JP5397382B2 - 光学フィルム、光学フィルムの製造方法、偏光板および液晶表示装置 - Google Patents
光学フィルム、光学フィルムの製造方法、偏光板および液晶表示装置 Download PDFInfo
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- JP5397382B2 JP5397382B2 JP2010532853A JP2010532853A JP5397382B2 JP 5397382 B2 JP5397382 B2 JP 5397382B2 JP 2010532853 A JP2010532853 A JP 2010532853A JP 2010532853 A JP2010532853 A JP 2010532853A JP 5397382 B2 JP5397382 B2 JP 5397382B2
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- 150000003918 triazines Chemical class 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
- B29C55/06—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/91—Heating, e.g. for cross linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
- B29C48/914—Cooling of flat articles, e.g. using specially adapted supporting means cooling drums
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
- B29C48/915—Cooling of flat articles, e.g. using specially adapted supporting means with means for improving the adhesion to the supporting means
- B29C48/9155—Pressure rollers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/30—Extrusion nozzles or dies
- B29C48/305—Extrusion nozzles or dies having a wide opening, e.g. for forming sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/362—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using static mixing devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/69—Filters or screens for the moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/69—Filters or screens for the moulding material
- B29C48/693—Substantially flat filters mounted at the end of an extruder screw perpendicular to the feed axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2001/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/256—Sheets, plates, blanks or films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/0034—Polarising
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/08—Cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polarising Elements (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Description
本発明に用いられるアクリル樹脂には、メタクリル樹脂も含まれる。樹脂としては特に制限されるものではないが、メチルメタクリレート単位50〜99質量%、およびこれと共重合可能な他の単量体単位1〜50質量%からなるものが好ましい。
カラム: Shodex K806、K805、K803G(昭和電工(株)製を3本接続して使用した)
カラム温度:25℃
試料濃度: 0.1質量%
検出器: RI Model 504(GLサイエンス社製)
ポンプ: L6000(日立製作所(株)製)
流量: 1.0ml/min
校正曲線: 標準ポリスチレンSTK standard ポリスチレン(東ソー(株)製)Mw=2,800,000〜500迄の13サンプルによる校正曲線を使用した。13サンプルは、ほぼ等間隔に用いることが好ましい。
本発明のセルロースエステル樹脂(B)は、特に脆性の改善やアクリル樹脂(A)と相溶させたときに透明性の観点から、アシル基の総置換度(T)が2.0〜3.0、炭素数が3〜7のアシル基の置換度が1.2〜3.0であり、炭素数3〜7のアシル基の置換度は、2.0〜3.0であることが好ましい。即ち、本発明のセルロースエステル樹脂は炭素数が3〜7のアシル基により置換されたセルロースエステル樹脂であり、具体的には、プロピオニル、ブチリル等が好ましく用いられるが、特にプロピオニル基が好ましく用いられる。
本発明の光学フィルムは、アクリル粒子を含有してもよい。
<その他の添加剤>
本発明の光学フィルムには、フィルムに加工性を付与する可塑剤、フィルムの劣化を防止する酸化防止剤、紫外線吸収機能を付与する紫外線吸収剤、フィルムに滑り性を付与する微粒子(マット剤)等の添加剤を含有させることが好ましい。
〈可塑剤〉
可塑剤としては、フタル酸エステル系、脂肪酸エステル系、トリメリット酸エステル系、リン酸エステル系、ポリエステル系、あるいはエポキシ系等が挙げられる。
〈酸化防止剤〉
本発明では、酸化防止剤としては、通常知られているものを使用することができる。
〈着色剤〉
本発明においては、着色剤を使用することが好ましい。着色剤と言うのは染料や顔料を意味するが、本発明では、液晶画面の色調を青色調にする効果またはイエローインデックスの調整、ヘイズの低減を有するものを指す。
〈紫外線吸収剤〉
本発明に用いられる紫外線吸収剤は特に限定されないが、例えばオキシベンゾフェノン系化合物、ベンゾトリアゾール系化合物、サリチル酸エステル系化合物、ベンゾフェノン系化合物、シアノアクリレート系化合物、トリアジン系化合物、ニッケル錯塩系化合物、無機粉体等が挙げられる。高分子型の紫外線吸収剤としてもよい。
〈マット剤〉
本発明では、フィルムの滑り性を付与するためにマット剤を添加することが好ましい。
〈粘度低下剤〉
本発明において、溶融粘度を低減する目的として、水素結合性溶媒を添加することができる。水素結合性溶媒とは、J.N.イスラエルアチビリ著、「分子間力と表面力」(近藤保、大島広行訳、マグロウヒル出版、1991年)に記載されるように、電気的に陰性な原子(酸素、窒素、フッ素、塩素)と電気的に陰性な原子と共有結合した水素原子間に生ずる、水素原子媒介「結合」を生ずることができるような有機溶媒、すなわち、結合モーメントが大きく、かつ水素を含む結合、例えば、O−H(酸素水素結合)、N−H(窒素水素結合)、F−H(フッ素水素結合)を含むことで近接した分子同士が配列できるような有機溶媒をいう。
a1:熱処理前の距離
a2:熱処理後の距離
液晶表示装置の偏光板用保護フィルムとして光学フィルムが用いられる場合は、吸湿による寸法変化により光学フィルムにムラや位相差値の変化が発生してしまい、コントラストの低下や色むらといった問題を発生させる。特に屋外で使用される液晶表示装置に用いられる偏光板保護フィルムであれば、上記の問題は顕著となる。しかし、上記の条件における寸法変化率(%)が0.5%未満であれば、十分な低吸湿性を示す光学フィルムであると評価できる。さらに、0.3%未満であることが好ましい。
<溶融流延製膜方法による光学フィルムの製造方法>
本発明の光学フィルムの製造方法は、アクリル樹脂(A)とセルロースエステル樹脂(B)を95:5から30:70の質量比で含有したものを溶融してダイから押出して、冷却ロール上に流延する光学フィルムの製造方法である。
溶融押出に用いるアクリル樹脂(A)、セルロースエステル樹脂(B)、その他の添加剤からなる光学フィルムを構成する組成物は、通常あらかじめ混錬してペレット化しておくことが好ましい。
まず、作製したペレットを1軸や2軸タイプの押出機を用いて、押し出す際の溶融温度Tmを200〜300℃程度とし、リーフディスクタイプのフィルターなどでろ過し異物を除去した後、Tダイからフィルム状に共押出し、冷却ロール上で固化し、弾性タッチロールと押圧しながら流延する。
本発明では、上記のようにして得られたフィルムは冷却ロールに接する工程を通過後、さらに少なくとも1方向に1.01〜3.0倍延伸することが好ましい。延伸により本発明の脆性を実現することができる。
<含有溶媒量>
本発明の光学フィルムは、溶融流延製膜方法によって作製することから、ロール状フィルムとして巻き取った時点で、含有している溶媒量が0.01質量%以下である。含有溶媒量は、下記の方法によって測定することができる。
機器:HP社 5890SERIES II
カラム:J&W社 DB−WAX(内径0.32mm、長さ30m)
検出:FID
GC昇温条件:40℃で5分間保持したあと、80℃/分で100℃まで昇温
ヘッドスペース加熱条件:120℃で20min
<清掃設備>
本発明の製造装置には、ベルトおよびロールを自動的に清掃する装置を付加させることが好ましい。清掃装置については特に限定はないが、例えば、ブラシ・ロール、吸水ロール、粘着ロール、ふき取りロール等をニップする方式、清浄エアーを吹き掛けるエアーブロー方式、レーザーによる焼却装置、あるいはこれらの組み合わせなどがある。
本発明の光学フィルムを偏光板用保護フィルムとして用いる場合、偏光板は一般的な方法で作製することが出来る。本発明の光学フィルムの裏面側に粘着層を設け、沃素溶液中に浸漬延伸して作製した偏光子の少なくとも一方の面に、貼り合わせることが好ましい。
本発明の光学フィルムを貼合した偏光板を液晶表示装置に組み込むことによって、種々の視認性に優れた液晶表示装置を作製することが出来るが、特に大型の液晶表示装置やデジタルサイネージ等の屋外用途の液晶表示装置に好ましく用いられる。本発明に係る偏光板は、前記粘着層等を介して液晶セルに貼合する。
〔アクリル樹脂の調製〕
以下のアクリル樹脂A2−A7、およびMS1、2を公知の方法によって調製した。
A3:モノマー質量比(MMA:MA=97:3)、Mw140000
A4:モノマー質量比(MMA:MA=97:3)、Mw200000
A5:モノマー質量比(MMA:MA=97:3)、Mw500000
A6:モノマー質量比(MMA:MA=97:3)、Mw550000
A7:モノマー質量比(MMA:MA=94:6)、Mw1000000
MMA:メチルメタクリレート
MA:メチルアクリレート
その他、以下の市販のアクリル樹脂を用いた。
A2を70質量部、セルロースエステルとしてセルロースアセテートプロピオネート(アセチル基の置換度0.19、プロピオニル基の置換度2.56、総アシル基置換度2.75、Mw=200000)30質量部、Tinuvin928(チバ・ジャパン(株)製)1.5質量部、ADK STAB PEP−36(旭電化工業(株)製)0.01質量部、Irganox1010(チバ・ジャパン(株)製)0.5質量部、SumilizerGS(住友化学(株)製)0.2質量部の割合で配合して、光学フィルム1を構成する組成物1を形成した。
《評価方法》
(ガラス転移温度)
延伸前の光学フィルムのTgは、作製した光学フィルムとほぼ同じなので、光学フィルムのTgを測定することにより、延伸前の光学フィルムのTgに代替した。
(張力軟化点)
23℃、55%RHの雰囲気下、テンシロン試験機(ORIENTEC社製、RTC−1225A)を用いて、以下のような評価を行った。
(耐折度)
光学フィルムを120mm(縦)×10mm(幅)で切り出し、温度23℃、相対湿度55%RHに調湿された部屋で4時間調湿した後、ISO877 6/2−1988に従い、折り曲げによって切断するまでの往復回数を求めた。
〈偏光板の作製〉
各光学フィルムを偏光板保護フィルムとした偏光板を、以下のようにして作製した。
(リワーク性)
23℃、55%RHの雰囲気下、作製した偏光板を20cm×20cmの大きさの正方形に断裁し、アクリル系接着剤を用いてガラス基板と貼り合わせる。次いで、貼り合わせた偏光板を角の部分から5Nの強さでガラスから剥がす。この作業を1種類のサンプルについて100枚の偏光板で行い、偏光板に裂け目が入って、完全に剥離されなかった偏光板の枚数を数える。リワーク性は以下の基準でランク付けする。
○△:6〜10枚
△ :11〜15枚
× :16枚以上
リワーク性は△レベル以上であれば実用上問題ないが、○△レベル以上であることが好ましく、○レベルであることが特に好ましい。
上記作製した各偏光板を使用して、光学フィルムの表示特性評価を行った。
黒表示時の光漏れを目視で下記基準により評価した。
×:強い光漏れが1〜2箇所ある
〈アクリル粒子(C1)の調製〉
内容積60リットルの還流冷却器付反応器に、イオン交換水38.2リットル、ジオクチルスルホコハク酸ナトリウム111.6gを投入し、250rpmの回転数で攪拌しながら、窒素雰囲気下75℃に昇温し、酸素の影響が事実上無い状態にした。APS0.36gを投入し、5分間攪拌後にMMA1657g、BA21.6g、およびALMA1.68gからなる単量体混合物を一括添加し、発熱ピークの検出後さらに20分間保持して最内硬質層の重合を完結させた。
MA;メチルアクリレート
BA;n−ブチルアクリレート
ALMA;アリルメタクリレート
PEGDA;ポリエチレングリコールジアクリレート(分子量200)
n−OM;n−オクチルメルカプタン
APS;過硫酸アンモニウム
以下、アクリル樹脂(A)、セルロースエステル樹脂(B)、アクリル粒子(C)、組成比を表4の記載のように変えた以外は、実施例1に記載の光学フィルム2の製造方法と同様にして、光学フィルム2−1と2−2を、光学フィルム1の製造方法と同様にして、光学フィルム1−1〜1−6を作製した。
チヌビン171(チバ・ジャパン(株)製) 0.7質量部
なお、これらの光学フィルムの含有溶媒量は、いずれも0.01質量%以下であった。
2 フィルター
3 スタチックミキサー
4 流延ダイ
5 回転支持体(第1冷却ロール)
6 挟圧回転体(タッチロール)
7 回転支持体(第2冷却ロール)
8 回転支持体(第3冷却ロール)
9、10、11、13、14 搬送ロール
12 延伸機
15 スリッター
16 巻き取り機
F 本発明の光学フィルム
Claims (4)
- アクリル樹脂(A)とセルロースエステル樹脂(B)を95:5から30:70の質量比で、前記アクリル樹脂(A)の重量平均分子量Mwが110000以上1000000以下であり、該セルロースエステル樹脂(B)のアシル基総置換度(T)が2.0以上3.0以下、炭素数が3以上、7以下のアシル基の置換度が1.2以上3.0以下であり、該セルロースエステル樹脂(B)の重量平均分子量Mwが75000以上300000以下であり、張力軟化点が105〜145℃、耐折度が50〜100回、含有している溶媒量が0.01質量%以下であることを特徴とする光学フィルムの製造方法であって、
光学フィルムを溶融流延製膜方法によって製造する工程と、
光学フィルムを搬送方向または幅手方向の少なくともいずれかの方向に延伸する工程と、を含み、
延伸の際の延伸温度が延伸前の光学フィルムのTg〜Tg+50℃である、光学フィルムの製造方法。 - 前記アクリル樹脂(A)の重量平均分子量Mwが120000以上300000以下である請求項1に記載の光学フィルムの製造方法。
- 前記アクリル樹脂(A)と前記セルロースエステル樹脂(B)とを90:10から30:70の質量比で含む、請求項1または2に記載の光学フィルムの製造方法。
- 前記張力軟化点が110〜130℃である請求項1〜3のいずれか1項に記載の光学フィルムの製造方法。
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CN106257314A (zh) * | 2015-06-19 | 2016-12-28 | 住友化学株式会社 | 带保护膜的偏光板的制造方法 |
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JP5424717B2 (ja) * | 2009-05-29 | 2014-02-26 | 株式会社日本触媒 | 光学フィルムの製造方法 |
JP2013029553A (ja) * | 2011-07-26 | 2013-02-07 | Fujifilm Corp | 光学フィルム及びその製造方法、積層光学フィルム、偏光板、並びに液晶表示装置 |
JP6075424B2 (ja) * | 2014-09-30 | 2017-02-08 | 住友化学株式会社 | 偏光板、液晶表示装置及び有機エレクトロルミネッセンス表示装置 |
CN109540895B (zh) * | 2018-12-27 | 2021-03-23 | 朱锦铃 | 一种燃气表膜质量检测装置 |
JPWO2020175208A1 (ja) * | 2019-02-28 | 2021-12-23 | 日東電工株式会社 | 光学積層体 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10336767A (ja) * | 1997-05-30 | 1998-12-18 | Sanyo Electric Co Ltd | 制御システム及び電子装置 |
JP2002356658A (ja) * | 2001-05-31 | 2002-12-13 | Nippon Carbide Ind Co Inc | アクリル系オーバーレイフィルム |
JP2007231157A (ja) * | 2005-03-10 | 2007-09-13 | Konica Minolta Opto Inc | 光学フィルム、光学フィルムの製造方法、光学補償フィルム、光学補償フィルムの製造方法、偏光板及び液晶表示装置 |
WO2008062610A1 (fr) * | 2006-11-25 | 2008-05-29 | Konica Minolta Opto, Inc. | Procédé de fabrication de film optique, film d'ester de cellulose, polariseur et dispositif d'affichage à cristaux liquides |
WO2009047924A1 (ja) * | 2007-10-13 | 2009-04-16 | Konica Minolta Opto, Inc. | 光学フィルム |
WO2009096070A1 (ja) * | 2008-01-30 | 2009-08-06 | Konica Minolta Opto, Inc. | アクリル樹脂含有フィルム、それを用いた偏光板及び液晶表示装置 |
JP2009179731A (ja) * | 2008-01-31 | 2009-08-13 | Konica Minolta Opto Inc | アクリル樹脂含有フィルム、それを用いた偏光板及び表示装置 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10316767A (ja) * | 1997-05-15 | 1998-12-02 | Asahi Chem Ind Co Ltd | セルロースとアクリル系重合体とのブレンド成形体及びその製造方法 |
US20030232030A1 (en) * | 2002-06-12 | 2003-12-18 | L'oreal | Compositions containing at least one oil structured with at least one silicone-polyamide polymer, and at least one gelling agent and methods of using the same |
CN1834705A (zh) * | 2005-03-10 | 2006-09-20 | 柯尼卡美能达精密光学株式会社 | 光学薄膜和光学补偿薄膜及制法、偏光板和液晶显示装置 |
CN101171291A (zh) * | 2005-05-10 | 2008-04-30 | 柯尼卡美能达精密光学株式会社 | 纤维素酯薄膜、偏振片及液晶显示装置 |
CN101247938B (zh) * | 2005-09-12 | 2010-09-08 | 富士胶片株式会社 | 纤维素酰化物薄膜的制备方法、偏振片以及液晶显示器 |
JP2007126603A (ja) * | 2005-11-07 | 2007-05-24 | Fujifilm Corp | ポリマーフィルム、ポリマーフィルムの製造方法、び偏光板及び液晶表示装置 |
CN101460306B (zh) * | 2006-03-31 | 2012-07-18 | 日本瑞翁株式会社 | 偏振片、液晶显示装置以及保护膜 |
TWI387526B (zh) * | 2006-06-06 | 2013-03-01 | Fujifilm Corp | 熱可塑性樹脂薄膜及其製法、以及偏光板、光學補償薄膜、抗反射薄膜與液晶顯示裝置 |
US20080049323A1 (en) * | 2006-07-27 | 2008-02-28 | Fujifilm Corporation | Optical film, production method of optical film, polarizing plate and liquid crystal display device |
-
2009
- 2009-08-10 CN CN2009801388295A patent/CN102171020B/zh not_active Expired - Fee Related
- 2009-08-10 JP JP2010532853A patent/JP5397382B2/ja active Active
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- 2009-08-10 WO PCT/JP2009/064122 patent/WO2010041513A1/ja active Application Filing
- 2009-09-30 TW TW098133195A patent/TW201030080A/zh unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10336767A (ja) * | 1997-05-30 | 1998-12-18 | Sanyo Electric Co Ltd | 制御システム及び電子装置 |
JP2002356658A (ja) * | 2001-05-31 | 2002-12-13 | Nippon Carbide Ind Co Inc | アクリル系オーバーレイフィルム |
JP2007231157A (ja) * | 2005-03-10 | 2007-09-13 | Konica Minolta Opto Inc | 光学フィルム、光学フィルムの製造方法、光学補償フィルム、光学補償フィルムの製造方法、偏光板及び液晶表示装置 |
WO2008062610A1 (fr) * | 2006-11-25 | 2008-05-29 | Konica Minolta Opto, Inc. | Procédé de fabrication de film optique, film d'ester de cellulose, polariseur et dispositif d'affichage à cristaux liquides |
WO2009047924A1 (ja) * | 2007-10-13 | 2009-04-16 | Konica Minolta Opto, Inc. | 光学フィルム |
WO2009096070A1 (ja) * | 2008-01-30 | 2009-08-06 | Konica Minolta Opto, Inc. | アクリル樹脂含有フィルム、それを用いた偏光板及び液晶表示装置 |
JP2009179731A (ja) * | 2008-01-31 | 2009-08-13 | Konica Minolta Opto Inc | アクリル樹脂含有フィルム、それを用いた偏光板及び表示装置 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106257314A (zh) * | 2015-06-19 | 2016-12-28 | 住友化学株式会社 | 带保护膜的偏光板的制造方法 |
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TW201030080A (en) | 2010-08-16 |
JPWO2010041513A1 (ja) | 2012-03-08 |
CN102171020A (zh) | 2011-08-31 |
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