JP4582541B2 - 煙道ガスから二酸化炭素を除去及び捕捉する方法 - Google Patents
煙道ガスから二酸化炭素を除去及び捕捉する方法 Download PDFInfo
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- JP4582541B2 JP4582541B2 JP2004546051A JP2004546051A JP4582541B2 JP 4582541 B2 JP4582541 B2 JP 4582541B2 JP 2004546051 A JP2004546051 A JP 2004546051A JP 2004546051 A JP2004546051 A JP 2004546051A JP 4582541 B2 JP4582541 B2 JP 4582541B2
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- carbon dioxide
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 160
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 80
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 80
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000003546 flue gas Substances 0.000 title claims abstract description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 83
- 230000008929 regeneration Effects 0.000 claims abstract description 46
- 238000011069 regeneration method Methods 0.000 claims abstract description 46
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 39
- 239000011707 mineral Substances 0.000 claims abstract description 39
- 238000000638 solvent extraction Methods 0.000 claims abstract description 26
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims abstract description 15
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 150000001412 amines Chemical class 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 5
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 4
- 239000000378 calcium silicate Substances 0.000 claims description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical group [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 230000001172 regenerating effect Effects 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- -1 amine compounds Chemical class 0.000 description 4
- 235000012241 calcium silicate Nutrition 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 238000006482 condensation reaction Methods 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 230000009919 sequestration Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 2
- 159000000009 barium salts Chemical class 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical group [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052607 cyclosilicate Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052645 tectosilicate Inorganic materials 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1418—Recovery of products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Description
2RNH2+CO2→RHN3 ++NRH−CO2 − 及び/又は
RNH2+CO2+H2O→(RHN3)++HCO3 −
煙道ガスから二酸化炭素を除去及び捕捉する方法であって:
(a)溶媒抽出ゾーンにおいて煙道ガスを溶媒に接触させることにより煙道ガスから二酸化炭素を抽出して二酸化炭素の奪われた煙道ガスを得るステップ;
(b)二酸化炭素含有溶媒を溶媒再生温度に加熱しその温度で維持することにより溶媒再生ゾーン内で溶媒を再生して再生溶媒と二酸化炭素流を得るステップ;及び
(c)ステップ(b)で得られた二酸化炭素流を水溶液中に分散した2価アルカリ土類金属ケイ酸塩粒子と接触させることにより、鉱物炭酸塩化ゾーン内で二酸化炭素流とケイ酸塩を反応させるステップ
を含む方法
に関する。
(Mg,Ca)xSiyOx+2y+xCO2→x(Mg,Ca)CO3+ySiO2
溶媒再生ステップで得られた二酸化炭素流は、水又は電解質水溶液中に分散したケイ酸塩粒子と接触させられる。このような分散中では、二酸化炭素の一部が溶解し、HCO3 −又はCO3 2−イオンの形態にて部分的に存在し得ることが分かるであろう。
図1は、溶媒抽出ゾーン1、溶媒再生ゾーン2及び鉱物炭酸塩化ゾーン3を含んだ本発明による方法の典型的な工程案を示す。
2 溶媒再生ゾーン
3 鉱物炭酸塩化ゾーン
4、6、7、9、11、13、14、15、16、18、20 管路
5 溶媒抽出反応器
8 溶媒加熱反応器
10 溶媒再生反応器
12 熱交換器
17 冷却器
19 圧縮機
22 鉱物炭酸塩化反応器
21、23、24、25、26、27 管路
Claims (10)
- 煙道ガスから二酸化炭素を除去及び捕捉する方法であって:
(a)溶媒抽出ゾーンにおいて煙道ガスを溶媒に接触させることにより煙道ガスから二酸化炭素を抽出して二酸化炭素の奪われた煙道ガスを得るステップ;
(b)二酸化炭素含有溶媒を溶媒再生温度に加熱しその温度で維持することにより溶媒再生ゾーン内で溶媒を再生して再生溶媒と二酸化炭素流を得るステップ;及び
(c)ステップ(b)で得られた二酸化炭素流を水溶液中に分散した2価アルカリ土類金属ケイ酸塩粒子と接触させることにより、鉱物炭酸塩化ゾーン内で二酸化炭素流とケイ酸塩を反応させるステップ
を含み、ステップ(c)で放出された熱をステップ(b)で使用する前記方法。 - ステップ(b)に必要な熱の少なくとも50%を、ステップ(c)で放出された熱により供給する請求項1に記載の方法。
- ステップ(b)に必要な熱の少なくとも65%を、ステップ(c)で放出された熱により供給する請求項1又は2に記載の方法。
- 鉱物炭酸塩化ゾーンの動作温度が溶媒再生温度より25℃〜35℃高い請求項1〜3のいずれか一項に記載の方法。
- 溶媒再生温度が100℃〜200℃である請求項1〜4のいずれか一項に記載の方法。
- ステップ(b)で得られた二酸化炭素流を、鉱物炭酸塩化ゾーンでケイ酸塩と反応する前に、3〜15バール(絶対)の範囲の圧力に加圧する請求項1〜5のいずれか一項に記載の方法。
- 鉱物炭酸塩化ゾーンの動作温度が140〜200℃の範囲にある請求項1〜6のいずれか一項に記載の方法。
- 前記溶媒がアミン水溶液である請求項1〜7のいずれか一項に記載の方法。
- 2価アルカリ土類金属ケイ酸塩がケイ酸マグネシウム又はケイ酸カルシウムである請求項1〜8のいずれか一項に記載の方法。
- ケイ酸塩粒子の平均直径が0.5mm以下である請求項1〜9のいずれか一項に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02079415 | 2002-10-23 | ||
PCT/EP2003/050753 WO2004037391A1 (en) | 2002-10-23 | 2003-10-23 | Process for removal and capture of carbon dioxide from flue gases |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006503692A JP2006503692A (ja) | 2006-02-02 |
JP4582541B2 true JP4582541B2 (ja) | 2010-11-17 |
Family
ID=32116286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004546051A Expired - Fee Related JP4582541B2 (ja) | 2002-10-23 | 2003-10-23 | 煙道ガスから二酸化炭素を除去及び捕捉する方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US20040126293A1 (ja) |
EP (1) | EP1554031B1 (ja) |
JP (1) | JP4582541B2 (ja) |
AT (1) | ATE348654T1 (ja) |
AU (1) | AU2003301647A1 (ja) |
CA (1) | CA2503096C (ja) |
DE (1) | DE60310594T2 (ja) |
NO (1) | NO20052434L (ja) |
WO (1) | WO2004037391A1 (ja) |
Families Citing this family (73)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002085788A1 (en) * | 2001-04-20 | 2002-10-31 | Shell Internationale Research Maatschappij B.V. | Process for mineral carbonation with carbon dioxide |
US7282189B2 (en) * | 2003-04-09 | 2007-10-16 | Bert Zauderer | Production of hydrogen and removal and sequestration of carbon dioxide from coal-fired furnaces and boilers |
US7722842B2 (en) * | 2003-12-31 | 2010-05-25 | The Ohio State University | Carbon dioxide sequestration using alkaline earth metal-bearing minerals |
US8864876B2 (en) * | 2005-02-14 | 2014-10-21 | Neumann Systems Group, Inc. | Indirect and direct method of sequestering contaminates |
US7379487B2 (en) | 2005-02-14 | 2008-05-27 | Neumann Information Systems, Inc. | Two phase reactor |
US8398059B2 (en) | 2005-02-14 | 2013-03-19 | Neumann Systems Group, Inc. | Gas liquid contactor and method thereof |
EP1951424A1 (en) | 2005-11-23 | 2008-08-06 | Shell Internationale Research Maatschappij B.V. | A process for sequestration of carbon dioxide by mineral carbonation |
WO2007068682A1 (en) * | 2005-12-12 | 2007-06-21 | Shell Internationale Research Maatschappij B.V. | Enhanced oil recovery process and a process for the sequestration of carbon dioxide |
KR101464010B1 (ko) | 2006-11-22 | 2014-11-20 | 오리카 익스플로시브스 테크놀로지 피티와이 리미티드 | 통합 화학 공정 |
US20080277319A1 (en) * | 2007-05-11 | 2008-11-13 | Wyrsta Michael D | Fine particle carbon dioxide transformation and sequestration |
WO2008148055A1 (en) * | 2007-05-24 | 2008-12-04 | Calera Corporation | Hydraulic cements comprising carbonate compounds compositions |
US7753618B2 (en) * | 2007-06-28 | 2010-07-13 | Calera Corporation | Rocks and aggregate, and methods of making and using the same |
CA2659451C (en) | 2007-06-28 | 2011-04-12 | Calera Corporation | Desalination methods and systems that include carbonate compound precipitation |
WO2009003238A1 (en) * | 2007-07-03 | 2009-01-08 | Dut Pty Ltd | Improvements in the recovery of carbon dioxide |
AU2008292143B2 (en) * | 2007-08-30 | 2011-12-08 | Shell Internationale Research Maatschappij B.V. | Process for removal of hydrogen sulphide and carbon dioxide from an acid gas stream |
EP2205341B1 (en) | 2007-09-20 | 2012-02-01 | Skyonic Corporation | Removing carbon dioxide from waste gas streams through co-generation of carbonate and/or bicarbonate minerals |
US8012453B2 (en) * | 2007-10-25 | 2011-09-06 | Surendra Saxena | Carbon sequestration and production of hydrogen and hydride |
DE102007062413B3 (de) * | 2007-12-20 | 2009-09-10 | Conera Process Solutions Gmbh | Verfahren und Vorrichtung zur Wiederaufbereitung von CO2-haltigen Abgasen |
US7749476B2 (en) * | 2007-12-28 | 2010-07-06 | Calera Corporation | Production of carbonate-containing compositions from material comprising metal silicates |
US20100239467A1 (en) | 2008-06-17 | 2010-09-23 | Brent Constantz | Methods and systems for utilizing waste sources of metal oxides |
KR20100105860A (ko) | 2007-12-28 | 2010-09-30 | 칼레라 코포레이션 | Co2 분리 방법 |
US7754169B2 (en) | 2007-12-28 | 2010-07-13 | Calera Corporation | Methods and systems for utilizing waste sources of metal oxides |
US7919064B2 (en) * | 2008-02-12 | 2011-04-05 | Michigan Technological University | Capture and sequestration of carbon dioxide in flue gases |
JP5194944B2 (ja) * | 2008-03-28 | 2013-05-08 | 東京電力株式会社 | 二酸化炭素の鉱物固定システム |
US8359856B2 (en) | 2008-04-09 | 2013-01-29 | Sustainx Inc. | Systems and methods for efficient pumping of high-pressure fluids for energy storage and recovery |
US8225606B2 (en) | 2008-04-09 | 2012-07-24 | Sustainx, Inc. | Systems and methods for energy storage and recovery using rapid isothermal gas expansion and compression |
US8250863B2 (en) | 2008-04-09 | 2012-08-28 | Sustainx, Inc. | Heat exchange with compressed gas in energy-storage systems |
EP2127726A1 (en) | 2008-05-29 | 2009-12-02 | Shell Internationale Researchmaatschappij B.V. | Method of regenerating a loaded sorbent using concentrated solar power and an apparatus therefor |
FI121216B (fi) * | 2008-06-30 | 2010-08-31 | Cuycha Innovation Oy | Menetelmä hiilidioksidin liuottamiseksi savu- tai muusta kaasusta ja saadun liuoksen happamuuden neutralisoimiseksi |
WO2010009273A1 (en) | 2008-07-16 | 2010-01-21 | Calera Corporation | Co2 utilization in electrochemical systems |
CA2700721C (en) | 2008-07-16 | 2015-04-21 | Calera Corporation | Low-energy 4-cell electrochemical system with carbon dioxide gas |
US7993500B2 (en) | 2008-07-16 | 2011-08-09 | Calera Corporation | Gas diffusion anode and CO2 cathode electrolyte system |
CN101868806A (zh) | 2008-09-11 | 2010-10-20 | 卡勒拉公司 | 二氧化碳商品交易系统和方法 |
CA2737946C (en) | 2008-09-26 | 2016-11-15 | The Ohio State University | Conversion of carbonaceous fuels into carbon free energy carriers |
US7939336B2 (en) | 2008-09-30 | 2011-05-10 | Calera Corporation | Compositions and methods using substances containing carbon |
US8869477B2 (en) | 2008-09-30 | 2014-10-28 | Calera Corporation | Formed building materials |
US7815880B2 (en) | 2008-09-30 | 2010-10-19 | Calera Corporation | Reduced-carbon footprint concrete compositions |
US7771684B2 (en) | 2008-09-30 | 2010-08-10 | Calera Corporation | CO2-sequestering formed building materials |
TW201033121A (en) | 2008-10-31 | 2010-09-16 | Calera Corp | Non-cementitious compositions comprising CO2 sequestering additives |
US9133581B2 (en) | 2008-10-31 | 2015-09-15 | Calera Corporation | Non-cementitious compositions comprising vaterite and methods thereof |
EP2291550A4 (en) * | 2008-12-23 | 2011-03-09 | Calera Corp | ELECTROMECHANICAL LOW-ENERGY HYDROXIDE SYSTEM AND METHOD |
US8834688B2 (en) | 2009-02-10 | 2014-09-16 | Calera Corporation | Low-voltage alkaline production using hydrogen and electrocatalytic electrodes |
CA2694959A1 (en) | 2009-03-02 | 2010-09-02 | Calera Corporation | Gas stream multi-pollutants control systems and methods |
US20100224503A1 (en) * | 2009-03-05 | 2010-09-09 | Kirk Donald W | Low-energy electrochemical hydroxide system and method |
US20100229725A1 (en) | 2009-03-10 | 2010-09-16 | Kasra Farsad | Systems and Methods for Processing CO2 |
US7993511B2 (en) | 2009-07-15 | 2011-08-09 | Calera Corporation | Electrochemical production of an alkaline solution using CO2 |
CN102695670B (zh) | 2009-09-08 | 2016-02-24 | 俄亥俄州立大学研究基金会 | 具有集成的碳捕集的重整/水裂解和用于发电的电化学系统的集成 |
CN102597173A (zh) | 2009-09-08 | 2012-07-18 | 俄亥俄州立大学研究基金会 | 具有原位co2捕集的合成燃料和化学品生产 |
EP2335813A1 (en) | 2009-12-01 | 2011-06-22 | Shell Internationale Research Maatschappij B.V. | Method and apparatus for the removal of a sorbate component from a process stream with subsequent regeneration of the sorbent using solar energy |
US20110147653A1 (en) * | 2009-12-22 | 2011-06-23 | Caterpillar Inc. | Preparation method for gas absorbent material |
KR20130000394A (ko) * | 2010-02-19 | 2013-01-02 | 코몬웰스 싸이언티픽 엔드 인더스트리얼 리서치 오가니제이션 | 용매 처리 방법 |
US8171728B2 (en) | 2010-04-08 | 2012-05-08 | Sustainx, Inc. | High-efficiency liquid heat exchange in compressed-gas energy storage systems |
CN107673352A (zh) | 2010-07-08 | 2018-02-09 | 斯凯约尼克公司 | 涉及基于两种盐的散热方法的二氧化碳封存 |
US8425655B2 (en) * | 2010-07-09 | 2013-04-23 | Carbon Capture Scientific, Llc | Gas pressurized separation column and process to generate a high pressure product gas |
WO2012028418A1 (en) | 2010-09-02 | 2012-03-08 | Novacem Limited | Integrated process for producing compositions containing magnesium |
US10010847B2 (en) | 2010-11-08 | 2018-07-03 | Ohio State Innovation Foundation | Circulating fluidized bed with moving bed downcomers and gas sealing between reactors |
EP2707583B1 (en) | 2011-05-11 | 2019-07-10 | Ohio State Innovation Foundation | Oxygen carrying materials |
CA2835419C (en) | 2011-05-11 | 2020-06-02 | Ohio State Innovation Foundation | Systems for converting fuel |
KR20140031319A (ko) | 2011-05-17 | 2014-03-12 | 서스테인쓰, 인크. | 압축 공기 에너지 저장 시스템 내의 효율적인 2상 열전달을 위한 시스템 및 방법 |
WO2013065880A1 (ko) * | 2011-10-31 | 2013-05-10 | 한국전력공사 | 건식 이산화탄소 포집 공정용 아민 또는 그 화합물을 포함하는 고체 이산화탄소 흡수제 및 그 제조방법 |
KR101419589B1 (ko) * | 2012-07-03 | 2014-07-16 | 연세대학교 산학협력단 | 이산화탄소 흡수제 및 이의 재생방법 |
CN105358475B (zh) | 2013-02-05 | 2018-12-04 | 俄亥俄州国家创新基金会 | 用于燃料转化的方法 |
US9616403B2 (en) | 2013-03-14 | 2017-04-11 | Ohio State Innovation Foundation | Systems and methods for converting carbonaceous fuels |
WO2015109190A1 (en) | 2014-01-17 | 2015-07-23 | Skyonic Corporation | Acid gas removal from a gaseous stream |
US20150238915A1 (en) | 2014-02-27 | 2015-08-27 | Ohio State Innovation Foundation | Systems and methods for partial or complete oxidation of fuels |
KR102537634B1 (ko) | 2015-02-23 | 2023-05-31 | 카본프리 케미칼스 홀딩스, 엘엘씨 | 수산화마그네슘을 사용하는 이산화탄소의 격리 및 수산화마그네슘의 재생성 |
EP3429738A4 (en) | 2016-04-12 | 2019-09-18 | Ohio State Innovation Foundation | PRODUCTION OF CHEMICAL LOOP SYNTHESIS GAS FROM CARBON FUELS |
US11090624B2 (en) | 2017-07-31 | 2021-08-17 | Ohio State Innovation Foundation | Reactor system with unequal reactor assembly operating pressures |
US10549236B2 (en) | 2018-01-29 | 2020-02-04 | Ohio State Innovation Foundation | Systems, methods and materials for NOx decomposition with metal oxide materials |
WO2020033500A1 (en) | 2018-08-09 | 2020-02-13 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
US11453626B2 (en) | 2019-04-09 | 2022-09-27 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
IT201900019256A1 (it) | 2019-10-18 | 2021-04-18 | Eni Spa | Processo per la mineralizzazione della co2 con fasi minerali naturali e utilizzo dei prodotti ottenuti |
WO2022195540A1 (en) * | 2021-03-17 | 2022-09-22 | Carboncure Technologies Inc. | Compositions and methods to couple carbon dioxide capture and waste heat |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1697722A (en) * | 1925-04-03 | 1929-01-01 | Deguide Camille | Process for recovering barium as barium carbonate from barium silicates |
FR685992A (fr) * | 1930-10-07 | 1930-07-21 | Girdler Corp | Perfectionnements à la séparation des gaz entre eux |
US1934472A (en) * | 1930-10-30 | 1933-11-07 | Albert S Allen | Method of separating carbon dioxide from a gas mixture |
SE420596B (sv) * | 1975-03-25 | 1981-10-19 | Osaka Packing | Formad kropp av amorf kiseldioxid, eventuellt innehallande kalciumkarbonat, sett att framstella en formad kropp av amorf kiseldioxid samt partikel av amorf kiseldioxid for framstellning av en formad kropp |
US4696803A (en) * | 1986-02-13 | 1987-09-29 | Texaco Inc. | Treatment of gas streams for removal of acid gases |
JPH05231A (ja) * | 1991-02-12 | 1993-01-08 | Chiyoda Corp | 燃焼排ガスのco2 除去方法 |
JP2792777B2 (ja) * | 1992-01-17 | 1998-09-03 | 関西電力株式会社 | 燃焼排ガス中の炭酸ガスの除去方法 |
JP3094093B2 (ja) * | 1997-03-11 | 2000-10-03 | 科学技術庁無機材質研究所長 | アルカリ土類珪酸塩によるco2の固定化方法 |
US6174506B1 (en) * | 1999-06-10 | 2001-01-16 | Praxair Technology, Inc. | Carbon dioxide recovery from an oxygen containing mixture |
US6497852B2 (en) * | 2000-12-22 | 2002-12-24 | Shrikar Chakravarti | Carbon dioxide recovery at high pressure |
JP3437174B2 (ja) * | 2001-04-12 | 2003-08-18 | 沖電気工業株式会社 | 省電力化集積回路および省電力化集積回路の制御方法 |
WO2002085788A1 (en) * | 2001-04-20 | 2002-10-31 | Shell Internationale Research Maatschappij B.V. | Process for mineral carbonation with carbon dioxide |
EP1951424A1 (en) * | 2005-11-23 | 2008-08-06 | Shell Internationale Research Maatschappij B.V. | A process for sequestration of carbon dioxide by mineral carbonation |
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2003
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- 2003-10-23 EP EP03809352A patent/EP1554031B1/en not_active Expired - Lifetime
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CA2503096A1 (en) | 2004-05-06 |
DE60310594D1 (de) | 2007-02-01 |
CA2503096C (en) | 2012-01-10 |
ATE348654T1 (de) | 2007-01-15 |
NO20052434L (no) | 2005-05-20 |
EP1554031B1 (en) | 2006-12-20 |
DE60310594T2 (de) | 2007-08-09 |
EP1554031A1 (en) | 2005-07-20 |
US20040126293A1 (en) | 2004-07-01 |
WO2004037391A1 (en) | 2004-05-06 |
AU2003301647A1 (en) | 2004-05-13 |
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