JP4883794B2 - 高温安定型水素化ホウ素配合物 - Google Patents
高温安定型水素化ホウ素配合物 Download PDFInfo
- Publication number
- JP4883794B2 JP4883794B2 JP2007163520A JP2007163520A JP4883794B2 JP 4883794 B2 JP4883794 B2 JP 4883794B2 JP 2007163520 A JP2007163520 A JP 2007163520A JP 2007163520 A JP2007163520 A JP 2007163520A JP 4883794 B2 JP4883794 B2 JP 4883794B2
- Authority
- JP
- Japan
- Prior art keywords
- borohydride
- sodium
- hydroxide
- aqueous
- aqueous mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001875 compounds Chemical class 0.000 title claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 28
- 229920000642 polymer Polymers 0.000 claims description 16
- 150000004692 metal hydroxides Chemical class 0.000 claims description 13
- 239000002250 absorbent Substances 0.000 claims description 12
- 230000002745 absorbent Effects 0.000 claims description 12
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 12
- 239000012279 sodium borohydride Substances 0.000 claims description 12
- 229920002125 Sokalan® Polymers 0.000 claims description 10
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 10
- 239000004584 polyacrylic acid Substances 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229920002717 polyvinylpyridine Polymers 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 229920002873 Polyethylenimine Polymers 0.000 claims description 3
- 229920006037 cross link polymer Polymers 0.000 claims description 3
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims description 3
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 230000000087 stabilizing effect Effects 0.000 claims description 2
- 229920003169 water-soluble polymer Polymers 0.000 claims description 2
- GLGNXYJARSMNGJ-VKTIVEEGSA-N (1s,2s,3r,4r)-3-[[5-chloro-2-[(1-ethyl-6-methoxy-2-oxo-4,5-dihydro-3h-1-benzazepin-7-yl)amino]pyrimidin-4-yl]amino]bicyclo[2.2.1]hept-5-ene-2-carboxamide Chemical compound CCN1C(=O)CCCC2=C(OC)C(NC=3N=C(C(=CN=3)Cl)N[C@H]3[C@H]([C@@]4([H])C[C@@]3(C=C4)[H])C(N)=O)=CC=C21 GLGNXYJARSMNGJ-VKTIVEEGSA-N 0.000 claims 2
- 150000001204 N-oxides Chemical class 0.000 claims 2
- 229940125758 compound 15 Drugs 0.000 claims 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 12
- 238000009472 formulation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- -1 acetate ester Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229940124531 pharmaceutical excipient Drugs 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 229920002785 Croscarmellose sodium Polymers 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- UIERETOOQGIECD-ARJAWSKDSA-N angelic acid Chemical compound C\C=C(\C)C(O)=O UIERETOOQGIECD-ARJAWSKDSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000010410 calcium alginate Nutrition 0.000 description 1
- 239000000648 calcium alginate Substances 0.000 description 1
- 229960002681 calcium alginate Drugs 0.000 description 1
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229940045110 chitosan Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229960001681 croscarmellose sodium Drugs 0.000 description 1
- 229960000913 crospovidone Drugs 0.000 description 1
- 235000010947 crosslinked sodium carboxy methyl cellulose Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229960000540 polacrilin potassium Drugs 0.000 description 1
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 description 1
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 description 1
- WVWZXTJUCNEUAE-UHFFFAOYSA-M potassium;1,2-bis(ethenyl)benzene;2-methylprop-2-enoate Chemical compound [K+].CC(=C)C([O-])=O.C=CC1=CC=CC=C1C=C WVWZXTJUCNEUAE-UHFFFAOYSA-M 0.000 description 1
- 229940069328 povidone Drugs 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- ILVXOBCQQYKLDS-UHFFFAOYSA-N pyridine N-oxide Chemical compound [O-][N+]1=CC=CC=C1 ILVXOBCQQYKLDS-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000008109 sodium starch glycolate Substances 0.000 description 1
- 229940079832 sodium starch glycolate Drugs 0.000 description 1
- 229920003109 sodium starch glycolate Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000007885 tablet disintegrant Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
- C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
- C01B6/15—Metal borohydrides; Addition complexes thereof
- C01B6/19—Preparation from other compounds of boron
- C01B6/21—Preparation of borohydrides of alkali metals, alkaline earth metals, magnesium or beryllium; Addition complexes thereof, e.g. LiBH4.2N2H4, NaB2H7
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
- Fuel Cell (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Claims (10)
- (a)水性混合物の重量基準で、少なくとも1種の水素化ホウ素化合物を15重量%〜65重量%;
(b)少なくとも1種の金属水酸化物を1重量%〜10重量%;および
(c)ポリアクリル酸、ポリビニルピロリドン、ポリビニルピリジン、ポリビニルピリジンN−オキシド、ポリビニルイミダゾール、エトキシル化ポリエチレンイミン、セルロースエステル、ヒドロキシアルキルセルロース、およびカルボキシメチルセルロースから選択される少なくとも1種の吸収性ポリマーを0.1重量%〜20重量%:
含む水性混合物。 - 前記少なくとも1種の水素化ホウ素化合物が水素化ホウ素ナトリウム、水素化ホウ素カリウムまたはそれらの組み合わせであり、および前記少なくとも1種の金属水酸化物が水酸化ナトリウム、水酸化リチウム、もしくは水酸化カリウム、またはそれらの組み合わせである、請求項1記載の水性混合物。
- 前記少なくとも1種の吸収性ポリマーが水溶性ポリマー、セルロースおよびその誘導体、並びに架橋ポリマーの中から選択される、請求項2記載の水性混合物。
- 前記水素化ホウ素化合物が水素化ホウ素ナトリウムであり、および前記金属水酸化物が水酸化ナトリウムである、請求項3記載の水性混合物。
- 水酸化ナトリウムを2重量%〜8重量%有し、および水素化ホウ素ナトリウムを20重量%〜50重量%有する、請求項4記載の水性混合物。
- 前記少なくとも1種の吸収性ポリマーは、ポリアクリル酸である、請求項5記載の水性混合物。
- ポリアクリル酸を0.1重量%〜1重量%有し、かつ前記ポリアクリル酸の重量平均分子量が少なくとも1500である、請求項6記載の水性混合物。
- 安定化された水性水素化ホウ素混合物の重量基準で、少なくとも1種の水素化ホウ素化合物を15重量%〜65重量%、および少なくとも1種の金属水酸化物を1重量%〜10重量%含有する水性水素化ホウ素混合物を安定化する方法であって、ポリアクリル酸、ポリビニルピロリドン、ポリビニルピリジン、ポリビニルピリジンN−オキシド、ポリビニルイミダゾール、エトキシル化ポリエチレンイミン、セルロースエステル、ヒドロキシアルキルセルロース、およびカルボキシメチルセルロースから選択される少なくとも1種の吸収性ポリマーを0.1重量%〜20重量%添加すること含む方法。
- 前記少なくとも1種の金属水酸化物が水酸化ナトリウムであり、および前記少なくとも1種の水素化ホウ素化合物が水素化ホウ素ナトリウムである、請求項8記載の方法。
- 前記水性水素化ホウ素混合物は水酸化ナトリウムを2重量%〜8重量%および水素化ホウ素ナトリウムを20重量%〜50重量%有する、請求項9記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US81860906P | 2006-07-05 | 2006-07-05 | |
US60/818,609 | 2006-07-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008013431A JP2008013431A (ja) | 2008-01-24 |
JP4883794B2 true JP4883794B2 (ja) | 2012-02-22 |
Family
ID=38577433
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007163520A Expired - Fee Related JP4883794B2 (ja) | 2006-07-05 | 2007-06-21 | 高温安定型水素化ホウ素配合物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US7648644B2 (ja) |
EP (1) | EP1876141B1 (ja) |
JP (1) | JP4883794B2 (ja) |
KR (2) | KR20080004355A (ja) |
CN (1) | CN101100286B (ja) |
CA (1) | CA2592655C (ja) |
DE (1) | DE602007010867D1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101633492B (zh) * | 2008-07-22 | 2013-02-27 | 汉能科技有限公司 | 一种固体硼氢化物制氢方法及其装置 |
KR101245914B1 (ko) * | 2010-12-21 | 2013-03-20 | 황보창수 | 건조오징어의 가공장치 |
US20170158390A1 (en) * | 2015-12-04 | 2017-06-08 | Mead Johnson Nutrition Company | Powder dosing closure |
JP2019026753A (ja) * | 2017-07-31 | 2019-02-21 | 株式会社ブリヂストン | ポリウレタン用アルデヒド捕捉剤、ポリウレタン、及びポリウレタンの製造方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2970114A (en) * | 1958-01-27 | 1961-01-31 | Metal Hydrides Inc | Stabilized aqueous solutions of sodium borohydride |
DE1567554A1 (de) * | 1966-04-02 | 1970-07-09 | Goerrig Dipl Chem Dr Rer Nat D | Festkoerper,enthaltend Alkalihydroxydhydrat,Alkaliboranat und gegebenenfalls Katalysatoren |
US3933676A (en) * | 1974-04-08 | 1976-01-20 | Ventron Corporation | Stabilized aqueous solutions of sodium borohydride |
US5169555A (en) * | 1990-11-09 | 1992-12-08 | Morton International, Inc. | Pulp bleaching solution |
US5354478A (en) * | 1993-06-09 | 1994-10-11 | Morton International, Inc. | Alkali metal borohydride/anionic polymer solutions |
FR2746328B1 (fr) * | 1996-03-21 | 1998-05-29 | Stmi Soc Tech Milieu Ionisant | Gel organomineral de decontamination et son utilisation pour la decontamination de surfaces |
JP2001019401A (ja) * | 1999-07-05 | 2001-01-23 | Seijiro Suda | 水素発生剤及びそれを用いる水素発生方法 |
JP2002201001A (ja) * | 2000-12-28 | 2002-07-16 | Toyota Motor Corp | 錯金属水素化物水溶液の安定化方法 |
JP2003146604A (ja) * | 2001-11-08 | 2003-05-21 | Sekisui Chem Co Ltd | 水素発生用圧縮成形体と、それを用いた水素発生方法及び装置 |
EP1478593A4 (en) * | 2001-11-13 | 2008-07-02 | Montgomery Chemicals Llc | AQUEOUS BOROHIDEIDE COMPOSITIONS |
JP2004196634A (ja) * | 2002-12-20 | 2004-07-15 | Honda Motor Co Ltd | 水素貯蔵・放出システムに用いられる水素化物粉末 |
JP4276854B2 (ja) * | 2003-01-30 | 2009-06-10 | ウチヤ・サーモスタット株式会社 | 水素発生材料、水素発生方法及び水素発生装置 |
CN100384736C (zh) * | 2004-10-18 | 2008-04-30 | 罗门哈斯公司 | 固体氢氧化钠生产中减少腐蚀的方法 |
JP4813790B2 (ja) * | 2004-12-03 | 2011-11-09 | セイコーインスツル株式会社 | 水素発生装置及び燃料電池システム |
-
2007
- 2007-06-21 CN CN2007101280211A patent/CN101100286B/zh not_active Expired - Fee Related
- 2007-06-21 CA CA2592655A patent/CA2592655C/en not_active Expired - Fee Related
- 2007-06-21 JP JP2007163520A patent/JP4883794B2/ja not_active Expired - Fee Related
- 2007-06-22 DE DE602007010867T patent/DE602007010867D1/de active Active
- 2007-06-22 EP EP07252555A patent/EP1876141B1/en not_active Expired - Fee Related
- 2007-06-28 KR KR1020070064111A patent/KR20080004355A/ko active Search and Examination
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Also Published As
Publication number | Publication date |
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EP1876141A2 (en) | 2008-01-09 |
US20080009575A1 (en) | 2008-01-10 |
KR20080004355A (ko) | 2008-01-09 |
EP1876141B1 (en) | 2010-12-01 |
JP2008013431A (ja) | 2008-01-24 |
US7648644B2 (en) | 2010-01-19 |
KR101113732B1 (ko) | 2012-02-27 |
CA2592655C (en) | 2011-04-19 |
DE602007010867D1 (de) | 2011-01-13 |
CA2592655A1 (en) | 2008-01-05 |
CN101100286A (zh) | 2008-01-09 |
KR20090051152A (ko) | 2009-05-21 |
EP1876141A3 (en) | 2008-01-23 |
CN101100286B (zh) | 2011-11-16 |
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