JP4948538B2 - 改良されたエレクトロブロー繊維紡糸法 - Google Patents
改良されたエレクトロブロー繊維紡糸法 Download PDFInfo
- Publication number
- JP4948538B2 JP4948538B2 JP2008527152A JP2008527152A JP4948538B2 JP 4948538 B2 JP4948538 B2 JP 4948538B2 JP 2008527152 A JP2008527152 A JP 2008527152A JP 2008527152 A JP2008527152 A JP 2008527152A JP 4948538 B2 JP4948538 B2 JP 4948538B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- liquid stream
- stream
- spinneret
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims description 59
- 238000009987 spinning Methods 0.000 title claims description 47
- 239000000835 fiber Substances 0.000 title claims description 42
- 229920000642 polymer Polymers 0.000 claims description 69
- 239000007788 liquid Substances 0.000 claims description 45
- 229920005594 polymer fiber Polymers 0.000 claims description 25
- 239000003380 propellant Substances 0.000 claims description 11
- 229920001940 conductive polymer Polymers 0.000 claims description 8
- 230000005684 electric field Effects 0.000 description 13
- 239000002904 solvent Substances 0.000 description 11
- 150000002500 ions Chemical class 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- -1 polyethylene terephthalate Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010891 electric arc Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002121 nanofiber Substances 0.000 description 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 2
- 229920000767 polyaniline Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 239000011112 polyethylene naphthalate Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004693 Polybenzimidazole Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001523 electrospinning Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012681 fiber drawing Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052500 inorganic mineral Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011707 mineral Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 239000001103 potassium chloride Chemical class 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Inorganic materials [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 230000001141 propulsive effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0092—Electro-spinning characterised by the electro-spinning apparatus characterised by the electrical field, e.g. combined with a magnetic fields, using biased or alternating fields
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
- D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/205,457 US7582247B2 (en) | 2005-08-17 | 2005-08-17 | Electroblowing fiber spinning process |
| US11/205,457 | 2005-08-17 | ||
| PCT/US2006/032213 WO2007022390A1 (en) | 2005-08-17 | 2006-08-17 | Improved electroblowing fiber spinning process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009504938A JP2009504938A (ja) | 2009-02-05 |
| JP2009504938A5 JP2009504938A5 (enExample) | 2009-10-01 |
| JP4948538B2 true JP4948538B2 (ja) | 2012-06-06 |
Family
ID=37564140
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008527152A Active JP4948538B2 (ja) | 2005-08-17 | 2006-08-17 | 改良されたエレクトロブロー繊維紡糸法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7582247B2 (enExample) |
| EP (1) | EP1915474B1 (enExample) |
| JP (1) | JP4948538B2 (enExample) |
| KR (1) | KR101290019B1 (enExample) |
| CN (1) | CN101248223B (enExample) |
| BR (1) | BRPI0616539A2 (enExample) |
| DE (1) | DE602006012058D1 (enExample) |
| WO (1) | WO2007022390A1 (enExample) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8808608B2 (en) * | 2004-12-27 | 2014-08-19 | E I Du Pont De Nemours And Company | Electroblowing web formation process |
| US20110111201A1 (en) * | 2006-01-20 | 2011-05-12 | Reneker Darrell H | Method of making coiled and buckled electrospun fiber structures and uses for same |
| US8361365B2 (en) * | 2006-12-20 | 2013-01-29 | E I Du Pont De Nemours And Company | Process for electroblowing a multiple layered sheet |
| US8277711B2 (en) * | 2007-03-29 | 2012-10-02 | E I Du Pont De Nemours And Company | Production of nanofibers by melt spinning |
| KR100925775B1 (ko) * | 2007-09-21 | 2009-11-11 | 경희대학교 산학협력단 | 압전성이 뛰어난 β-결정을 다량 함유하는 폴리비닐리덴플루오라이드 나노섬유 웹의 제조 방법 |
| US8337742B2 (en) * | 2007-09-25 | 2012-12-25 | The University Of Akron | Bubble launched electrospinning jets |
| KR20100100814A (ko) * | 2007-11-20 | 2010-09-15 | 다우 코닝 코포레이션 | 섬유를 포함하는 물품과 상기 물품을 형성하는 방법 |
| US8211353B2 (en) * | 2008-09-05 | 2012-07-03 | E. I. Du Pont De Nemours And Company | Fiber spinning process using a weakly interacting polymer |
| US20100059906A1 (en) * | 2008-09-05 | 2010-03-11 | E. I. Du Pont De Nemours And Company | High throughput electroblowing process |
| JP5375022B2 (ja) * | 2008-10-17 | 2013-12-25 | 旭硝子株式会社 | 繊維の製造方法および触媒層の製造方法 |
| WO2010107503A1 (en) | 2009-03-19 | 2010-09-23 | Millipore Corporation | Removal of microorganisms from fluid samples using nanofiber filtration media |
| JP5479845B2 (ja) * | 2009-10-26 | 2014-04-23 | 国立大学法人信州大学 | 極細繊維製造装置及び極細繊維製造方法 |
| CN102803585A (zh) * | 2010-02-15 | 2012-11-28 | 康奈尔大学 | 电纺丝设备及由其生产的纳米纤维 |
| KR20130125287A (ko) * | 2010-05-29 | 2013-11-18 | 애쉴리 에스. 스코트 | 정전기 유도 용매 분출 또는 입자 형성을 위한 장치, 방법 및 유체 조성물 |
| ES2792823T3 (es) | 2010-07-02 | 2020-11-12 | Procter & Gamble | Artículo de estructura de trama fibrosa soluble que comprende principios activos |
| CN108579207A (zh) | 2010-08-10 | 2018-09-28 | Emd密理博公司 | 用于去除反转录病毒的方法 |
| KR101251731B1 (ko) * | 2010-10-29 | 2013-04-05 | 고려대학교 산학협력단 | 전기방사법을 이용한 나노섬유 제조장치 |
| ES2886043T3 (es) | 2011-04-01 | 2021-12-16 | Emd Millipore Corp | Estructuras compuestas que contienen nanofibras |
| KR101246095B1 (ko) * | 2011-05-25 | 2013-03-20 | 한국에너지기술연구원 | 이온분사 부직포 제조 장치 및 제조 방법 |
| EP2900852B1 (en) * | 2012-08-06 | 2020-10-07 | Parker-Hannificn Corporation | Devices and methods for the production of microfibers and nanofibers |
| US9090996B2 (en) | 2012-08-15 | 2015-07-28 | E I Du Pont De Nemours And Company | Multizone electroblowing process |
| GB201303413D0 (en) * | 2013-02-26 | 2013-04-10 | Univ Keele | Polymer electrospinning apparatus |
| DK177766B3 (da) * | 2013-03-19 | 2018-04-30 | Tresu As | Enhed og fremgangsmåde til koronabehandling |
| CN103334165B (zh) * | 2013-06-13 | 2015-09-09 | 厦门大学 | 一种静电纺丝装置 |
| WO2015034431A1 (en) * | 2013-09-09 | 2015-03-12 | Ngee Ann Polytechnic | An electrospinning apparatus and method for the continuous production of fibres |
| US10106915B2 (en) * | 2013-12-18 | 2018-10-23 | Anf Inc. | Electro-spinning type pattern forming apparatus |
| US20150315350A1 (en) | 2014-04-22 | 2015-11-05 | The Procter & Gamble Company | Compositions in the Form of Dissolvable Solid Structures |
| ES2962695T3 (es) | 2014-06-26 | 2024-03-20 | Emd Millipore Corp | Dispositivo de filtración de fluidos con capacidad de retención de suciedad mejorada |
| WO2016167871A1 (en) | 2015-04-17 | 2016-10-20 | Emd Millipore Corporation | Method of purifying a biological materia of interest in a sample using nanofiber ultrafiltration membranes operated in tangential flow filtration mode |
| US20180142382A1 (en) * | 2015-06-12 | 2018-05-24 | Reliance Industries Limited | Electrostatic intermingling device and a process for intermingling filaments |
| JP6820336B2 (ja) | 2015-12-03 | 2021-01-27 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 繊維状構造体及びこれに関する方法 |
| BR112018069478B1 (pt) | 2016-02-25 | 2023-04-25 | Avintiv Specialty Materials Inc | Panos de não tecido com propriedades de aprimoramento de barreira aditivas |
| JP6427518B2 (ja) * | 2016-03-17 | 2018-11-21 | 株式会社東芝 | ノズルヘッドモジュール、および電界紡糸装置 |
| WO2019016605A1 (en) | 2017-07-21 | 2019-01-24 | Merck Millipore Ltd | MEMBRANES OF NONWOVEN FIBERS |
| CN112458560A (zh) * | 2020-11-13 | 2021-03-09 | 广东新会美达锦纶股份有限公司 | 一种纺丝生产的热媒加热系统 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3338992A (en) * | 1959-12-15 | 1967-08-29 | Du Pont | Process for forming non-woven filamentary structures from fiber-forming synthetic organic polymers |
| US3387326A (en) | 1964-06-04 | 1968-06-11 | Du Pont | Apparatus for charging and spreading a web |
| US3535588A (en) * | 1967-04-06 | 1970-10-20 | Du Pont | Apparatus for charging fibrous material |
| US3824052A (en) * | 1971-04-15 | 1974-07-16 | Deering Milliken Res Corp | Apparatus to produce nonwoven fabric |
| US4215682A (en) * | 1978-02-06 | 1980-08-05 | Minnesota Mining And Manufacturing Company | Melt-blown fibrous electrets |
| US4233014A (en) * | 1979-09-19 | 1980-11-11 | E. I. Du Pont De Nemours And Company | Apparatus for preparing a nonwoven web |
| JPS6094664A (ja) * | 1983-10-26 | 1985-05-27 | 旭化成株式会社 | フィラメント群の開繊法 |
| US4904174A (en) * | 1988-09-15 | 1990-02-27 | Peter Moosmayer | Apparatus for electrically charging meltblown webs (B-001) |
| US5509952A (en) * | 1992-11-23 | 1996-04-23 | Alcatel Network Systems, Inc. | Method for bonding a fiber to a sleeve for fiber optic packaging applications |
| US20020084178A1 (en) * | 2000-12-19 | 2002-07-04 | Nicast Corporation Ltd. | Method and apparatus for manufacturing polymer fiber shells via electrospinning |
| US6709623B2 (en) * | 2000-12-22 | 2004-03-23 | Kimberly-Clark Worldwide, Inc. | Process of and apparatus for making a nonwoven web |
| US6872311B2 (en) * | 2002-01-31 | 2005-03-29 | Koslow Technologies Corporation | Nanofiber filter media |
| KR100549140B1 (ko) * | 2002-03-26 | 2006-02-03 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 일렉트로-브로운 방사법에 의한 초극세 나노섬유 웹제조방법 |
| AU2003214634A1 (en) | 2002-03-27 | 2003-10-08 | Council Of Scientific And Industrial Research | Anti peptic ulcer activity of an extract of a plant flower woodfordia fruticosa |
| US8808608B2 (en) | 2004-12-27 | 2014-08-19 | E I Du Pont De Nemours And Company | Electroblowing web formation process |
-
2005
- 2005-08-17 US US11/205,457 patent/US7582247B2/en active Active
-
2006
- 2006-08-17 CN CN2006800298993A patent/CN101248223B/zh not_active Expired - Fee Related
- 2006-08-17 BR BRPI0616539-7A patent/BRPI0616539A2/pt not_active IP Right Cessation
- 2006-08-17 KR KR1020087006231A patent/KR101290019B1/ko not_active Expired - Fee Related
- 2006-08-17 EP EP06789834A patent/EP1915474B1/en not_active Ceased
- 2006-08-17 WO PCT/US2006/032213 patent/WO2007022390A1/en not_active Ceased
- 2006-08-17 JP JP2008527152A patent/JP4948538B2/ja active Active
- 2006-08-17 DE DE602006012058T patent/DE602006012058D1/de active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20070040305A1 (en) | 2007-02-22 |
| JP2009504938A (ja) | 2009-02-05 |
| BRPI0616539A2 (pt) | 2011-06-21 |
| CN101248223B (zh) | 2010-12-22 |
| EP1915474A1 (en) | 2008-04-30 |
| CN101248223A (zh) | 2008-08-20 |
| KR101290019B1 (ko) | 2013-07-30 |
| US7582247B2 (en) | 2009-09-01 |
| EP1915474B1 (en) | 2010-01-27 |
| DE602006012058D1 (de) | 2010-03-18 |
| KR20080038222A (ko) | 2008-05-02 |
| WO2007022390A1 (en) | 2007-02-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4948538B2 (ja) | 改良されたエレクトロブロー繊維紡糸法 | |
| JP4948537B2 (ja) | 改良された繊維帯電装置 | |
| JP5102631B2 (ja) | 電気ブローイング・ウェブ形成方法 | |
| JP5204493B2 (ja) | 改良された電気ブローイング・ウェブ形成方法 | |
| US20060012084A1 (en) | Electroblowing web formation process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20090221 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090817 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090817 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110722 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110801 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20111101 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20111109 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120131 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120227 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120306 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150316 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 Ref document number: 4948538 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |