JP4077403B2 - レーザーマーキング方法 - Google Patents
レーザーマーキング方法 Download PDFInfo
- Publication number
- JP4077403B2 JP4077403B2 JP2003504161A JP2003504161A JP4077403B2 JP 4077403 B2 JP4077403 B2 JP 4077403B2 JP 2003504161 A JP2003504161 A JP 2003504161A JP 2003504161 A JP2003504161 A JP 2003504161A JP 4077403 B2 JP4077403 B2 JP 4077403B2
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- Japan
- Prior art keywords
- alkyl
- methyl
- diethylamino
- copolymers
- ring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000010330 laser marking Methods 0.000 title description 4
- 239000002253 acid Substances 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 19
- 238000004040 coloring Methods 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 20
- 239000002861 polymer material Substances 0.000 claims description 17
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
- 125000000623 heterocyclic group Chemical group 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 125000004122 cyclic group Chemical group 0.000 claims description 7
- 125000006413 ring segment Chemical group 0.000 claims description 7
- 125000001424 substituent group Chemical group 0.000 claims description 7
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- FLFWJIBUZQARMD-UHFFFAOYSA-N 2-mercapto-1,3-benzoxazole Chemical compound C1=CC=C2OC(S)=NC2=C1 FLFWJIBUZQARMD-UHFFFAOYSA-N 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 5
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 150000002596 lactones Chemical class 0.000 claims description 3
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 claims description 3
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract 1
- -1 4-hydroxy-3- i-propyl-6-methylphenyl Chemical group 0.000 description 109
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- 239000000203 mixture Substances 0.000 description 21
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- 239000005977 Ethylene Substances 0.000 description 16
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 15
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
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- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 4
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- 150000007513 acids Chemical class 0.000 description 4
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- 229920001971 elastomer Polymers 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 125000004076 pyridyl group Chemical group 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- 229920002396 Polyurea Polymers 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
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- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
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- 125000004434 sulfur atom Chemical group 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- RMZZBGUNXMGXCD-UHFFFAOYSA-N 3',6,6'-tris(dimethylamino)spiro[2-benzofuran-3,9'-fluorene]-1-one Chemical compound C12=CC=C(N(C)C)C=C2C2=CC(N(C)C)=CC=C2C21OC(=O)C1=CC(N(C)C)=CC=C21 RMZZBGUNXMGXCD-UHFFFAOYSA-N 0.000 description 2
- CONFUNYOPVYVDC-UHFFFAOYSA-N 3,3-bis(1-ethyl-2-methylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC=C2C(C3(C4=CC=CC=C4C(=O)O3)C3=C(C)N(C4=CC=CC=C43)CC)=C(C)N(CC)C2=C1 CONFUNYOPVYVDC-UHFFFAOYSA-N 0.000 description 2
- XOEUNIAGBKGZLU-UHFFFAOYSA-N 3,3-bis(2-methyl-1-octylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC=C2C(C3(C4=CC=CC=C4C(=O)O3)C3=C(C)N(C4=CC=CC=C43)CCCCCCCC)=C(C)N(CCCCCCCC)C2=C1 XOEUNIAGBKGZLU-UHFFFAOYSA-N 0.000 description 2
- ABJAMKKUHBSXDS-UHFFFAOYSA-N 3,3-bis(6-amino-1,4-dimethylcyclohexa-2,4-dien-1-yl)-2-benzofuran-1-one Chemical compound C1=CC(C)=CC(N)C1(C)C1(C2(C)C(C=C(C)C=C2)N)C2=CC=CC=C2C(=O)O1 ABJAMKKUHBSXDS-UHFFFAOYSA-N 0.000 description 2
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 2
- UFPJLFNADVHTGA-UHFFFAOYSA-N 7-[4-(2-cyclohexylethylamino)-2-methoxyphenyl]-7-(1-ethyl-2-methylindol-3-yl)furo[3,4-b]pyridin-5-one Chemical compound C12=CC=CC=C2N(CC)C(C)=C1C1(C2=NC=CC=C2C(=O)O1)C(C(=C1)OC)=CC=C1NCCC1CCCCC1 UFPJLFNADVHTGA-UHFFFAOYSA-N 0.000 description 2
- RCVMSMLWRJESQC-UHFFFAOYSA-N 7-[4-(diethylamino)-2-ethoxyphenyl]-7-(1-ethyl-2-methylindol-3-yl)furo[3,4-b]pyridin-5-one Chemical compound CCOC1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C2=NC=CC=C2C(=O)O1 RCVMSMLWRJESQC-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
- G03F7/105—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having substances, e.g. indicators, for forming visible images
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/72—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
- G03C1/73—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705 containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/333—Colour developing components therefor, e.g. acidic compounds
- B41M5/3333—Non-macromolecular compounds
- B41M5/3335—Compounds containing phenolic or carboxylic acid groups or metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0077—Preparations with possibly reduced vat, sulfur or indigo dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
- B41M5/327—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
- B41M5/327—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
- B41M5/3275—Fluoran compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Optics & Photonics (AREA)
- General Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Dot-Matrix Printers And Others (AREA)
- Paper (AREA)
- Laser Beam Processing (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0114266.0A GB0114266D0 (en) | 2001-06-12 | 2001-06-12 | Laser marking method |
| PCT/EP2002/006105 WO2002101462A1 (en) | 2001-06-12 | 2002-06-04 | Laser marking method |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004529395A JP2004529395A (ja) | 2004-09-24 |
| JP2004529395A5 JP2004529395A5 (enExample) | 2006-01-05 |
| JP4077403B2 true JP4077403B2 (ja) | 2008-04-16 |
Family
ID=9916404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003504161A Expired - Fee Related JP4077403B2 (ja) | 2001-06-12 | 2002-06-04 | レーザーマーキング方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7264916B2 (enExample) |
| EP (1) | EP1407322B1 (enExample) |
| JP (1) | JP4077403B2 (enExample) |
| KR (1) | KR100866271B1 (enExample) |
| CN (1) | CN100354750C (enExample) |
| AT (1) | ATE418089T1 (enExample) |
| BR (1) | BR0210343A (enExample) |
| CA (1) | CA2448380A1 (enExample) |
| CZ (1) | CZ200445A3 (enExample) |
| DE (1) | DE60230417D1 (enExample) |
| GB (1) | GB0114266D0 (enExample) |
| IL (2) | IL158925A0 (enExample) |
| MX (1) | MXPA03011066A (enExample) |
| TW (1) | TWI226970B (enExample) |
| WO (1) | WO2002101462A1 (enExample) |
| ZA (1) | ZA200308987B (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7393623B2 (en) | 2001-06-06 | 2008-07-01 | Spectra Systems Corporation | Incorporation of markings in optical media |
| AU2002346244A1 (en) | 2001-06-06 | 2002-12-16 | Spectra Systems Corporation | Marking articles using a covert digitally watermarked image |
| GB0228647D0 (en) * | 2002-12-09 | 2003-01-15 | Ciba Sc Holding Ag | Polyeric material containing a latent acid |
| US20070080146A1 (en) * | 2003-11-10 | 2007-04-12 | Werner Stockum | Coloured laser marking |
| US7727702B2 (en) * | 2004-04-07 | 2010-06-01 | Ciba Specialty Chemicals Corp. | Method of coloring a coating composition |
| KR101193824B1 (ko) * | 2004-07-20 | 2012-10-24 | 시바 홀딩 인크 | 옥심 유도체 및 잠산으로서의 이의 용도 |
| US20060072444A1 (en) * | 2004-09-29 | 2006-04-06 | Engel David B | Marked article and method of making the same |
| US7459259B2 (en) | 2004-09-29 | 2008-12-02 | Sabic Innovative Plastics Ip B.V. | Marked article and method of making the same |
| EP1916278A4 (en) * | 2005-08-18 | 2011-07-20 | Mitsubishi Eng Plastics Corp | POYAMIDE RESIN COMPOSITION FOR LASER MARKING AND LASER MARKED POLYAMIDE RESIN COMPONENTS |
| US20070248781A1 (en) * | 2006-04-25 | 2007-10-25 | Gore Makarand P | Photochemical and photothermal rearrangements for optical data and image recording |
| WO2008022952A1 (en) | 2006-08-24 | 2008-02-28 | Ciba Holding Inc. | Uv-dosis indicators |
| DE102007036623A1 (de) | 2007-07-03 | 2009-01-08 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal und Verfahren zu seiner Herstellung |
| US8120811B2 (en) | 2007-11-21 | 2012-02-21 | Quad/Graphics, Inc. | System and method for adding data to a printed publication |
| EP2240831B1 (en) | 2008-01-24 | 2015-03-25 | Quad/Graphics, Inc. | Printing using color changeable material |
| DE102008019092A1 (de) | 2008-04-16 | 2009-10-22 | Giesecke & Devrient Gmbh | Verfahren zur Herstellung eines Sicherheits- oder Wertdokuments |
| DE102008049848A1 (de) | 2008-10-01 | 2010-04-08 | Tesa Se | Mehrbereichsindikator |
| DE102009011424A1 (de) | 2008-12-22 | 2010-07-01 | Giesecke & Devrient Gmbh | Datenträger mit Durchsichtsbereich |
| KR20110137821A (ko) | 2009-03-30 | 2011-12-23 | 바스프 에스이 | Ｕｖ-조사량 인디케이터 필름 |
| DE102010022990A1 (de) * | 2010-06-08 | 2011-12-08 | Giesecke & Devrient Gmbh | Datenträger mit Merkmalsbereich |
| CN104004426B (zh) * | 2014-06-17 | 2016-08-17 | 上海交通大学 | 一种对紫外光有响应特性的高分子水性涂料 |
| BR112017023170B1 (pt) | 2015-04-29 | 2022-08-16 | Bsn Medical Gmbh | Dispositivo de banho medicinal e seu uso |
| CN107809996A (zh) | 2015-04-29 | 2018-03-16 | Bsn医疗有限公司 | 一氧化氮产生的多步骤方法 |
| DE102015005672A1 (de) | 2015-05-04 | 2016-11-10 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
| DE102016002120A1 (de) | 2016-02-24 | 2017-08-24 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
| DE102016006929A1 (de) | 2016-06-06 | 2017-12-07 | Giesecke+Devrient Currency Technology Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
| DE102016006931A1 (de) | 2016-06-06 | 2017-12-07 | Giesecke+Devrient Currency Technology Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4343885A (en) | 1978-05-09 | 1982-08-10 | Dynachem Corporation | Phototropic photosensitive compositions containing fluoran colorformer |
| US4552830A (en) * | 1978-05-09 | 1985-11-12 | Dynachem Corporation | Carbonylic halides as activators for phototropic compositions |
| WO1988007222A1 (en) * | 1987-03-19 | 1988-09-22 | Xytronyx, Inc. | Systems for the visualization of exposure to ultraviolet radiation and for the utilization of ultraviolet radiation to effect color changes |
| JP2779559B2 (ja) * | 1991-09-04 | 1998-07-23 | 本田技研工業株式会社 | レーダ装置 |
| US5677107A (en) | 1991-10-02 | 1997-10-14 | Spectra Group Limited, Inc. | Production of three-dimensional objects |
| JP2751089B2 (ja) | 1992-11-30 | 1998-05-18 | 大日本インキ化学工業株式会社 | レーザーマーキング方法及び印刷インキ |
| DE69418826T2 (de) * | 1993-11-22 | 1999-10-21 | Ciba Specialty Chemicals Holding Inc., Basel | Zusammensetzungen zur Herstellung strukturierter Farbbilder und deren Anwendung |
| US5885746A (en) | 1994-12-29 | 1999-03-23 | Tokyo Ohka Kogyo Co., Ltd. | Photosensitive resin composition, photosensitive printing plate using the same and method of manufacturing printing master plate |
| JPH08240908A (ja) * | 1994-12-29 | 1996-09-17 | Tokyo Ohka Kogyo Co Ltd | 感光性樹脂組成物、それを用いた感光性平版印刷版、および平版印刷用版材の製造方法 |
| DE69632168T2 (de) * | 1995-05-12 | 2004-08-12 | Ciba Specialty Chemicals Holding Inc. | Verfahren zum Färben von hochmolekularen organischen Kunststoffen in der Masse mit löslichen phthalocyaninen Precursoren |
| US5568086A (en) * | 1995-05-25 | 1996-10-22 | Motorola, Inc. | Linear power amplifier for high efficiency multi-carrier performance |
| GB0114265D0 (en) * | 2001-06-12 | 2001-08-01 | Ciba Sc Holding Ag | Polymeric material containing a latent acid |
-
2001
- 2001-06-12 GB GBGB0114266.0A patent/GB0114266D0/en not_active Ceased
-
2002
- 2002-06-04 WO PCT/EP2002/006105 patent/WO2002101462A1/en not_active Ceased
- 2002-06-04 JP JP2003504161A patent/JP4077403B2/ja not_active Expired - Fee Related
- 2002-06-04 EP EP02778877A patent/EP1407322B1/en not_active Expired - Lifetime
- 2002-06-04 CA CA002448380A patent/CA2448380A1/en not_active Abandoned
- 2002-06-04 DE DE60230417T patent/DE60230417D1/de not_active Expired - Lifetime
- 2002-06-04 KR KR1020037016213A patent/KR100866271B1/ko not_active Expired - Fee Related
- 2002-06-04 CN CNB028117301A patent/CN100354750C/zh not_active Expired - Fee Related
- 2002-06-04 AT AT02778877T patent/ATE418089T1/de not_active IP Right Cessation
- 2002-06-04 MX MXPA03011066A patent/MXPA03011066A/es active IP Right Grant
- 2002-06-04 CZ CZ200445A patent/CZ200445A3/cs unknown
- 2002-06-04 BR BR0210343-5A patent/BR0210343A/pt not_active IP Right Cessation
- 2002-06-04 IL IL15892502A patent/IL158925A0/xx active IP Right Grant
- 2002-06-04 US US10/479,944 patent/US7264916B2/en not_active Expired - Fee Related
- 2002-06-10 TW TW091112498A patent/TWI226970B/zh not_active IP Right Cessation
-
2003
- 2003-11-18 IL IL158925A patent/IL158925A/en not_active IP Right Cessation
- 2003-11-19 ZA ZA200308987A patent/ZA200308987B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR100866271B1 (ko) | 2008-11-03 |
| IL158925A0 (en) | 2004-05-12 |
| EP1407322A1 (en) | 2004-04-14 |
| KR20040030670A (ko) | 2004-04-09 |
| DE60230417D1 (de) | 2009-01-29 |
| CZ200445A3 (cs) | 2004-04-14 |
| BR0210343A (pt) | 2004-07-20 |
| US7264916B2 (en) | 2007-09-04 |
| CA2448380A1 (en) | 2002-12-19 |
| EP1407322B1 (en) | 2008-12-17 |
| CN100354750C (zh) | 2007-12-12 |
| JP2004529395A (ja) | 2004-09-24 |
| US20040152008A1 (en) | 2004-08-05 |
| MXPA03011066A (es) | 2004-03-19 |
| WO2002101462A1 (en) | 2002-12-19 |
| TWI226970B (en) | 2005-01-21 |
| ZA200308987B (en) | 2004-06-09 |
| IL158925A (en) | 2008-06-05 |
| ATE418089T1 (de) | 2009-01-15 |
| CN1514952A (zh) | 2004-07-21 |
| GB0114266D0 (en) | 2001-08-01 |
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