JP4516955B2 - ホログラフィックセンサー及びその製造 - Google Patents
ホログラフィックセンサー及びその製造 Download PDFInfo
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- JP4516955B2 JP4516955B2 JP2006500256A JP2006500256A JP4516955B2 JP 4516955 B2 JP4516955 B2 JP 4516955B2 JP 2006500256 A JP2006500256 A JP 2006500256A JP 2006500256 A JP2006500256 A JP 2006500256A JP 4516955 B2 JP4516955 B2 JP 4516955B2
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- Prior art keywords
- polymer
- medium
- sensor
- holographic
- crosslinking
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title description 6
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 229920000642 polymer Polymers 0.000 claims description 42
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 238000004132 cross linking Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- 230000008961 swelling Effects 0.000 claims description 9
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 235000010323 ascorbic acid Nutrition 0.000 claims description 4
- 239000011668 ascorbic acid Substances 0.000 claims description 4
- 229960005070 ascorbic acid Drugs 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 229920006037 cross link polymer Polymers 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- 239000011159 matrix material Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 8
- 102100026735 Coagulation factor VIII Human genes 0.000 description 7
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- GJKGAPPUXSSCFI-UHFFFAOYSA-N 2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone Chemical compound CC(C)(O)C(=O)C1=CC=C(OCCO)C=C1 GJKGAPPUXSSCFI-UHFFFAOYSA-N 0.000 description 5
- UJKWLAZYSLJTKA-UHFFFAOYSA-N edma Chemical compound O1CCOC2=CC(CC(C)NC)=CC=C21 UJKWLAZYSLJTKA-UHFFFAOYSA-N 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- -1 silver halide Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 108010010803 Gelatin Proteins 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 239000012085 test solution Substances 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000012491 analyte Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000017 hydrogel Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000012062 aqueous buffer Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000001427 coherent effect Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- ZMLXKXHICXTSDM-UHFFFAOYSA-N n-[1,2-dihydroxy-2-(prop-2-enoylamino)ethyl]prop-2-enamide Chemical compound C=CC(=O)NC(O)C(O)NC(=O)C=C ZMLXKXHICXTSDM-UHFFFAOYSA-N 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YERHJBPPDGHCRJ-UHFFFAOYSA-N 1-[4-(1-oxoprop-2-enyl)-1-piperazinyl]-2-propen-1-one Chemical compound C=CC(=O)N1CCN(C(=O)C=C)CC1 YERHJBPPDGHCRJ-UHFFFAOYSA-N 0.000 description 1
- ZCXVJRGWDAFVTK-UHFFFAOYSA-N 2,3-dihydroxyocta-2,6-dienediamide Chemical compound NC(=O)C=CCCC(O)=C(O)C(N)=O ZCXVJRGWDAFVTK-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- WIYVVIUBKNTNKG-UHFFFAOYSA-N 6,7-dimethoxy-3,4-dihydronaphthalene-2-carboxylic acid Chemical group C1CC(C(O)=O)=CC2=C1C=C(OC)C(OC)=C2 WIYVVIUBKNTNKG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 229920000936 Agarose Polymers 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- ONQPQIFFWHMGGE-UHFFFAOYSA-L barium(2+);prop-2-enoate Chemical compound [Ba+2].[O-]C(=O)C=C.[O-]C(=O)C=C ONQPQIFFWHMGGE-UHFFFAOYSA-L 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 239000012949 free radical photoinitiator Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
- G01N21/4788—Diffraction
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/32—Holograms used as optical elements
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H1/024—Hologram nature or properties
- G03H1/0248—Volume holograms
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/0005—Adaptation of holography to specific applications
- G03H2001/0033—Adaptation of holography to specific applications in hologrammetry for measuring or analysing
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H2001/026—Recording materials or recording processes
- G03H2001/0264—Organic recording material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/22—Processes or apparatus for obtaining an optical image from holograms
- G03H1/2286—Particular reconstruction light ; Beam properties
- G03H2001/2289—Particular reconstruction light ; Beam properties when reconstruction wavelength differs form recording wavelength
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2210/00—Object characteristics
- G03H2210/63—Environment affecting the recording, e.g. underwater
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2260/00—Recording materials or recording processes
- G03H2260/12—Photopolymer
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Optics & Photonics (AREA)
- Holo Graphy (AREA)
- Burglar Alarm Systems (AREA)
Description
DMPA=2,2−ジメトキシ−2−フェニルアセトフェノン
HEMA=ヒドロキシエチルメタクリレート
MAA=メタクリル酸
EDMA=エチレンジメタクリレート
DMAEM=2−(ジメチルアミノ)エチルメタクリレート
DHEBA=ジヒドロキシエチレンビスアクリルアミド
MBA=メチレンビスアクリルアミド
BAP=ビス(アクリロイル)ピペラジン
2−プロパノール 4.0ml
DMPA 25mg
HEMA 3.65ml(30mmole)
MAA 0.84ml(10mmole)
EDMA 0.18(0.5mmole)
「XL1」
DMPA 25mg
メタノール 7.0ml
EDMA 2.0ml
HEMA 0.20ml
エタンジオール 0.020ml
脱イオン水 0.020ml
DMPA 20mg
2−プロパノール 3.0ml
HEMA 2.43ml
EDMA 0.21ml
DMAEM 0.37ml
XL2はXL1と同じである。
DMPA 15mg
メタノール 0.20ml
脱イオン水 4.0ml
アクリルアミド 2.0g
メタクリルアミド 1.0g
DHEBA 0.126g
イタコン酸 40mg
「XL3」
メタノール 10ml
DMPA 15mg
脱イオン水 9ml
エタンジオール 1.0ml
MBA 1.2g
(後者を溶解させるため、約50℃まで加熱する必要がある。)
架橋剤BAPを使用するXL4は以下のとおりである。
BAP 2.5g
Irgacure 2959 0.05g
メタノール 2.5ml
脱イオン水 4.0ml
エタンジオール 2.0ml
XL4は、実施例1〜3のアクリルアミドポリマー(A)のいずれか一つの中に浸透した後、良好に作用する。
屈折率の高い重金属塩を含むXL5は以下のとおりである。
Irgacure 2959 15mg
メタノール 1.0ml
アクリルアミド 0.50g
ジアクリル酸バリウム(1.5M水溶液) 4.0ml
得られたバリウム含有組成物は、ホログラム格子中で良好に作用した。攪拌された脱イオン水中で時間が経つと、おそらくはBaを失ったために、ホログラムが消失した。
XL6は以下のとおりである。
DMPA 10mg
Irgacure 2959 10mg
メタノール 7.0ml
EDMA 2.0ml
HEMA 0.5ml
トリエタノールアミン 0.02ml
脱イオン水 0.02ml
ヒドロキノン溶液(2%メタノール溶液) 0.50ml
XL7は以下のとおりである。
DMPA 5mg
Irgacure 2959 5mg
メタノール 1ml
BAP 0.4g
ジエチレングリコール 0.50ml
その後、この溶液を加熱振とうして透明にし、以下を添加した。
脱イオン水 4.0ml
トリエタノールアミン 0.04ml
アスコルビン酸(1%(w/v)水溶液) 0.20ml
Claims (6)
- 媒体、及び、その全体積にわたって配置された、反射型ホログラムを提供するホログラフィック素子を有するセンサーであって、
前記素子の縞は、試験液体中での膨潤度の差異によって規定され、
膨潤度の差異は、ポリマー媒体の架橋度の差異に相当する
センサー。 - 媒体の選択的な(解)重合によるホログラフィック画像を記録する工程を含み、
記録中に媒体が膨潤状態にある
請求項1に記載のセンサーの製造方法。 - 非架橋ポリマー、又は、実質的に均一架橋したポリマーを選択的に架橋する工程を含む
請求項2に記載の方法。 - ポリマーを膨潤させる揮発性溶媒中に架橋剤を添加する工程、及び、その後、選択的な(
解)重合の前に、該溶媒を除去する工程を含む
請求項3に記載の方法。 - 選択的な架橋がフリーラジカル重合阻害剤の存在下で行われる
請求項3又は4に記載の方法。 - 阻害剤が、酸素、ヒドロキノン又はアスコルビン酸である
請求項5に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0305590.2A GB0305590D0 (en) | 2003-03-11 | 2003-03-11 | Sensors and their production |
PCT/GB2004/000976 WO2004081676A1 (en) | 2003-03-11 | 2004-03-11 | Holographic sensors and their production |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2006520009A JP2006520009A (ja) | 2006-08-31 |
JP2006520009A5 JP2006520009A5 (ja) | 2009-04-16 |
JP4516955B2 true JP4516955B2 (ja) | 2010-08-04 |
Family
ID=9954581
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006500256A Expired - Fee Related JP4516955B2 (ja) | 2003-03-11 | 2004-03-11 | ホログラフィックセンサー及びその製造 |
Country Status (11)
Country | Link |
---|---|
US (1) | US20060234132A1 (ja) |
EP (1) | EP1602013B1 (ja) |
JP (1) | JP4516955B2 (ja) |
KR (1) | KR20050117549A (ja) |
CN (1) | CN1754133B (ja) |
AT (1) | ATE466314T1 (ja) |
AU (1) | AU2004219443B2 (ja) |
CA (1) | CA2515703A1 (ja) |
DE (1) | DE602004026839D1 (ja) |
GB (1) | GB0305590D0 (ja) |
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Families Citing this family (13)
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KR20070083451A (ko) * | 2004-06-08 | 2007-08-24 | 캠브리지 엔터프라이즈 리미티드 | 홀로그래픽 또는 회절장치 |
GB0416132D0 (en) * | 2004-07-19 | 2004-08-18 | Univ Cambridge Tech | Production of a sensor |
GB0419827D0 (en) * | 2004-09-07 | 2004-10-13 | Univ Cambridge Tech | Sensor |
GB0509434D0 (en) * | 2005-05-09 | 2005-06-15 | Smart Holograms Ltd | Sensor |
GB0514699D0 (en) * | 2005-07-18 | 2005-08-24 | Smart Holograms Ltd | Holographic sensors and their use |
GB0520116D0 (en) * | 2005-10-03 | 2005-11-09 | Smart Holograms Ltd | Use of holographic sensors |
US8697314B2 (en) * | 2007-02-28 | 2014-04-15 | Dai Nippon Printing Co., Ltd. | Method of producing volume hologram laminate |
US20110117477A1 (en) * | 2008-04-16 | 2011-05-19 | Smart Holograms Limited | Photopolymerizable Compositions |
JP5023239B2 (ja) | 2009-05-15 | 2012-09-12 | 株式会社東芝 | 非水電解質電池、それに用いる負極活物質、及び電池パック |
US9763605B2 (en) | 2013-11-27 | 2017-09-19 | Verily Life Sciences Llc | Adjustment of sensor sensitivity by controlling copolymer film thickness through a controlled drying step |
KR102383995B1 (ko) * | 2014-06-25 | 2022-04-07 | 뉴욕 유니버시티 | 인라인 입자 특징화 |
CN107340243B (zh) * | 2016-11-24 | 2020-03-10 | 临沂大学 | β-环糊精修饰全息传感器定量分析生物试样中布洛芬的方法 |
CN114879467A (zh) * | 2022-03-08 | 2022-08-09 | 武汉大学 | 基于液体浸润式的动态全息片上超表面及其显示方法 |
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US3694218A (en) * | 1970-03-03 | 1972-09-26 | Hughes Aircraft Co | Method of hologram recording |
US3667946A (en) * | 1970-09-23 | 1972-06-06 | Holotron Corp | Surface treatment of photopolymer film used for recording holograms |
US3963490A (en) * | 1974-09-25 | 1976-06-15 | The United States Of America As Represented By The Secretary Of The Air Force | Dye sensitized dichromated gelatin holographic material |
JPS5315152A (en) * | 1976-07-27 | 1978-02-10 | Canon Inc | Hologram |
US4133600A (en) * | 1976-10-01 | 1979-01-09 | Eli S. Jacobs | Method of manufacturing and utilizing holographic lens means |
US4187106A (en) * | 1979-03-23 | 1980-02-05 | The United States Of America As Represented By The Secretary Of The Army | Process for making phase holograms |
US4588664A (en) * | 1983-08-24 | 1986-05-13 | Polaroid Corporation | Photopolymerizable compositions used in holograms |
US4970129A (en) * | 1986-12-19 | 1990-11-13 | Polaroid Corporation | Holograms |
DE3738567A1 (de) * | 1987-03-12 | 1988-09-22 | Merck Patent Gmbh | Coreaktive fotoinitiatoren |
US4913990A (en) * | 1987-10-20 | 1990-04-03 | Rallison Richard D | Method of tuning a volume phase recording |
US4965152A (en) * | 1988-01-15 | 1990-10-23 | E. I. Du Pont De Nemours And Company | Holographic notch filters |
US4942112A (en) * | 1988-01-15 | 1990-07-17 | E. I. Du Pont De Nemours And Company | Photopolymerizable compositions and elements for refractive index imaging |
US4963471A (en) * | 1989-07-14 | 1990-10-16 | E. I. Du Pont De Nemours And Company | Holographic photopolymer compositions and elements for refractive index imaging |
US5230969A (en) * | 1990-08-09 | 1993-07-27 | Physical Optics Corporation | Composite graft optical polymer |
JPH05181399A (ja) * | 1991-12-24 | 1993-07-23 | Canon Inc | 体積位相型ホログラム記録媒体及びこれを用いた体積位相型ホログラム作製方法 |
JPH06150385A (ja) * | 1992-11-10 | 1994-05-31 | Pioneer Electron Corp | 光記録媒体 |
US7132200B1 (en) * | 1992-11-27 | 2006-11-07 | Dai Nippon Printing Co., Ltd. | Hologram recording sheet, holographic optical element using said sheet, and its production process |
JPH06258997A (ja) * | 1993-03-09 | 1994-09-16 | Canon Inc | 長波長対応体積位相型ホログラムの作製方法 |
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US7215451B1 (en) * | 1996-04-15 | 2007-05-08 | Dai Nippon Printing Co., Ltd. | Reflection type diffuse hologram, hologram for reflection hologram color filters, etc., and reflection type display device using such holograms |
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GB9811655D0 (en) * | 1998-05-29 | 1998-07-29 | Univ Cambridge Tech | Methods and materials for producing holographic sensors |
CN2506985Y (zh) * | 2001-11-08 | 2002-08-21 | 中国科学院西安光学精密机械研究所 | 光纤光栅流量传感器 |
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2003
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2004
- 2004-03-11 DE DE602004026839T patent/DE602004026839D1/de not_active Expired - Lifetime
- 2004-03-11 AU AU2004219443A patent/AU2004219443B2/en not_active Ceased
- 2004-03-11 KR KR1020057016851A patent/KR20050117549A/ko not_active Application Discontinuation
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KR20050117549A (ko) | 2005-12-14 |
CA2515703A1 (en) | 2004-09-23 |
CN1754133A (zh) | 2006-03-29 |
US20060234132A1 (en) | 2006-10-19 |
ATE466314T1 (de) | 2010-05-15 |
DE602004026839D1 (ja) | 2010-06-10 |
CN1754133B (zh) | 2010-09-01 |
WO2004081676A1 (en) | 2004-09-23 |
AU2004219443B2 (en) | 2007-04-26 |
EP1602013B1 (en) | 2010-04-28 |
GB0305590D0 (en) | 2003-04-16 |
JP2006520009A (ja) | 2006-08-31 |
AU2004219443A1 (en) | 2004-09-23 |
EP1602013A1 (en) | 2005-12-07 |
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