JP4180383B2 - 水系システム用腐食防止剤 - Google Patents
水系システム用腐食防止剤 Download PDFInfo
- Publication number
- JP4180383B2 JP4180383B2 JP2002577739A JP2002577739A JP4180383B2 JP 4180383 B2 JP4180383 B2 JP 4180383B2 JP 2002577739 A JP2002577739 A JP 2002577739A JP 2002577739 A JP2002577739 A JP 2002577739A JP 4180383 B2 JP4180383 B2 JP 4180383B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- corrosion
- water
- hypophosphite
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
- C02F5/145—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus combined with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/54—Compositions for in situ inhibition of corrosion in boreholes or wells
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/12—Oxygen-containing compounds
- C23F11/128—Esters of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/167—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/173—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F14/00—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes
- C23F14/02—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes by chemical means
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fireproofing Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US82449201A | 2001-04-02 | 2001-04-02 | |
| PCT/US2002/005598 WO2002079105A1 (en) | 2001-04-02 | 2002-02-25 | Corrosion inhibitors for aqueous systems |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004532351A JP2004532351A (ja) | 2004-10-21 |
| JP2004532351A5 JP2004532351A5 (enExample) | 2008-09-04 |
| JP4180383B2 true JP4180383B2 (ja) | 2008-11-12 |
Family
ID=25241530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002577739A Expired - Lifetime JP4180383B2 (ja) | 2001-04-02 | 2002-02-25 | 水系システム用腐食防止剤 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6572789B1 (enExample) |
| EP (1) | EP1379473B1 (enExample) |
| JP (1) | JP4180383B2 (enExample) |
| KR (1) | KR100983521B1 (enExample) |
| CN (1) | CN1244503C (enExample) |
| AT (1) | ATE527218T1 (enExample) |
| AU (1) | AU2002252089B2 (enExample) |
| BR (1) | BR0208594B1 (enExample) |
| CA (1) | CA2442474C (enExample) |
| ES (1) | ES2374284T3 (enExample) |
| HU (1) | HU228325B1 (enExample) |
| PL (1) | PL206324B1 (enExample) |
| RU (1) | RU2324767C2 (enExample) |
| WO (1) | WO2002079105A1 (enExample) |
Families Citing this family (90)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2002346240B2 (en) * | 2001-06-06 | 2006-10-26 | Thermphos Trading Gmbh | Method and aqueous composition for the production of improved pulp |
| MY138251A (en) * | 2001-06-06 | 2009-05-29 | Thermphos Trading Gmbh | Method for inhibiting calcium salt scale |
| MY129053A (en) * | 2001-06-06 | 2007-03-30 | Thermphos Trading Gmbh | Composition for inhibiting calcium salt scale |
| US7578968B1 (en) | 2002-05-03 | 2009-08-25 | Albemarle Corporation | Microbiological control in oil or gas field operations |
| US20040120853A1 (en) * | 2002-12-20 | 2004-06-24 | Carpenter Joel F. | Biocidal control in recovery of oil by water injection |
| US7152662B2 (en) * | 2003-07-30 | 2006-12-26 | Alcoa Inc. | Method of preventing cracking in direct chill cast ingots |
| US7223719B1 (en) | 2004-03-16 | 2007-05-29 | Albemarle Corporation | Breaker composition and process |
| KR101300541B1 (ko) | 2005-06-24 | 2013-09-02 | 프레스톤 프로닥츠 코포레이션 | 경납땜된 금속 표면의 부식을 억제하는 방법 및 거기에사용하기 위한 냉각제 및 첨가제 |
| US8673297B2 (en) | 2006-02-28 | 2014-03-18 | Basf Corporation | Chlorine dioxide based cleaner/sanitizer |
| RU2327650C1 (ru) * | 2006-08-30 | 2008-06-27 | Сергей Васильевич Петров | Композиция для предотвращения солеотложений и коррозии |
| US20080169243A1 (en) * | 2007-01-11 | 2008-07-17 | Dave Bhasker B | Method of inhibiting scale formation and deposition in desalination systems |
| US20090101587A1 (en) * | 2007-10-22 | 2009-04-23 | Peter Blokker | Method of inhibiting scale formation and deposition in desalination systems |
| US9187650B2 (en) | 2007-11-02 | 2015-11-17 | United Technologies Corporation | Anodic-cathodic corrosion inhibitor-conductive polymer composite |
| US8771542B2 (en) * | 2008-07-11 | 2014-07-08 | Prestone Products Corporation | Heat transfer fluid, additive package, system and method |
| JP5914907B2 (ja) * | 2008-08-11 | 2016-05-11 | 株式会社オートネットワーク技術研究所 | 防錆剤および表面処理金属材 |
| US20100063180A1 (en) * | 2008-09-05 | 2010-03-11 | Seungkoo Kang | Fire protection and/or fire fighting additives, associated compositions, and associated methods |
| US8025840B2 (en) * | 2008-10-31 | 2011-09-27 | General Electric Company | Compositions and methods for inhibiting corrosion in aqueous media |
| US8021607B2 (en) * | 2008-10-31 | 2011-09-20 | General Electric Company | Methods for inhibiting corrosion in aqueous media |
| WO2010054224A2 (en) | 2008-11-07 | 2010-05-14 | Honeywell International Inc. | Heat transfer fluids and corrosion inhibitor formulations for use thereof |
| KR101090702B1 (ko) | 2009-06-25 | 2011-12-08 | 현대자동차주식회사 | 알루미늄 백록 저감 조성물 |
| RU2430997C2 (ru) * | 2009-09-24 | 2011-10-10 | Федеральное государственное унитарное предприятие "Российский научный центр "Прикладная химия" | Ингибитор коррозии |
| JP5571795B2 (ja) | 2009-10-16 | 2014-08-13 | ダウ グローバル テクノロジーズ エルエルシー | ダイヤモンドワイヤーソーと共に使用する水性切削液 |
| MX2009013704A (es) | 2009-12-15 | 2011-06-15 | Mexicano Inst Petrol | Nuevos surfactantes geminales, proceso de obtencion y uso como inhibidores de corrosion multifuncionales. |
| US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
| US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
| CN102080233B (zh) * | 2010-12-23 | 2012-05-30 | 常州市科威精细化工有限公司 | 用于循环冷却水系统预膜处理的无磷预膜剂及其使用方法 |
| EP2681157B1 (de) * | 2011-03-04 | 2019-12-18 | Aquis Wasser-Luft-Systeme GmbH, Lindau, Zweigniederlassung Rebstein | Wasserkonditionierungsvorrichtung zur vermeidung oder reduzierung von mineralausfällungen |
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| RU2489467C2 (ru) * | 2011-04-18 | 2013-08-10 | Государственное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный университет низкотемпературных и пищевых технологий" | Хладоноситель |
| CN102747372B (zh) * | 2011-04-22 | 2014-09-17 | 比亚迪股份有限公司 | 一种铜保护剂及其制备方法和铜的保护方法 |
| US10259734B1 (en) * | 2011-04-26 | 2019-04-16 | Mansour S. Bader | Effective de-scaling for desalination plants and a new brine-forward multi-stage flash concept |
| US8845986B2 (en) | 2011-05-13 | 2014-09-30 | ADA-ES, Inc. | Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers |
| RU2486139C2 (ru) * | 2011-06-22 | 2013-06-27 | Государственное образовательное учреждение высшего профессионального образования Уральский государственный лесотехнический университет | Способ предотвращения солеотложений и коррозии в системах водоснабжения |
| KR101782585B1 (ko) | 2011-08-03 | 2017-09-28 | 삼성디스플레이 주식회사 | 광 감지 패널 및 이를 갖는 표시장치 |
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| JP6227248B2 (ja) * | 2012-12-27 | 2017-11-08 | 出光興産株式会社 | 水系冷却剤 |
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| US10351453B2 (en) * | 2016-04-14 | 2019-07-16 | Nch Corporation | Composition and method for inhibiting corrosion |
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| TW201816069A (zh) | 2016-07-12 | 2018-05-01 | 美商普勒斯頓產物公司 | 熱傳送流體及防止熱傳送系統腐蝕之方法 |
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| US20190226094A1 (en) * | 2018-01-19 | 2019-07-25 | Baker Hughes, A Ge Company, Llc | Phosphorous-free, and iron activating agent-free rust removal, inhibition, and passivation |
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| WO2021025888A1 (en) | 2019-08-07 | 2021-02-11 | Ecolab Usa Inc. | Corrosion inhibitor for systems with mixed metallurgy |
| WO2021080780A1 (en) | 2019-10-23 | 2021-04-29 | Baker Hughes Oilfield Operations Llc | Energized well treating fluids and methods of using same |
| CN115667585A (zh) | 2020-05-28 | 2023-01-31 | 埃科莱布美国股份有限公司 | 采用聚马来酸盐和非硼酸盐缓冲液的闭环冷却水腐蚀抑制 |
| CN119053560A (zh) * | 2022-06-23 | 2024-11-29 | 埃科莱布美国股份有限公司 | 在工业水系统中抑制金属腐蚀的方法 |
| CN115233231B (zh) * | 2022-07-29 | 2024-08-20 | 北京蓝星清洗有限公司 | 具有清洗功能的组合物和应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3389173A (en) * | 1966-03-31 | 1968-06-18 | Halcon International Inc | Process for preparing fumaric acid of good color from maleic acid |
| GB1521440A (en) | 1976-07-01 | 1978-08-16 | Nalco Chemical Co | Method of producing phosphinico substituted aliphatic carboxylic acids |
| US4088678A (en) | 1976-07-01 | 1978-05-09 | Nalco Chemical Company | Substituted succinic acid compounds and their use as chelants |
| AU572825B2 (en) | 1983-03-03 | 1988-05-19 | Fmc Corporation (Uk) Limited | Inhibition of corrosion and scale formation of metal surfaces |
| US5085794A (en) | 1990-04-25 | 1992-02-04 | Nalco Chemical Company | Oligomer containing phosphinate compositions and their method of manufacture |
| US5023000A (en) | 1990-05-10 | 1991-06-11 | Nalco Chemical Company | Oligomer-containing phosphate scale inhibitors |
| US5018577A (en) | 1990-08-02 | 1991-05-28 | Nalco Chemical Company | Phosphinate inhibitor for scale squeeze applications |
| US5386038A (en) | 1990-12-18 | 1995-01-31 | Albright & Wilson Limited | Water treatment agent |
| GB9610112D0 (en) * | 1996-05-15 | 1996-07-24 | Albright & Wilson | Water treatment compositions |
-
2001
- 2001-12-06 US US10/010,021 patent/US6572789B1/en not_active Expired - Lifetime
-
2002
- 2002-02-25 BR BRPI0208594-1A patent/BR0208594B1/pt not_active IP Right Cessation
- 2002-02-25 RU RU2003132068/15A patent/RU2324767C2/ru active
- 2002-02-25 HU HU0303762A patent/HU228325B1/hu unknown
- 2002-02-25 AT AT02721144T patent/ATE527218T1/de active
- 2002-02-25 ES ES02721144T patent/ES2374284T3/es not_active Expired - Lifetime
- 2002-02-25 WO PCT/US2002/005598 patent/WO2002079105A1/en not_active Ceased
- 2002-02-25 KR KR1020037013011A patent/KR100983521B1/ko not_active Expired - Lifetime
- 2002-02-25 CN CNB028110706A patent/CN1244503C/zh not_active Expired - Lifetime
- 2002-02-25 JP JP2002577739A patent/JP4180383B2/ja not_active Expired - Lifetime
- 2002-02-25 EP EP02721144A patent/EP1379473B1/en not_active Expired - Lifetime
- 2002-02-25 AU AU2002252089A patent/AU2002252089B2/en not_active Expired
- 2002-02-25 PL PL364137A patent/PL206324B1/pl unknown
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Also Published As
| Publication number | Publication date |
|---|---|
| ATE527218T1 (de) | 2011-10-15 |
| BR0208594B1 (pt) | 2011-02-08 |
| US6572789B1 (en) | 2003-06-03 |
| RU2003132068A (ru) | 2005-03-10 |
| JP2004532351A (ja) | 2004-10-21 |
| ES2374284T3 (es) | 2012-02-15 |
| CA2442474A1 (en) | 2002-10-10 |
| CN1512968A (zh) | 2004-07-14 |
| HUP0303762A2 (hu) | 2004-03-01 |
| KR20030097819A (ko) | 2003-12-31 |
| KR100983521B1 (ko) | 2010-09-27 |
| EP1379473A4 (en) | 2005-08-10 |
| HU228325B1 (en) | 2013-03-28 |
| EP1379473A1 (en) | 2004-01-14 |
| WO2002079105A1 (en) | 2002-10-10 |
| HUP0303762A3 (en) | 2008-03-28 |
| EP1379473B1 (en) | 2011-10-05 |
| AU2002252089B2 (en) | 2007-11-29 |
| CN1244503C (zh) | 2006-03-08 |
| RU2324767C2 (ru) | 2008-05-20 |
| PL364137A1 (en) | 2004-12-13 |
| BR0208594A (pt) | 2004-12-21 |
| CA2442474C (en) | 2009-12-08 |
| PL206324B1 (pl) | 2010-07-30 |
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