JP5324442B2 - 溶融加工によるそれらの製造中ポリエチレン製品の改良加工条件 - Google Patents
溶融加工によるそれらの製造中ポリエチレン製品の改良加工条件 Download PDFInfo
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- JP5324442B2 JP5324442B2 JP2009521251A JP2009521251A JP5324442B2 JP 5324442 B2 JP5324442 B2 JP 5324442B2 JP 2009521251 A JP2009521251 A JP 2009521251A JP 2009521251 A JP2009521251 A JP 2009521251A JP 5324442 B2 JP5324442 B2 JP 5324442B2
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- polyethylene
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- stearate
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- -1 polyethylene Polymers 0.000 title claims description 56
- 239000004698 Polyethylene Substances 0.000 title claims description 47
- 229920000573 polyethylene Polymers 0.000 title claims description 47
- 238000004519 manufacturing process Methods 0.000 title description 5
- 238000010128 melt processing Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 57
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical group [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 23
- 238000001175 rotational moulding Methods 0.000 claims description 21
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 13
- 239000008116 calcium stearate Substances 0.000 claims description 11
- 235000013539 calcium stearate Nutrition 0.000 claims description 11
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 9
- 229920001179 medium density polyethylene Polymers 0.000 claims description 9
- 239000004701 medium-density polyethylene Substances 0.000 claims description 9
- BLDFSDCBQJUWFG-UHFFFAOYSA-N 2-(methylamino)-1,2-diphenylethanol Chemical compound C=1C=CC=CC=1C(NC)C(O)C1=CC=CC=C1 BLDFSDCBQJUWFG-UHFFFAOYSA-N 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 8
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 8
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 8
- 229960001545 hydrotalcite Drugs 0.000 claims description 8
- 230000000087 stabilizing effect Effects 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 230000006641 stabilisation Effects 0.000 claims description 5
- 238000011105 stabilization Methods 0.000 claims description 5
- 238000001746 injection moulding Methods 0.000 claims description 4
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 238000010101 extrusion blow moulding Methods 0.000 claims description 3
- 238000010102 injection blow moulding Methods 0.000 claims description 3
- 238000000071 blow moulding Methods 0.000 claims description 2
- 229940069428 antacid Drugs 0.000 claims 1
- 239000003159 antacid agent Substances 0.000 claims 1
- 229920000092 linear low density polyethylene Polymers 0.000 claims 1
- 239000004707 linear low-density polyethylene Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 22
- 239000000047 product Substances 0.000 description 18
- 239000004615 ingredient Substances 0.000 description 16
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- 239000003381 stabilizer Substances 0.000 description 12
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 11
- 229920003023 plastic Polymers 0.000 description 11
- 239000004033 plastic Substances 0.000 description 11
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 10
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- 239000011787 zinc oxide Chemical group 0.000 description 6
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- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 5
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 5
- NWYAYUUUUMPAEF-UHFFFAOYSA-N C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C Chemical compound C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C NWYAYUUUUMPAEF-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 0 CC(C)(C)c(cc(c(C)c1)Sc(c(*)c2)cc(C(C)(C)CI)c2O)c1O Chemical compound CC(C)(C)c(cc(c(C)c1)Sc(c(*)c2)cc(C(C)(C)CI)c2O)c1O 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 4
- ZSSVCEUEVMALRD-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol Chemical group OC1=CC(OCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 ZSSVCEUEVMALRD-UHFFFAOYSA-N 0.000 description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
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- 238000013329 compounding Methods 0.000 description 3
- 230000006698 induction Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 3
- 239000004299 sodium benzoate Substances 0.000 description 3
- 235000010234 sodium benzoate Nutrition 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical group OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- ISDGWTZFJKFKMO-UHFFFAOYSA-N 2-phenyl-1,3-dioxane-4,6-dione Chemical group O1C(=O)CC(=O)OC1C1=CC=CC=C1 ISDGWTZFJKFKMO-UHFFFAOYSA-N 0.000 description 2
- JMTMSDXUXJISAY-UHFFFAOYSA-N 2H-benzotriazol-4-ol Chemical group OC1=CC=CC2=C1N=NN2 JMTMSDXUXJISAY-UHFFFAOYSA-N 0.000 description 2
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical group OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- CMXLJKWFEJEFJE-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-[(4-methoxyphenyl)methylidene]propanedioate Chemical compound C1=CC(OC)=CC=C1C=C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)C(=O)OC1CC(C)(C)N(C)C(C)(C)C1 CMXLJKWFEJEFJE-UHFFFAOYSA-N 0.000 description 2
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 2
- 229960002401 calcium lactate Drugs 0.000 description 2
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- 235000011086 calcium lactate Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
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- ALSOCDGAZNNNME-UHFFFAOYSA-N ethene;hex-1-ene Chemical compound C=C.CCCCC=C ALSOCDGAZNNNME-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- NPZTUJOABDZTLV-UHFFFAOYSA-N hydroxybenzotriazole Substances O=C1C=CC=C2NNN=C12 NPZTUJOABDZTLV-UHFFFAOYSA-N 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
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- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
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- 150000003568 thioethers Chemical class 0.000 description 2
- HSCIDDFNIHSEDR-UHFFFAOYSA-N (2-hydroxyphenyl)-(2-methoxyphenyl)methanone Chemical compound COC1=CC=CC=C1C(=O)C1=CC=CC=C1O HSCIDDFNIHSEDR-UHFFFAOYSA-N 0.000 description 1
- RGASRBUYZODJTG-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C RGASRBUYZODJTG-UHFFFAOYSA-N 0.000 description 1
- QNEVKCBGTUWWOH-UHFFFAOYSA-N 1,2,3,4-tetrakis(2,4-ditert-butylphenyl)-5-phenylbenzene Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1C(C(=C1C=2C(=CC(=CC=2)C(C)(C)C)C(C)(C)C)C=2C(=CC(=CC=2)C(C)(C)C)C(C)(C)C)=CC(C=2C=CC=CC=2)=C1C1=CC=C(C(C)(C)C)C=C1C(C)(C)C QNEVKCBGTUWWOH-UHFFFAOYSA-N 0.000 description 1
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- RTNVDKBRTXEWQE-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-butan-2-yl-4-tert-butylphenol Chemical compound CCC(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O RTNVDKBRTXEWQE-UHFFFAOYSA-N 0.000 description 1
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- WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 description 1
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- HQQTZCPKNZVLFF-UHFFFAOYSA-N 4h-1,2-benzoxazin-3-one Chemical group C1=CC=C2ONC(=O)CC2=C1 HQQTZCPKNZVLFF-UHFFFAOYSA-N 0.000 description 1
- LQYZKSSUQDTYTR-UHFFFAOYSA-N 7-(4-methoxyphenyl)-1,5-dioxocane-2,4-dione Chemical compound C1=CC(OC)=CC=C1C1COC(=O)CC(=O)OC1 LQYZKSSUQDTYTR-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- MODAJCKVRUSEKK-UHFFFAOYSA-N C(C)OP(OCC)=O.[Ca] Chemical compound C(C)OP(OCC)=O.[Ca] MODAJCKVRUSEKK-UHFFFAOYSA-N 0.000 description 1
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- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical group COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 1
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- 239000012963 UV stabilizer Substances 0.000 description 1
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 1
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- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 1
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- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
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- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 1
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical group C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
- FDAKZQLBIFPGSV-UHFFFAOYSA-N n-butyl-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CCCCNC1CC(C)(C)NC(C)(C)C1 FDAKZQLBIFPGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- OHFCLJNYYRPINY-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butylphenyl)-2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(O)CC1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1 OHFCLJNYYRPINY-UHFFFAOYSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06291216.7 | 2006-07-25 | ||
| EP06291216 | 2006-07-25 | ||
| PCT/EP2007/057647 WO2008012319A1 (en) | 2006-07-25 | 2007-07-25 | Improved processing conditions of polyethylene articles in course of their manufacture by melt processing |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009544786A JP2009544786A (ja) | 2009-12-17 |
| JP2009544786A5 JP2009544786A5 (enExample) | 2013-01-24 |
| JP5324442B2 true JP5324442B2 (ja) | 2013-10-23 |
Family
ID=37198924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009521251A Expired - Fee Related JP5324442B2 (ja) | 2006-07-25 | 2007-07-25 | 溶融加工によるそれらの製造中ポリエチレン製品の改良加工条件 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20090186987A1 (enExample) |
| EP (1) | EP2046883B1 (enExample) |
| JP (1) | JP5324442B2 (enExample) |
| KR (1) | KR101356922B1 (enExample) |
| CN (1) | CN101495557B (enExample) |
| BR (1) | BRPI0714661A2 (enExample) |
| CA (1) | CA2655220C (enExample) |
| DE (1) | DE602007003737D1 (enExample) |
| ES (1) | ES2333558T3 (enExample) |
| TW (1) | TWI425041B (enExample) |
| WO (1) | WO2008012319A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010025342A2 (en) | 2008-08-28 | 2010-03-04 | Dow Global Technologies Inc. | Process and compositions for injections blow molding |
| JPWO2013161405A1 (ja) * | 2012-04-26 | 2015-12-24 | Jsr株式会社 | 電解質膜用組成物、固体高分子電解質膜、該電解質膜の製造方法、膜−電極接合体、固体高分子型燃料電池、水電解セルおよび水電解装置 |
| US20140127438A1 (en) * | 2012-11-08 | 2014-05-08 | Robert L. Sherman, Jr. | Stabilized high-density polyethylene composition with improved resistance to deterioration and stabilizer system |
| KR102389451B1 (ko) * | 2017-05-25 | 2022-04-22 | 셰브론 필립스 케미컬 컴퍼니 엘피 | 폴리에틸렌 수지에서 색 안정성을 개선하는 방법 |
| CN111073119A (zh) * | 2018-10-18 | 2020-04-28 | 中国石油化工股份有限公司 | 助剂组合物和线性中密度聚乙烯组合物及其制备方法以及聚乙烯滚塑制品 |
| KR102240969B1 (ko) * | 2018-12-27 | 2021-04-15 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL128918C (enExample) * | 1960-08-27 | |||
| US3755610A (en) | 1971-09-15 | 1973-08-28 | Hercules Inc | Electrically conductive cable |
| JPH0662817B2 (ja) * | 1988-05-06 | 1994-08-17 | ユニオン・カーバイド・コーポレーション | 優れた耐熱老化性を有するｖｌｄｐｅ基材組成物 |
| DE4405387A1 (de) * | 1994-02-19 | 1995-08-24 | Hoechst Ag | Verfahren zur Herstellung von Polyalkyl-1-oxa-diazaspirodecan-Verbindungen |
| JP2001505950A (ja) * | 1996-12-09 | 2001-05-08 | イーストマン ケミカル カンパニー | 安定化ポリオレフィン組成物及びその製造方法 |
| DE19820157B4 (de) * | 1997-05-13 | 2010-04-08 | Clariant Produkte (Deutschland) Gmbh | Neue Verbindungen auf Basis von Polyalkyl-1-oxa-diazaspirodecan-Verbindungen |
| DE19812224A1 (de) * | 1998-03-20 | 1999-09-23 | Clariant Gmbh | Oligomeres Stabilisatorgemisch |
| CN1115349C (zh) * | 1998-04-03 | 2003-07-23 | 中国石油化工集团公司 | 一种制备稳定聚烯烃的方法 |
| GB0004043D0 (en) * | 2000-02-21 | 2000-04-12 | Borealis Polymers Oy | Polymer |
| EP1236770B1 (en) * | 2001-03-01 | 2006-06-07 | Borealis Technology Oy | Polyethylene compositions for rotomolding |
| ES2281700T3 (es) * | 2001-05-02 | 2007-10-01 | Borealis Technology Oy | Utilizacion de compuestos de polisulfuro, para la estabilizacion de polimeros reticulados que contienen grupos silano. |
| CA2449242A1 (en) * | 2001-06-29 | 2003-01-09 | Ciba Specialty Chemicals Holding Inc. | Synergistic combinations of nano-scaled fillers and hindered amine light stabilizers |
| US6653494B2 (en) * | 2001-11-26 | 2003-11-25 | Strides Inc. | Processes for producing triaryl phosphite |
-
2007
- 2007-07-23 TW TW096126792A patent/TWI425041B/zh not_active IP Right Cessation
- 2007-07-25 US US12/374,769 patent/US20090186987A1/en not_active Abandoned
- 2007-07-25 CN CN2007800286562A patent/CN101495557B/zh not_active Expired - Fee Related
- 2007-07-25 JP JP2009521251A patent/JP5324442B2/ja not_active Expired - Fee Related
- 2007-07-25 KR KR1020097001535A patent/KR101356922B1/ko not_active Expired - Fee Related
- 2007-07-25 DE DE602007003737T patent/DE602007003737D1/de active Active
- 2007-07-25 WO PCT/EP2007/057647 patent/WO2008012319A1/en not_active Ceased
- 2007-07-25 BR BRPI0714661-2A patent/BRPI0714661A2/pt not_active Application Discontinuation
- 2007-07-25 EP EP07787877A patent/EP2046883B1/en not_active Not-in-force
- 2007-07-25 CA CA2655220A patent/CA2655220C/en not_active Expired - Fee Related
- 2007-07-25 ES ES07787877T patent/ES2333558T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2046883B1 (en) | 2009-12-09 |
| ES2333558T3 (es) | 2010-02-23 |
| CN101495557A (zh) | 2009-07-29 |
| WO2008012319A1 (en) | 2008-01-31 |
| CN101495557B (zh) | 2012-01-11 |
| KR101356922B1 (ko) | 2014-01-28 |
| TW200815517A (en) | 2008-04-01 |
| HK1136000A1 (en) | 2010-06-18 |
| JP2009544786A (ja) | 2009-12-17 |
| TWI425041B (zh) | 2014-02-01 |
| BRPI0714661A2 (pt) | 2014-09-16 |
| KR20090046796A (ko) | 2009-05-11 |
| CA2655220A1 (en) | 2008-01-31 |
| US20090186987A1 (en) | 2009-07-23 |
| EP2046883A1 (en) | 2009-04-15 |
| CA2655220C (en) | 2014-06-10 |
| DE602007003737D1 (de) | 2010-01-21 |
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