JP4608701B2 - 乳化重合方法およびその方法のための反応器 - Google Patents
乳化重合方法およびその方法のための反応器 Download PDFInfo
- Publication number
- JP4608701B2 JP4608701B2 JP2001536285A JP2001536285A JP4608701B2 JP 4608701 B2 JP4608701 B2 JP 4608701B2 JP 2001536285 A JP2001536285 A JP 2001536285A JP 2001536285 A JP2001536285 A JP 2001536285A JP 4608701 B2 JP4608701 B2 JP 4608701B2
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- JP
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- Prior art keywords
- reactor
- carrier liquid
- liquid
- emulsion polymerization
- cleaning liquid
- Prior art date
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- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 23
- 230000008569 process Effects 0.000 title claims abstract description 22
- 238000007720 emulsion polymerization reaction Methods 0.000 title claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 72
- 229920000642 polymer Polymers 0.000 claims abstract description 40
- 239000003381 stabilizer Substances 0.000 claims abstract description 29
- 239000000839 emulsion Substances 0.000 claims abstract description 28
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 238000005406 washing Methods 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims description 42
- 239000002245 particle Substances 0.000 claims description 34
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000010556 emulsion polymerization method Methods 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 20
- 238000001816 cooling Methods 0.000 description 23
- 239000008346 aqueous phase Substances 0.000 description 21
- 239000000203 mixture Substances 0.000 description 17
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- -1 chloric acid Alkali metal salt Chemical class 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
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- 239000012966 redox initiator Substances 0.000 description 4
- 229920001567 vinyl ester resin Polymers 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
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- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004908 Emulsion polymer Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
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- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical class O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical class [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
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- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- 229940001584 sodium metabisulfite Drugs 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
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- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical class [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- CVMIVKAWUQZOBP-UHFFFAOYSA-L manganic acid Chemical compound O[Mn](O)(=O)=O CVMIVKAWUQZOBP-UHFFFAOYSA-L 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- BUFQZEHPOKLSTP-UHFFFAOYSA-M sodium;oxido hydrogen sulfate Chemical compound [Na+].OS(=O)(=O)O[O-] BUFQZEHPOKLSTP-UHFFFAOYSA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical class OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/918—Polymerization reactors for addition polymer preparation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99309005 | 1999-11-11 | ||
| EP99309005.9 | 1999-11-11 | ||
| PCT/EP2000/009909 WO2001034293A1 (en) | 1999-11-11 | 2000-10-06 | Emulsion polymerization process and reactor for such a process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003514072A JP2003514072A (ja) | 2003-04-15 |
| JP2003514072A5 JP2003514072A5 (https=) | 2007-12-06 |
| JP4608701B2 true JP4608701B2 (ja) | 2011-01-12 |
Family
ID=8241728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001536285A Expired - Fee Related JP4608701B2 (ja) | 1999-11-11 | 2000-10-06 | 乳化重合方法およびその方法のための反応器 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6569961B1 (https=) |
| EP (1) | EP1230019B1 (https=) |
| JP (1) | JP4608701B2 (https=) |
| AT (1) | ATE298625T1 (https=) |
| AU (1) | AU7786600A (https=) |
| CA (1) | CA2390505C (https=) |
| DE (1) | DE60021103T2 (https=) |
| ES (1) | ES2243308T3 (https=) |
| WO (1) | WO2001034293A1 (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19754555A1 (de) | 1997-12-09 | 1999-06-24 | Clariant Gmbh | Verfahren zur Herstellung von Ethylen-Mischpolymerisaten und deren Verwendung als Zusatz zu Mineralöl und Mineralöldestillaten |
| JP4120382B2 (ja) * | 2002-12-12 | 2008-07-16 | 東ソー株式会社 | ペースト加工用塩化ビニル系重合体水性分散液の貯蔵方法 |
| US7858715B2 (en) * | 2005-09-12 | 2010-12-28 | Crown Brands Limited | Loop reactor for emulsion polymerisation |
| MY150051A (en) * | 2006-07-18 | 2013-11-29 | Celanese Int Corp | Emulsion polymerisation process |
| EP2125903B1 (en) * | 2006-07-18 | 2014-01-15 | Celanese International Corporation | Emulsion polymerisation process |
| EP2133141A1 (en) * | 2008-06-10 | 2009-12-16 | Nederlandse Organisatie voor Toegepast-Natuuurwetenschappelijk Onderzoek TNO | Process for carrying out multi-phase reactions |
| MX2009010135A (es) | 2009-09-22 | 2011-03-22 | Inst Mexicano Del Petroleo Star | Formulacion de polimeros aleatorios para mejorar flujo de crudos del petroleo. |
| CN103240142A (zh) * | 2013-05-22 | 2013-08-14 | 南京林业大学 | 一种树脂合成反应器 |
| DE102013226113A1 (de) * | 2013-12-16 | 2015-06-18 | Wacker Chemie Ag | Verfahren zum Applizieren von Dispersionsklebstoffen |
| US20160032023A1 (en) * | 2014-07-31 | 2016-02-04 | Celanese Emulsions Gmbh | Continuous emulsion polymerization process and initiation system |
| CN107793518A (zh) * | 2016-09-07 | 2018-03-13 | 中国石油化工股份有限公司 | 中和剂在控制eva弹性体乳液的乳液粒径中的应用 |
| CN107793520B (zh) * | 2016-09-07 | 2020-10-23 | 中国石油化工股份有限公司 | 一种制备聚乙烯-聚乙酸乙烯酯弹性体无皂微乳液的方法 |
| EP3784702B2 (de) | 2019-05-10 | 2024-10-02 | Wacker Chemie AG | Verfahren zur reinigung eines polymerisationsreaktors |
| CN119552295A (zh) * | 2023-09-01 | 2025-03-04 | 中国石油化工股份有限公司 | 丙烯酸酯橡胶的制备方法和丙烯酸酯橡胶及其应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2072904A (en) * | 1933-04-26 | 1937-03-09 | Du Pont | Polymerization of organic compounds |
| US3262922A (en) * | 1963-02-08 | 1966-07-26 | Phillips Petroleum Co | Polymerization process |
| DE1240286B (de) * | 1965-01-02 | 1967-05-11 | Basf Ag | Verfahren zur kontinuierlichen Emulsions-polymerisation olefinisch ungesaettigter Verbindungen |
| CH510066A (de) * | 1967-12-20 | 1971-07-15 | Dynamit Nobel Ag | Verfahren zur kontinuierlichen Polymerisation oder Copolymerisation in Emulsion von äthylenisch ungesättigten Verbindungen |
| US4121029A (en) * | 1976-12-06 | 1978-10-17 | Phillips Petroleum Company | Polyolefin reactor system |
| JPS56133302A (en) * | 1980-03-25 | 1981-10-19 | Nippon Zeon Co Ltd | Production of high-purity polymer by emulsion polymerization |
| IN158315B (https=) * | 1981-06-19 | 1986-10-18 | Mitsui Toatsu Chemicals | |
| GB8330804D0 (en) * | 1983-11-18 | 1983-12-29 | Reed Int Plc | Emulsion polymers |
| HU205030B (en) * | 1988-04-18 | 1992-03-30 | Nitrokemia Ipartelepek | Method for washing-off and recuperating sulfonating acid in the course of the production of strongly acidic cation-exchanging artificial resin |
| JPH10218907A (ja) * | 1997-02-05 | 1998-08-18 | Mitsubishi Chem Corp | 塩化ビニル系単量体の重合排水の利用方法 |
| JP3786316B2 (ja) * | 1997-06-20 | 2006-06-14 | 株式会社プライムポリマー | プロピレンの重合方法 |
| JPH11112308A (ja) | 1997-10-06 | 1999-04-23 | Nec Corp | 同期遅延回路装置 |
-
2000
- 2000-10-06 AT AT00967847T patent/ATE298625T1/de not_active IP Right Cessation
- 2000-10-06 JP JP2001536285A patent/JP4608701B2/ja not_active Expired - Fee Related
- 2000-10-06 DE DE60021103T patent/DE60021103T2/de not_active Expired - Lifetime
- 2000-10-06 WO PCT/EP2000/009909 patent/WO2001034293A1/en not_active Ceased
- 2000-10-06 CA CA002390505A patent/CA2390505C/en not_active Expired - Fee Related
- 2000-10-06 ES ES00967847T patent/ES2243308T3/es not_active Expired - Lifetime
- 2000-10-06 EP EP00967847A patent/EP1230019B1/en not_active Expired - Lifetime
- 2000-10-06 AU AU77866/00A patent/AU7786600A/en not_active Abandoned
- 2000-11-13 US US09/710,945 patent/US6569961B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2243308T3 (es) | 2005-12-01 |
| DE60021103D1 (de) | 2005-08-04 |
| JP2003514072A (ja) | 2003-04-15 |
| AU7786600A (en) | 2001-06-06 |
| DE60021103T2 (de) | 2006-05-18 |
| WO2001034293A1 (en) | 2001-05-17 |
| CA2390505A1 (en) | 2001-05-17 |
| CA2390505C (en) | 2007-06-19 |
| EP1230019A1 (en) | 2002-08-14 |
| ATE298625T1 (de) | 2005-07-15 |
| US6569961B1 (en) | 2003-05-27 |
| EP1230019B1 (en) | 2005-06-29 |
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