JP5382982B2

JP5382982B2 - プロピレン重合体、及び該重合体から得られる成形体

プロピレン重合体、及び該重合体から得られる成形体 Download PDF

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Publication number: JP5382982B2
Authority: JP; Japan
Prior art keywords: propylene polymer; cyclopentadienyl; zirconium dichloride; butylfluorenyl; ditert
Prior art date: 2006-02-24
Legal status : Active

Application number

JP2006155038A

Other languages

English (en)

Japanese (ja)

Other versions

JP2007308667A5 (enrdf_load_stackoverflow

JP2007308667A (ja

Inventor

勝彦岡本

亮二森

貴中川

靖土肥

智弘山口

匡史樋口

康夫一木

Current Assignee

Mitsui Chemicals Inc

Original Assignee

Mitsui Chemicals Inc

Priority date

2006-02-24

Filing date

2006-06-02

Publication date

2014-01-08

2006-06-02 Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc

2006-06-02 Priority to JP2006155038A priority Critical patent/JP5382982B2/ja

2007-11-29 Publication of JP2007308667A publication Critical patent/JP2007308667A/ja

2009-05-28 Publication of JP2007308667A5 publication Critical patent/JP2007308667A5/ja

2014-01-08 Application granted granted Critical

2014-01-08 Publication of JP5382982B2 publication Critical patent/JP5382982B2/ja

Status Active legal-status Critical Current

2026-06-02 Anticipated expiration legal-status Critical

Links

229920001155 polypropylene Polymers 0.000 title claims description 173
229920000642 polymer Polymers 0.000 title claims description 45
238000002425 crystallisation Methods 0.000 claims description 48
230000008025 crystallization Effects 0.000 claims description 47
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 40
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 40
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 24
125000004432 carbon atom Chemical group C* 0.000 claims description 21
239000004711 α-olefin Substances 0.000 claims description 20
238000002844 melting Methods 0.000 claims description 12
230000008018 melting Effects 0.000 claims description 12
230000035515 penetration Effects 0.000 claims description 7
230000004927 fusion Effects 0.000 claims description 6
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 5
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
239000005977 Ethylene Substances 0.000 claims description 5
-1 Polypropylene Polymers 0.000 description 110
150000001875 compounds Chemical class 0.000 description 51
238000000034 method Methods 0.000 description 44
238000006116 polymerization reaction Methods 0.000 description 44
239000004743 Polypropylene Substances 0.000 description 38
239000000243 solution Substances 0.000 description 36
239000010408 film Substances 0.000 description 31
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
239000000047 product Substances 0.000 description 27
238000000465 moulding Methods 0.000 description 26
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 25
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 25
238000005259 measurement Methods 0.000 description 20
239000003054 catalyst Substances 0.000 description 19
239000000463 material Substances 0.000 description 19
239000000203 mixture Substances 0.000 description 18
239000000178 monomer Substances 0.000 description 14
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 13
238000004519 manufacturing process Methods 0.000 description 13
230000000704 physical effect Effects 0.000 description 13
229920005989 resin Polymers 0.000 description 13
239000011347 resin Substances 0.000 description 13
VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 13
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 11
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
238000005481 NMR spectroscopy Methods 0.000 description 11
125000005234 alkyl aluminium group Chemical group 0.000 description 11
238000006243 chemical reaction Methods 0.000 description 11
238000001746 injection moulding Methods 0.000 description 11
229910052757 nitrogen Inorganic materials 0.000 description 11
239000002904 solvent Substances 0.000 description 11
230000015572 biosynthetic process Effects 0.000 description 10
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 10
150000002430 hydrocarbons Chemical group 0.000 description 10
238000003786 synthesis reaction Methods 0.000 description 10
238000012360 testing method Methods 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
150000001336 alkenes Chemical class 0.000 description 9
238000002347 injection Methods 0.000 description 9
239000007924 injection Substances 0.000 description 9
150000002500 ions Chemical class 0.000 description 9
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 9
239000002685 polymerization catalyst Substances 0.000 description 9
229910004298 SiO 2 Inorganic materials 0.000 description 8
239000002734 clay mineral Substances 0.000 description 8
238000011156 evaluation Methods 0.000 description 8
239000010410 layer Substances 0.000 description 8
238000000113 differential scanning calorimetry Methods 0.000 description 7
239000007789 gas Substances 0.000 description 7
239000011521 glass Substances 0.000 description 7
150000008040 ionic compounds Chemical class 0.000 description 7
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 7
VFLWKHBYVIUAMP-UHFFFAOYSA-N n-methyl-n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCC VFLWKHBYVIUAMP-UHFFFAOYSA-N 0.000 description 7
239000002667 nucleating agent Substances 0.000 description 7
239000000843 powder Substances 0.000 description 7
239000007787 solid Substances 0.000 description 7
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 6
238000001125 extrusion Methods 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000012299 nitrogen atmosphere Substances 0.000 description 6
239000004745 nonwoven fabric Substances 0.000 description 6
150000002894 organic compounds Chemical class 0.000 description 6
239000012071 phase Substances 0.000 description 6
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
238000005160 1H NMR spectroscopy Methods 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical class C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 5
HFKJQIJFRMRSKM-UHFFFAOYSA-N [3,5-bis(trifluoromethyl)phenoxy]boronic acid Chemical compound OB(O)OC1=CC(C(F)(F)F)=CC(C(F)(F)F)=C1 HFKJQIJFRMRSKM-UHFFFAOYSA-N 0.000 description 5
239000000654 additive Substances 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
238000001816 cooling Methods 0.000 description 5
239000013078 crystal Substances 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
239000003999 initiator Substances 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
239000008188 pellet Substances 0.000 description 5
229920000573 polyethylene Polymers 0.000 description 5
230000008569 process Effects 0.000 description 5
150000003254 radicals Chemical class 0.000 description 5
239000000126 substance Substances 0.000 description 5
150000003624 transition metals Chemical class 0.000 description 5
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 5
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 5
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 5
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
HZAGIPZYQVBIFN-UHFFFAOYSA-L [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 Chemical compound [Cl-].[Cl-].C=[Zr+2](C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1)C1C=CC=C1 HZAGIPZYQVBIFN-UHFFFAOYSA-L 0.000 description 4
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UHOVQNZJYSORNB-MZWXYZOWSA-N benzene-d6 Chemical compound [2H]C1=C([2H])C([2H])=C([2H])C([2H])=C1[2H] UHOVQNZJYSORNB-MZWXYZOWSA-N 0.000 description 4
238000000071 blow moulding Methods 0.000 description 4
150000001735 carboxylic acids Chemical class 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
238000000434 field desorption mass spectrometry Methods 0.000 description 4
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150000003839 salts Chemical class 0.000 description 4
229910052710 silicon Inorganic materials 0.000 description 4
238000001228 spectrum Methods 0.000 description 4
HTGQCLJTWPSFNL-UHFFFAOYSA-N (2-methylphenoxy)boronic acid Chemical compound CC1=CC=CC=C1OB(O)O HTGQCLJTWPSFNL-UHFFFAOYSA-N 0.000 description 3
229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
229910010413 TiO 2 Inorganic materials 0.000 description 3
GGEPCFWWZHYSIG-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1=C(C(=CC=2C3=CC(=C(C=C3CC1=2)C1=CC=CC=C1)C(C)(C)C)C(C)(C)C)C1=CC=CC=C1 GGEPCFWWZHYSIG-UHFFFAOYSA-L 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
235000010210 aluminium Nutrition 0.000 description 3
150000003863 ammonium salts Chemical class 0.000 description 3
239000003963 antioxidant agent Substances 0.000 description 3
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229910001502 inorganic halide Inorganic materials 0.000 description 3
239000012774 insulation material Substances 0.000 description 3
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229910052943 magnesium sulfate Inorganic materials 0.000 description 3
235000019341 magnesium sulphate Nutrition 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 3
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230000037048 polymerization activity Effects 0.000 description 3
229920005629 polypropylene homopolymer Polymers 0.000 description 3
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229920006395 saturated elastomer Polymers 0.000 description 3
239000010703 silicon Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical class O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 3
239000011949 solid catalyst Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000010936 titanium Substances 0.000 description 3
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VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
229910052723 transition metal Inorganic materials 0.000 description 3
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
238000010792 warming Methods 0.000 description 3
229910052726 zirconium Inorganic materials 0.000 description 3
LCKLYZIOVDCDIS-UHFFFAOYSA-N (3,5-dimethylphenoxy)boronic acid Chemical compound CC1=CC(C)=CC(OB(O)O)=C1 LCKLYZIOVDCDIS-UHFFFAOYSA-N 0.000 description 2
DQVXWCCLFKMJTQ-UHFFFAOYSA-N (4-methylphenoxy)boronic acid Chemical compound CC1=CC=C(OB(O)O)C=C1 DQVXWCCLFKMJTQ-UHFFFAOYSA-N 0.000 description 2
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
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GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
CJAWGCMXXRQNNO-UHFFFAOYSA-N 2,7-dibromo-3,6-ditert-butyl-9h-fluorene Chemical compound BrC1=C(C(C)(C)C)C=C2C(C=C(C(=C3)Br)C(C)(C)C)=C3CC2=C1 CJAWGCMXXRQNNO-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
101100494773 Caenorhabditis elegans ctl-2 gene Proteins 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
101100112369 Fasciola hepatica Cat-1 gene Proteins 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
101100005271 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) cat-1 gene Proteins 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
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239000007983 Tris buffer Substances 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
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NDUUEFPGQBSFPV-UHFFFAOYSA-N tri(butan-2-yl)alumane Chemical compound CCC(C)[Al](C(C)CC)C(C)CC NDUUEFPGQBSFPV-UHFFFAOYSA-N 0.000 description 1
URNNTTSIHDDFIB-UHFFFAOYSA-N tri(cyclooctyl)alumane Chemical compound C1CCCCCCC1[Al](C1CCCCCCC1)C1CCCCCCC1 URNNTTSIHDDFIB-UHFFFAOYSA-N 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
ZIYNWDQDHKSRCE-UHFFFAOYSA-N tricyclohexylalumane Chemical compound C1CCCCC1[Al](C1CCCCC1)C1CCCCC1 ZIYNWDQDHKSRCE-UHFFFAOYSA-N 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
UYPYRKYUKCHHIB-UHFFFAOYSA-N trimethylamine N-oxide Chemical compound C[N+](C)(C)[O-] UYPYRKYUKCHHIB-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 description 1
LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
RTAKQLTYPVIOBZ-UHFFFAOYSA-N tritert-butylalumane Chemical compound CC(C)(C)[Al](C(C)(C)C)C(C)(C)C RTAKQLTYPVIOBZ-UHFFFAOYSA-N 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
239000010455 vermiculite Substances 0.000 description 1
229910052902 vermiculite Inorganic materials 0.000 description 1
235000019354 vermiculite Nutrition 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000003643 water by type Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1