JP4733003B2 - 内燃機関の排ガス浄化装置 - Google Patents
内燃機関の排ガス浄化装置 Download PDFInfo
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- JP4733003B2 JP4733003B2 JP2006317855A JP2006317855A JP4733003B2 JP 4733003 B2 JP4733003 B2 JP 4733003B2 JP 2006317855 A JP2006317855 A JP 2006317855A JP 2006317855 A JP2006317855 A JP 2006317855A JP 4733003 B2 JP4733003 B2 JP 4733003B2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9495—Controlling the catalytic process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0871—Regulation of absorbents or adsorbents, e.g. purging
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N9/00—Electrical control of exhaust gas treating apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/021—Introducing corrections for particular conditions exterior to the engine
- F02D41/0235—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
- F02D41/027—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus
- F02D41/0275—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus the exhaust gas treating apparatus being a NOx trap or adsorbent
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
- F01N2550/02—Catalytic activity of catalytic converters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B37/00—Engines characterised by provision of pumps driven at least for part of the time by exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D2200/00—Input parameters for engine control
- F02D2200/02—Input parameters for engine control the parameters being related to the engine
- F02D2200/08—Exhaust gas treatment apparatus parameters
- F02D2200/0811—NOx storage efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/40—Engine management systems
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Toxicology (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Description
また、上述した構成によれば、触媒の上流側の温度および下流側の温度が検出され、触媒の温度が検出されるとともに、還元制御の実行中に検出された上流側の温度に対する下流側の温度の上昇度合が、上昇度合算出手段によって算出される。さらに、検出された触媒の温度が高いほど、算出された上昇度合がより低くなるように、上昇度合補正手段によって補正されるとともに、補正された上昇度合が低いほど、触媒の劣化度合がより高くなるように推定される。
触媒の劣化度合が高いほど、触媒の酸素貯蔵能力および酸化能力が低下し、還元剤の酸化反応によって発生する熱量が小さくなるため、触媒の下流側の温度上昇の度合はより低くなる。したがって、この構成によれば、還元制御の実行中に検出された上流側の温度に対する下流側の温度の上昇度合をパラメータとして、触媒の劣化度合を適切に推定することができる。
QEGR = QA×KEGR_F/(1−KEGR_F) ・・・(1)
2 ECU(NOx還元制御手段、劣化度合推定手段、補正手段、上昇度合算出手段、 上昇度合補正手段、還元剤供給量算出手段、還元制御終了手段)
3 内燃機関
5 排気管(排気系)
6 インジェクタ(NOx還元制御手段)
12 スロットル弁(NOx還元制御手段)
16 三元触媒(触媒)
17 NOx触媒
36 三元触媒温度センサ(触媒温度検出手段)
38 第1温度センサ(上流側温度検出手段)
39 第2温度センサ(下流側温度検出手段)
DEGRA 三元触媒の劣化度合
QDAL 還元剤供給量
S_QDAL 還元剤供給量積算値(還元剤供給量)
S_QDAREF 還元剤量判定値(しきい値)
TTWC 三元触媒温度(触媒の温度)
TTWC1 上流側温度(触媒の上流側の温度)
TTWC2 下流側温度(触媒の下流側の温度)
S_DTTWC 温度偏差積算値(上流側の温度に対する下流側の温度の上昇度合)
KDEGRA1 第1劣化補正係数(補正手段)
KDEGRA2 第2劣化補正係数(補正手段)
Claims (3)
- 内燃機関から排気系に排出された排ガスを浄化する内燃機関の排ガス浄化装置であって、
前記排気系に設けられ、排ガスを浄化するための酸化機能を有する触媒と、
前記排気系の前記触媒よりも下流側に設けられ、酸化雰囲気下で排ガス中のNOxを捕捉するとともに、還元雰囲気下で、捕捉したNOxを還元することによって浄化するNOx触媒と、
前記NOx触媒にNOxの還元動作を行わせるために、前記触媒の上流側に還元剤を供給することにより、前記NOx触媒に流入する排ガスを還元雰囲気に制御する還元制御を実行するNOx還元制御手段と、
前記触媒の劣化度合を推定する劣化度合推定手段と、
当該推定された触媒の劣化度合に応じて、前記NOx還元制御手段による還元制御の実行期間を補正する補正手段と、を備え、
前記劣化度合推定手段は、
前記触媒の上流側の温度を検出する上流側温度検出手段と、
前記触媒の下流側の温度を検出する下流側温度検出手段と、
前記触媒の温度を検出する触媒温度検出手段と、
前記還元制御の実行中に検出された前記上流側の温度に対する前記下流側の温度の上昇度合を算出する上昇度合算出手段と、
前記検出された触媒の温度が高いほど、前記算出された上昇度合をより低くなるように補正する上昇度合補正手段と、を有し、
当該補正された上昇度合が低いほど、前記触媒の劣化度合をより高くなるように推定することを特徴とする内燃機関の排ガス浄化装置。 - 前記NOx還元制御手段は、
前記NOx触媒に供給された還元剤供給量を算出する還元剤供給量算出手段と、
当該算出された還元剤供給量がしきい値を超えたときに、前記還元制御を終了する還元制御終了手段と、を有し、
前記補正手段は、前記推定された触媒の劣化度合が高いほど、前記しきい値をより小さくなるように補正することを特徴とする、請求項1に記載の内燃機関の排ガス浄化装置。 - 前記NOx還元制御手段は、
前記NOx触媒に供給された還元剤供給量を算出する還元剤供給量算出手段と、
当該算出された還元剤供給量がしきい値を超えたときに、前記還元制御を終了する還元制御終了手段と、を有し、
前記補正手段は、前記推定された触媒の劣化度合が高いほど、前記算出された還元剤供給量をより大きくなるように補正することを特徴とする、請求項1に記載の内燃機関の排ガス浄化装置。
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006317855A JP4733003B2 (ja) | 2006-11-24 | 2006-11-24 | 内燃機関の排ガス浄化装置 |
US11/942,039 US8117829B2 (en) | 2006-11-24 | 2007-11-19 | Exhaust emission control device and method for internal combustion engine, and engine control unit |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006317855A JP4733003B2 (ja) | 2006-11-24 | 2006-11-24 | 内燃機関の排ガス浄化装置 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008128217A JP2008128217A (ja) | 2008-06-05 |
JP4733003B2 true JP4733003B2 (ja) | 2011-07-27 |
Family
ID=39462299
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2006317855A Expired - Fee Related JP4733003B2 (ja) | 2006-11-24 | 2006-11-24 | 内燃機関の排ガス浄化装置 |
Country Status (2)
Country | Link |
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US (1) | US8117829B2 (ja) |
JP (1) | JP4733003B2 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4759496B2 (ja) * | 2006-11-24 | 2011-08-31 | 本田技研工業株式会社 | 内燃機関の排ガス浄化装置 |
WO2010134204A1 (ja) * | 2009-05-19 | 2010-11-25 | トヨタ自動車株式会社 | 内燃機関の排気浄化装置 |
WO2012047193A1 (en) * | 2010-10-04 | 2012-04-12 | International Engine Intellectual Property Company, Llc | Diagnostics for hydrocarbon injection for filter regeneration |
US9157391B2 (en) * | 2013-03-14 | 2015-10-13 | EMIT Technologies, Inc. | Systems and methods for controlling a combustion engine |
KR101518941B1 (ko) | 2013-12-23 | 2015-05-11 | 현대자동차 주식회사 | 선택적 환원 촉매의 제어 로직 보정 방법 및 이를 이용한 배기 장치 |
KR101905561B1 (ko) * | 2016-10-07 | 2018-11-21 | 현대자동차 주식회사 | 촉매 산소 퍼지 제어 장치 및 방법 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0350315A (ja) * | 1989-07-17 | 1991-03-04 | Nissan Motor Co Ltd | 触媒の劣化検出装置 |
JPH11200853A (ja) * | 1998-01-14 | 1999-07-27 | Nissan Motor Co Ltd | エンジンの排気浄化装置 |
JPH11311142A (ja) * | 1998-04-27 | 1999-11-09 | Denso Corp | 内燃機関の空燃比制御装置 |
JP2006017056A (ja) * | 2004-07-02 | 2006-01-19 | Honda Motor Co Ltd | 内燃機関の排ガス浄化装置 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5201802A (en) * | 1991-02-04 | 1993-04-13 | Toyota Jidosha Kabushiki Kaisha | Exhaust gas purification system for an internal combustion engine |
US5363647A (en) * | 1992-10-13 | 1994-11-15 | Mitsubishi Denki Kabushiki Kaisha | Dual-sensor type air fuel ratio control system for internal combustion engine and catalytic converter diagnosis apparatus for the same |
US6718756B1 (en) * | 1999-01-21 | 2004-04-13 | Mitsubishi Jidosha Kogyo Kabushiki Kaisha | Exhaust gas purifier for use in internal combustion engine |
JP3846375B2 (ja) * | 2002-07-10 | 2006-11-15 | トヨタ自動車株式会社 | 触媒劣化判定方法 |
-
2006
- 2006-11-24 JP JP2006317855A patent/JP4733003B2/ja not_active Expired - Fee Related
-
2007
- 2007-11-19 US US11/942,039 patent/US8117829B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0350315A (ja) * | 1989-07-17 | 1991-03-04 | Nissan Motor Co Ltd | 触媒の劣化検出装置 |
JPH11200853A (ja) * | 1998-01-14 | 1999-07-27 | Nissan Motor Co Ltd | エンジンの排気浄化装置 |
JPH11311142A (ja) * | 1998-04-27 | 1999-11-09 | Denso Corp | 内燃機関の空燃比制御装置 |
JP2006017056A (ja) * | 2004-07-02 | 2006-01-19 | Honda Motor Co Ltd | 内燃機関の排ガス浄化装置 |
Also Published As
Publication number | Publication date |
---|---|
US20080120965A1 (en) | 2008-05-29 |
JP2008128217A (ja) | 2008-06-05 |
US8117829B2 (en) | 2012-02-21 |
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