JP4922558B2 - 環状オレフィンモノマーの環挿入重合による大環状ポリマーの合成 - Google Patents

環状オレフィンモノマーの環挿入重合による大環状ポリマーの合成 Download PDF

Info

Publication number
JP4922558B2
JP4922558B2 JP2004526342A JP2004526342A JP4922558B2 JP 4922558 B2 JP4922558 B2 JP 4922558B2 JP 2004526342 A JP2004526342 A JP 2004526342A JP 2004526342 A JP2004526342 A JP 2004526342A JP 4922558 B2 JP4922558 B2 JP 4922558B2
Authority
JP
Japan
Prior art keywords
cyclic
polymer
substituted
alkyl
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2004526342A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005534777A5 (enExample
JP2005534777A (ja
Inventor
ロバート グラブス，
クリス ビーラウスキー，
ディエゴ ベニテズ，
Original Assignee
カリフォルニア インスティテュート オブ テクノロジー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by カリフォルニア インスティテュート オブ テクノロジー filed Critical カリフォルニア インスティテュート オブ テクノロジー
Publication of JP2005534777A publication Critical patent/JP2005534777A/ja
Publication of JP2005534777A5 publication Critical patent/JP2005534777A5/ja
Application granted granted Critical
Publication of JP4922558B2 publication Critical patent/JP4922558B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2004526342A 2002-08-01 2003-08-01 環状オレフィンモノマーの環挿入重合による大環状ポリマーの合成 Expired - Fee Related JP4922558B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US40040002P 2002-08-01 2002-08-01
US60/400,400 2002-08-01
PCT/US2003/024222 WO2004013198A2 (en) 2002-08-01 2003-08-01 Synthesis of macrocyclic polymers by ring insertion polymerization of cyclic olefin monomers

Publications (3)

Publication Number Publication Date
JP2005534777A JP2005534777A (ja) 2005-11-17
JP2005534777A5 JP2005534777A5 (enExample) 2006-09-14
JP4922558B2 true JP4922558B2 (ja) 2012-04-25

Family

ID=31495817

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004526342A Expired - Fee Related JP4922558B2 (ja) 2002-08-01 2003-08-01 環状オレフィンモノマーの環挿入重合による大環状ポリマーの合成

Country Status (5)

Country Link
US (1) US6946533B2 (enExample)
EP (1) EP1543043B1 (enExample)
JP (1) JP4922558B2 (enExample)
AU (1) AU2003258013A1 (enExample)
WO (1) WO2004013198A2 (enExample)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2512815A1 (en) * 2003-01-13 2004-07-29 Cargill, Incorporated Method for making industrial chemicals
AU2005280639A1 (en) * 2004-02-17 2006-03-09 Billy T. Fowler Methods, compositions, and apparatuses for forming macrocyclic compounds
WO2006012294A2 (en) * 2004-06-25 2006-02-02 Arkema Inc. Chemical vapor deposition with nucleophilic stable carbene-containing precursors
US8742052B2 (en) * 2005-01-11 2014-06-03 Nuplex Resins B.V. Polyurea compound
WO2007081987A2 (en) * 2006-01-10 2007-07-19 Elevance Renewable Sciences, Inc. Method of making hydrogenated metathesis products
EP2046719B1 (en) 2006-07-12 2013-09-04 Elevance Renewable Sciences, Inc. Ring opening cross-metathesis reaction of cyclic olefins with seed oils and the like
WO2008010961A2 (en) 2006-07-13 2008-01-24 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
EP1902865A1 (en) * 2006-09-21 2008-03-26 The Goodyear Tire & Rubber Company Pneumatic tire
US7629409B2 (en) 2006-09-21 2009-12-08 The Goodyear Tire & Rubber Company Pneumatic tire
WO2008140468A2 (en) 2006-10-13 2008-11-20 Elevance Renewable Sciences, Inc. METHODS OF MAKING α, ω -DICARBOXYLIC ACID ALKENE DERIVATIVES BY METATHESIS
WO2008048520A2 (en) 2006-10-13 2008-04-24 Elevance Renewable Sciences, Inc. Methods of making organic compounds by metathesis and hydrocyanation
WO2008046106A2 (en) 2006-10-13 2008-04-17 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes via olefin metathesis
WO2010022284A1 (en) * 2008-08-20 2010-02-25 The Research Foundation Of The State University Of New York Alternating ring-opening metathesis polymerization
MX2011011742A (es) * 2009-05-05 2011-12-08 Stepan Co Tensoactivo de olefina interna sulfonada para recuperacion mejorada de petroleo.
EP2280017B1 (en) * 2009-07-21 2013-01-02 Rimtec Corporation Catalytic complex for olefin metathesis reactions, process for the preparation thereof and use thereof
US9206266B2 (en) 2011-12-07 2015-12-08 University Of Florida Research Foundation, Inc. Tridentate pincer ligand supported metal-alkylidyne and metallacycloalkylene complexes for alkyne polymerization
US9890239B2 (en) 2013-09-04 2018-02-13 California Institute Of Technology Functionalized linear and cyclic polyolefins
CN116120715A (zh) * 2015-02-12 2023-05-16 马特里亚公司 包含官能弹性体的环烯烃树脂组合物
US10639620B2 (en) 2015-09-18 2020-05-05 University Of Florida Research Foundation, Inc. Catalyst for ring expansion metathesis polymerization of cyclic monomers
EP3153227A1 (de) * 2015-10-07 2017-04-12 Evonik Degussa GmbH Verfahren zur herstellung von polyalkenameren für verpackungsanwendungen
WO2017214637A1 (en) 2016-06-10 2017-12-14 Nirvana Sciences Inc. Hydroporphyrin beads with narrow fluorescence emissions
CN110662748A (zh) 2017-02-03 2020-01-07 尼尔瓦纳科学股份有限公司 用于光声成像的氢卟啉
US11904026B2 (en) 2017-02-03 2024-02-20 Nirvana Sciences Inc. Metallohydroporphyrins for photoacoustic imaging
US10730972B2 (en) * 2017-09-22 2020-08-04 University Of Florida Research Foundation, Inc. Cyclic polyolefins derived from hexyne, octyne, nonyne, pentadecyne and their copolymers with acetylene
US11807694B2 (en) 2017-09-22 2023-11-07 University Of Florida Research Foundation, Incorporated Macrocyclic poly(akane)s and poly(alkane-co-alkene)s
CN107987107B (zh) * 2017-12-15 2020-03-20 上海克琴科技有限公司 钌卡宾催化剂及其催化的降冰片烯开环易位聚合反应
JP7194426B2 (ja) * 2018-12-21 2022-12-22 国立大学法人 東京大学 動的架橋エラストマー
US20220249707A1 (en) 2019-05-20 2022-08-11 Nirvana Sciences Inc. Narrow emission dyes, compositions comprising same, and methods for making and using same
WO2020236828A1 (en) 2019-05-20 2020-11-26 Nirvana Sciences Inc. Narrow emission dyes, compositions comprising same, and methods for making and using same
WO2021060418A1 (ja) * 2019-09-25 2021-04-01 日本ゼオン株式会社 環状ポリマー水素化物及びその製造方法、並びに、樹脂組成物
CN113019124A (zh) * 2019-12-24 2021-06-25 天津膜天膜科技股份有限公司 膜法制备提纯环状聚合物

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10139804A (ja) * 1996-11-07 1998-05-26 Bridgestone Corp Ｉｉａおよびｉｉｂ族の金属を含む環状の有機金属開始剤を用いた大環状ポリマー合成
US6080826A (en) * 1997-01-06 2000-06-27 California Institute Of Technology Template-directed ring-closing metathesis and ring-opening metathesis polymerization of functionalized dienes
JP2001278963A (ja) * 2000-03-31 2001-10-10 Nippon Zeon Co Ltd 硬化可能な成形材、成形品およびそれらの製造方法
JP2002509961A (ja) * 1998-03-31 2002-04-02 クライオバック・インコーポレイテツド 新規な位置規則的コポリマー及びその製造方法
JP2003500412A (ja) * 1999-05-24 2003-01-07 カリフォルニア インスティチュート オブ テクノロジー イミダゾリジンに基づく金属カルベンメタセシス触媒
JP2003176294A (ja) * 2001-08-24 2003-06-24 California Inst Of Technol ６配位ルテニウムまたはオスミウム金属カルベンメタセシス触媒
JP2004530540A (ja) * 2001-03-23 2004-10-07 カリフォルニア　インスティチュート　オブ　テクノロジー 熱活性化ｎ−複素環カルベン前駆体の使用により生成される高活性金属カルベンメタセシス触媒
JP2005517774A (ja) * 2002-02-19 2005-06-16 カリフォルニア インスティテュート オブ テクノロジー 非環式ジエンを用いるオレフィンメタセシス反応による、環式オレフィンの環拡大
JP2007016247A (ja) * 1995-12-07 2007-01-25 Advanced Polymer Technologies オレフィンメタセシス重合反応の可使時間の延長方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5312940A (en) * 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
JP3067031B2 (ja) * 1992-04-03 2000-07-17 カリフォルニア インスティチュート オブ テクノロジー オレフィンメタセシス重合方法
US5831108A (en) * 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US6310121B1 (en) * 1996-12-02 2001-10-30 Cymetech, Llc Polymeric composites including dicyclopentadiene and related monomers
IL153578A0 (en) * 2000-06-23 2003-07-06 California Inst Of Techn Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing metathesis
US6610626B2 (en) * 2000-09-05 2003-08-26 Cymetech, Llp Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors
US6838489B2 (en) * 2001-03-23 2005-01-04 Cymetech, Llc High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor
JP4271942B2 (ja) * 2001-03-30 2009-06-03 カリフォルニア インスティチュート オブ テクノロジー シクロオレフィンの選択的開環クロス−メタセシス
AU2003232067A1 (en) * 2002-05-06 2003-11-17 Kerr Corporation Composition curable by metathesis reaction

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007016247A (ja) * 1995-12-07 2007-01-25 Advanced Polymer Technologies オレフィンメタセシス重合反応の可使時間の延長方法
JPH10139804A (ja) * 1996-11-07 1998-05-26 Bridgestone Corp Ｉｉａおよびｉｉｂ族の金属を含む環状の有機金属開始剤を用いた大環状ポリマー合成
US6080826A (en) * 1997-01-06 2000-06-27 California Institute Of Technology Template-directed ring-closing metathesis and ring-opening metathesis polymerization of functionalized dienes
JP2002509961A (ja) * 1998-03-31 2002-04-02 クライオバック・インコーポレイテツド 新規な位置規則的コポリマー及びその製造方法
JP2003500412A (ja) * 1999-05-24 2003-01-07 カリフォルニア インスティチュート オブ テクノロジー イミダゾリジンに基づく金属カルベンメタセシス触媒
JP2001278963A (ja) * 2000-03-31 2001-10-10 Nippon Zeon Co Ltd 硬化可能な成形材、成形品およびそれらの製造方法
JP2004530540A (ja) * 2001-03-23 2004-10-07 カリフォルニア　インスティチュート　オブ　テクノロジー 熱活性化ｎ−複素環カルベン前駆体の使用により生成される高活性金属カルベンメタセシス触媒
JP2003176294A (ja) * 2001-08-24 2003-06-24 California Inst Of Technol ６配位ルテニウムまたはオスミウム金属カルベンメタセシス触媒
JP2005517774A (ja) * 2002-02-19 2005-06-16 カリフォルニア インスティテュート オブ テクノロジー 非環式ジエンを用いるオレフィンメタセシス反応による、環式オレフィンの環拡大

Also Published As

Publication number Publication date
AU2003258013A8 (en) 2004-02-23
US6946533B2 (en) 2005-09-20
WO2004013198A3 (en) 2004-06-17
AU2003258013A1 (en) 2004-02-23
US20040132934A1 (en) 2004-07-08
WO2004013198A2 (en) 2004-02-12
EP1543043A4 (en) 2005-11-02
JP2005534777A (ja) 2005-11-17
EP1543043A2 (en) 2005-06-22
EP1543043B1 (en) 2013-10-02

Similar Documents

Publication Publication Date Title
JP4922558B2 (ja) 環状オレフィンモノマーの環挿入重合による大環状ポリマーの合成
JP2005534777A5 (enExample)
CN1659172B (zh) 直接被吸电子基团取代的烯烃使用过渡金属卡宾催化剂的交叉-易位
US8871879B2 (en) Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand
JP5100728B2 (ja) メタセシスに使用される金属錯体
CN101243098B (zh) 作为烯烃易位反应催化剂的含阳离子取代基的过渡金属卡宾配合物
US6987154B2 (en) Synthesis of A,B-alternating copolymers by olefin metathesis reactions of cyclic olefins or olefinic polymers with an acyclic diene
EP2251360B1 (en) Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms
JP7039565B2 (ja) メタセシス触媒の合成および特性決定
CN114106057B (zh) Ru亚烷基络合物的合成与表征
CN101090915A (zh) 含有n－杂环卡宾配体的潜伏的高活性烯烃置换催化剂
Nazarov et al. Synthesis and metathesis polymerization of (1 r, 2 r, 6 s, 7 s)-4-(1-phenylethyl)-4-azatricyclo [5.2. 1.02, 6] dec-8-ene-3, 5-dione

Legal Events

Date Code Title Description
A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20060726

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060726

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20090430

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090508

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090806

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090813

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090907

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090914

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20091008

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20091016

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20091109

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101012

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110111

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110118

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110210

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110218

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20110310

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20110317

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110412

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120111

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120206

R150 Certificate of patent or registration of utility model

Ref document number: 4922558

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150210

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees