JP4724468B2 - 難燃性樹脂組成物およびそれを使用した成形品 - Google Patents
難燃性樹脂組成物およびそれを使用した成形品 Download PDFInfo
- Publication number
- JP4724468B2 JP4724468B2 JP2005159694A JP2005159694A JP4724468B2 JP 4724468 B2 JP4724468 B2 JP 4724468B2 JP 2005159694 A JP2005159694 A JP 2005159694A JP 2005159694 A JP2005159694 A JP 2005159694A JP 4724468 B2 JP4724468 B2 JP 4724468B2
- Authority
- JP
- Japan
- Prior art keywords
- modified
- resin composition
- retardant resin
- reactive functional
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011342 resin composition Substances 0.000 title claims description 71
- 239000003063 flame retardant Substances 0.000 title claims description 70
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 66
- 125000000524 functional group Chemical group 0.000 claims description 50
- 229920005989 resin Polymers 0.000 claims description 41
- 239000011347 resin Substances 0.000 claims description 41
- 150000001875 compounds Chemical class 0.000 claims description 29
- 229920005672 polyolefin resin Polymers 0.000 claims description 26
- 150000002736 metal compounds Chemical class 0.000 claims description 24
- 229920006465 Styrenic thermoplastic elastomer Polymers 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- -1 polypropylene Polymers 0.000 claims description 15
- 230000009257 reactivity Effects 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 11
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 10
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 239000004020 conductor Substances 0.000 claims description 9
- 239000000347 magnesium hydroxide Substances 0.000 claims description 9
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 9
- 239000012212 insulator Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 125000003700 epoxy group Chemical group 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 238000012360 testing method Methods 0.000 description 38
- 229920002725 thermoplastic elastomer Polymers 0.000 description 26
- 150000003440 styrenes Chemical class 0.000 description 20
- 238000001125 extrusion Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 13
- 229920001971 elastomer Polymers 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 230000032683 aging Effects 0.000 description 11
- 239000000945 filler Substances 0.000 description 10
- 238000000465 moulding Methods 0.000 description 10
- 239000000806 elastomer Substances 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000009413 insulation Methods 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000012790 confirmation Methods 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000009864 tensile test Methods 0.000 description 6
- 238000010894 electron beam technology Methods 0.000 description 5
- 230000003993 interaction Effects 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- 238000003466 welding Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000006057 Non-nutritive feed additive Substances 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 150000004292 cyclic ethers Chemical class 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000010292 electrical insulation Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 150000003018 phosphorus compounds Chemical class 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000010734 process oil Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000257465 Echinoidea Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000006078 metal deactivator Substances 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229920001384 propylene homopolymer Polymers 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YAXWOADCWUUUNX-UHFFFAOYSA-N 1,2,2,3-tetramethylpiperidine Chemical compound CC1CCCN(C)C1(C)C YAXWOADCWUUUNX-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- 241000473391 Archosargus rhomboidalis Species 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical group C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Inorganic Insulating Materials (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
- Insulating Bodies (AREA)
Description
また、加熱変形性の点から変性ポリプロピレンがより好ましい。このポリプロピレン樹脂を変性する反応性官能基としては、上記した変性スチレン系熱可塑性エラストマーと同様、水酸基、カルボキシル基及びその無水二量化物等のカルボニル基、エポキシ基などの3員環から6員環までの環状エーテル類、アミノ基、イソシアネート基などがある。
(基本的実施の形態の効果)
(第1の実施の形態)
(第2の実施の形態)
(第3の実施の形態)
(第4の実施の形態)
(第5の実施の形態)
(第6の実施の形態)
(実施例)
(比較例)
(絶縁線の場合の試験及び評価方法)
残率=(老化後の値)÷(常態の値)×100
加熱変形率=(加熱前の肉厚−加熱後の肉厚)÷(加熱前の肉厚)×100
メヤニ発生量(mg/km)=メヤニ採取重量×(1000÷線速)÷10
(ケーブルの外被の場合の試験及び評価方法)
残率=(老化後の値)÷(常態の値)×100
加熱変形率=(加熱前の肉厚一加熱後の肉厚)÷(加熱前の肉厚)×100
Claims (7)
- 水素添加スチレン系熱可塑性エラストマー30〜80重量部と、
反応性官能基によって変性された変性スチレン系熱可塑性エラストマー1〜50重量部と、
反応性官能基によって変性された変性ポリオレフィン樹脂5〜40重量部と、
1分子中に反応性官能基を複数もつ多官能化合物1〜30重量部とを配合した配合物の合計100重量部に対して、
水和金属化合物を150〜300重量部配合した難燃性樹脂組成物であって、
前記変性スチレン系熱可塑性エラストマー、前記変性ポリオレフィン樹脂、及び前記多官能化合物から任意に選択される2つの物質は、同一構造を持つ反応性官能基によって変性され、残りの物質の反応性官能基は前記2つの物質が持つ前記反応性官能基と反応性を有することを特徴とする難燃性樹脂組成物。 - 前記変性スチレン系熱可塑性エラストマー及び前記変性ポリオレフィン樹脂は、無水マレイン酸基によって変性されており、かつ前記多官能化合物の反応性官能基は、エポキシ基であることを特徴とする請求項1記載の難燃性樹脂組成物。
- 前記変性ポリオレフィン樹脂は、変性ポリプロピレン樹脂であることを特徴とする請求
項1記載の難燃性樹脂組成物。 - 前記水和金属化合物は、水酸化マグネシウムであることを特徴とする請求項1記載の難燃性樹脂組成物。
- 導体の外周に絶縁体を有する電線であって、前記絶縁体が請求項1乃至4のいずれかの難燃性樹脂組成物を有して構成されていることを特徴とする電線。
- 電線を束ねさらに外周に外被を有するケーブルであって、前記外被が請求項1乃至4のいずれかの難燃性樹脂組成物を有して構成されていることを特徴とするケーブル。
- 請求項1乃至4のいずれかに記載の難燃性樹脂組成物を有して構成されることを特徴とする電気絶縁チューブ。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005159694A JP4724468B2 (ja) | 2005-05-31 | 2005-05-31 | 難燃性樹脂組成物およびそれを使用した成形品 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005159694A JP4724468B2 (ja) | 2005-05-31 | 2005-05-31 | 難燃性樹脂組成物およびそれを使用した成形品 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006335811A JP2006335811A (ja) | 2006-12-14 |
JP4724468B2 true JP4724468B2 (ja) | 2011-07-13 |
Family
ID=37556654
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005159694A Active JP4724468B2 (ja) | 2005-05-31 | 2005-05-31 | 難燃性樹脂組成物およびそれを使用した成形品 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4724468B2 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6052042B2 (ja) * | 2013-04-26 | 2016-12-27 | 株式会社オートネットワーク技術研究所 | シラン架橋性難燃性組成物、絶縁電線及びその製造方法 |
CN109486086A (zh) * | 2018-12-29 | 2019-03-19 | 无锡鑫宏业特塑线缆有限公司 | 耐折弯无卤光伏电缆 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63172759A (ja) * | 1986-12-29 | 1988-07-16 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 低煙性ポリプロピレン絶縁組成物およびその製造方法 |
JP2001226536A (ja) * | 2000-02-18 | 2001-08-21 | Sumitomo Wiring Syst Ltd | オレフィン系樹脂組成物および被覆電線 |
JP2005135788A (ja) * | 2003-10-31 | 2005-05-26 | Hitachi Cable Ltd | ノンハロゲン難燃性電線及びノンハロゲン難燃性ケーブル |
JP2005213281A (ja) * | 2004-01-27 | 2005-08-11 | Asahi Kasei Chemicals Corp | 難燃性組成物 |
-
2005
- 2005-05-31 JP JP2005159694A patent/JP4724468B2/ja active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63172759A (ja) * | 1986-12-29 | 1988-07-16 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 低煙性ポリプロピレン絶縁組成物およびその製造方法 |
JP2001226536A (ja) * | 2000-02-18 | 2001-08-21 | Sumitomo Wiring Syst Ltd | オレフィン系樹脂組成物および被覆電線 |
JP2005135788A (ja) * | 2003-10-31 | 2005-05-26 | Hitachi Cable Ltd | ノンハロゲン難燃性電線及びノンハロゲン難燃性ケーブル |
JP2005213281A (ja) * | 2004-01-27 | 2005-08-11 | Asahi Kasei Chemicals Corp | 難燃性組成物 |
Also Published As
Publication number | Publication date |
---|---|
JP2006335811A (ja) | 2006-12-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI409322B (zh) | 無鹵素難燃性樹脂組成物及使用它之電線/電纜 | |
US10497489B2 (en) | Cable | |
JP5549675B2 (ja) | ノンハロゲン難燃性樹脂組成物およびそれを用いた電線・ケーブル | |
US9234088B2 (en) | Non-halogen flame-retardant resin composition, and insulated electric wire and tube using the same | |
JP6329948B2 (ja) | 耐熱性シラン架橋樹脂成形体及びその製造方法、並びに、耐熱性シラン架橋樹脂成形体を用いた耐熱性製品 | |
JP4255368B2 (ja) | 架橋型難燃性樹脂組成物ならびにこれを用いた絶縁電線およびワイヤーハーネス | |
JP5387944B2 (ja) | ハロゲンフリー難燃絶縁電線 | |
WO2011043259A1 (ja) | 難燃性樹脂組成物及びそれを用いた絶縁電線、フラットケーブル、成形品 | |
JP5569363B2 (ja) | 絶縁電線およびその製造方法 | |
JP2015000913A (ja) | ノンハロゲン難燃性樹脂組成物、並びにこれを用いた電線及びケーブル | |
JP4956234B2 (ja) | 難燃性樹脂組成物及び当該樹脂組成物を被覆した絶縁電線 | |
JP5182580B2 (ja) | ハロゲンフリー難燃絶縁電線 | |
KR20160127287A (ko) | 전선용 열가소성 수지 조성물 및 이로부터 제조된 절연 전선 | |
JP2005314516A (ja) | ノンハロゲン難燃性樹脂組成物 | |
JP5275547B2 (ja) | 難燃性樹脂組成物の製造方法 | |
JP2008239901A (ja) | 難燃性樹脂組成物及び当該樹脂組成物を被覆した絶縁電線 | |
JP3464410B2 (ja) | 絶縁樹脂組成物およびそれを用いた絶縁電線と絶縁部材 | |
JP4724468B2 (ja) | 難燃性樹脂組成物およびそれを使用した成形品 | |
JP2007197619A (ja) | ノンハロゲン難燃性樹脂組成物およびそれを用いた電線・ケーブル | |
KR100874538B1 (ko) | 내 컷스루 특성을 갖는 난연성이 개선된 절연재 제조용조성물, 절연전선, 전선용 절연재 및 절연재 제조방법 | |
CN111499950A (zh) | 无卤素树脂组合物、电线和电缆 | |
JP2006002117A (ja) | ノンハロゲン難燃性樹脂組成物及びそれを用いた電線・ケーブル | |
JP2020164695A (ja) | 樹脂組成物、及びそれを用いた配線材 | |
JP2006182875A (ja) | 難燃性熱可塑性樹脂組成物 | |
JP2006002029A (ja) | ポリオレフィン系難燃性樹脂組成物および耐熱性耐摩耗性難燃性絶縁電線 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080325 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100903 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100914 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101115 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110111 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110405 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110411 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140415 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4724468 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |