JP5222303B2 - 触媒マイクロチャネル改質装置 - Google Patents
触媒マイクロチャネル改質装置 Download PDFInfo
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- JP5222303B2 JP5222303B2 JP2009542928A JP2009542928A JP5222303B2 JP 5222303 B2 JP5222303 B2 JP 5222303B2 JP 2009542928 A JP2009542928 A JP 2009542928A JP 2009542928 A JP2009542928 A JP 2009542928A JP 5222303 B2 JP5222303 B2 JP 5222303B2
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- hydrogen gas
- reaction zone
- reaction
- hydrogen
- gas
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- 230000003197 catalytic effect Effects 0.000 title description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 137
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 97
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 52
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 52
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 48
- 239000001257 hydrogen Substances 0.000 claims abstract description 46
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 45
- 239000000919 ceramic Substances 0.000 claims abstract description 41
- 239000000446 fuel Substances 0.000 claims abstract description 39
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 38
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- 238000002407 reforming Methods 0.000 claims abstract description 12
- 239000003345 natural gas Substances 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 36
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 29
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000000843 powder Substances 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 12
- 238000009792 diffusion process Methods 0.000 claims description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
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- 238000002485 combustion reaction Methods 0.000 claims description 7
- 239000003814 drug Substances 0.000 claims description 7
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- 239000001569 carbon dioxide Substances 0.000 claims description 5
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- -1 hydrogen ions Chemical class 0.000 claims description 5
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- 239000002283 diesel fuel Substances 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 238000001991 steam methane reforming Methods 0.000 description 28
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
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- 150000002500 ions Chemical class 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
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- 229920002799 BoPET Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
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- 230000015556 catabolic process Effects 0.000 description 1
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- 239000000571 coke Substances 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
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- 238000009833 condensation Methods 0.000 description 1
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- 230000003247 decreasing effect Effects 0.000 description 1
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- 230000001052 transient effect Effects 0.000 description 1
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- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/145—At least two purification steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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Description
供給されてもよい。
Claims (22)
- 炭化水素の改質によって得られる水素の収率および純度を向上させるための方法であって、当該方法は、原料炭化水素燃料と水蒸気とを反応ゾーンに受容する工程と、反応ゾーンにおいて原料炭化水素燃料と水蒸気とを反応させて水素ガスを製造する工程と、反応を行いながら膜を介して反応ゾーンから水素ガスを選択的に取り除く工程とから成り、水素ガスを選択的に取り除く工程が、多孔質セラミック膜を介して水素を拡散させる工程から成り、多孔質セラミック膜が、アルミナ粉末と、当該アルミナ粉末と反応するフォスフェイト含有薬剤とから製造されることを特徴とする炭化水素の改質によって得られる水素の収率および純度を向上させるための方法。
- 原料炭化水素燃料と水蒸気が、反応ゾーンにおいて更に一酸化炭素を含む請求項1に記載の方法。
- 反応ゾーンにおいて、更に、一酸化炭素と水蒸気とが反応して水素ガスと二酸化炭素とを製造する工程を含む請求項2に記載の方法。
- 反応ゾーンから水素ガスを選択的に取り除く工程において、水素ガス以外のガスの多孔質セラミック膜を介する拡散速度が、水素ガスの拡散速度よりも低い請求項1に記載の方法。
- 水素ガス以外のガスが、一酸化炭素、二酸化炭素、水蒸気およびガス状炭化水素の何れか1つ以上である請求項4に記載の方法。
- 更に、反応ゾーンに熱を供給して原料炭化水素燃料および水蒸気との反応を促進する工程を有する請求項1に記載の方法。
- 更に、反応ゾーンから受容される残余の原料炭化水素燃料、水素ガス、一酸化炭素の少なくとも1つを燃焼させることによって熱を供給する工程を含む請求項6に記載の方法。
- 原料炭化水素燃料が、メタン、気化メタノール、天然ガス、気化ディーゼル燃料およびこれらの組合せ並びにこれらの副構成成分から成る群から選択される請求項1に記載の方法。
- 更に、反応中に、原料炭化水素燃料、水蒸気、水素ガス及び触媒を密接に接触させる工程を含む請求項1に記載の方法。
- 炭化水素の改質によって得られる水素の収率および純度を向上させるための装置であって、原料炭化水素燃料と水蒸気とを供給するための注入口と、当該注入口に連結し、原料炭化水素燃料と水蒸気とを反応させて水素ガスを製造するための反応ゾーンと、当該反応ゾーンと連結し、反応中に反応ゾーンから選択的に水素ガスを取り除き、原料炭化水素燃料と水蒸気との反応の程度を増加させるための多孔質セラミック膜とから成り、多孔質セラミック膜が、アルミナ粉末と、当該アルミナ粉末と反応するフォスフェイト含有薬剤とから製造されることを特徴とする炭化水素の改質によって得られる水素の収率および純度を向上させるための装置。
- 反応ゾーンが、更に、一酸化炭素と水蒸気とが反応して水素ガスと二酸化炭素とを製造できるように構成されている請求項10に記載の装置。
- 多孔質セラミック膜が、更に、水素ガスよりも低い拡散速度で反応ゾーンから他のガスを取り除くことが出来るように構成されている請求項10に記載の装置。
- 他のガスが、一酸化炭素、二酸化炭素、水蒸気およびガス状炭化水素の少なくとも1種から成る請求項12に記載の装置。
- 更に、残余の原料炭化水素燃料、水素ガス、一酸化炭素の少なくとも1つを燃焼させ、反応ゾーンに熱を供給するための燃焼ゾーンを有する請求項10に記載の装置。
- 原料炭化水素燃料が、メタン、気化メタノール、天然ガス、気化ディーゼル燃料およびこれらの組合せ並びにこれらの副構成成分から成る群から選択される請求項10に記載の方法。
- 更に、反応ゾーンに近接して、触媒が浸透されている多孔質セラミック層を有する請求項10に記載の方法。
- 原料炭化水素燃料を改質して水素ガスを製造するセラミックマイクロチャネル装置から成る装置であって、当該セラミックマイクロチャネル装置の少なくとも1つが、アルミナ粉末と、当該アルミナ粉末と反応するフォスフェイト含有薬剤とから製造されたセラミックにより形成されていることを特徴とする装置。
- セラミックマイクロチャネル装置が、炭化水素と水蒸気とを反応させて水素ガスを製造するための反応ゾーンから成る請求項17に記載の装置。
- セラミックマイクロチャネル装置が、更に、反応ゾーンに連結する多孔質セラミック膜を有し、反応の際に反応ゾーンから水素ガスを取り除く請求項17に記載の装置。
- 炭化水素の改質によって得られる水素の収率および純度を向上させるための方法であって、当該方法は、原料炭化水素燃料と水蒸気とを反応ゾーンに受容する工程と、反応ゾーンにおいて原料炭化水素燃料と水蒸気とを反応させて水素ガスを製造する工程と、反応を行いながらセラミック膜を介し、水素ガス又は水素イオンの何れかを抽出することによって反応ゾーンから水素ガスを選択的に取り除く工程とから成り、多孔質セラミック膜が、アルミナ粉末と、当該アルミナ粉末と反応するフォスフェイト含有薬剤とから製造されることを特徴とする炭化水素の改質によって得られる水素の収率および純度を向上させるための方法。
- 水素ガスを選択的に取り除く工程が、セラミック膜を介して水素ガスを拡散する工程から成る請求項20に記載の方法。
- 水素ガスを選択的に取り除く工程が、セラミック膜を介して水素イオンを拡散する工程から成る請求項20に記載の方法。
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US87139806P | 2006-12-21 | 2006-12-21 | |
US60/871,398 | 2006-12-21 | ||
PCT/US2007/026101 WO2008079309A1 (en) | 2006-12-21 | 2007-12-19 | Catalytic microchannel reformer |
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JP5222303B2 true JP5222303B2 (ja) | 2013-06-26 |
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US (2) | US8961625B2 (ja) |
EP (1) | EP2099709A4 (ja) |
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WO (1) | WO2008079309A1 (ja) |
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US8308828B1 (en) * | 2008-07-30 | 2012-11-13 | Bossard Peter R | Multiple tube micro-channel steam reformer and method |
US8105402B1 (en) * | 2008-07-30 | 2012-01-31 | Bossard Peter R | Micro-channel steam reformer and system for extracting ultra-pure hydrogen gas from a hydrocarbon fuel |
KR101283326B1 (ko) * | 2011-10-31 | 2013-07-09 | 한국에너지기술연구원 | 혼합부를 갖는 수소 정제 분리막 모듈 |
US8870735B2 (en) | 2012-05-17 | 2014-10-28 | Strategic Environmental & Energy Resources, Inc. | Waste disposal |
US20140174329A1 (en) * | 2012-12-26 | 2014-06-26 | King Fahd University Of Petroleum And Minerals | Controlled temperature ion transport membrane reactor |
US9843062B2 (en) | 2016-03-23 | 2017-12-12 | Energyield Llc | Vortex tube reformer for hydrogen production, separation, and integrated use |
US9840413B2 (en) | 2015-05-18 | 2017-12-12 | Energyield Llc | Integrated reformer and syngas separator |
DE102019112518A1 (de) * | 2019-05-14 | 2020-11-19 | Karlsruher Institut für Technologie | Membranreformer |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2441297A (en) | 1944-05-03 | 1948-05-11 | Union Oil Co | Process for dehydrogenation of hydrocarbons by contact with catalysts supported on alumina stabilized by aluminum phosphate |
US4846906A (en) * | 1987-12-02 | 1989-07-11 | The Duriron Company, Inc. | Methods for the manufacture of porous ceramic shapes containing membraneous surfaces |
JP3217447B2 (ja) * | 1992-05-27 | 2001-10-09 | 三菱重工業株式会社 | 脱水素反応用メンブレンリアクタ |
CA2100811C (en) * | 1992-08-19 | 1999-01-19 | Akhilesh Kapoor | Hydrogen and carbon monoxide production by partial oxidation of hydrocarbon feed |
JP3406021B2 (ja) | 1993-06-11 | 2003-05-12 | 東京瓦斯株式会社 | 水素製造装置 |
JPH0717701A (ja) * | 1993-06-23 | 1995-01-20 | Yazaki Corp | メタンの水蒸気改質方法 |
JP3599370B2 (ja) * | 1994-05-23 | 2004-12-08 | 日本碍子株式会社 | 水素製造装置 |
JP3373057B2 (ja) * | 1994-07-29 | 2003-02-04 | エヌオーケー株式会社 | 水素分離膜の製造法 |
US5997594A (en) | 1996-10-30 | 1999-12-07 | Northwest Power Systems, Llc | Steam reformer with internal hydrogen purification |
US5938800A (en) * | 1997-11-13 | 1999-08-17 | Mcdermott Technology, Inc. | Compact multi-fuel steam reformer |
EP1138096B1 (en) * | 1998-10-14 | 2010-10-06 | IdaTech, LLC | Fuel processing system |
US6207132B1 (en) * | 1998-12-04 | 2001-03-27 | Chinese Petroleum Corporation | Process for producing high purity hydrogen |
AU779487B2 (en) * | 1999-08-17 | 2005-01-27 | Battelle Memorial Institute | Chemical reactor and method for catalytic gas phase reactions |
US6488838B1 (en) * | 1999-08-17 | 2002-12-03 | Battelle Memorial Institute | Chemical reactor and method for gas phase reactant catalytic reactions |
US6409940B1 (en) * | 1999-10-18 | 2002-06-25 | Conoco Inc. | Nickel-rhodium based catalysts and process for preparing synthesis gas |
US6830596B1 (en) * | 2000-06-29 | 2004-12-14 | Exxonmobil Research And Engineering Company | Electric power generation with heat exchanged membrane reactor (law 917) |
DE10061920A1 (de) * | 2000-12-13 | 2002-06-20 | Creavis Tech & Innovation Gmbh | Kationen-/protonenleitende keramische Membran auf Basis einer Hydroxysilylsäure, Verfahren zu deren Herstellung und die Verwendung der Membran |
JP2004531440A (ja) * | 2001-03-05 | 2004-10-14 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 水素の製造装置及び製造方法 |
US6569226B1 (en) | 2001-09-28 | 2003-05-27 | The United States Of America As Represented By The United States Department Of Energy | Metal/ceramic composites with high hydrogen permeability |
US6899744B2 (en) * | 2002-03-05 | 2005-05-31 | Eltron Research, Inc. | Hydrogen transport membranes |
US7527661B2 (en) * | 2005-04-18 | 2009-05-05 | Intelligent Energy, Inc. | Compact devices for generating pure hydrogen |
US6854602B2 (en) | 2002-06-04 | 2005-02-15 | Conocophillips Company | Hydrogen-selective silica-based membrane |
US6858174B2 (en) * | 2002-09-03 | 2005-02-22 | Ceramatec, Inc. | Process for casting ceramic materials |
US7217303B2 (en) * | 2003-02-28 | 2007-05-15 | Exxonmobil Research And Engineering Company | Pressure swing reforming for fuel cell systems |
US20060013759A1 (en) * | 2004-07-13 | 2006-01-19 | Conocophillips Company | Systems and methods for hydrogen production |
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EP2099709A4 (en) | 2012-02-08 |
US20150174548A1 (en) | 2015-06-25 |
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