JP5241502B2 - 膨張したシリコーン組成物、並びにその調製方法及びそれを含む製品 - Google Patents
膨張したシリコーン組成物、並びにその調製方法及びそれを含む製品 Download PDFInfo
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- JP5241502B2 JP5241502B2 JP2008540122A JP2008540122A JP5241502B2 JP 5241502 B2 JP5241502 B2 JP 5241502B2 JP 2008540122 A JP2008540122 A JP 2008540122A JP 2008540122 A JP2008540122 A JP 2008540122A JP 5241502 B2 JP5241502 B2 JP 5241502B2
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- monomer
- silicone
- carbon atoms
- sio
- silicone composition
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- 229920001296 polysiloxane Polymers 0.000 title claims description 264
- 239000000203 mixture Substances 0.000 title claims description 207
- 238000000034 method Methods 0.000 title claims description 45
- 238000002360 preparation method Methods 0.000 title claims description 25
- 230000008569 process Effects 0.000 title description 4
- 239000000178 monomer Substances 0.000 claims description 165
- 125000004432 carbon atom Chemical group C* 0.000 claims description 138
- 239000007795 chemical reaction product Substances 0.000 claims description 115
- 239000007788 liquid Substances 0.000 claims description 94
- 239000000499 gel Substances 0.000 claims description 83
- -1 polysiloxanes Polymers 0.000 claims description 66
- 150000002430 hydrocarbons Chemical group 0.000 claims description 64
- 239000007787 solid Substances 0.000 claims description 63
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 60
- 229920000642 polymer Polymers 0.000 claims description 56
- 150000001875 compounds Chemical class 0.000 claims description 54
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 47
- 229920000570 polyether Polymers 0.000 claims description 47
- 238000006243 chemical reaction Methods 0.000 claims description 42
- 238000006116 polymerization reaction Methods 0.000 claims description 38
- 238000004132 cross linking Methods 0.000 claims description 33
- 125000003342 alkenyl group Chemical group 0.000 claims description 31
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 27
- HLPWCQDWRYCGLK-UHFFFAOYSA-N ethyl-methyl-bis(trimethylsilyloxy)silane Chemical compound C[Si](C)(C)O[Si](C)(CC)O[Si](C)(C)C HLPWCQDWRYCGLK-UHFFFAOYSA-N 0.000 claims description 26
- 150000004985 diamines Chemical class 0.000 claims description 25
- 229920005989 resin Polymers 0.000 claims description 25
- 239000011347 resin Substances 0.000 claims description 25
- 239000000047 product Substances 0.000 claims description 23
- 239000012530 fluid Substances 0.000 claims description 22
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 10
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 10
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 10
- 230000001588 bifunctional effect Effects 0.000 claims description 10
- 229920001021 polysulfide Polymers 0.000 claims description 10
- 230000001166 anti-perspirative effect Effects 0.000 claims description 9
- 239000003213 antiperspirant Substances 0.000 claims description 9
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 claims description 9
- 125000003545 alkoxy group Chemical group 0.000 claims description 8
- 125000001033 ether group Chemical group 0.000 claims description 8
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 claims description 7
- 125000004429 atom Chemical group 0.000 claims description 7
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920005862 polyol Polymers 0.000 claims description 7
- 150000003077 polyols Chemical class 0.000 claims description 7
- 239000004909 Moisturizer Substances 0.000 claims description 6
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000002781 deodorant agent Substances 0.000 claims description 6
- 230000001333 moisturizer Effects 0.000 claims description 6
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 claims description 5
- 229930182556 Polyacetal Natural products 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 5
- 229920002732 Polyanhydride Polymers 0.000 claims description 5
- 239000004642 Polyimide Substances 0.000 claims description 5
- 229920002396 Polyurea Polymers 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 150000001347 alkyl bromides Chemical class 0.000 claims description 5
- 150000001413 amino acids Chemical class 0.000 claims description 5
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- 239000004202 carbamide Substances 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 239000002537 cosmetic Substances 0.000 claims description 5
- 150000002009 diols Chemical class 0.000 claims description 5
- 150000004676 glycans Chemical class 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 5
- 150000002772 monosaccharides Chemical class 0.000 claims description 5
- OLAPPGSPBNVTRF-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1C(O)=O OLAPPGSPBNVTRF-UHFFFAOYSA-N 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004417 polycarbonate Substances 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 229920001721 polyimide Polymers 0.000 claims description 5
- 229920006324 polyoxymethylene Polymers 0.000 claims description 5
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 239000005017 polysaccharide Substances 0.000 claims description 5
- 239000005077 polysulfide Substances 0.000 claims description 5
- 150000008117 polysulfides Polymers 0.000 claims description 5
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 claims description 5
- 102000004169 proteins and genes Human genes 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- SPDPBNKCNIQAOH-UHFFFAOYSA-N bis[[ethyl(dimethyl)silyl]oxy]-dimethylsilane Chemical compound CC[Si](C)(C)O[Si](C)(C)O[Si](C)(C)CC SPDPBNKCNIQAOH-UHFFFAOYSA-N 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 claims description 4
- 239000006210 lotion Substances 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- 239000013503 personal care ingredient Substances 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- HFRICAKEFCIBMJ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-ethyl-dimethylsilane Chemical compound CC[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C HFRICAKEFCIBMJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 239000003242 anti bacterial agent Substances 0.000 claims description 3
- 239000003429 antifungal agent Substances 0.000 claims description 3
- 229940121375 antifungal agent Drugs 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 239000003599 detergent Substances 0.000 claims description 3
- NKNJFTJIZOSWNM-UHFFFAOYSA-N diethyl-bis(trimethylsilyloxy)silane Chemical compound C[Si](C)(C)O[Si](CC)(CC)O[Si](C)(C)C NKNJFTJIZOSWNM-UHFFFAOYSA-N 0.000 claims description 3
- 125000005442 diisocyanate group Chemical group 0.000 claims description 3
- 238000012377 drug delivery Methods 0.000 claims description 3
- 239000003792 electrolyte Substances 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 230000001815 facial effect Effects 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
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- 239000005556 hormone Substances 0.000 claims description 3
- 229940088597 hormone Drugs 0.000 claims description 3
- 239000002917 insecticide Substances 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000419 plant extract Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 239000011782 vitamin Substances 0.000 claims description 3
- 229940088594 vitamin Drugs 0.000 claims description 3
- 229930003231 vitamin Natural products 0.000 claims description 3
- 235000013343 vitamin Nutrition 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims 4
- 229920006136 organohydrogenpolysiloxane Polymers 0.000 claims 4
- 150000001298 alcohols Chemical class 0.000 claims 2
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- 239000011252 protective cream Substances 0.000 claims 2
- 230000000699 topical effect Effects 0.000 claims 2
- FMUSYAWFJOLIMV-UHFFFAOYSA-N ethyl-bis[[ethyl(dimethyl)silyl]oxy]-methylsilane Chemical compound CC[Si](C)(C)O[Si](C)(CC)O[Si](C)(C)CC FMUSYAWFJOLIMV-UHFFFAOYSA-N 0.000 claims 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 46
- 239000003054 catalyst Substances 0.000 description 29
- 229910052697 platinum Inorganic materials 0.000 description 23
- 239000000725 suspension Substances 0.000 description 20
- 239000004711 α-olefin Substances 0.000 description 20
- 239000000463 material Substances 0.000 description 19
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 18
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- 239000004205 dimethyl polysiloxane Substances 0.000 description 15
- XAYDWGMOPRHLEP-UHFFFAOYSA-N 6-ethenyl-7-oxabicyclo[4.1.0]heptane Chemical compound C1CCCC2OC21C=C XAYDWGMOPRHLEP-UHFFFAOYSA-N 0.000 description 13
- 125000000962 organic group Chemical group 0.000 description 13
- 239000000843 powder Substances 0.000 description 13
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 12
- 150000004678 hydrides Chemical class 0.000 description 12
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
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- QYWFUCXJWVFMFO-UHFFFAOYSA-N butyl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C QYWFUCXJWVFMFO-UHFFFAOYSA-N 0.000 description 2
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- FYBYQXQHBHTWLP-UHFFFAOYSA-N bis(silyloxysilyloxy)silane Chemical compound [SiH3]O[SiH2]O[SiH2]O[SiH2]O[SiH3] FYBYQXQHBHTWLP-UHFFFAOYSA-N 0.000 description 1
- IHIHWDWZXUUGCK-UHFFFAOYSA-N bis[[dimethyl(propyl)silyl]oxy]-dimethylsilane Chemical compound CCC[Si](C)(C)O[Si](C)(C)O[Si](C)(C)CCC IHIHWDWZXUUGCK-UHFFFAOYSA-N 0.000 description 1
- IMLREYFJPXWLCY-UHFFFAOYSA-N bis[[tert-butyl(dimethyl)silyl]oxy]-dimethylsilane Chemical compound CC(C)(C)[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C(C)(C)C IMLREYFJPXWLCY-UHFFFAOYSA-N 0.000 description 1
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- BSAFXXVXXFRPRG-UHFFFAOYSA-N butan-2-yl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCC(C)[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C BSAFXXVXXFRPRG-UHFFFAOYSA-N 0.000 description 1
- VWKJPEJDHKSUJL-UHFFFAOYSA-N butyl-[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilane Chemical compound CCCC[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C VWKJPEJDHKSUJL-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PSCLWXNXYREBTJ-UHFFFAOYSA-N di(propan-2-yl)-bis(trimethylsilyloxy)silane Chemical compound C[Si](C)(C)O[Si](C(C)C)(O[Si](C)(C)C)C(C)C PSCLWXNXYREBTJ-UHFFFAOYSA-N 0.000 description 1
- HDPOGAHRVOLDPV-UHFFFAOYSA-N dibutyl-bis(trimethylsilyloxy)silane Chemical compound CCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)CCCC HDPOGAHRVOLDPV-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- JNSGIVNNHKGGRU-JYRVWZFOSA-N diethoxyphosphinothioyl (2z)-2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoacetate Chemical compound CCOP(=S)(OCC)OC(=O)C(=N/OC)\C1=CSC(N)=N1 JNSGIVNNHKGGRU-JYRVWZFOSA-N 0.000 description 1
- LZKUTZXMOXXZFT-UHFFFAOYSA-N dimethyl-bis(triethylsilyloxy)silane Chemical compound CC[Si](CC)(CC)O[Si](C)(C)O[Si](CC)(CC)CC LZKUTZXMOXXZFT-UHFFFAOYSA-N 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- POJVZMLYQHGZBY-UHFFFAOYSA-N dipropyl-bis(trimethylsilyloxy)silane Chemical compound CCC[Si](CCC)(O[Si](C)(C)C)O[Si](C)(C)C POJVZMLYQHGZBY-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- UWQPBOYPTIIARE-UHFFFAOYSA-N ethyl(silyloxysilyloxy)silane Chemical class CC[SiH2]O[SiH2]O[SiH3] UWQPBOYPTIIARE-UHFFFAOYSA-N 0.000 description 1
- 230000003090 exacerbative effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZKXLCEBTPLJGGJ-UHFFFAOYSA-N hexan-2-yl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCCCC(C)[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C ZKXLCEBTPLJGGJ-UHFFFAOYSA-N 0.000 description 1
- QBPSJZHQKWHDQQ-UHFFFAOYSA-N hexan-3-yl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCCC(CC)[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C QBPSJZHQKWHDQQ-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PNJMJEXVQAFSBS-UHFFFAOYSA-N hexyl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C PNJMJEXVQAFSBS-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035910 sensory benefits Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229960004029 silicic acid Drugs 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- QNHGVVMOYPEFLU-UHFFFAOYSA-N tert-butyl-methyl-bis(trimethylsilyloxy)silane Chemical compound C[Si](C)(C)O[Si](C)(C(C)(C)C)O[Si](C)(C)C QNHGVVMOYPEFLU-UHFFFAOYSA-N 0.000 description 1
- RSNQKPMXXVDJFG-UHFFFAOYSA-N tetrasiloxane Chemical compound [SiH3]O[SiH2]O[SiH2]O[SiH3] RSNQKPMXXVDJFG-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- SRPFBWXLOGEXJT-UHFFFAOYSA-N trimethyl-(methyl-pentyl-trimethylsilyloxysilyl)oxysilane Chemical compound CCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C SRPFBWXLOGEXJT-UHFFFAOYSA-N 0.000 description 1
- PGRZLADNCDNGTC-UHFFFAOYSA-N trimethyl-(methyl-propyl-trimethylsilyloxysilyl)oxysilane Chemical compound CCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C PGRZLADNCDNGTC-UHFFFAOYSA-N 0.000 description 1
- IIPLONCQUDDCAY-UHFFFAOYSA-N trimethyl-[methyl-(2-methylbutan-2-yl)-trimethylsilyloxysilyl]oxysilane Chemical compound CCC(C)(C)[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C IIPLONCQUDDCAY-UHFFFAOYSA-N 0.000 description 1
- YTEFCOWNTDERNN-UHFFFAOYSA-N trimethyl-[methyl-(2-methylpropyl)-trimethylsilyloxysilyl]oxysilane Chemical compound CC(C)C[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C YTEFCOWNTDERNN-UHFFFAOYSA-N 0.000 description 1
- GQRUIQOFMCJKJP-UHFFFAOYSA-N trimethyl-[methyl-(3-methylbutyl)-trimethylsilyloxysilyl]oxysilane Chemical compound CC(C)CC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C GQRUIQOFMCJKJP-UHFFFAOYSA-N 0.000 description 1
- FMIMVQOAKBPLEJ-UHFFFAOYSA-N trimethyl-[methyl-(4-methylpentyl)-trimethylsilyloxysilyl]oxysilane Chemical compound CC(C)CCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C FMIMVQOAKBPLEJ-UHFFFAOYSA-N 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
- C08L83/12—Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Medicinal Chemistry (AREA)
- Birds (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epidemiology (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Silicon Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/274,450 | 2005-11-15 | ||
| US11/274,450 US8017687B2 (en) | 2005-11-15 | 2005-11-15 | Swollen silicone composition and process of producing same |
| US11/474,571 | 2006-06-26 | ||
| US11/474,571 US7863361B2 (en) | 2005-11-15 | 2006-06-26 | Swollen silicone composition, process of producing same and products thereof |
| PCT/US2006/043314 WO2007061623A1 (en) | 2005-11-15 | 2006-11-06 | Swollen silicone composition, process of producing same and products thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009516024A JP2009516024A (ja) | 2009-04-16 |
| JP2009516024A5 JP2009516024A5 (enExample) | 2009-12-24 |
| JP5241502B2 true JP5241502B2 (ja) | 2013-07-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008540122A Expired - Fee Related JP5241502B2 (ja) | 2005-11-15 | 2006-11-06 | 膨張したシリコーン組成物、並びにその調製方法及びそれを含む製品 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7863361B2 (enExample) |
| EP (1) | EP1962791A1 (enExample) |
| JP (1) | JP5241502B2 (enExample) |
| KR (1) | KR101441552B1 (enExample) |
| CN (1) | CN102138868B (enExample) |
| AU (1) | AU2006316830B2 (enExample) |
| BR (1) | BRPI0618584B1 (enExample) |
| CA (1) | CA2629520A1 (enExample) |
| RU (1) | RU2008123843A (enExample) |
| WO (1) | WO2007061623A1 (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8017687B2 (en) * | 2005-11-15 | 2011-09-13 | Momentive Performance Materials Inc. | Swollen silicone composition and process of producing same |
| US20090053312A1 (en) * | 2007-08-20 | 2009-02-26 | High Desert Pharmaceuticals, Inc. | Methodology and Composition for a Skin Lubricant |
| US20100003201A1 (en) * | 2008-07-07 | 2010-01-07 | Momentive Performance Materials, Inc. | Silicone composition |
| JP2010037457A (ja) * | 2008-08-06 | 2010-02-18 | Nitto Denko Corp | 無機微粒子を含有するシリコーン樹脂組成物 |
| US20100135949A1 (en) * | 2008-12-01 | 2010-06-03 | Becton, Dickinson And Company | Antimicrobial compositions |
| US8821455B2 (en) | 2009-07-09 | 2014-09-02 | Becton, Dickinson And Company | Antimicrobial coating for dermally invasive devices |
| KR20130038847A (ko) | 2010-03-23 | 2013-04-18 | 가부시키가이샤 아사히 러버 | 실리콘 수지제 반사 기재, 그 제조 방법, 및 그 반사 기재에 이용하는 원재료 조성물 |
| EP2716687A4 (en) | 2011-05-30 | 2015-02-25 | Dow Corning Toray Co Ltd | ORGANOPOLYSILOXANE ELASTOMER MODIFIED BY A MONO- / DIGLYCEROL DERIVATIVE AND USE THEREOF |
| CN103156796A (zh) * | 2011-12-14 | 2013-06-19 | 吴江市冰心文教用品有限公司 | 一种染发颜料及其生产方法 |
| US9352119B2 (en) | 2012-05-15 | 2016-05-31 | Becton, Dickinson And Company | Blood control IV catheter with antimicrobial properties |
| US9579486B2 (en) | 2012-08-22 | 2017-02-28 | Becton, Dickinson And Company | Blood control IV catheter with antimicrobial properties |
| JP2016502979A (ja) | 2012-12-07 | 2016-02-01 | ダウ グローバル テクノロジーズ エルエルシー | パーソナルケア用途におけるシリコーン変性ポリオレフィン |
| BR112015012520B8 (pt) | 2012-12-19 | 2020-03-24 | Dow Global Technologies Llc | formulação para cuidado pessoal, e, métodos para tratamento do corpo e para melhorar a sensação de formulações para cuidado pessoal |
| US9750928B2 (en) | 2013-02-13 | 2017-09-05 | Becton, Dickinson And Company | Blood control IV catheter with stationary septum activator |
| US9695323B2 (en) | 2013-02-13 | 2017-07-04 | Becton, Dickinson And Company | UV curable solventless antimicrobial compositions |
| US9750927B2 (en) | 2013-03-11 | 2017-09-05 | Becton, Dickinson And Company | Blood control catheter with antimicrobial needle lube |
| US9327095B2 (en) | 2013-03-11 | 2016-05-03 | Becton, Dickinson And Company | Blood control catheter with antimicrobial needle lube |
| US9789279B2 (en) | 2014-04-23 | 2017-10-17 | Becton, Dickinson And Company | Antimicrobial obturator for use with vascular access devices |
| US10376686B2 (en) | 2014-04-23 | 2019-08-13 | Becton, Dickinson And Company | Antimicrobial caps for medical connectors |
| US9675793B2 (en) | 2014-04-23 | 2017-06-13 | Becton, Dickinson And Company | Catheter tubing with extraluminal antimicrobial coating |
| US10232088B2 (en) | 2014-07-08 | 2019-03-19 | Becton, Dickinson And Company | Antimicrobial coating forming kink resistant feature on a vascular access device |
| US9839602B2 (en) * | 2014-12-16 | 2017-12-12 | Momentive Performance Materials Inc. | Personal care compositions containing crosslinked silicone polymer networks and their method of preparation |
| US10493244B2 (en) | 2015-10-28 | 2019-12-03 | Becton, Dickinson And Company | Extension tubing strain relief |
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-
2006
- 2006-06-26 US US11/474,571 patent/US7863361B2/en not_active Expired - Lifetime
- 2006-11-06 KR KR1020087011486A patent/KR101441552B1/ko not_active Expired - Fee Related
- 2006-11-06 JP JP2008540122A patent/JP5241502B2/ja not_active Expired - Fee Related
- 2006-11-06 CA CA002629520A patent/CA2629520A1/en not_active Abandoned
- 2006-11-06 RU RU2008123843/04A patent/RU2008123843A/ru not_active Application Discontinuation
- 2006-11-06 WO PCT/US2006/043314 patent/WO2007061623A1/en not_active Ceased
- 2006-11-06 CN CN201110076146.0A patent/CN102138868B/zh active Active
- 2006-11-06 BR BRPI0618584A patent/BRPI0618584B1/pt not_active IP Right Cessation
- 2006-11-06 EP EP06847467A patent/EP1962791A1/en not_active Withdrawn
- 2006-11-06 AU AU2006316830A patent/AU2006316830B2/en not_active Expired - Fee Related
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2010
- 2010-12-17 US US12/971,857 patent/US20110085988A1/en not_active Abandoned
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|---|---|
| US20070112146A1 (en) | 2007-05-17 |
| BRPI0618584B1 (pt) | 2016-03-01 |
| CN102138868A (zh) | 2011-08-03 |
| US20110085988A1 (en) | 2011-04-14 |
| AU2006316830A1 (en) | 2007-05-31 |
| AU2006316830B2 (en) | 2011-08-25 |
| KR20080075112A (ko) | 2008-08-14 |
| WO2007061623A1 (en) | 2007-05-31 |
| US7863361B2 (en) | 2011-01-04 |
| CN102138868B (zh) | 2017-05-24 |
| EP1962791A1 (en) | 2008-09-03 |
| KR101441552B1 (ko) | 2014-09-17 |
| BRPI0618584A2 (pt) | 2011-09-06 |
| RU2008123843A (ru) | 2009-12-27 |
| CA2629520A1 (en) | 2007-05-31 |
| JP2009516024A (ja) | 2009-04-16 |
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