JP4580241B2 - 蛍光増白剤の混合物 - Google Patents
蛍光増白剤の混合物 Download PDFInfo
- Publication number
- JP4580241B2 JP4580241B2 JP2004558099A JP2004558099A JP4580241B2 JP 4580241 B2 JP4580241 B2 JP 4580241B2 JP 2004558099 A JP2004558099 A JP 2004558099A JP 2004558099 A JP2004558099 A JP 2004558099A JP 4580241 B2 JP4580241 B2 JP 4580241B2
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- formula
- weight
- compound
- optical brighteners
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 230000003287 optical effect Effects 0.000 title claims description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 229920000728 polyester Polymers 0.000 abstract description 10
- 230000002087 whitening effect Effects 0.000 abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 239000012209 synthetic fiber Substances 0.000 abstract description 3
- 229920002994 synthetic fiber Polymers 0.000 abstract description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000000034 method Methods 0.000 description 9
- -1 tert-amyl (1,1-dimethylpropyl) Chemical group 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 3
- 238000009998 heat setting Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 125000004924 2-naphthylethyl group Chemical group C1=C(C=CC2=CC=CC=C12)CC* 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- CLWOHDDTHJOGOJ-UHFFFAOYSA-N 3,6-bis(2-phenylethenyl)benzene-1,2-dicarbonitrile Chemical compound C1=CC(C=CC=2C=CC=CC=2)=C(C#N)C(C#N)=C1C=CC1=CC=CC=C1 CLWOHDDTHJOGOJ-UHFFFAOYSA-N 0.000 description 1
- KBKUMWYMXOAMKS-UHFFFAOYSA-N 4-[2-[1-cyano-4-(2-phenylethenyl)cyclohexa-2,4-dien-1-yl]ethenyl]benzonitrile Chemical compound C1=CC(C#N)=CC=C1C=CC1(C#N)C=CC(C=CC=2C=CC=CC=2)=CC1 KBKUMWYMXOAMKS-UHFFFAOYSA-N 0.000 description 1
- UQRONKZLYKUEMO-UHFFFAOYSA-N 4-methyl-1-(2,4,6-trimethylphenyl)pent-4-en-2-one Chemical group CC(=C)CC(=O)Cc1c(C)cc(C)cc1C UQRONKZLYKUEMO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229920001586 anionic polysaccharide Polymers 0.000 description 1
- 150000004836 anionic polysaccharides Chemical class 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- KHKQTRJMBORFEK-UHFFFAOYSA-N ethane-1,2-diamine;oxirane Chemical compound C1CO1.NCCN KHKQTRJMBORFEK-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000010016 exhaust dyeing Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000004923 naphthylmethyl group Chemical group C1(=CC=CC2=CC=CC=C12)C* 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical compound OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 description 1
- 125000005561 phenanthryl group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/614—Optical bleaching or brightening in aqueous solvents
- D06L4/636—Optical bleaching or brightening in aqueous solvents with disperse brighteners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/65—Optical bleaching or brightening with mixtures of optical brighteners
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02406084 | 2002-12-10 | ||
| PCT/EP2003/050913 WO2004053221A1 (en) | 2002-12-10 | 2003-12-01 | Mixtures of fluorescent whitening agents |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006509087A JP2006509087A (ja) | 2006-03-16 |
| JP2006509087A5 JP2006509087A5 (enExample) | 2007-01-11 |
| JP4580241B2 true JP4580241B2 (ja) | 2010-11-10 |
Family
ID=32479850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004558099A Expired - Fee Related JP4580241B2 (ja) | 2002-12-10 | 2003-12-01 | 蛍光増白剤の混合物 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7497971B2 (enExample) |
| EP (1) | EP1570122B1 (enExample) |
| JP (1) | JP4580241B2 (enExample) |
| CN (1) | CN100338296C (enExample) |
| AT (1) | ATE413489T1 (enExample) |
| AU (1) | AU2003298335A1 (enExample) |
| BR (1) | BR0317151A (enExample) |
| DE (1) | DE60324588D1 (enExample) |
| ES (1) | ES2316862T3 (enExample) |
| MX (1) | MXPA05005771A (enExample) |
| TW (1) | TW200413596A (enExample) |
| WO (1) | WO2004053221A1 (enExample) |
| ZA (1) | ZA200503644B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005019189A1 (en) * | 2003-08-21 | 2005-03-03 | Ciba Specialty Chemicals Holding Inc. | Optical brighteners |
| CN103314154B (zh) * | 2011-01-20 | 2016-09-14 | 亨斯迈先进材料（瑞士）有限公司 | 分散形式的荧光增白剂制剂 |
| CN105019221A (zh) * | 2014-08-20 | 2015-11-04 | 太仓市璜泾太华化纤助剂厂 | 一种提高化纤白度的化纤助剂 |
| GB2551487A (en) * | 2016-06-15 | 2017-12-27 | Reckitt Benckiser Vanish Bv | Composition |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH577062B5 (enExample) * | 1973-09-05 | 1976-06-30 | Ciba Geigy Ag | |
| US4105399A (en) * | 1973-09-05 | 1978-08-08 | Ciba-Geigy Corporation | Optically brightening with a synergistic mixture |
| DE2807497A1 (de) * | 1978-02-22 | 1979-08-23 | Bayer Ag | Distyryl-verbindungen |
| DE2929687A1 (de) * | 1979-07-21 | 1981-02-12 | Hoechst Ag | Mischungen von optischen aufhellern |
| CH650792A5 (en) * | 1979-12-13 | 1985-08-15 | Ciba Geigy Ag | Optical brighteners from bisstyrylbenzene compounds and preparation thereof |
| EP0030917B2 (de) * | 1979-12-13 | 1991-03-20 | Ciba-Geigy Ag | Optische Aufheller aus Bis-styrylbenzolverbindungen, Verfahren zu deren Herstellung und deren Verwendung |
| DE3313332A1 (de) * | 1983-04-13 | 1984-10-18 | Hoechst Ag, 6230 Frankfurt | Mischungen von optischen aufhellern zum aufhellen von polyvinylchlorid |
| DE3769352D1 (de) * | 1986-04-02 | 1991-05-23 | Ciba Geigy Ag | Mischungen von optischen aufhellern. |
| DE3878540D1 (de) * | 1987-11-27 | 1993-03-25 | Ciba Geigy Ag | Aufhellerdispersion. |
| ES2053807T3 (es) * | 1987-11-27 | 1994-08-01 | Ciba Geigy Ag | Dispersion blanqueadora acuosa y procedimiento para su preparacion. |
| DE19732109A1 (de) * | 1997-07-25 | 1999-01-28 | Clariant Gmbh | Mischungen von optischen Aufhellern |
| TWI255304B (en) * | 1999-09-06 | 2006-05-21 | Ciba Sc Holding Ag | Mixtures of fluorescent whitening agents |
| TWI252270B (en) * | 2000-07-20 | 2006-04-01 | Ciba Sc Holding Ag | A method for the fluorescent whitening of cotton |
| US7425222B2 (en) * | 2002-02-18 | 2008-09-16 | Ciba Specialty Chemicals Corp. | Process for improving the sun protection factor of cellulosic fibre material |
| AU2003227043A1 (en) * | 2002-03-18 | 2003-09-29 | Ciba Specialty Chemicals Holding Inc. | A process for improving the sun protection factor of cellulosic fibre material |
| DE10219993A1 (de) * | 2002-05-03 | 2003-11-20 | Basf Ag | Verfahren zum Aufhellen von textilen Materialien |
-
2003
- 2003-12-01 ES ES03796069T patent/ES2316862T3/es not_active Expired - Lifetime
- 2003-12-01 JP JP2004558099A patent/JP4580241B2/ja not_active Expired - Fee Related
- 2003-12-01 DE DE60324588T patent/DE60324588D1/de not_active Expired - Lifetime
- 2003-12-01 BR BR0317151-5A patent/BR0317151A/pt not_active Application Discontinuation
- 2003-12-01 AU AU2003298335A patent/AU2003298335A1/en not_active Abandoned
- 2003-12-01 WO PCT/EP2003/050913 patent/WO2004053221A1/en not_active Ceased
- 2003-12-01 CN CNB2003801055478A patent/CN100338296C/zh not_active Expired - Fee Related
- 2003-12-01 EP EP03796069A patent/EP1570122B1/en not_active Expired - Lifetime
- 2003-12-01 MX MXPA05005771A patent/MXPA05005771A/es active IP Right Grant
- 2003-12-01 US US10/537,062 patent/US7497971B2/en not_active Expired - Fee Related
- 2003-12-01 AT AT03796069T patent/ATE413489T1/de not_active IP Right Cessation
- 2003-12-08 TW TW092134543A patent/TW200413596A/zh unknown
-
2005
- 2005-05-06 ZA ZA200503644A patent/ZA200503644B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN100338296C (zh) | 2007-09-19 |
| US20060048309A1 (en) | 2006-03-09 |
| JP2006509087A (ja) | 2006-03-16 |
| AU2003298335A1 (en) | 2004-06-30 |
| BR0317151A (pt) | 2005-11-01 |
| ATE413489T1 (de) | 2008-11-15 |
| WO2004053221A1 (en) | 2004-06-24 |
| MXPA05005771A (es) | 2005-08-16 |
| TW200413596A (en) | 2004-08-01 |
| CN1723311A (zh) | 2006-01-18 |
| EP1570122B1 (en) | 2008-11-05 |
| ES2316862T3 (es) | 2009-04-16 |
| ZA200503644B (en) | 2006-07-26 |
| US7497971B2 (en) | 2009-03-03 |
| DE60324588D1 (de) | 2008-12-18 |
| EP1570122A1 (en) | 2005-09-07 |
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