JP5287410B2 - 床用化粧材 - Google Patents
床用化粧材 Download PDFInfo
- Publication number
- JP5287410B2 JP5287410B2 JP2009075348A JP2009075348A JP5287410B2 JP 5287410 B2 JP5287410 B2 JP 5287410B2 JP 2009075348 A JP2009075348 A JP 2009075348A JP 2009075348 A JP2009075348 A JP 2009075348A JP 5287410 B2 JP5287410 B2 JP 5287410B2
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- JP
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- Prior art keywords
- layer
- resin
- vinyl acetate
- acetate copolymer
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000463 material Substances 0.000 title claims description 20
- 239000010410 layer Substances 0.000 claims description 103
- 229920005989 resin Polymers 0.000 claims description 89
- 239000011347 resin Substances 0.000 claims description 89
- 229920000554 ionomer Polymers 0.000 claims description 31
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 30
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- 239000012790 adhesive layer Substances 0.000 claims description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- 238000009408 flooring Methods 0.000 claims description 5
- 238000009864 tensile test Methods 0.000 claims description 4
- 238000012360 testing method Methods 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 3
- 229920006026 co-polymeric resin Polymers 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 238000010030 laminating Methods 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000004049 embossing Methods 0.000 description 7
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000011256 inorganic filler Substances 0.000 description 6
- 229910003475 inorganic filler Inorganic materials 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 238000009823 thermal lamination Methods 0.000 description 5
- 238000003475 lamination Methods 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- -1 for example Substances 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229920005672 polyolefin resin Polymers 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920008790 Amorphous Polyethylene terephthalate Polymers 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 229920008651 Crystalline Polyethylene terephthalate Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Floor Finish (AREA)
- Laminated Bodies (AREA)
Description
従来のポリ塩化ビニル樹脂製の化粧シートの場合と同様に、熱ラミネーション法によって製造することができる。まず、着色エチレン−酢酸ビニル共重合体樹脂層3、絵柄模様層4、接着剤層5、透明アイオノマー樹脂層6を積層して中間樹脂層とし、この下面に下層1、上側に上層2を配し、これら3層を熱ラミネート法により同時に貼り合わせて一体化する。
絵柄模様層4として、前記コロナ処理面に、2液ウレタン系印刷インキ(東洋インキ製造(株)製、ラミスター系インキ)を使用してグラビア印刷法により石目柄を印刷した。
接着剤層5として、前記絵柄模様層4を印刷した面に2液ポリエステル系接着剤(東洋インキ製造(株)製)を塗布量約5g/m2に塗布した。
表1に、着色エチレン−酢酸ビニル共重合体樹脂層の厚さと酢酸含有率をかえたときのそれぞれのJIS K7113に規定されている引張試験方法により測定された床用化粧材の25%モジュラスのデータを記す。測定条件は引張速度が50mm/min、試験片は幅25mmのダンベル型、単位はNである。
2…上層
3…着色エチレン−酢酸ビニル共重合体樹脂層
4…絵柄模様層
5…接着剤層
6…透明アイオノマー層
Claims (2)
- エチレン−酢酸ビニル共重合体樹脂を主体とする下層とアイオノマー樹脂からなる上層の間に中間樹脂層を有する床用化粧材において、前記中間樹脂層は、下層側から着色エチレン−酢酸ビニル共重合体樹脂層、絵柄模様層、接着剤層、透明アイオノマー樹脂層をこの順に有してなり、前記着色エチレン−酢酸ビニル共重合体樹脂の酢酸ビニル含有量が5%〜10%であり、前記着色エチレン−酢酸ビニル共重合体樹脂層の層厚が100〜150μmであることを特徴とする床用化粧材。
- 前記着色エチレン−酢酸ビニル共重合体樹脂層が、JIS K7113に規定されている引張試験方法により測定した床用化粧材の25%モジュラスで、測定条件は引張速度が50mm/min、試験片は幅25mmのダンベル型で、7.4N以上であることを特徴とする請求項1記載の床用化粧材。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009075348A JP5287410B2 (ja) | 2009-03-26 | 2009-03-26 | 床用化粧材 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009075348A JP5287410B2 (ja) | 2009-03-26 | 2009-03-26 | 床用化粧材 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010228123A JP2010228123A (ja) | 2010-10-14 |
JP5287410B2 true JP5287410B2 (ja) | 2013-09-11 |
Family
ID=43044472
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009075348A Active JP5287410B2 (ja) | 2009-03-26 | 2009-03-26 | 床用化粧材 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5287410B2 (ja) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995008593A1 (en) * | 1993-09-20 | 1995-03-30 | The Amtico Company Limited | Floor coverings |
JP3259897B2 (ja) * | 1995-12-01 | 2002-02-25 | 凸版印刷株式会社 | 化粧材 |
JP3843547B2 (ja) * | 1997-07-31 | 2006-11-08 | タキロン株式会社 | 長尺床材 |
JP2000158604A (ja) * | 1998-12-01 | 2000-06-13 | Mitsubishi Chem Mkv Co | 積層体 |
JP4592986B2 (ja) * | 2001-03-21 | 2010-12-08 | タキロン株式会社 | 長尺床材 |
JP4269697B2 (ja) * | 2003-01-22 | 2009-05-27 | 凸版印刷株式会社 | 化粧材およびその製造方法 |
JP4992564B2 (ja) * | 2007-06-18 | 2012-08-08 | 株式会社トッパン・コスモ | 化粧シート |
-
2009
- 2009-03-26 JP JP2009075348A patent/JP5287410B2/ja active Active
Also Published As
Publication number | Publication date |
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JP2010228123A (ja) | 2010-10-14 |
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