JP4348657B2 - 反応帯域に組み合わされる安定化蒸留物の抜き出しを含む蒸留帯域内での処理による炭化水素転換方法およびベンゼンの水素化におけるその使用法 - Google Patents
反応帯域に組み合わされる安定化蒸留物の抜き出しを含む蒸留帯域内での処理による炭化水素転換方法およびベンゼンの水素化におけるその使用法 Download PDFInfo
- Publication number
- JP4348657B2 JP4348657B2 JP09849699A JP9849699A JP4348657B2 JP 4348657 B2 JP4348657 B2 JP 4348657B2 JP 09849699 A JP09849699 A JP 09849699A JP 9849699 A JP9849699 A JP 9849699A JP 4348657 B2 JP4348657 B2 JP 4348657B2
- Authority
- JP
- Japan
- Prior art keywords
- zone
- distillation
- level
- reaction zone
- hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims description 176
- 238000000034 method Methods 0.000 title claims description 96
- 238000004821 distillation Methods 0.000 title claims description 94
- 238000006243 chemical reaction Methods 0.000 title claims description 75
- 238000005984 hydrogenation reaction Methods 0.000 title claims description 54
- 229930195733 hydrocarbon Natural products 0.000 title claims description 32
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 32
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 25
- 239000007788 liquid Substances 0.000 claims description 64
- 239000001257 hydrogen Substances 0.000 claims description 53
- 229910052739 hydrogen Inorganic materials 0.000 claims description 53
- 239000003054 catalyst Substances 0.000 claims description 50
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 45
- 150000001875 compounds Chemical class 0.000 claims description 27
- 238000010992 reflux Methods 0.000 claims description 25
- 239000007789 gas Substances 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 150000001336 alkenes Chemical group 0.000 claims description 11
- 239000012530 fluid Substances 0.000 claims description 11
- 150000002431 hydrogen Chemical class 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 20
- 239000000203 mixture Substances 0.000 description 12
- 238000000605 extraction Methods 0.000 description 9
- 238000011084 recovery Methods 0.000 description 9
- 238000010926 purge Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000004088 simulation Methods 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002452 interceptive effect Effects 0.000 description 2
- 238000000066 reactive distillation Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000009928 pasteurization Methods 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9804351A FR2777012B1 (fr) | 1998-04-06 | 1998-04-06 | Procede de conversion d'hydrocarbures par traitement dans une zone de distillation comprenant le soutirage d'un distillat stabilise, associee a une zone reactionnelle, et son utilisation en hydrogenation du benzene |
| FR9804351 | 1998-04-06 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11323357A JPH11323357A (ja) | 1999-11-26 |
| JPH11323357A5 JPH11323357A5 (enExample) | 2006-05-25 |
| JP4348657B2 true JP4348657B2 (ja) | 2009-10-21 |
Family
ID=9524984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP09849699A Expired - Lifetime JP4348657B2 (ja) | 1998-04-06 | 1999-04-06 | 反応帯域に組み合わされる安定化蒸留物の抜き出しを含む蒸留帯域内での処理による炭化水素転換方法およびベンゼンの水素化におけるその使用法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6261442B1 (enExample) |
| EP (1) | EP0949315B1 (enExample) |
| JP (1) | JP4348657B2 (enExample) |
| CA (1) | CA2265991C (enExample) |
| DE (1) | DE69926430T2 (enExample) |
| ES (1) | ES2246560T3 (enExample) |
| FR (1) | FR2777012B1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6855853B2 (en) * | 2002-09-18 | 2005-02-15 | Catalytic Distillation Technologies | Process for the production of low benzene gasoline |
| FR2933987B1 (fr) * | 2008-07-18 | 2010-08-27 | Inst Francais Du Petrole | Procede d'hydrogenation du benzene |
| CN101649221B (zh) * | 2008-08-13 | 2012-12-12 | 中国石油天然气股份有限公司 | 一种汽油轻馏分和中馏分生产重整原料的方法 |
| US7910070B2 (en) * | 2008-12-09 | 2011-03-22 | Uop Llc | Process for reducing benzene concentration in reformate |
| EP2277980B1 (fr) * | 2009-07-21 | 2018-08-08 | IFP Energies nouvelles | Procédé de réduction sélective de la teneur en benzène et en composés insatures legers de differentes coupes hydrocarbures |
| FR2948380B1 (fr) * | 2009-07-21 | 2011-08-12 | Inst Francais Du Petrole | Procede de reduction selective de la teneur en benzene et en composes insatures legers de differentes coupes hydrocarbures |
| EP2809749B1 (en) | 2012-02-01 | 2017-11-01 | Saudi Arabian Oil Company | Catalytic reforming process and system for producing reduced benzene gasoline |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3655551A (en) | 1970-06-01 | 1972-04-11 | Union Oil Co | Hydrocracking-hydrogenation process |
| US3926785A (en) * | 1971-11-01 | 1975-12-16 | Chevron Res | Integrated distillation and hydrodesulfurization process for jet fuel production |
| US4302356A (en) | 1978-07-27 | 1981-11-24 | Chemical Research & Licensing Co. | Process for separating isobutene from C4 streams |
| US4622955A (en) | 1985-09-05 | 1986-11-18 | Mehdi Fakhrai | Surgical retractor for dissection of internal mammary artery |
| US5073236A (en) | 1989-11-13 | 1991-12-17 | Gelbein Abraham P | Process and structure for effecting catalytic reactions in distillation structure |
| US5302356A (en) | 1992-03-04 | 1994-04-12 | Arizona Board Of Reagents Acting On Behalf Of University Of Arizona | Ultrapure water treatment system |
| US5258560A (en) | 1992-06-22 | 1993-11-02 | Uop | Etherification of C5 -plus olefins by catalytic distillation |
| FR2743080B1 (fr) * | 1995-12-27 | 1998-02-06 | Inst Francais Du Petrole | Procede de reduction selective de la teneur en benzene et en composes insatures legers d'une coupe d'hydrocarbures |
| FR2753701B1 (fr) | 1996-09-24 | 1998-11-27 | Procede pour reduire la teneur en benzene d'une coupe d'hydrocarbures |
-
1998
- 1998-04-06 FR FR9804351A patent/FR2777012B1/fr not_active Expired - Lifetime
-
1999
- 1999-03-25 DE DE69926430T patent/DE69926430T2/de not_active Expired - Lifetime
- 1999-03-25 ES ES99400738T patent/ES2246560T3/es not_active Expired - Lifetime
- 1999-03-25 EP EP99400738A patent/EP0949315B1/fr not_active Expired - Lifetime
- 1999-04-01 CA CA002265991A patent/CA2265991C/fr not_active Expired - Lifetime
- 1999-04-05 US US09/285,679 patent/US6261442B1/en not_active Expired - Lifetime
- 1999-04-06 JP JP09849699A patent/JP4348657B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0949315B1 (fr) | 2005-08-03 |
| CA2265991A1 (fr) | 1999-10-06 |
| EP0949315A1 (fr) | 1999-10-13 |
| DE69926430D1 (de) | 2005-09-08 |
| US6261442B1 (en) | 2001-07-17 |
| DE69926430T2 (de) | 2006-01-26 |
| FR2777012B1 (fr) | 2000-08-25 |
| FR2777012A1 (fr) | 1999-10-08 |
| ES2246560T3 (es) | 2006-02-16 |
| JPH11323357A (ja) | 1999-11-26 |
| CA2265991C (fr) | 2009-06-23 |
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