15 | 2006-12-04 | Aqueous polyolefin dispersions for textile impregnation |
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JP2016035061A (ja) * | 2005-12-15 | 2016-03-17 | ダウ グローバル テクノロジーズ エルエルシー | 生地含浸用の水性ポリオレフィン分散物 |
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JP6064008B2 (ja) | 2017-01-18 |
CA2633974A1 (en) | 2007-07-12 |
KR101323470B1 (ko) | 2013-10-30 |
EP1963564B1 (en) | 2013-02-13 |
CN104532574B (zh) | 2018-06-05 |
US7528080B2 (en) | 2009-05-05 |
JP2016035061A (ja) | 2016-03-17 |
WO2007078536B1 (en) | 2007-09-20 |
IN266885B (ja) | 2015-06-11 |
BRPI0620708B1 (pt) | 2017-04-25 |
RU2008128825A (ru) | 2010-01-20 |
JP2014040604A (ja) | 2014-03-06 |
WO2007078536A1 (en) | 2007-07-12 |
KR20080081170A (ko) | 2008-09-08 |
US20070141933A1 (en) | 2007-06-21 |
PL1963564T3 (pl) | 2013-07-31 |
US7998531B2 (en) | 2011-08-16 |
ES2404098T3 (es) | 2013-05-23 |
US20090253321A1 (en) | 2009-10-08 |
EP1963564A1 (en) | 2008-09-03 |
CN101356312B (zh) | 2015-05-27 |
JP2009520053A (ja) | 2009-05-21 |
CN104532574A (zh) | 2015-04-22 |
BRPI0620708A2 (pt) | 2011-11-22 |
TW200736447A (en) | 2007-10-01 |
CN101356312A (zh) | 2009-01-28 |
ZA200805196B (en) | 2009-09-30 |
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