JP4342730B2 - 液状洗浄剤組成物に使用するためのヒドロトロープ及び皮膚コンディショニング剤 - Google Patents
液状洗浄剤組成物に使用するためのヒドロトロープ及び皮膚コンディショニング剤 Download PDFInfo
- Publication number
- JP4342730B2 JP4342730B2 JP2000547191A JP2000547191A JP4342730B2 JP 4342730 B2 JP4342730 B2 JP 4342730B2 JP 2000547191 A JP2000547191 A JP 2000547191A JP 2000547191 A JP2000547191 A JP 2000547191A JP 4342730 B2 JP4342730 B2 JP 4342730B2
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- Prior art keywords
- liquid detergent
- hydrotrope
- alkyl
- group
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims description 151
- 239000003752 hydrotrope Substances 0.000 title claims description 93
- 239000003599 detergent Substances 0.000 title claims description 75
- 239000007788 liquid Substances 0.000 title claims description 55
- 239000003795 chemical substances by application Substances 0.000 title description 7
- 230000003750 conditioning effect Effects 0.000 title description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 90
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 81
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 67
- -1 fatty acid salt Chemical class 0.000 claims description 52
- 239000004094 surface-active agent Substances 0.000 claims description 46
- 150000001298 alcohols Chemical class 0.000 claims description 41
- 239000003945 anionic surfactant Substances 0.000 claims description 37
- 235000011187 glycerol Nutrition 0.000 claims description 33
- 239000002202 Polyethylene glycol Substances 0.000 claims description 32
- 229920001223 polyethylene glycol Polymers 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 31
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 27
- 239000006260 foam Substances 0.000 claims description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 23
- 239000003623 enhancer Substances 0.000 claims description 16
- 125000000129 anionic group Chemical group 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
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- 229930182478 glucoside Natural products 0.000 claims description 5
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims description 2
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- 125000004432 carbon atom Chemical group C* 0.000 description 46
- 150000002314 glycerols Chemical class 0.000 description 36
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 30
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 24
- 238000004140 cleaning Methods 0.000 description 21
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
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- 150000001875 compounds Chemical class 0.000 description 9
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- 239000011591 potassium Substances 0.000 description 6
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 5
- 125000003158 alcohol group Chemical group 0.000 description 5
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- 238000009472 formulation Methods 0.000 description 4
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- 239000004615 ingredient Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000002540 palm oil Substances 0.000 description 4
- 150000003138 primary alcohols Chemical class 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
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- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
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- 229910052717 sulfur Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 206010015150 Erythema Diseases 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical group C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
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- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000002535 acidifier Substances 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
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Images
Classifications
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A61Q19/10—Washing or bathing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
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- Birds (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
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| US09/073,229 US6423678B1 (en) | 1998-05-05 | 1998-05-05 | Alcohol ethoxylate-peg ether of glycerin |
| US09/073,229 | 1998-05-05 | ||
| PCT/US1999/009936 WO1999057234A1 (en) | 1998-05-05 | 1999-05-05 | Hydrotrope and skin conditioning agents for use in liquid detergent compositions |
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| SG139699A1 (en) * | 2006-08-02 | 2008-02-29 | Fujimi Inc | Polishing composition and polishing process |
| CN102159692A (zh) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | 超浓缩的液体洗衣洗涤剂 |
| JP5613677B2 (ja) * | 2009-10-15 | 2014-10-29 | ライオン株式会社 | 液体洗浄剤組成物 |
| WO2012026710A2 (ko) * | 2010-08-23 | 2012-03-01 | 주식회사그린바이오 | 친환경 및 무독성 저수조 세정액 |
| KR101042488B1 (ko) | 2010-08-23 | 2011-06-16 | 주식회사그린바이오 | 친환경 및 무독성 저수조 세정액 |
| KR101035436B1 (ko) | 2010-08-23 | 2011-05-18 | 주식회사그린바이오 | 무독성 급배수관 세정액 |
| US10045529B2 (en) | 2012-06-29 | 2018-08-14 | Ecolab Usa Inc. | Quat cleaner with glycerin ether ethoxylates |
| WO2014003839A1 (en) * | 2012-06-29 | 2014-01-03 | Ecolab Usa Inc. | Glycerin ether ethoxylate solfactants |
| WO2015032083A1 (en) * | 2013-09-09 | 2015-03-12 | The Procter & Gamble Company | Process of making a liquid cleaning composition |
| EP3298119B2 (en) | 2015-05-22 | 2022-05-25 | The Procter & Gamble Company | Surfactant and detergent compositions containing ethoxylated glycerine |
| CN105273857B (zh) * | 2015-10-30 | 2018-05-01 | 武汉理工大学 | 一种多功能绿色水基清洗剂及其制备方法 |
| CN109963930A (zh) * | 2016-10-31 | 2019-07-02 | 沙特基础工业全球技术有限公司 | 在去除美容品污渍中作为活性成分的甘油乙氧基化物 |
| JP7102008B2 (ja) * | 2017-06-15 | 2022-07-19 | ディコン７ システムズ インク | 浄化製剤 |
| US12466922B2 (en) | 2021-09-27 | 2025-11-11 | Shpp Global Technologies B.V. | Film extrusion composition and associated extruded film, metallized film, and capacitor |
| GB2630014A (en) * | 2023-04-04 | 2024-11-20 | Reckitt Benckiser Espana S L | Phosphonate-free liquid laundry detergent composition |
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| GB836774A (en) | 1955-01-13 | 1960-06-09 | Domestos Ltd | Detergent compositions |
| US4102826A (en) | 1972-12-06 | 1978-07-25 | Colgate-Palmolive Company | Liquid detergent |
| GB1538747A (en) | 1975-07-17 | 1979-01-24 | Shell Int Research | Detergent compositions |
| US4079020A (en) | 1975-11-07 | 1978-03-14 | Lever Brothers Company | Cleaning composition |
| US4206070A (en) | 1975-12-24 | 1980-06-03 | The Procter & Gamble Company | Detergent compositions |
| AU528816B2 (en) | 1978-02-14 | 1983-05-12 | Unilever Ltd. | Detergent composotions |
| US4248729A (en) | 1978-12-13 | 1981-02-03 | The Procter & Gamble Company | Detergency booster |
| US4457856A (en) | 1980-01-07 | 1984-07-03 | The Procter & Gamble Company | Liquid detergent composition contains abrasive particles, anionic and nonionic surfactants |
| US4492646A (en) | 1980-02-05 | 1985-01-08 | The Procter & Gamble Company | Liquid dishwashing detergent containing anionic surfactant, suds stabilizer and highly ethoxylated nonionic drainage promotor |
| AU554574B2 (en) | 1982-03-19 | 1986-08-28 | Colgate-Palmolive Pty. Ltd. | Shampoo |
| US4483779A (en) | 1982-04-26 | 1984-11-20 | The Procter & Gamble Company | Detergent compositions comprising polyglycoside and polyethoxylate surfactants and anionic fluorescer |
| US4743394A (en) | 1984-03-23 | 1988-05-10 | Kaufmann Edward J | Concentrated non-phosphate detergent paste compositions |
| US4857213A (en) | 1988-02-08 | 1989-08-15 | The Procter & Gamble Company | Liquid detergent containing conditioning agent and high levels of alkyl sulfate/alkyl ethoxylated sulfate |
| GB9110720D0 (en) | 1991-05-17 | 1991-07-10 | Unilever Plc | Detergent composition |
| US5298195A (en) | 1992-03-09 | 1994-03-29 | Amway Corporation | Liquid dishwashing detergent |
| ATE117363T1 (de) * | 1992-07-20 | 1995-02-15 | Kao Corp Sa | Waschmittelzusammensetzungen. |
| US5403509A (en) | 1992-07-20 | 1995-04-04 | Kao Corporation, S.A. | Detergent composition comprising a mono-, di- and tri-ester mixture and method of manufacturing same |
| NZ259340A (en) | 1992-12-15 | 1996-05-28 | Shell Int Research | Surfactant composition and preparation containing a secondary alkyl sulphate and a zeolite |
| US5389277A (en) | 1993-09-30 | 1995-02-14 | Shell Oil Company | Secondary alkyl sulfate-containing powdered laundry detergent compositions |
| USH1467H (en) | 1993-11-16 | 1995-08-01 | Shell Oil Company | Detergent formulations containing a surface active composition containing a nonionic surfactant component and a secondary alkyl sulfate anionic surfactant component |
| US5561106A (en) * | 1994-02-07 | 1996-10-01 | Erilli; Rita | High foaming light duty liquid detergent composition comprising partially esterified ethoxylated polyhydric alcohol solubilizing agent |
| USH1665H (en) | 1994-12-09 | 1997-07-01 | Brumbaugh; Ernest H. | Liquid dishwashing detergent |
| US5476614A (en) * | 1995-01-17 | 1995-12-19 | Colgate Palmolive Co. | High foaming nonionic surfactant based liquid detergent |
| US5767050A (en) * | 1995-01-17 | 1998-06-16 | Colgate-Palmolive Co. | Light duty liquid cleaning compositions comprising partially esterified polyhydric alcohol solubilizing agent |
| DE69634211T2 (de) | 1995-11-16 | 2005-06-23 | Access Business Group International Llc, Ada | Flüssiges geschirrspülmittel |
| US5866527A (en) * | 1997-08-01 | 1999-02-02 | Colgate Palmolive Company | All purpose liquid cleaning compositions comprising anionic EO nonionic and EO-BO nonionic surfactants |
| US5858956A (en) * | 1997-12-03 | 1999-01-12 | Colgate-Palmolive Company | All purpose liquid cleaning compositions comprising anionic, EO nonionic and EO-BO nonionic surfactants |
-
1998
- 1998-05-05 US US09/073,229 patent/US6423678B1/en not_active Expired - Lifetime
-
1999
- 1999-05-05 WO PCT/US1999/009936 patent/WO1999057234A1/en not_active Ceased
- 1999-05-05 JP JP2000547191A patent/JP4342730B2/ja not_active Expired - Lifetime
- 1999-05-05 AU AU38860/99A patent/AU3886099A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| AU3886099A (en) | 1999-11-23 |
| JP2002513853A (ja) | 2002-05-14 |
| WO1999057234A1 (en) | 1999-11-11 |
| US6423678B1 (en) | 2002-07-23 |
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