JP5211042B2 - スピノシン燻蒸剤 - Google Patents
スピノシン燻蒸剤 Download PDFInfo
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- JP5211042B2 JP5211042B2 JP2009512142A JP2009512142A JP5211042B2 JP 5211042 B2 JP5211042 B2 JP 5211042B2 JP 2009512142 A JP2009512142 A JP 2009512142A JP 2009512142 A JP2009512142 A JP 2009512142A JP 5211042 B2 JP5211042 B2 JP 5211042B2
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- 235000019253 formic acid Nutrition 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
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- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
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- 239000012669 liquid formulation Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
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- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
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- WLJVXDMOQOGPHL-UHFFFAOYSA-M phenylacetate Chemical compound [O-]C(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-M 0.000 description 1
- 229940049953 phenylacetate Drugs 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
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- 229960004889 salicylic acid Drugs 0.000 description 1
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- SRJQTHAZUNRMPR-UYQKXTDMSA-N spinosyn A Chemical compound O([C@H]1CCC[C@@H](OC(=O)C[C@H]2[C@@H]3C=C[C@@H]4C[C@H](C[C@H]4[C@@H]3C=C2C(=O)[C@@H]1C)O[C@H]1[C@@H]([C@H](OC)[C@@H](OC)[C@H](C)O1)OC)CC)[C@H]1CC[C@H](N(C)C)[C@@H](C)O1 SRJQTHAZUNRMPR-UYQKXTDMSA-N 0.000 description 1
- RDECBWLKMPEKPM-UHFFFAOYSA-N spinosyn D Natural products CC1C(=O)C2=CC3C4CC(OC5C(C(OC)C(OC)C(C)O5)OC)CC4C(C)=CC3C2CC(=O)OC(CC)CCCC1OC1CCC(N(C)C)C(C)O1 RDECBWLKMPEKPM-UHFFFAOYSA-N 0.000 description 1
- RDECBWLKMPEKPM-PSCJHHPTSA-N spinosyn D Chemical compound O([C@H]1CCC[C@@H](OC(=O)C[C@H]2[C@@H]3C=C(C)[C@@H]4C[C@H](C[C@H]4[C@@H]3C=C2C(=O)[C@@H]1C)O[C@H]1[C@@H]([C@H](OC)[C@@H](OC)[C@H](C)O1)OC)CC)[C@H]1CC[C@H](N(C)C)[C@@H](C)O1 RDECBWLKMPEKPM-PSCJHHPTSA-N 0.000 description 1
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- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Description
a.400ミクロン以上の粒径の液滴をもつ粗いスプレー、
b.100〜400ミクロンの粒径の液滴をもつ微細スプレー、
c.50〜100ミクロンの液滴をもつ霧、
d.0.1〜50ミクロンの範囲の粒径をもつ粒状物又は液滴をもつエアゾール、霧及び超低容量(ULV)の霧又は煙(熱い空気の爆風(熱霧)中への殺虫剤の注入、液化ガスとの混合、小孔を通す放出(アエゾール)、非常に微細なノズルを通す噴霧化、又は高速ローターでの分離により生成される)、
f.すべての粒状物が0.001ミクロン未満の粒径をもつ蒸気(熱発生装置により生成)、
g.ガス。
本発明は、1種又は複数のスピノシン化合物を利用する燻蒸法を対象とする。
実験室試験を熱噴霧器の送達による殺虫作用に対してスピノサド及びスピネトラムを試験するために実施した。試験昆虫は、エデス・エギプチ(Aedes aegypti)黄熱病の蚊、ドロソフィラ・メラノガステル(Drosophila melanogaster)ショウジョウバエ、ムスカ・ドメスチカ(Musca domestica)イエバエ及びプロジア・インテルプンクテラ(Plodia interpunctella)ひきわりトウモロコシ蛾、を包含した。
テスト室はPVCパイプの支持構造物からポリエチレン(PE)の袋を吊るすことにより開発された。袋は、約100ft3(28.3m3)の密閉内容積をもつ、48”(122cm)W×48”(122cm)D×102”(259cm)H(ULINE製品#S−8366)の測定値をもつ3milのPEのパレットカバーであった。室は平坦な4milのPEシートに床レベルでシールされた。4種の処理複製物及び1種の溶媒ブランク対照を収納するために5室を作製した。すべての室を1適用につき1回使用して、次に廃棄した。
黄熱病の蚊、イエハエ及びひきわりトウモロコシ蛾用保持ケージを、18×16メッシュの標準アルミニウム防虫網から作製した。円形ケージは3.5”(8.75cm)の直径及び5.5”(14.0cm)の高さの大きさに作製した。保持ケージの床及び天井は滅菌アクリルペトリ皿のカバー及び底であった。各保持ケージ中の昆虫に、7.5mlのガラスバイヤル及び滅菌糸芯から10%蔗糖溶液を供給した。ショウジョウバエに対しては、0.8mmメッシュの開口部をもつ白色ポリエステルの蚊用網を果物用ビンの蓋に糊付けし、ペトリ皿の底中に置いて、適当な保持ケージを作製した。砂糖水を2mlのバイアルから提供した。
Dynafog Trailblazerモデル2600E、シリーズ3熱噴霧装置を適用に使用した。噴霧装置は0.5〜50ミクロンの範囲の粒径をもち、1時間当り19リットルまでの調合物を送達するようになっている。それは500ft3(141.5m3)を超える密閉空間に適用するようになっている。その結果、噴霧器は、100ft3(28.3m3)のテスト室を入れるように調整することができる、より小さい容量を送達するように修飾された。
ひきわりトウモロコシ蛾の採集は培養ビンから二酸化炭素麻酔した個体を選択することにより実施した。成虫黄熱病蚊、イエハエ及びショウジョウバエは培養ビンから50mlの保持ビン中に吸引し、次に二酸化炭素で麻酔し、採集した。すべての昆虫を試験開始の前少なくとも1時間は麻酔から回復させた。各反復試験に50匹の成虫を使用した。処理から死亡した、又は傷害されたあらゆる昆虫を前処理死亡率データとして記録した。
試験に使用された調合物は1.1%スピノサド(90%純度)、1.5%イソプロピルミリステート(Cognis Corporation,Cincinnati,OH)、4.0%Emersol 213(Cognis Corporation)及び93.4%Exxsol D80(ExxonMobil,Houston,TX)又は、1.2%スピネトラム(81%純度)、1.5%イソプロピルミリステート(Cognis Corporation)、4.0%Emersol 213(Cognis Corporation)及び93.3%Exxsol D80(ExxonMobil)よりなった。溶媒混合物だけを伴うブランク処理は対照処理の1つであった。他の対照処理は有効成分及び溶媒の不在であった。
1.噴霧器のスイッチを入れて温度まで暖めた(3〜5分)。
2.トグル弁を開いて、各処理の実行前に調合物をラインに充填させた(〜50ml)。
3.調合物タンク内の調合物の量をSartorius BL1500秤上で秤量し、次に噴霧器に再度取り付けた。
4.噴霧器を処理室中の長方形の開口切り口の前に配置した。デジタルタイマーをセットし、トグル弁を開いて、調合物又は溶媒を適用した。
5.5〜7秒後に、トグル弁を閉め、噴霧器を停めた。
6.長方形の開口部をパッキングテープで即座にシールした。
7.調合物タンクを秤量し、秒における適用時間における質量の差を記録した。
8.タンクを再度取り付け、工程4〜7を次の3つの処理室に対して反復した。
9.4つの処理室を実施後に、噴霧器を清浄な溶媒(〜50ml)でフラッシュして噴霧器から調合物を除去した。
10.次に秤量後、溶媒のみを含む新規調合物タンクを再度取り付けた。
11.噴霧器に溶媒を充填し、次に工程3〜7を溶媒ブランク処理室について実施した。
適用の効果は1時間、4時間、18時間及び24時間に記録した。すべての処理、溶媒対照及び未処理対照試験ケージにつき、各期間に、生存及び死亡昆虫数を記録した。
可燃性コイル
最初に0.5gのスピネトラムを20mlのアセトンに溶解する。溶液を均一に撹拌し、99.4gの蚊取りコイル用担体(4:3:3のカンファー粉末:かす(lees)粉末:木粉の混合物)と混合する。それに120mlの水を添加し、混合物を十分混練し、次に成形し、乾燥すると可燃性コイルを得る。
コイル
最初に0.5gの各スピネトラムを20mlのアセトンに溶解する。溶液を、99.4gの蚊取りコイル用担体(4:3:3の比率のタブー粉末:除虫菊絞りカス粉末:木粉を混合することにより製造)と撹拌しながら均一に混合する。混合物を120mlの水で十分混練し、次に成形し、乾燥すると可燃性コイルを与える。
電気マット
アセトンを0.5gのスピネトラム及び0.4gのピペニルブトキシドに添加して、成分を溶解して、総量10ml量の溶液を製造する。2.5cm×1.5cm×0.3cmの厚さの電気マット用基材(シートに固めた綿リンター及びパルプの混合物のフィブリル)を前記の溶液で均一に含浸すると電気マットを得る。
熱燻蒸剤
最初に100mgのスピネトラムを適量のアセトンに溶解する。4.0cm×4.0cm×1.2cmの厚さの多孔質セラミックシートを生成された溶液で含浸させると熱燻蒸剤を得る。
Claims (18)
- 節足動物害虫の抑制が望まれる空間にスピネトラム及び液体担体を含んでなる組成物を分散する方法を含んでなり、そこで組成物が0.001ミクロン以下の粒径を有する液滴又は粒状物の形態で分散されて蒸気を生成する、節足動物害虫の抑制法。
- 組成物が密閉空間中に分散される請求項1の方法。
- 0.001ミクロン以下の粒径を有する液滴又は粒状物の形態の、スピネトラム及び非水性有機溶媒を含んでなる組成物を空間に分散させて蒸気を生成する方法を含んでなる、空間の害虫を駆除する方法。
- 甲虫、ゴキブリ又はアリを抑制するために使用される請求項1の方法。
- 蝿又は蛾を抑制するために使用される請求項1の方法。
- 空間が温室内である、請求項1の方法。
- 節足動物害虫の抑制が所望される空間に、スピノシン及び液体担体を含んでなる組成物を分散する方法を含んでなり、そこで組成物が0.001ミクロン以下の粒径を有する液滴又は粒状物の形態で分散されて蒸気を生成する、節足動物害虫の抑制法。
- 組成物が密閉空間内に分散される、請求項7の方法。
- 0.001ミクロン以下の粒径を有する液滴又は粒状物の形態の、スピノシン及び非水性有機溶媒を含んでなる組成物を空間に分散して、蒸気を形成する方法を含んでなる、空間の害虫駆除法。
- 甲虫、ゴキブリ又はアリを抑制するために使用される請求項7の方法。
- 蝿又は蛾を抑制するために使用される請求項7の方法。
- 空間が温室内である、請求項8の方法。
- 節足動物害虫の抑制が所望される空間に、スピノサド及び液体担体を含んでなる組成物を分散する方法を含んでなり、そこで組成物が0.001ミクロン以下の粒径を有する液滴又は粒状物の形態で分散されて蒸気を生成する、節足動物害虫の抑制法。
- 組成物が密閉空間内に分散される、請求項13の方法。
- 0.001ミクロン以下の粒径を有する液滴又は粒状物の形態の、スピノサド及び非水性有機溶媒を含んでなる組成物を空間に分散して、蒸気を形成する方法を含んでなる、空間の害虫駆除法。
- 甲虫、ゴキブリ又はアリを抑制するために使用される請求項13の方法。
- 蝿又は蛾を抑制するために使用される請求項13の方法。
- 空間が温室内である、請求項14の方法。
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Application Number | Priority Date | Filing Date | Title |
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US80851006P | 2006-05-25 | 2006-05-25 | |
US80837206P | 2006-05-25 | 2006-05-25 | |
US60/808,372 | 2006-05-25 | ||
US60/808,510 | 2006-05-25 | ||
PCT/US2007/012365 WO2007139872A2 (en) | 2006-05-25 | 2007-05-24 | Spinosyn fumigants |
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JP2009545520A JP2009545520A (ja) | 2009-12-24 |
JP5211042B2 true JP5211042B2 (ja) | 2013-06-12 |
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JP2009512142A Expired - Fee Related JP5211042B2 (ja) | 2006-05-25 | 2007-05-24 | スピノシン燻蒸剤 |
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US (2) | US7737122B2 (ja) |
EP (1) | EP2019589B1 (ja) |
JP (1) | JP5211042B2 (ja) |
KR (1) | KR101404913B1 (ja) |
CN (1) | CN101917851B (ja) |
AR (1) | AR061123A1 (ja) |
AU (1) | AU2007267952B2 (ja) |
ES (1) | ES2477465T3 (ja) |
HK (1) | HK1148437A1 (ja) |
TW (1) | TWI381804B (ja) |
WO (1) | WO2007139872A2 (ja) |
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WO2007144786A2 (en) * | 2006-05-26 | 2007-12-21 | Entarco Sa | The vapor-phase application of spinosyn for the control of pests, and formulations and products utilizing the same |
WO2009095204A2 (en) * | 2008-01-29 | 2009-08-06 | Syngenta Participations Ag | Use of spinetoram as molluscicide and compositon containing it |
WO2009118663A2 (en) * | 2008-03-27 | 2009-10-01 | Entarco Sa | Spinosyn bait formulations for the control of cockroaches and methods of using the same |
BRPI0919048B8 (pt) * | 2008-09-12 | 2022-10-11 | Dow Agrosciences Llc | Composições pesticidas |
TWI510189B (zh) * | 2009-06-19 | 2015-12-01 | Lilly Co Eli | 殺外寄生蟲之方法及調配物 |
JP2013542737A (ja) * | 2010-11-05 | 2013-11-28 | イーライ リリー アンド カンパニー | 昆虫侵入を阻害するための方法 |
KR101960110B1 (ko) * | 2010-12-29 | 2019-03-19 | 다우 아그로사이언시즈 엘엘씨 | 곤충 방제 방법 |
CN105746521B (zh) * | 2012-04-12 | 2018-08-03 | 陕西韦尔奇作物保护有限公司 | 一种含氟虱磺胺与生物源类的农药组合物 |
CN103329902B (zh) * | 2013-07-03 | 2014-12-24 | 江苏龙灯化学有限公司 | 一种含有乙基多杀菌素和杀虫单的杀虫组合物 |
KR102152386B1 (ko) | 2013-07-12 | 2020-09-04 | 고려대학교 산학협력단 | 훈증살충력 측정용 기구 |
US9526238B2 (en) * | 2013-11-18 | 2016-12-27 | Edgar Lyle Mitchell | Chemical delivery system for controlling beetle populations in a poultry house |
CN103907628A (zh) * | 2014-03-31 | 2014-07-09 | 马瑞 | 一种蟑螂防治剂 |
CN104322597A (zh) * | 2014-11-23 | 2015-02-04 | 青岛锐志农业技术服务有限公司 | 一种防治储粮害虫的农药及其制备方法 |
KR101713649B1 (ko) * | 2016-10-27 | 2017-03-08 | 농업회사법인 주식회사 과농 | 저온 무염 훈소 과정을 이용한 훈연제 및 그의 제조방법 |
IL266806B2 (en) * | 2016-11-23 | 2024-05-01 | Agrofresh Inc | Methods and device for combined treatment of crop protection chemicals with growth regulators for plants |
CN109430273A (zh) * | 2018-12-06 | 2019-03-08 | 山东圣鹏科技股份有限公司 | 一种含多杀霉素的储粮杀虫剂及其制备方法以及应用 |
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IL56337A (en) * | 1978-12-29 | 1983-05-15 | Makhteshim Chem Works Ltd | Pesticide fogging composition and solvents therefor |
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2007
- 2007-05-24 KR KR1020087031345A patent/KR101404913B1/ko active IP Right Grant
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- 2007-05-24 JP JP2009512142A patent/JP5211042B2/ja not_active Expired - Fee Related
- 2007-05-24 AU AU2007267952A patent/AU2007267952B2/en not_active Ceased
- 2007-05-24 TW TW096118515A patent/TWI381804B/zh not_active IP Right Cessation
- 2007-05-24 CN CN200780023099.5A patent/CN101917851B/zh not_active Expired - Fee Related
- 2007-05-24 WO PCT/US2007/012365 patent/WO2007139872A2/en active Application Filing
- 2007-05-24 AR ARP070102251A patent/AR061123A1/es unknown
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Also Published As
Publication number | Publication date |
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KR20090015137A (ko) | 2009-02-11 |
EP2019589A2 (en) | 2009-02-04 |
CN101917851A (zh) | 2010-12-15 |
ES2477465T3 (es) | 2014-07-17 |
US7737122B2 (en) | 2010-06-15 |
JP2009545520A (ja) | 2009-12-24 |
KR101404913B1 (ko) | 2014-06-09 |
WO2007139872A3 (en) | 2010-09-02 |
TW200803728A (en) | 2008-01-16 |
CN101917851B (zh) | 2014-02-12 |
AU2007267952A1 (en) | 2007-12-06 |
US20070274924A1 (en) | 2007-11-29 |
TWI381804B (zh) | 2013-01-11 |
US20100215706A1 (en) | 2010-08-26 |
EP2019589B1 (en) | 2014-06-04 |
WO2007139872A2 (en) | 2007-12-06 |
AR061123A1 (es) | 2008-08-06 |
AU2007267952B2 (en) | 2012-04-19 |
HK1148437A1 (en) | 2011-09-09 |
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