JP4550818B2 - 過塩素酸アンモニウム含有ガス発生剤 - Google Patents
過塩素酸アンモニウム含有ガス発生剤 Download PDFInfo
- Publication number
- JP4550818B2 JP4550818B2 JP2006521969A JP2006521969A JP4550818B2 JP 4550818 B2 JP4550818 B2 JP 4550818B2 JP 2006521969 A JP2006521969 A JP 2006521969A JP 2006521969 A JP2006521969 A JP 2006521969A JP 4550818 B2 JP4550818 B2 JP 4550818B2
- Authority
- JP
- Japan
- Prior art keywords
- composition
- weight percent
- ammonium perchlorate
- gas generant
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 title claims description 105
- 239000000203 mixture Substances 0.000 claims description 296
- 239000007789 gas Substances 0.000 claims description 217
- 239000000460 chlorine Substances 0.000 claims description 70
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 68
- 229910052801 chlorine Inorganic materials 0.000 claims description 68
- 239000010949 copper Substances 0.000 claims description 55
- 229910052802 copper Inorganic materials 0.000 claims description 53
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 52
- 238000002485 combustion reaction Methods 0.000 claims description 50
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 47
- 239000002245 particle Substances 0.000 claims description 42
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 34
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 33
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 32
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 32
- 239000002516 radical scavenger Substances 0.000 claims description 32
- 239000000654 additive Substances 0.000 claims description 27
- 229910044991 metal oxide Inorganic materials 0.000 claims description 26
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 24
- 150000004706 metal oxides Chemical class 0.000 claims description 24
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 23
- 239000000446 fuel Substances 0.000 claims description 22
- 230000000996 additive effect Effects 0.000 claims description 21
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 claims description 20
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 19
- 150000004985 diamines Chemical class 0.000 claims description 19
- 239000002893 slag Substances 0.000 claims description 18
- 230000002708 enhancing effect Effects 0.000 claims description 16
- -1 amine nitrates Chemical class 0.000 claims description 15
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 13
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 claims description 11
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 11
- UGWHPQNZVGJHMU-UHFFFAOYSA-Q triazanium trinitrate Chemical compound [NH4+].[NH4+].[NH4+].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O UGWHPQNZVGJHMU-UHFFFAOYSA-Q 0.000 claims description 10
- YTNLBRCAVHCUPD-UHFFFAOYSA-N 5-(1$l^{2},2,3,4-tetrazol-5-yl)-1$l^{2},2,3,4-tetrazole Chemical compound [N]1N=NN=C1C1=NN=N[N]1 YTNLBRCAVHCUPD-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229960004643 cupric oxide Drugs 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- FGHAZDVJHATENE-UHFFFAOYSA-N [N-]=[N+]=[N-].[N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH6+3] Chemical compound [N-]=[N+]=[N-].[N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH6+3] FGHAZDVJHATENE-UHFFFAOYSA-N 0.000 claims 1
- 150000001879 copper Chemical class 0.000 claims 1
- WXYNCCWBUXKSBG-UHFFFAOYSA-N copper;nitric acid Chemical compound [Cu].O[N+]([O-])=O WXYNCCWBUXKSBG-UHFFFAOYSA-N 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- 239000002243 precursor Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000007800 oxidant agent Substances 0.000 description 14
- 230000001590 oxidative effect Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 239000006227 byproduct Substances 0.000 description 10
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 10
- 239000000049 pigment Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 8
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 8
- 229940045803 cuprous chloride Drugs 0.000 description 8
- 229910004013 NO 2 Inorganic materials 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 6
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 6
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 6
- 230000001965 increasing effect Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 5
- 229910017840 NH 3 Inorganic materials 0.000 description 5
- 239000010426 asphalt Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000013618 particulate matter Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 2
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910001510 metal chloride Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910001120 nichrome Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005502 peroxidation Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000013638 trimer Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000000441 X-ray spectroscopy Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- UDPYNCXWXQWOTC-UHFFFAOYSA-O azanium copper trinitrate Chemical compound [NH4+].[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O UDPYNCXWXQWOTC-UHFFFAOYSA-O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/02—Compositions characterised by non-explosive or non-thermic constituents for neutralising poisonous gases from explosives produced during blasting
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B29/00—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
- C06B29/22—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate the salt being ammonium perchlorate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Air Bags (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/627,433 US20050016646A1 (en) | 2003-07-25 | 2003-07-25 | Chlorine-containing gas generant compositions including a copper-containing chlorine scavenger |
| PCT/US2004/024016 WO2005012208A2 (en) | 2003-07-25 | 2004-07-26 | Ammonium perchlorate-containing gas generants |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007500124A JP2007500124A (ja) | 2007-01-11 |
| JP2007500124A5 JP2007500124A5 (enExample) | 2007-07-26 |
| JP4550818B2 true JP4550818B2 (ja) | 2010-09-22 |
Family
ID=34080639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006521969A Expired - Fee Related JP4550818B2 (ja) | 2003-07-25 | 2004-07-26 | 過塩素酸アンモニウム含有ガス発生剤 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US20050016646A1 (enExample) |
| EP (1) | EP1648844B1 (enExample) |
| JP (1) | JP4550818B2 (enExample) |
| CN (1) | CN100579941C (enExample) |
| WO (1) | WO2005012208A2 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060289096A1 (en) * | 2003-07-25 | 2006-12-28 | Mendenhall Ivan V | Extrudable gas generant |
| US8101033B2 (en) * | 2004-07-26 | 2012-01-24 | Autoliv Asp, Inc. | Alkali metal perchlorate-containing gas generants |
| JP4767487B2 (ja) * | 2003-10-20 | 2011-09-07 | ダイセル化学工業株式会社 | ガス発生剤組成物 |
| US20050098246A1 (en) * | 2003-11-07 | 2005-05-12 | Mendenhall Ivan V. | Burn rate enhancement via metal aminotetrazole hydroxides |
| FR2892117B1 (fr) * | 2005-10-13 | 2008-05-02 | Snpe Materiaux Energetiques Sa | Composition pyrotechnique generatrice de gaz rapide et procede d'obtention |
| US7758709B2 (en) * | 2006-06-21 | 2010-07-20 | Autoliv Asp, Inc. | Monolithic gas generant grains |
| US9193639B2 (en) * | 2007-03-27 | 2015-11-24 | Autoliv Asp, Inc. | Methods of manufacturing monolithic generant grains |
| US8057611B2 (en) * | 2007-08-13 | 2011-11-15 | Autoliv Asp, Inc. | Multi-composition pyrotechnic grain |
| US8815029B2 (en) * | 2008-04-10 | 2014-08-26 | Autoliv Asp, Inc. | High performance gas generating compositions |
| US8808476B2 (en) | 2008-11-12 | 2014-08-19 | Autoliv Asp, Inc. | Gas generating compositions having glass fibers |
| FR2975097B1 (fr) * | 2011-05-09 | 2015-11-20 | Sme | Composes pyrotechniques generateurs de gaz |
| US8657333B2 (en) | 2011-07-27 | 2014-02-25 | Autoliv Asp, Inc. | Inflator device with fuel-rich monolithic grain and oxidant-enhanced combustion |
| US8980023B2 (en) | 2011-07-27 | 2015-03-17 | Autoliv Asp, Inc. | Gas generation via elemental carbon-based compositions |
| CN102992926A (zh) * | 2012-12-13 | 2013-03-27 | 煤炭科学研究总院 | 一种厌氧性压控发热剂及其用途 |
| US20140261927A1 (en) * | 2013-03-13 | 2014-09-18 | Autoliv Asp, Inc. | Enhanced slag formation for copper-containing gas generants |
| US9051223B2 (en) | 2013-03-15 | 2015-06-09 | Autoliv Asp, Inc. | Generant grain assembly formed of multiple symmetric pieces |
| WO2016109851A1 (en) * | 2015-01-04 | 2016-07-07 | Thync, Inc. | Methods and apparatuses for transdermal stimulation of the outer ear |
| JP1550021S (enExample) * | 2015-02-20 | 2016-05-23 | ||
| JP1552868S (enExample) * | 2015-02-20 | 2016-06-27 | ||
| CN106631645B (zh) * | 2016-09-30 | 2018-09-21 | 唐山师范学院 | 二氧化碳相变致裂用发热剂 |
| CN106478324B (zh) * | 2016-09-30 | 2018-09-21 | 唐山师范学院 | 二氧化碳气体爆破器用发热剂 |
| CN114539011B (zh) * | 2022-02-21 | 2023-03-28 | 张延松 | 一种安全高效的高能膨胀剂及其制备方法与应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3656432A (en) * | 1969-05-26 | 1972-04-18 | Thiokol Chemical Corp | Granular ammonium perchlorate propellant |
| FR2266674A1 (en) * | 1974-04-08 | 1975-10-31 | Aerojet General Co | Solid propellant compns - contg. porous ammonium inorg. salt particles coated with polymer |
| JPH0794359B2 (ja) * | 1991-11-01 | 1995-10-11 | 旭化成工業株式会社 | 過塩素酸アンモニウムコンポジット推進薬 |
| JPH05294773A (ja) * | 1992-04-23 | 1993-11-09 | Nissan Motor Co Ltd | コンポジット推進薬 |
| US5518054A (en) | 1993-12-10 | 1996-05-21 | Morton International, Inc. | Processing aids for gas generants |
| CA2181543C (en) * | 1994-01-19 | 1999-04-20 | Jerald C. Hinshaw | Metal complexes for use as gas generants |
| US5725699A (en) * | 1994-01-19 | 1998-03-10 | Thiokol Corporation | Metal complexes for use as gas generants |
| DE4442169C1 (de) * | 1994-11-26 | 1995-12-21 | Fraunhofer Ges Forschung | Gaserzeugende Mischung |
| US5641938A (en) | 1995-03-03 | 1997-06-24 | Primex Technologies, Inc. | Thermally stable gas generating composition |
| US5670740A (en) | 1995-10-06 | 1997-09-23 | Morton International, Inc. | Heterogeneous gas generant charges |
| US5608183A (en) * | 1996-03-15 | 1997-03-04 | Morton International, Inc. | Gas generant compositions containing amine nitrates plus basic copper (II) nitrate and/or cobalt(III) triammine trinitrate |
| US5635668A (en) | 1996-03-15 | 1997-06-03 | Morton International, Inc. | Gas generant compositions containing copper nitrate complexes |
| US5959242A (en) * | 1996-05-14 | 1999-09-28 | Talley Defense Systems, Inc. | Autoignition composition |
| EP0958264B1 (en) * | 1996-07-25 | 2011-06-01 | Alliant Techsystems Inc. | Metal complexes for use as gas generants |
| US5861571A (en) * | 1997-04-18 | 1999-01-19 | Atlantic Research Corporation | Gas-generative composition consisting essentially of ammonium perchlorate plus a chlorine scavenger and an organic fuel |
| FR2772370B1 (fr) | 1997-12-12 | 2000-01-07 | Poudres & Explosifs Ste Nale | Compositions pyrotechniques generatrices de gaz non toxiques a base de perchlorate d'ammonium |
| DE29722912U1 (de) | 1997-12-29 | 1998-02-19 | TRW Airbag Systems GmbH & Co. KG, 84544 Aschau | Azidfreie gaserzeugende Zusammensetzung |
| DE29806504U1 (de) * | 1998-04-08 | 1998-08-06 | TRW Airbag Systems GmbH & Co. KG, 84544 Aschau | Azidfreie, gaserzeugende Zusammensetzung |
| US6096147A (en) * | 1998-07-30 | 2000-08-01 | Autoliv Asp, Inc. | Ignition enhanced gas generant and method |
| US6132538A (en) * | 1998-07-30 | 2000-10-17 | Autoliv Development Ab | High gas yield generant compositions |
| US6051158A (en) * | 1998-07-30 | 2000-04-18 | Autoliv Asp, Inc. | Treatment of airbag inflation gases |
| US6136113A (en) * | 1998-08-07 | 2000-10-24 | Atlantic Research Corporation | Gas generating composition |
| US6045638A (en) * | 1998-10-09 | 2000-04-04 | Atlantic Research Corporation | Monopropellant and propellant compositions including mono and polyaminoguanidine dinitrate |
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| JP2000219589A (ja) * | 1999-01-27 | 2000-08-08 | Daicel Chem Ind Ltd | ガス発生剤用燃料及びガス発生剤組成物 |
| US6077372A (en) * | 1999-02-02 | 2000-06-20 | Autoliv Development Ab | Ignition enhanced gas generant and method |
| US6143102A (en) * | 1999-05-06 | 2000-11-07 | Autoliv Asp, Inc. | Burn rate-enhanced basic copper nitrate-containing gas generant compositions and methods |
| DE19932466A1 (de) * | 1999-07-12 | 2001-01-18 | Trw Airbag Sys Gmbh & Co Kg | Azidfreie gaserzeugende Zusammensetzung |
| DE10009819A1 (de) * | 2000-03-01 | 2001-09-06 | Trw Airbag Sys Gmbh & Co Kg | Verfahren zur Herstellung von Treibstoff-Formlingen |
| JP2002012492A (ja) * | 2000-06-22 | 2002-01-15 | Nof Corp | プリテンショナー用ガス発生剤組成物 |
| US6436211B1 (en) * | 2000-07-18 | 2002-08-20 | Autoliv Asp, Inc. | Gas generant manufacture |
| FR2818636B1 (fr) * | 2000-12-22 | 2003-02-28 | Poudres & Explosifs Ste Nale | Compositions pyrotechniques generatrices de gaz a liant hydrocarbone et procede de fabrication en continu |
| JP3972628B2 (ja) * | 2001-10-23 | 2007-09-05 | 日本油脂株式会社 | ガス発生剤組成物及びガス発生器 |
| US6712918B2 (en) | 2001-11-30 | 2004-03-30 | Autoliv Asp, Inc. | Burn rate enhancement via a transition metal complex of diammonium bitetrazole |
| US6875295B2 (en) * | 2001-12-27 | 2005-04-05 | Trw Inc. | Cool burning gas generating material for a vehicle occupant protection apparatus |
| DE10230402B4 (de) | 2002-07-05 | 2007-01-11 | Trw Airbag Systems Gmbh & Co. Kg | Verfahren zur Herstellung einer gaserzeugenden Zusammensetzung |
| US6958101B2 (en) | 2003-04-11 | 2005-10-25 | Autoliv Asp, Inc. | Substituted basic metal nitrates in gas generation |
-
2003
- 2003-07-25 US US10/627,433 patent/US20050016646A1/en not_active Abandoned
-
2004
- 2004-07-26 CN CN200480021318A patent/CN100579941C/zh not_active Expired - Fee Related
- 2004-07-26 JP JP2006521969A patent/JP4550818B2/ja not_active Expired - Fee Related
- 2004-07-26 EP EP04779190.0A patent/EP1648844B1/en not_active Expired - Lifetime
- 2004-07-26 WO PCT/US2004/024016 patent/WO2005012208A2/en not_active Ceased
- 2004-07-26 US US10/899,451 patent/US7147733B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1648844A2 (en) | 2006-04-26 |
| US7147733B2 (en) | 2006-12-12 |
| US20050016646A1 (en) | 2005-01-27 |
| WO2005012208A2 (en) | 2005-02-10 |
| CN100579941C (zh) | 2010-01-13 |
| CN1826301A (zh) | 2006-08-30 |
| US20050067076A1 (en) | 2005-03-31 |
| EP1648844B1 (en) | 2016-03-16 |
| WO2005012208A3 (en) | 2005-12-22 |
| EP1648844A4 (en) | 2010-12-08 |
| JP2007500124A (ja) | 2007-01-11 |
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