JP4400230B2 - ポリ乳酸系フィルムおよび装飾シート - Google Patents
ポリ乳酸系フィルムおよび装飾シート Download PDFInfo
- Publication number
- JP4400230B2 JP4400230B2 JP2004020848A JP2004020848A JP4400230B2 JP 4400230 B2 JP4400230 B2 JP 4400230B2 JP 2004020848 A JP2004020848 A JP 2004020848A JP 2004020848 A JP2004020848 A JP 2004020848A JP 4400230 B2 JP4400230 B2 JP 4400230B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- layer
- film
- polylactic acid
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920006381 polylactic acid film Polymers 0.000 title claims description 33
- 229920005989 resin Polymers 0.000 claims description 50
- 239000011347 resin Substances 0.000 claims description 50
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 46
- 239000004626 polylactic acid Substances 0.000 claims description 46
- 238000007639 printing Methods 0.000 claims description 27
- 229920000178 Acrylic resin Polymers 0.000 claims description 25
- 239000004925 Acrylic resin Substances 0.000 claims description 25
- 229920001225 polyester resin Polymers 0.000 claims description 20
- 239000004645 polyester resin Substances 0.000 claims description 20
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 20
- 239000000314 lubricant Substances 0.000 claims description 16
- 238000005034 decoration Methods 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 239000010954 inorganic particle Substances 0.000 claims description 10
- 238000002834 transmittance Methods 0.000 claims description 10
- 230000003746 surface roughness Effects 0.000 claims description 9
- 239000011146 organic particle Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 description 39
- -1 polyethylene terephthalate Polymers 0.000 description 34
- 239000011248 coating agent Substances 0.000 description 32
- 238000000034 method Methods 0.000 description 30
- 239000000178 monomer Substances 0.000 description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 24
- 239000003431 cross linking reagent Substances 0.000 description 20
- 239000000976 ink Substances 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 19
- 239000007788 liquid Substances 0.000 description 18
- 229920000877 Melamine resin Polymers 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 16
- 238000010438 heat treatment Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 13
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- 229920000728 polyester Polymers 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 239000002585 base Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000000835 fiber Substances 0.000 description 10
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 125000000129 anionic group Chemical group 0.000 description 8
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 7
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
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- 238000004519 manufacturing process Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
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- 239000004640 Melamine resin Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
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- 238000002156 mixing Methods 0.000 description 5
- 239000005056 polyisocyanate Substances 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 4
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 4
- REKYPYSUBKSCAT-UHFFFAOYSA-N 3-hydroxypentanoic acid Chemical compound CCC(O)CC(O)=O REKYPYSUBKSCAT-UHFFFAOYSA-N 0.000 description 4
- FMHKPLXYWVCLME-UHFFFAOYSA-N 4-hydroxy-valeric acid Chemical compound CC(O)CCC(O)=O FMHKPLXYWVCLME-UHFFFAOYSA-N 0.000 description 4
- 239000004970 Chain extender Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- 150000007942 carboxylates Chemical group 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000011094 fiberboard Substances 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 4
- 235000014655 lactic acid Nutrition 0.000 description 4
- 229910003002 lithium salt Inorganic materials 0.000 description 4
- 159000000002 lithium salts Chemical class 0.000 description 4
- 150000007974 melamines Chemical class 0.000 description 4
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- 229930182843 D-Lactic acid Natural products 0.000 description 3
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
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- 230000000996 additive effect Effects 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000003851 corona treatment Methods 0.000 description 3
- 229940022769 d- lactic acid Drugs 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
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- 238000003475 lamination Methods 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
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Images
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- Laminated Bodies (AREA)
Description
本発明は、上記課題を解決するため、次の構成を有する。すなわち本発明のポリ乳酸系フィルムは、ポリ乳酸系樹脂からなる層(A層)の少なくとも片面に、アクリル樹脂、ポリエステル樹脂およびウレタン樹脂からなる群より選ばれる少なくとも1種の樹脂を主たる構成成分としてなる層(B層)を積層してなり、B層が、無機粒子または有機粒子を含有し、これらのB層中への添加量が0.01〜10重量%であり、B層の厚みが0.01〜5μmであり、光線透過率が90%以上である。
などのビニルエーテル類、エチレン、プロピレンなどのオレフィン類、塩化ビニル、塩化ビニリデン、フッ化ビニルなどの含ハロゲン−α,β−不飽和モノマー類、スチレン、α−メチルスチレンなどのα,β−不飽和芳香族モノマー類などを用いることができ、これらは1種または2種以上の混合物を使用することもできる。
[特性の測定方法]
(1)表面粗さ
小坂研究所製ET−10を用いて触針先端半径0.5μm、針圧5mg、測定長1mm、カットオフ0.08mmの条件にて中心線平均粗さ(Ra)を測定した。測定はフィルムの長手方向に5点行い、その平均値を表面粗さの測定値とした。
スガ試験器製ヘイズメーターを使用し、JIS−K7105に準じて測定を行った。
下記3種類のインクをロールコート法で、フィルムB層表面に1.5μmの厚みに塗布した。インクA、Bについては、紫外線ランプにて、照射強度80W/cm、照射距離9cm、照射時間5秒で硬化させた。インクCは40℃×30分の条件で乾燥させた。
インクB:東洋インキ製造(株)製“FLASH DRY”FDカルトンP墨
インクC:(株)セイコーアドバンス製CAVメイバン。
○:80〜99(合格)
△:50〜79(合格)
×:0〜49(不合格)。
(A層作成用原料:溶融押出製膜用樹脂)
・ポリ乳酸A
重量平均分子量20万、L−乳酸成分量98.5%、D−乳酸成分量1.5%、融点169℃、カルボキシル末端基濃度35当量/トンのポリ乳酸樹脂。
ポリ乳酸Aに対し、平均粒径1.6μmのシリカ粒子〈水澤化学工業(株)製ミズカシルP−527〉を210℃で二軸押出機を用いて、シリカ濃度5重量%混合したポリ乳酸樹脂。
・塗液1(アクリルA)
下に示す(A)/(D)/(E)/(F)を固形分重量比で75/25/5/0.5で配合し、水で希釈混合して固形分濃度を4重量%としたアクリルエマルジョンである。
下に示す(A)/(D)を固形分重量比で75/25で配合し、水で希釈混合して固形分濃度を4重量%としたアクリルエマルジョンである。
下に示す(B)/(E)/(F)を固形分重量比:100/5/0.5で配合し、水で希釈混合して固形分濃度を4重量%としたポリエステルエマルジョンである。
下に示す(B)/(E)/(F)を固形分重量比:100/5/5で配合し、水で希釈混合して固形分濃度を4重量%としたポリエステルエマルジョンである。
下に示す(C)/(E)/(F)を固形分重量比:100/5/0.5で配合し、水で希釈して固形分濃度4%に調整したポリウレタンプレポリマー水分散体である。
メチルメタクリレート 60重量%
ブチルアクリレート 38重量%
アクリル酸 1重量%
N−メチロールアクリルアミド 1重量%
の共重合体の水性エマルジョン。
酸成分
テレフタル酸 60モル%
イソフタル酸 14モル%
セバシン酸 6モル%
トリメリット酸 20モル%
ジオール成分
エチレングリコール 28モル%
ネオペンチルグリコール 38モル%
1,4−ブタンジオール 34モル%
上記酸性分とジオールからなるポリエステル樹脂をアンモニア水で水性化した水分散体。
ポリブタジエンポリオール 70重量部
ポリエチレングリコール 30重量部
ヘキサメチレンジイソシアネート 17重量部
ブタノンオキシム 4.4重量部
ジメチロールプロピオン酸 3.3重量部
トリエチルアミン 2.5重量部
の組成比のポリウレタンプレポリマーの水分散体。
ポリスチレンスルホン酸アンモニウム塩(分子量=約4万)の水分散体。
メチロール化メラミンをイソプロピルアルコール/水の混合溶媒=10/90(重量比)に希釈した塗液。
日産化学工業社製:スノーテックOL、平均粒径40nmの水分散体。
(実施例1)
ポリ乳酸Aを120℃、2KPa以下の真空条件下で5時間乾燥した。乾燥後の樹脂をスクリュー径50mmの単軸押出機に供給し、押出機シリンダ温度230℃で溶融させた。溶融ポリマーは20μmの濾過精度を有する焼結ディスクフィルターを通過せしめ、引き続き口金温度220℃でフィルム状に押し出し、30℃に冷却した鏡面ドラム上に静電印加キャストして無配向フィルムを作成した。引き続き連続して80℃の加熱ロール間で長手方向に3倍延伸した後、フィルム両面に塗液1(アクリルA)をメタバーにて塗布した。さらに引き続きフィルム端部をクリップで把持してテンター内に導き、78℃の温度で加熱しつつ横方向に3.2倍延伸し、幅方向に2%弛緩させながら140℃、12秒間の熱処理を行い、全厚み150μm、B層の厚み片面当たり0.12μmのポリ乳酸系フィルムを得た。表1に得られたフィルムの特性を示す。透明性に優れ、インク密着性にも優れるフィルムであった。
使用する樹脂をポリ乳酸A:ポリ乳酸B=99:1の重量比率で混合したものとした。また、B層を形成するための塗液をフィルム片面に塗液2(アクリルB)とした以外は実施例1と同じ条件にて、全厚み150μm、B層厚み0.12μmのポリ乳酸系フィルムを得た。
塗布液を塗液3(ポリエステルA)とした以外は参考例2と同様の手法にて、ポリ乳酸系フィルムを得た。
長手方向に延伸した後に、塗液を塗布せず、横方向の延伸を行った以外は参考例2と同様の手法にて、ポリ乳酸系フィルムを作成した。
塗布液を塗液5(ウレタン)とした以外は、参考例2と同様の手法にて、ポリ乳酸系フィルムを得た。特にインク密着性に優れるフィルムであった。
使用する樹脂をポリ乳酸A:ポリ乳酸B=96:4の重量比率で混合したものとした。塗布液を塗液4(ポリエステルB)とした以外は参考例2と同様の手法にて、ポリ乳酸系フィルムを得た。
長手方向に延伸した後に、塗液を塗布せず、横方向の延伸を行った以外は実施例1と同様の手法にて、150μmの厚みのポリ乳酸系フィルムを得た。
実施例1との比較のため、ポリ乳酸系樹脂の代わりにポリエチレンテレフタレート樹脂をA層とした構成のフィルムを以下の手順にて作成した。
評価の基準フィルムとして、“ルミラー”T60(厚み188μm)の片面にコロナ放電処理を施し、さらに上記塗液塗液2をグラビアコーターにて塗布、乾燥し、厚み1.2μmのB層を形成したフィルムを準備した。
2 B層:易接着層
3 ポリ乳酸系フィルム
4 印刷層
5 基材シート
6 表面機能膜層
7 装飾シートの表面
Claims (5)
- ポリ乳酸系樹脂からなる層(A層)の少なくとも片面に、アクリル樹脂、ポリエステル樹脂、およびウレタン樹脂からなる群より選ばれる少なくとも1種の樹脂を主たる構成成分としてなる層(B層)を積層してなり、
B層が、無機粒子または有機粒子を含有し、これらのB層中への添加量が0.01〜10重量%であり、
B層の厚みが0.01〜5μmであり、
光線透過率が90%以上であることを特徴とするポリ乳酸系フィルム。 - A層中のポリ乳酸系樹脂中の滑剤含有量が0.08重量%以下である請求項1に記載のポリ乳酸系フィルム。
- 少なくとも片面の2次元表面粗さ(Ra)が0.1〜100nmの範囲の請求項1または2に記載のポリ乳酸系フィルム
- 装飾シートとして用いられる請求項1〜3に記載のポリ乳酸系フィルム。
- 請求項1〜3に記載のポリ乳酸系フィルムに、少なくとも印刷層、基材シートを順に配置してなる装飾シート。
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JP4948874B2 (ja) * | 2006-03-31 | 2012-06-06 | 株式会社フジシールインターナショナル | 積層シュリンクラベル |
JP4964529B2 (ja) * | 2006-07-28 | 2012-07-04 | 三井化学株式会社 | 成形体 |
JP4962268B2 (ja) * | 2007-02-07 | 2012-06-27 | 東レ株式会社 | ポリ乳酸系樹脂積層シートおよびそれからなる成形体 |
JP5151189B2 (ja) * | 2007-03-09 | 2013-02-27 | 東レ株式会社 | 積層シートおよびそれからなる成形体 |
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JP5104358B2 (ja) * | 2008-02-05 | 2012-12-19 | 凸版印刷株式会社 | 化粧シート |
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JP2010052308A (ja) * | 2008-08-29 | 2010-03-11 | Toppan Cosmo Inc | 化粧シート |
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JP5097733B2 (ja) * | 2009-03-16 | 2012-12-12 | 三菱樹脂株式会社 | 熱収縮性フィルム、該熱収縮性フィルムを基材として用いた成形品および熱収縮性ラベル、ならびに、該成形品および熱収縮性ラベルを装着した容器 |
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KR101267223B1 (ko) | 2010-06-11 | 2013-05-24 | 성균관대학교산학협력단 | 복합필름 및 그 제조 방법 |
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WO2022114877A1 (ko) * | 2020-11-27 | 2022-06-02 | 주식회사 동성케미컬 | 폐쇄형 셀층을 갖는 시트 |
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