JP4474419B2 - グリコールアルデヒドの調製方法 - Google Patents

グリコールアルデヒドの調製方法 Download PDF

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JP4474419B2
JP4474419B2 JP2006544436A JP2006544436A JP4474419B2 JP 4474419 B2 JP4474419 B2 JP 4474419B2 JP 2006544436 A JP2006544436 A JP 2006544436A JP 2006544436 A JP2006544436 A JP 2006544436A JP 4474419 B2 JP4474419 B2 JP 4474419B2
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group
formaldehyde
carbon atoms
ligand
phospha
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JP2007516976A (ja
JP2007516976A5 (enExample
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アルメイダ・レネーロ,カリーナ,ケザリー
ドレント,エイト
フアン・ヒンケル,ルーロフ
パフ,ロベルト・イーアン
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シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/248Bridged ring systems, e.g. 9-phosphabicyclononane
    • B01J31/2485Tricyclic systems, e.g. phosphaadamantanes and hetero analogues
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60Reduction reactions, e.g. hydrogenation
    • B01J2231/64Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/648Fischer-Tropsch-type reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234Beta-dicarbonyl ligands, e.g. acetylacetonates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2006544436A 2003-12-16 2004-12-15 グリコールアルデヒドの調製方法 Expired - Lifetime JP4474419B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03257883 2003-12-16
PCT/EP2004/053492 WO2005058788A1 (en) 2003-12-16 2004-12-15 Process of preparing glycolaldehyde

Publications (3)

Publication Number Publication Date
JP2007516976A JP2007516976A (ja) 2007-06-28
JP2007516976A5 JP2007516976A5 (enExample) 2009-04-09
JP4474419B2 true JP4474419B2 (ja) 2010-06-02

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JP2006544436A Expired - Lifetime JP4474419B2 (ja) 2003-12-16 2004-12-15 グリコールアルデヒドの調製方法

Country Status (11)

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US (2) US7449607B2 (enExample)
EP (1) EP1697291A1 (enExample)
JP (1) JP4474419B2 (enExample)
KR (1) KR20060117345A (enExample)
CN (1) CN100434412C (enExample)
AU (1) AU2004298446B2 (enExample)
BR (1) BRPI0417643A (enExample)
CA (1) CA2549456A1 (enExample)
MX (1) MXPA06006705A (enExample)
RU (1) RU2371429C2 (enExample)
WO (1) WO2005058788A1 (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7858787B2 (en) * 2006-09-22 2010-12-28 Shell Oil Company Process for producing olefins
US7301054B1 (en) 2006-09-29 2007-11-27 Eastman Chemical Company Process for the preparation of glycolaldehyde
US7420093B2 (en) 2006-09-29 2008-09-02 Eastman Chemical Company Process for the preparation of glycolaldehyde
US7674937B2 (en) 2008-05-28 2010-03-09 Eastman Chemical Company Hydroformylation catalysts
FR2943061B1 (fr) * 2009-03-13 2011-02-25 Rhodia Operations Composes organophosphores, systemes catalytiques comprenant ces composes et procede d'hydrocyanation ou d'hydroformylation utilisant ces systemes catalytiques
RU2573570C2 (ru) 2009-12-17 2016-01-20 Басф Се Превращение гликолевого альдегида со средством аминирования
WO2011082967A1 (de) 2009-12-17 2011-07-14 Basf Se Verfahren zur herstellung von höheren ethanolaminen
CN101811933B (zh) * 2010-04-26 2013-05-08 常州大学 一种催化合成乙二醇的方法
TWI508937B (zh) * 2014-04-30 2015-11-21 Chien An Chen 使用甲醇為原料經由甲醛、乙醇醛的中間產物而合成乙二醇的製造方法
CN105085211B (zh) * 2014-05-16 2017-09-05 陈建安 一种甲醛、乙醇醛及乙二醇的制造方法
CA2949512C (en) * 2014-05-19 2020-08-18 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates
US9926247B2 (en) * 2014-06-30 2018-03-27 Haldor Topsoe A/S Process for the preparation of ethylene glycol from sugars
RU2737159C2 (ru) 2016-01-07 2020-11-25 Хальдор Топсёэ А/С Способ получения этиленгликоля из сахаров
EP3400207B1 (en) 2016-01-07 2023-06-07 Topsoe A/S Process for the preparation of ethylene glycol from sugars
CN105618035B (zh) * 2016-02-02 2018-05-11 中国科学院福建物质结构研究所 合成气制备乙醇醛所用的负载型铑催化剂及其制备方法
PL3551602T3 (pl) 2016-12-08 2025-04-14 Topsoe A/S Wytwarzanie aldehydu glikolowego przez fragmentację termolityczną
GB201904612D0 (en) 2019-04-02 2019-05-15 Univ Leuven Kath Reaction of glycoladehyde
WO2020095147A1 (en) * 2018-11-07 2020-05-14 Sabic Global Technologies B.V. Catalyst systems and methods for their use in selective hydroformylation of formaldehyde to glycolaldehyde
WO2020249427A1 (en) 2019-06-11 2020-12-17 Basf Se Gas-phase process for the conversion of glycolaldehyde with an aminating agent
WO2020249428A1 (en) 2019-06-11 2020-12-17 Basf Se Products obtained by the conversion of glycolaldehyde derivatives and aminating agents and their conversion to ethyleneamines and ethanolamines
WO2020249426A1 (en) 2019-06-11 2020-12-17 Basf Se Conversion of glycolaldehyde with an aminating agent
CN112337508A (zh) * 2020-11-03 2021-02-09 中国科学院福建物质结构研究所 一种乙醇醛合成用铑基催化剂及其制备方法
DE202021103519U1 (de) 2021-07-01 2021-07-16 Schill + Seilacher Gmbh Gerbmittel, Verwendung des Gerbmittels zum Gerben von Tierhäuten und Fellen und daraus erhaltenes Leder
ES2975566T3 (es) 2021-07-01 2024-07-09 Schill Seilacher Gmbh Agente curtiente, uso de un curtiente y procedimiento de curtido de pieles de animales y del cuero obtenido a partir de las mismas
CN114751813B (zh) * 2022-05-05 2023-12-15 天津大学 一种甲醛氢甲酰化制备乙醇醛的方法
CN115108887A (zh) * 2022-08-18 2022-09-27 山东能源集团有限公司 一种乙二醇的制备方法
CN115340440B (zh) * 2022-08-18 2024-09-06 山东能源集团有限公司 一种制备乙二醇的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3050531A (en) * 1960-07-06 1962-08-21 American Cyanamid Co Substituted 10-phosphatricyclo [3.3.1.1] decanes and methods of preparing same
US4414421A (en) * 1981-08-03 1983-11-08 Shell Oil Company Process for the preparation of glycol aldehyde
US4608444A (en) * 1984-04-05 1986-08-26 The Halcon Sd Group, Inc. Process and accompanying catalysts for the hydroformylation of formaldehyde to glycol-aldehyde
US4847423A (en) * 1988-03-03 1989-07-11 Hoechst Celanese Corporation Hydroformylation of aqueous formaldehyde using a rhodium-tricyclohexylphosphine catalyst system
SU1608182A1 (ru) * 1988-09-15 1990-11-23 Предприятие П/Я В-2287 Способ получени гликолевого альдегида
US5567856A (en) * 1995-05-30 1996-10-22 Hoechst Celanese Corporation Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands
US6156934A (en) * 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
DE10023468A1 (de) * 2000-05-12 2001-11-15 Basf Ag Verfahren zur Hydroformylierung ethylenisch ungesättigter Verbindungen und Ligand-Metall-Komplex als Katalysator hierfür

Also Published As

Publication number Publication date
AU2004298446A1 (en) 2005-06-30
US7449607B2 (en) 2008-11-11
RU2006125408A (ru) 2008-01-27
AU2004298446B2 (en) 2008-07-31
KR20060117345A (ko) 2006-11-16
US7511178B2 (en) 2009-03-31
RU2371429C2 (ru) 2009-10-27
EP1697291A1 (en) 2006-09-06
CA2549456A1 (en) 2005-06-30
US20090012333A1 (en) 2009-01-08
MXPA06006705A (es) 2006-08-23
US20070249871A1 (en) 2007-10-25
JP2007516976A (ja) 2007-06-28
CN1894188A (zh) 2007-01-10
CN100434412C (zh) 2008-11-19
BRPI0417643A (pt) 2007-03-27
WO2005058788A1 (en) 2005-06-30

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