JP4521731B2 - ガラスおよびセラミック基材をコーティングするための方法および組成物 - Google Patents
ガラスおよびセラミック基材をコーティングするための方法および組成物 Download PDFInfo
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- JP4521731B2 JP4521731B2 JP2006520416A JP2006520416A JP4521731B2 JP 4521731 B2 JP4521731 B2 JP 4521731B2 JP 2006520416 A JP2006520416 A JP 2006520416A JP 2006520416 A JP2006520416 A JP 2006520416A JP 4521731 B2 JP4521731 B2 JP 4521731B2
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Classifications
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
- C03C17/326—Epoxy resins
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/48—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
- C03C2217/485—Pigments
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- Chemical & Material Sciences (AREA)
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- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Composite Materials (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49020903P | 2003-07-25 | 2003-07-25 | |
| PCT/US2004/023277 WO2005012199A1 (en) | 2003-07-25 | 2004-07-21 | Method and compositions for coating glass and ceramic substrates |
| US10/895,739 US20050025891A1 (en) | 2003-07-25 | 2004-07-21 | Method and compositions for coating ceramic substrates |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009092520A Division JP2009149913A (ja) | 2003-07-25 | 2009-04-06 | ガラスおよびセラミック基材をコーティングするための方法および組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007523820A JP2007523820A (ja) | 2007-08-23 |
| JP4521731B2 true JP4521731B2 (ja) | 2010-08-11 |
Family
ID=34107830
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006520416A Expired - Fee Related JP4521731B2 (ja) | 2003-07-25 | 2004-07-21 | ガラスおよびセラミック基材をコーティングするための方法および組成物 |
| JP2009092520A Pending JP2009149913A (ja) | 2003-07-25 | 2009-04-06 | ガラスおよびセラミック基材をコーティングするための方法および組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009092520A Pending JP2009149913A (ja) | 2003-07-25 | 2009-04-06 | ガラスおよびセラミック基材をコーティングするための方法および組成物 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20050025891A1 (enExample) |
| EP (1) | EP1658244A1 (enExample) |
| JP (2) | JP4521731B2 (enExample) |
| KR (1) | KR100765583B1 (enExample) |
| AR (1) | AR045106A1 (enExample) |
| AU (1) | AU2004261569B2 (enExample) |
| BR (1) | BRPI0412829A (enExample) |
| CA (1) | CA2531357C (enExample) |
| MX (1) | MXPA06000756A (enExample) |
| PE (1) | PE20050641A1 (enExample) |
| RU (1) | RU2378230C2 (enExample) |
| WO (1) | WO2005012199A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070087118A1 (en) * | 2003-06-19 | 2007-04-19 | Tang Robert H | Method and compositions with nonexpandable or expanded beads for coating ceramic substrates |
| US20050069714A1 (en) * | 2003-09-30 | 2005-03-31 | Hart Terence J. | Method and compositions for improving durability of coated or decorated ceramic substrates |
| RU2473523C1 (ru) * | 2011-05-27 | 2013-01-27 | Государственное образовательное учреждение высшего профессионального образования "Российский государственный педагогический университет им. А.И. Герцена" | Паста для декорирования |
| DE102014018464A1 (de) * | 2014-12-12 | 2016-06-16 | Schott Ag | Thermochrome pigmente, thermochrome beschichtung, verfahren zu deren herstellung sowie deren verwendung |
| US9871176B2 (en) | 2015-02-02 | 2018-01-16 | Ferro Corporation | Glass compositions and glass frit composites for use in optical applications |
| DE102015122034A1 (de) | 2015-12-16 | 2017-06-22 | Ferro Gmbh | Thermoplastische Siebdruckpaste |
| ES2781403T3 (es) | 2017-03-17 | 2020-09-01 | Anheuser Busch Inbev Sa | Método para la fabricación de un recipiente de vidrio que tiene una imagen impresa por chorro de tinta |
| KR102383584B1 (ko) * | 2017-11-30 | 2022-04-11 | 쌩-고벵 글래스 프랑스 | 인쇄 코팅된 패널을 생산하는 방법 |
| DE102018109102A1 (de) * | 2018-04-17 | 2019-10-17 | Schott Ag | Bedruckte Gerätekomponente |
Family Cites Families (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3386848A (en) * | 1964-10-05 | 1968-06-04 | Neville Chemical Co | Epoxy resin ink for printing on glass |
| US3471312A (en) * | 1965-10-21 | 1969-10-07 | Morton Int Inc | Epoxy coated substrate and method of making same |
| US3425859A (en) * | 1965-10-23 | 1969-02-04 | Owens Illinois Inc | Glass surfaces having dual protective,label accepting coatings and method |
| US3468835A (en) * | 1966-02-04 | 1969-09-23 | Neville Chemical Co | Cold color printing compositions |
| US3507680A (en) * | 1966-09-09 | 1970-04-21 | Owens Illinois Inc | Glass substrate coated with modified or non-modified organopolysiloxane |
| US3607349A (en) | 1969-05-07 | 1971-09-21 | Neville Chemical Co | Printing on substrates such as glass using epoxy resin ink compositions |
| US3712829A (en) * | 1969-11-28 | 1973-01-23 | Owens Illinois Inc | Lubricious,label-accepting glass surface coating |
| US3854267A (en) * | 1971-03-15 | 1974-12-17 | Tile Council Of America | Grout compositions |
| US3872044A (en) * | 1972-09-25 | 1975-03-18 | Ferro Corp | Thermoplastic screen process inks |
| US3903339A (en) * | 1973-05-25 | 1975-09-02 | Liberty Glass Co | Glass container coated with plastic containment film and method of making |
| US4171228A (en) * | 1976-05-19 | 1979-10-16 | Lowrey Hugh W | Pigment composition for high build protective coating |
| NZ186925A (en) * | 1977-04-25 | 1979-12-11 | Ici Ltd | Top-coating based on a basecoat and top-coat compositions not requiring an intermediate baking operation |
| US4195104A (en) * | 1978-05-25 | 1980-03-25 | American Can Company | Videojet ink composition |
| JPS56133370A (en) * | 1980-03-25 | 1981-10-19 | Kansai Paint Co Ltd | Slurry coating composition capable of forming multilayer coating film |
| JPS57134493A (en) * | 1981-02-12 | 1982-08-19 | Sankin Kogyo Kk | Phosphoric ester derivative |
| US4533715A (en) * | 1983-09-07 | 1985-08-06 | Hexcel Corporation | Single package epoxy resin system |
| SU1191433A1 (ru) * | 1984-02-08 | 1985-11-15 | Институт механики металлополимерных систем АН БССР | Защитное покрытие дл стекла и способ его нанесени |
| US4620993A (en) * | 1984-03-30 | 1986-11-04 | Ppg Industries, Inc. | Color plus clear coating system utilizing organo-modified clay in combination with organic polymer microparticles |
| DE3587822T2 (de) * | 1984-12-13 | 1994-10-27 | Morton Int Inc | Grundieranstrich-Zusammensetzung und Verfahren zu deren Herstellung. |
| SU1564131A1 (ru) * | 1988-05-18 | 1990-05-15 | Гусевский Филиал Государственного Научно-Исследовательского Института Стекла | Состав дл покрыти стеклоизделий |
| JP2601717B2 (ja) * | 1989-02-27 | 1997-04-16 | ハニー化成株式会社 | ガラス積層体 |
| US4957801A (en) * | 1989-05-17 | 1990-09-18 | American Cyanamid Company | Advance composites with thermoplastic particles at the interface between layers |
| US6124401A (en) * | 1989-10-06 | 2000-09-26 | Ferro Corporation | Thermoplastic coating compositions and process using same |
| JP2889991B2 (ja) * | 1990-08-31 | 1999-05-10 | ハニー化成株式会社 | ガラス用被覆組成物 |
| US5268223A (en) * | 1991-05-31 | 1993-12-07 | Amoco Corporation | Toughened fiber-reinforced composites |
| CA2074896C (en) * | 1992-07-29 | 2002-07-30 | Linh Ngo Phong | Process for making cuo superconductors |
| US5346933A (en) * | 1992-12-30 | 1994-09-13 | Cerdec Corporation | Thermoplastic/thermosettable coatings or inks for glass, ceramic and other hard surfaces |
| JP3315004B2 (ja) * | 1993-05-14 | 2002-08-19 | 旭硝子株式会社 | 表面処理された基材およびその製造方法 |
| DE69412168T2 (de) * | 1993-05-14 | 1998-12-10 | Asahi Glass Co. Ltd., Tokio/Tokyo | Oberflächenbehandeltes Substrat und Verfahren zu seiner Herstellung |
| JPH073188A (ja) * | 1993-06-18 | 1995-01-06 | Cemedine Co Ltd | 水性耐チッピング塗料用組成物 |
| US5478885A (en) * | 1994-04-15 | 1995-12-26 | Shell Oil Company | Composition of epoxy resin, epoxidized block polydiene and curing agent |
| JP3385163B2 (ja) * | 1995-09-04 | 2003-03-10 | 吉野電化工業株式会社 | 電磁波シールド及びその形成方法 |
| US5656336A (en) * | 1996-03-08 | 1997-08-12 | Revlon Consumer Products Corporation | Glass decorating method using bis-phenol-a epoxy resins and related compositions and articles |
| US5736602A (en) * | 1996-04-09 | 1998-04-07 | Crocker; George L. | Retroreflective coating composition for coil coating application, method for application, and articles produced therefrom |
| TW336251B (en) * | 1996-06-19 | 1998-07-11 | Matsumoto Yushi Seiyaku Kk | A stripping resistant paint |
| JPH1025332A (ja) * | 1996-07-09 | 1998-01-27 | Asahi Chem Ind Co Ltd | 水性ブロックポリイソシアネート組成物の製造方法 |
| DE19628341C2 (de) * | 1996-07-13 | 1998-09-17 | Sihl Gmbh | Aufzeichnungsmaterial für Tintenstrahlverfahren mit wäßriger Tinte und Verwendung zum Herstellen wasserfester und lichtbeständiger Aufzeichnungen auf diesem Material |
| DE19632664B4 (de) * | 1996-08-14 | 2004-09-23 | Schott Glas | Glasfläschchen mit einem umspritzten Kunststoffüberzug, Verfahren zu seiner Herstellung und Vorrichtung zur Durchführung des Verfahrens |
| US6093455A (en) * | 1997-05-23 | 2000-07-25 | Deco Patents, Inc. | Method and compositions for decorating glass |
| US6074761A (en) * | 1997-06-13 | 2000-06-13 | Ppg Industries Ohio, Inc. | Inkjet printing media |
| US6077563A (en) * | 1997-11-10 | 2000-06-20 | Cerdec Corporation | Overprintable thermoset decorating inks and method of application |
| US6136382A (en) * | 1997-12-29 | 2000-10-24 | Deco Patents, Inc. | Method and compositions for decorating vitreous articles with radiation curable inks having improved adhesion and durability |
| US6025068A (en) * | 1998-02-13 | 2000-02-15 | Ppg Industries Ohio, Inc. | Inkjet printable coating for microporous materials |
| US6096408A (en) * | 1998-06-08 | 2000-08-01 | Avery Dennison Corporation | Heat-transfer label and method of decorating polyethylene-coated glass using same |
| US6562172B1 (en) * | 1998-08-17 | 2003-05-13 | Deco Patents, Inc. | Glass decorating method using ink compositions containing N-vinyl lactams |
| US6207077B1 (en) * | 2000-02-18 | 2001-03-27 | Orion 21 A.D. Pty Ltd | Luminescent gel coats and moldable resins |
| US6797746B2 (en) * | 1998-12-22 | 2004-09-28 | Vidriera Monterrey, S.A. De C.V. | Ultraviolet radiation curable ink composition and a process for its application on glass substrates |
| US6214414B1 (en) | 1999-07-22 | 2001-04-10 | Ppg Industries Ohio, Inc. | Method for forming a sequence of crosslinked pigmented coatings on ceramic substrates |
| JP2001314811A (ja) * | 2000-05-10 | 2001-11-13 | Nippon Paint Co Ltd | 高意匠性複層塗膜形成方法 |
| JP2002047452A (ja) * | 2000-08-01 | 2002-02-12 | Nisshin Steel Co Ltd | 材料表面の摺動性改善用塗料、その塗装方法及び塗装物ならびに上記塗装物を用いた自動販売機のシューター |
| US6403222B1 (en) * | 2000-09-22 | 2002-06-11 | Henkel Corporation | Wax-modified thermosettable compositions |
| US6451876B1 (en) * | 2000-10-10 | 2002-09-17 | Henkel Corporation | Two component thermosettable compositions useful for producing structural reinforcing adhesives |
| US6709756B2 (en) * | 2001-05-21 | 2004-03-23 | Shin-Etsu Chemical Co., Ltd. | Optical device-related adhesive and optical device |
| US6709758B2 (en) * | 2001-11-09 | 2004-03-23 | Lord Corporation | Room temperature curable X-HNBR coating |
| US7157119B2 (en) * | 2002-06-25 | 2007-01-02 | Ppg Industries Ohio, Inc. | Method and compositions for applying multiple overlying organic pigmented decorations on ceramic substrates |
| US7150901B2 (en) * | 2003-12-05 | 2006-12-19 | Eastman Kodak Company | Plasma treatment of porous inkjet receivers |
-
2004
- 2004-07-21 EP EP04757142A patent/EP1658244A1/en not_active Withdrawn
- 2004-07-21 US US10/895,739 patent/US20050025891A1/en not_active Abandoned
- 2004-07-21 JP JP2006520416A patent/JP4521731B2/ja not_active Expired - Fee Related
- 2004-07-21 AU AU2004261569A patent/AU2004261569B2/en not_active Ceased
- 2004-07-21 CA CA2531357A patent/CA2531357C/en not_active Expired - Fee Related
- 2004-07-21 BR BRPI0412829-0A patent/BRPI0412829A/pt not_active Application Discontinuation
- 2004-07-21 KR KR1020067001335A patent/KR100765583B1/ko not_active Expired - Fee Related
- 2004-07-21 WO PCT/US2004/023277 patent/WO2005012199A1/en not_active Ceased
- 2004-07-21 MX MXPA06000756A patent/MXPA06000756A/es unknown
- 2004-07-21 RU RU2006105507/03A patent/RU2378230C2/ru not_active IP Right Cessation
- 2004-07-26 PE PE2004000724A patent/PE20050641A1/es not_active Application Discontinuation
- 2004-07-26 AR ARP040102636A patent/AR045106A1/es active IP Right Grant
-
2009
- 2009-04-06 JP JP2009092520A patent/JP2009149913A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| PE20050641A1 (es) | 2005-08-16 |
| EP1658244A1 (en) | 2006-05-24 |
| BRPI0412829A (pt) | 2006-09-26 |
| US20050025891A1 (en) | 2005-02-03 |
| CA2531357A1 (en) | 2005-02-10 |
| MXPA06000756A (es) | 2006-03-30 |
| RU2006105507A (ru) | 2006-07-10 |
| KR20060052846A (ko) | 2006-05-19 |
| AR045106A1 (es) | 2005-10-19 |
| KR100765583B1 (ko) | 2007-10-09 |
| AU2004261569B2 (en) | 2007-02-22 |
| JP2007523820A (ja) | 2007-08-23 |
| JP2009149913A (ja) | 2009-07-09 |
| RU2378230C2 (ru) | 2010-01-10 |
| AU2004261569A1 (en) | 2005-02-10 |
| CA2531357C (en) | 2010-09-21 |
| WO2005012199A1 (en) | 2005-02-10 |
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