JP4231480B2 - ガスクロマトグラフィー用の化合物前処理濃縮器 - Google Patents
ガスクロマトグラフィー用の化合物前処理濃縮器 Download PDFInfo
- Publication number
- JP4231480B2 JP4231480B2 JP2004523394A JP2004523394A JP4231480B2 JP 4231480 B2 JP4231480 B2 JP 4231480B2 JP 2004523394 A JP2004523394 A JP 2004523394A JP 2004523394 A JP2004523394 A JP 2004523394A JP 4231480 B2 JP4231480 B2 JP 4231480B2
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- JP
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- Prior art keywords
- housing
- carrier gas
- tube
- compound
- adsorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 title claims description 100
- 238000004817 gas chromatography Methods 0.000 title claims description 13
- 238000004587 chromatography analysis Methods 0.000 claims description 100
- 239000012159 carrier gas Substances 0.000 claims description 97
- 239000003463 adsorbent Substances 0.000 claims description 76
- 239000000203 mixture Substances 0.000 claims description 31
- 238000009423 ventilation Methods 0.000 claims description 25
- 239000012530 fluid Substances 0.000 claims description 23
- 239000007789 gas Substances 0.000 claims description 23
- 238000002955 isolation Methods 0.000 claims description 22
- 238000010438 heat treatment Methods 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 238000005070 sampling Methods 0.000 claims description 12
- 238000004891 communication Methods 0.000 claims description 11
- 238000012546 transfer Methods 0.000 claims description 7
- 239000006229 carbon black Substances 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 239000000523 sample Substances 0.000 description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 241000255925 Diptera Species 0.000 description 3
- 230000000712 assembly Effects 0.000 description 3
- 238000000429 assembly Methods 0.000 description 3
- 239000012494 Quartz wool Substances 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000011491 glass wool Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000004094 preconcentration Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
- G01N1/2226—Sampling from a closed space, e.g. food package, head space
- G01N2001/2229—Headspace sampling, i.e. vapour over liquid
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/08—Preparation using an enricher
- G01N2030/085—Preparation using an enricher using absorbing precolumn
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
- G01N2030/121—Preparation by evaporation cooling; cold traps
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
- G01N2030/126—Preparation by evaporation evaporating sample
- G01N2030/127—PTV evaporation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
- G01N2030/126—Preparation by evaporation evaporating sample
- G01N2030/128—Thermal desorption analysis
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sampling And Sample Adjustment (AREA)
- Drying Of Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/202,147 US6652625B1 (en) | 2002-07-24 | 2002-07-24 | Analyte pre-concentrator for gas chromatography |
| US10/625,259 US6814785B2 (en) | 2002-07-24 | 2003-07-22 | Analyte pre-concentrator for gas chromatography |
| PCT/US2003/023223 WO2004009202A2 (en) | 2002-07-24 | 2003-07-24 | Analyte pre-concentrator for gas chromatography |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006516717A JP2006516717A (ja) | 2006-07-06 |
| JP2006516717A5 JP2006516717A5 (https=) | 2008-07-03 |
| JP4231480B2 true JP4231480B2 (ja) | 2009-02-25 |
Family
ID=31980922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004523394A Expired - Lifetime JP4231480B2 (ja) | 2002-07-24 | 2003-07-24 | ガスクロマトグラフィー用の化合物前処理濃縮器 |
Country Status (6)
| Country | Link |
|---|---|
| US (4) | US6814785B2 (https=) |
| EP (1) | EP1585586B1 (https=) |
| JP (1) | JP4231480B2 (https=) |
| AU (1) | AU2003256772A1 (https=) |
| CA (1) | CA2493449C (https=) |
| WO (1) | WO2004009202A2 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2697575C1 (ru) * | 2018-05-03 | 2019-08-15 | Общество с ограниченной ответственностью "КимТэк" | Устройство подготовки пробы для анализа примесей малолетучих полярных веществ в жидких средах |
Families Citing this family (44)
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|---|---|---|---|---|
| US6814785B2 (en) * | 2002-07-24 | 2004-11-09 | Perkinelmer Instruments Llc | Analyte pre-concentrator for gas chromatography |
| ES2245236B1 (es) * | 2004-06-01 | 2006-12-01 | Universidad De Huelva | Hibridacion de las tecnicas de espacio de cabeza dinamico y perevaporacion analitica. |
| US7284410B2 (en) * | 2004-06-29 | 2007-10-23 | Perkinelmer Las, Inc. | Chromatographic interface for thermal desorption systems |
| IL162906A (en) * | 2004-07-07 | 2013-12-31 | Israel Inst Biolog Res | Method, device and system for detecting and identifying chemical agents |
| WO2006015008A1 (en) * | 2004-07-26 | 2006-02-09 | Perkinelmer Las, Inc. | System for regulating fluid flowing through chromatographic column |
| JP4600053B2 (ja) * | 2005-01-24 | 2010-12-15 | 東ソー株式会社 | クロマトグラフ分析に使用されるデータ処理装置 |
| US7517395B2 (en) * | 2005-12-01 | 2009-04-14 | Agilent Technologies, Inc. | Seal having low friction non-stick surface layer |
| DE102005060291A1 (de) * | 2005-12-15 | 2007-06-28 | Gerstel Systemtechnik Gmbh & Co.Kg | Verfahren zur Vorbereitung von Proben für ein Analysegerät und Probennahmestation hierfür |
| DE102005060303A1 (de) * | 2005-12-16 | 2007-06-28 | Gerstel Systemtechnik Gmbh & Co.Kg | Verfahren zur Vorbereitung von Proben für ein Analysegerät und Probenvorbereitungsstation hierfür |
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| US7524363B2 (en) * | 2006-05-16 | 2009-04-28 | Alliant Techsystems Inc. | Gas chromatograph column assembly |
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| EP2541244B1 (en) * | 2006-08-18 | 2017-05-03 | PerkinElmer, Inc. | Devices for circulating air in a gas chromatography system |
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| US8506688B2 (en) * | 2008-01-18 | 2013-08-13 | Restek Corporation | Gas chromatographic device |
| US7867325B2 (en) * | 2008-01-18 | 2011-01-11 | Restek Corporation | Gas chromatographic device |
| JP5695561B2 (ja) | 2008-05-27 | 2015-04-08 | パーキンエルマー・ヘルス・サイエンシーズ・インコーポレイテッドPerkinelmer Health Sciences, Inc. | クロマトグラフィーシステムおよびそれを用いた方法 |
| JP4840409B2 (ja) * | 2008-06-17 | 2011-12-21 | 株式会社島津製作所 | ガスクロマトグラフ |
| JP4743270B2 (ja) * | 2008-12-24 | 2011-08-10 | 株式会社島津製作所 | ガスクロマトグラフ |
| DE102009003429B3 (de) * | 2009-02-04 | 2010-07-01 | Joint Analytical Systems Gmbh | Vorrichtung und Verfahren zum Aufbereiten von Proben für die Gaschromatografie |
| AU2010228936B2 (en) * | 2009-03-24 | 2015-07-09 | Perkinelmer U.S. Llc | Sorbent devices with longitudinal diffusion paths and methods of using them |
| US8388736B2 (en) * | 2009-10-02 | 2013-03-05 | Perkinelmer Health Sciences, Inc. | Sorbent devices and methods of using them |
| AU2011267964B2 (en) | 2010-06-14 | 2015-07-09 | Perkinelmer U.S. Llc | Fluidic devices and methods of using them |
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| EP2618913B1 (en) | 2010-09-22 | 2019-07-03 | PerkinElmer Health Sciences, Inc. | Backflush methods and devices for chromatography |
| WO2012074560A1 (en) * | 2010-12-03 | 2012-06-07 | Restek Corporation | Gas chromatography inlet liner having a colored region |
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| US11467136B2 (en) * | 2017-12-20 | 2022-10-11 | Chromatography Research Supplies, Inc. | Chambered septum |
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| CN116194752A (zh) | 2020-08-11 | 2023-05-30 | 因泰科设备股份有限公司 | 用于在gcms分析之前改进样品制备的基质加速真空辅助吸附剂萃取的系统和方法 |
| IT202000019936A1 (it) * | 2020-08-11 | 2022-02-11 | Chemical Res 2000 Srl | Preparazione di filtri adsorbenti premarcati con standards per la valutazione di campionamenti d’inquinanti in matrici liquide e aeriformi |
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-
2003
- 2003-07-22 US US10/625,259 patent/US6814785B2/en not_active Expired - Lifetime
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2697575C1 (ru) * | 2018-05-03 | 2019-08-15 | Общество с ограниченной ответственностью "КимТэк" | Устройство подготовки пробы для анализа примесей малолетучих полярных веществ в жидких средах |
Also Published As
| Publication number | Publication date |
|---|---|
| US20080098887A1 (en) | 2008-05-01 |
| WO2004009202A3 (en) | 2004-03-04 |
| AU2003256772A1 (en) | 2004-02-09 |
| JP2006516717A (ja) | 2006-07-06 |
| CA2493449A1 (en) | 2004-01-29 |
| CA2493449C (en) | 2008-11-18 |
| US20050039602A1 (en) | 2005-02-24 |
| EP1585586A4 (en) | 2006-01-04 |
| AU2003256772A8 (en) | 2004-02-09 |
| EP1585586A2 (en) | 2005-10-19 |
| US6814785B2 (en) | 2004-11-09 |
| WO2004009202B1 (en) | 2004-04-29 |
| US7572319B2 (en) | 2009-08-11 |
| EP1585586B1 (en) | 2015-09-02 |
| US6974495B2 (en) | 2005-12-13 |
| US20040016341A1 (en) | 2004-01-29 |
| WO2004009202A2 (en) | 2004-01-29 |
| US20060021504A1 (en) | 2006-02-02 |
| US7311757B2 (en) | 2007-12-25 |
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