JP4308025B2 - 異なる再帰反射色の領域を有するレトロクロミック物品 - Google Patents
異なる再帰反射色の領域を有するレトロクロミック物品 Download PDFInfo
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- JP4308025B2 JP4308025B2 JP2003584781A JP2003584781A JP4308025B2 JP 4308025 B2 JP4308025 B2 JP 4308025B2 JP 2003584781 A JP2003584781 A JP 2003584781A JP 2003584781 A JP2003584781 A JP 2003584781A JP 4308025 B2 JP4308025 B2 JP 4308025B2
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- beads
- retrochromic
- retroreflective
- intrinsic
- refractive index
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
- B29C70/585—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres incorporation of light reflecting filler, e.g. lamellae to obtain pearlescent effet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00605—Production of reflex reflectors
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Optical Elements Other Than Lenses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/122,520 US7036944B2 (en) | 2002-04-11 | 2002-04-11 | Retrochromic articles |
| PCT/US2003/006597 WO2003087896A1 (en) | 2002-04-11 | 2003-03-03 | Retrochromic articles having regions of different retroreflective colors |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005522730A JP2005522730A (ja) | 2005-07-28 |
| JP2005522730A5 JP2005522730A5 (https=) | 2006-03-30 |
| JP4308025B2 true JP4308025B2 (ja) | 2009-08-05 |
Family
ID=28790560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003584781A Expired - Fee Related JP4308025B2 (ja) | 2002-04-11 | 2003-03-03 | 異なる再帰反射色の領域を有するレトロクロミック物品 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7036944B2 (https=) |
| EP (1) | EP1495348B1 (https=) |
| JP (1) | JP4308025B2 (https=) |
| CN (1) | CN1646950B (https=) |
| AU (1) | AU2003213713A1 (https=) |
| DE (1) | DE60328370D1 (https=) |
| WO (1) | WO2003087896A1 (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070092701A1 (en) * | 2005-10-11 | 2007-04-26 | Jeng Jong P | Building material having a fluorocarbon based capstock layer and process of manufacturing same with less dimensional distortion |
| US7694887B2 (en) | 2001-12-24 | 2010-04-13 | L-1 Secure Credentialing, Inc. | Optically variable personalized indicia for identification documents |
| ATE552120T1 (de) | 2001-12-24 | 2012-04-15 | L 1 Secure Credentialing Inc | Verdeckte variableninformationen auf id- dokumenten und verfahren zu ihrer herstellung |
| WO2003088144A2 (en) * | 2002-04-09 | 2003-10-23 | Digimarc Id Systems, Llc | Image processing techniques for printing identification cards and documents |
| US7824029B2 (en) | 2002-05-10 | 2010-11-02 | L-1 Secure Credentialing, Inc. | Identification card printer-assembler for over the counter card issuing |
| US7349155B2 (en) * | 2002-10-28 | 2008-03-25 | Hewlett-Packard Development Company, L.P. | Screen having a layer of reflectors |
| AU2003298731A1 (en) | 2002-11-26 | 2004-06-18 | Digimarc Id Systems | Systems and methods for managing and detecting fraud in image databases used with identification documents |
| US7225991B2 (en) | 2003-04-16 | 2007-06-05 | Digimarc Corporation | Three dimensional data storage |
| WO2005047604A1 (en) * | 2003-11-06 | 2005-05-26 | 3M Innovative Properties Company | Retroreflective elements comprising a bonded resin core and pavement markings |
| WO2005100041A2 (en) * | 2004-04-13 | 2005-10-27 | Digimarc Corporation | Retroreflective security features in secure documents |
| AU2005238775B2 (en) | 2004-04-28 | 2008-06-12 | Kiwa Chemical Industry Co., Ltd. | Hue variable retroreflective sheet |
| JP4734893B2 (ja) * | 2004-11-04 | 2011-07-27 | 凸版印刷株式会社 | 偽造防止媒体、偽造防止シールおよびその読み取り方法 |
| US7224533B2 (en) * | 2004-11-08 | 2007-05-29 | Hewlett-Packard Development Company, L.P. | Optically retro-reflecting sphere |
| US8002932B2 (en) * | 2005-12-28 | 2011-08-23 | Bridgestone Sports Co., Ltd. | Method for preparing golf ball with indicia having metallic luster |
| US7609452B2 (en) * | 2006-06-12 | 2009-10-27 | Guardian Industries Corp. | 3D gauge face for vehicle dashboard |
| GB0613737D0 (en) * | 2006-07-11 | 2006-08-23 | Oakley John P | Retroreflector |
| AU2008284435B2 (en) * | 2007-05-21 | 2013-07-18 | Light Engine Limited | LED luminance-augmentation via specular retroreflection, including collimators that escape the etendue limit |
| EP2169434B1 (en) * | 2007-06-19 | 2016-10-19 | Marujin Co., Ltd. | Iridescent reflected light emitting retroreflective material |
| JP2011509422A (ja) * | 2007-12-21 | 2011-03-24 | スリーエム イノベイティブ プロパティズ カンパニー | 再帰反射安全物品 |
| EP2232310A1 (en) * | 2007-12-21 | 2010-09-29 | 3M Innovative Properties Company | Retroreflective artcles in the form of garments, fibers and filaments |
| WO2009082644A1 (en) * | 2007-12-21 | 2009-07-02 | 3M Innovative Properties Company | Retroreflective articles and retroreflective elements comprising a spherical core and two concentric optical interference layers |
| WO2009085550A1 (en) * | 2007-12-21 | 2009-07-09 | 3M Innovative Properties Company | Retroreflective pavement markings |
| CN102898003B (zh) * | 2012-10-23 | 2015-01-28 | 陕西科技大学 | 一种彩色玻璃微珠的制备方法 |
| WO2019234633A1 (en) | 2018-06-06 | 2019-12-12 | 3M Innovative Properties Company | Two-part dental sealant, method of applying with a syringe device, and kit |
| US12161523B2 (en) | 2018-06-06 | 2024-12-10 | Solventum Intellectual Properties Company | Hardenable dental compositions comprising basic core material encapsulated in an inorganic shell and dispensing devices therewith |
Family Cites Families (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2326634A (en) | 1941-12-26 | 1943-08-10 | Minnesota Mining & Mfg | Reflex light reflector |
| US2407680A (en) | 1945-03-02 | 1946-09-17 | Minnesota Mining & Mfg | Reflex light reflector |
| US2713286A (en) | 1949-10-22 | 1955-07-19 | Minnesota Mining & Mfg | Reflex light reflectors and glass bead elements thereof |
| US2963378A (en) | 1955-04-25 | 1960-12-06 | Minnesota Mining & Mfg | Ass beads hemispherically reflectorled with metallic coating and compositions thereof |
| US3025764A (en) | 1956-10-04 | 1962-03-20 | Minnesota Mining & Mfg | Retroreflective elements and structures |
| NL257502A (https=) | 1959-11-02 | |||
| US3154872A (en) | 1963-02-13 | 1964-11-03 | Minnesota Mining & Mfg | Tamper-proof markings for reflecting structures |
| US3758192A (en) | 1970-08-20 | 1973-09-11 | Minnesota Mining & Mfg | Reflex-reflective structures including fabric and transfer foils |
| US3700478A (en) | 1970-11-09 | 1972-10-24 | Minnesota Mining & Mfg | Microspheres having an antireflection coating and their use |
| US3700305A (en) | 1970-12-14 | 1972-10-24 | Minnesota Mining & Mfg | Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres |
| NL7300593A (https=) | 1972-01-15 | 1973-07-17 | ||
| US3858977A (en) | 1972-01-18 | 1975-01-07 | Canadian Patents Dev | Optical interference authenticating means |
| US3767291A (en) | 1972-03-31 | 1973-10-23 | Minnesota Mining & Mfg | Retroviewer |
| US3832038A (en) | 1972-08-09 | 1974-08-27 | Minnesota Mining & Mfg | Hand retroviewer |
| US3801183A (en) | 1973-06-01 | 1974-04-02 | Minnesota Mining & Mfg | Retro-reflective film |
| US4022318A (en) | 1975-11-03 | 1977-05-10 | Morris Goodman | Jewelry kit with decorative yarn or beads |
| US4099838A (en) | 1976-06-07 | 1978-07-11 | Minnesota Mining And Manufacturing Company | Reflective sheet material |
| US4102562A (en) | 1976-06-14 | 1978-07-25 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| US4082426A (en) | 1976-11-26 | 1978-04-04 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting with retroreflective markings |
| US4367920A (en) | 1979-10-01 | 1983-01-11 | Minnesota Mining And Manufacturing Company | Retroflective sheeting |
| US4630891A (en) | 1984-09-14 | 1986-12-23 | Minnesota Mining And Manufacturing Company | Tamper resistant security film |
| US4564556A (en) | 1984-09-24 | 1986-01-14 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous ceramic particulate |
| JPS61166501A (ja) | 1985-01-18 | 1986-07-28 | Yoshio Morita | 水溶液反応による二酸化チタン光学薄膜の形成方法 |
| US4688894A (en) | 1985-05-13 | 1987-08-25 | Minnesota Mining And Manufacturing Company | Transparent retroreflective sheets containing directional images and method for forming the same |
| CA1308845C (en) | 1986-01-13 | 1992-10-13 | Roger W. Lange | Pavement markings containing transparent non-vitreous ceramic microspheres |
| US4896943A (en) | 1987-05-13 | 1990-01-30 | Minnesota Mining And Manufacturing Company | Encapsulated-lens retroreflective sheeting having improved cover film |
| JP2546853B2 (ja) | 1987-09-03 | 1996-10-23 | オーツタイヤ株式会社 | 装飾性ビーズコートシートおよびその製造方法 |
| US4988541A (en) | 1988-06-09 | 1991-01-29 | Minnesota Mining And Manufacturing Company | Process for making retroreflector sheet |
| US4988555A (en) | 1988-06-09 | 1991-01-29 | Minnesota Mining And Manufacturing Company | Patterned pavement marking |
| US5227221A (en) | 1988-06-09 | 1993-07-13 | Minnesota Mining And Manufacturing Company | Patterned skid preventative sheet |
| JPH0299988A (ja) | 1988-10-06 | 1990-04-11 | Ichikoh Ind Ltd | 虹彩発光するマーク類の形成方法 |
| US4957335A (en) | 1989-05-26 | 1990-09-18 | Minnesota Mining And Manufacturing Company | Microsphere-based retroreflective articles with enhanced retroreflective brightness |
| DK257390A (da) | 1990-10-25 | 1992-04-26 | Reflex Promotion | Transfer til dekorering af overflader med billeder, der er ekstremt holdbare, og specielt billeder omfattende lysreflekterende og farvede omraader i vilkaarlig kombination, samt fremgangsmaade til fremstilling deraf |
| US5229882A (en) | 1990-05-16 | 1993-07-20 | Reflexite Corporation | Colored retroreflective sheeting and method of making same |
| US5254390B1 (en) | 1990-11-15 | 1999-05-18 | Minnesota Mining & Mfg | Plano-convex base sheet for retroreflective articles |
| US5169707A (en) | 1991-05-08 | 1992-12-08 | Minnesota Mining And Manufacturing Company | Retroreflective security laminates with dual level verification |
| JP2513976B2 (ja) | 1991-12-13 | 1996-07-10 | エイ・ティ・アンド・ティ・コーポレーション | 複数の球状部品の被覆方法 |
| US5344705A (en) | 1993-05-05 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| US5814367A (en) * | 1993-08-13 | 1998-09-29 | General Atomics | Broadband infrared and signature control materials and methods of producing the same |
| US5344024A (en) | 1993-09-28 | 1994-09-06 | Cohu Gary D | Case for storing, organizing and sorting small articles |
| WO1995031739A1 (en) | 1994-05-12 | 1995-11-23 | Minnesota Mining And Manufacturing Company | Retroreflective article and method of making same |
| US5673148A (en) | 1994-06-23 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Encapsulated retroreflective elements and method for making same |
| US5516227A (en) | 1994-07-07 | 1996-05-14 | Iit Research Institute | Spherodized fluorescent beads for improved roadway pavement marker visibility |
| EP0819953A3 (en) | 1994-11-29 | 1998-03-25 | Minnesota Mining And Manufacturing Company | Graphic media, transfer graphic, and decorative article formed therefrom |
| US5624731A (en) | 1995-03-10 | 1997-04-29 | Desjardins; Alexander | Multi-color, multi-image retroflective goniochromatic display |
| US5477219A (en) | 1995-03-30 | 1995-12-19 | Minnesota Mining And Manufacturing Company | Composite electronic article surveillance, identification, and security marker assembly and system |
| WO1997001776A1 (en) | 1995-06-29 | 1997-01-16 | Minnesota Mining & Mfg | Rainbow sheeting having distinct color changes and/or hidden images |
| US5620775A (en) | 1995-11-03 | 1997-04-15 | Minnesota Mining And Manufacturing Company | Low refractive index glass microsphere coated article having a smooth surface and a method for preparing same |
| JP3686167B2 (ja) | 1996-06-10 | 2005-08-24 | 日鉄鉱業株式会社 | 多層膜被覆粉体 |
| TW338078B (en) | 1996-07-08 | 1998-08-11 | Scapa Group Plc | Membrane felt for use in yankee machine |
| JPH10170710A (ja) | 1996-12-12 | 1998-06-26 | Minnesota Mining & Mfg Co <3M> | 光再帰性反射シート |
| US6000804A (en) | 1997-09-30 | 1999-12-14 | Shiseido Co., Ltd. | Colored light retroreflective material and retroreflective hologram reconstructor using the same |
| US6010770A (en) | 1997-10-21 | 2000-01-04 | Advanced Deposition Technologies, Inc. | Patterned retroreflective film and methods to produce |
| GB9816617D0 (en) | 1997-10-28 | 1998-09-30 | Melba Prod | Safety assemblies |
| JPH11175007A (ja) * | 1997-11-21 | 1999-07-02 | Minnesota Mining & Mfg Co <3M> | 自発光可能な再帰性反射シートおよびその製造方法 |
| US6045894A (en) | 1998-01-13 | 2000-04-04 | 3M Innovative Properties Company | Clear to colored security film |
| US6157486A (en) | 1998-01-13 | 2000-12-05 | 3M Innovative Properties Company | Retroreflective dichroic reflector |
| CA2329011A1 (en) | 1998-04-29 | 1999-11-04 | 3M Innovative Properties Company | Receptor sheet for inkjet printing having an embossed surface |
| ATE294963T1 (de) * | 1998-10-30 | 2005-05-15 | Avery Dennison Corp | Retroreflektierende folie mit einem bild zur echtheitsprüfung und verfahren zur ihrer herstellung |
| JP2000321414A (ja) | 1999-04-28 | 2000-11-24 | Three M Innovative Properties Co | 光再帰性反射シート |
| US6245700B1 (en) | 1999-07-27 | 2001-06-12 | 3M Innovative Properties Company | Transparent microspheres |
| JP2001272727A (ja) * | 2000-03-27 | 2001-10-05 | Olympus Optical Co Ltd | 透過型スクリーン |
| US6571955B1 (en) | 2000-06-27 | 2003-06-03 | Terri Rossman | Bead holder |
| US6500526B1 (en) * | 2000-09-28 | 2002-12-31 | Avery Dennison Corporation | Retroreflective sheeting containing a validation image and methods of making the same |
-
2002
- 2002-04-11 US US10/122,520 patent/US7036944B2/en not_active Expired - Lifetime
-
2003
- 2003-03-03 WO PCT/US2003/006597 patent/WO2003087896A1/en not_active Ceased
- 2003-03-03 AU AU2003213713A patent/AU2003213713A1/en not_active Abandoned
- 2003-03-03 EP EP03711401A patent/EP1495348B1/en not_active Expired - Lifetime
- 2003-03-03 JP JP2003584781A patent/JP4308025B2/ja not_active Expired - Fee Related
- 2003-03-03 DE DE60328370T patent/DE60328370D1/de not_active Expired - Lifetime
- 2003-03-03 CN CN03808051.6A patent/CN1646950B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1646950A (zh) | 2005-07-27 |
| WO2003087896A1 (en) | 2003-10-23 |
| EP1495348A1 (en) | 2005-01-12 |
| EP1495348B1 (en) | 2009-07-15 |
| US7036944B2 (en) | 2006-05-02 |
| CN1646950B (zh) | 2010-05-26 |
| JP2005522730A (ja) | 2005-07-28 |
| DE60328370D1 (de) | 2009-08-27 |
| AU2003213713A1 (en) | 2003-10-27 |
| US20030193718A1 (en) | 2003-10-16 |
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