JP3974152B2 - 低密着性材料、樹脂成形型及び防汚性材料 - Google Patents
低密着性材料、樹脂成形型及び防汚性材料 Download PDFInfo
- Publication number
- JP3974152B2 JP3974152B2 JP2006017335A JP2006017335A JP3974152B2 JP 3974152 B2 JP3974152 B2 JP 3974152B2 JP 2006017335 A JP2006017335 A JP 2006017335A JP 2006017335 A JP2006017335 A JP 2006017335A JP 3974152 B2 JP3974152 B2 JP 3974152B2
- Authority
- JP
- Japan
- Prior art keywords
- low adhesion
- materials
- sro
- resin
- adhesion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims description 510
- 229920005989 resin Polymers 0.000 title claims description 144
- 239000011347 resin Substances 0.000 title claims description 144
- 230000003373 anti-fouling effect Effects 0.000 title claims description 28
- 239000000126 substance Substances 0.000 claims description 104
- 229910021193 La 2 O 3 Inorganic materials 0.000 claims description 102
- 239000006104 solid solution Substances 0.000 claims description 88
- 239000002131 composite material Substances 0.000 claims description 60
- 239000000203 mixture Substances 0.000 claims description 42
- 239000002994 raw material Substances 0.000 claims description 41
- 230000014759 maintenance of location Effects 0.000 claims description 36
- 239000012530 fluid Substances 0.000 claims description 30
- 239000000853 adhesive Substances 0.000 claims description 14
- 230000001070 adhesive effect Effects 0.000 claims description 14
- 239000005416 organic matter Substances 0.000 claims description 4
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 description 71
- 239000003822 epoxy resin Substances 0.000 description 19
- 229920000647 polyepoxide Polymers 0.000 description 19
- 229910002056 binary alloy Inorganic materials 0.000 description 15
- 238000010587 phase diagram Methods 0.000 description 15
- 238000000034 method Methods 0.000 description 11
- 238000000465 moulding Methods 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000012986 modification Methods 0.000 description 8
- 230000004048 modification Effects 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- 229910052746 lanthanum Inorganic materials 0.000 description 7
- 239000011368 organic material Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 6
- 229910052712 strontium Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- -1 polytetrafluoroethylene Polymers 0.000 description 5
- 229910001315 Tool steel Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000001721 transfer moulding Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005090 crystal field Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
- C04B35/505—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds based on yttrium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3213—Strontium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3227—Lanthanum oxide or oxide-forming salts thereof
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006017335A JP3974152B2 (ja) | 2006-01-26 | 2006-01-26 | 低密着性材料、樹脂成形型及び防汚性材料 |
| KR1020077027278A KR100961798B1 (ko) | 2006-01-26 | 2006-12-27 | 저밀착성 재료, 수지 성형틀 및 방오성 재료 |
| KR1020097013884A KR20090082293A (ko) | 2006-01-26 | 2006-12-27 | 저밀착성 재료, 수지 성형틀 및 방오성 재료 |
| EP06843407A EP1978005A4 (en) | 2006-01-26 | 2006-12-27 | LOW-ADHESIVE MATERIAL, RESIN FORMING AND STAIN-RESISTANT MATERIAL |
| PCT/JP2006/326025 WO2007086228A1 (ja) | 2006-01-26 | 2006-12-27 | 低密着性材料、樹脂成形型および防汚性材料 |
| US11/920,421 US20080296532A1 (en) | 2006-01-26 | 2006-12-27 | Low Adhesion Material, Resin Molding Die, and Soil Resistant Material |
| CNA2006800290224A CN101238081A (zh) | 2006-01-26 | 2006-12-27 | 低粘附性材料、树脂成形模以及防污性材料 |
| TW095150108A TW200730467A (en) | 2006-01-26 | 2006-12-29 | Low adhesion material, resin forming mold and anti-fouling materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006017335A JP3974152B2 (ja) | 2006-01-26 | 2006-01-26 | 低密着性材料、樹脂成形型及び防汚性材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007197251A JP2007197251A (ja) | 2007-08-09 |
| JP3974152B2 true JP3974152B2 (ja) | 2007-09-12 |
Family
ID=38309029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006017335A Expired - Fee Related JP3974152B2 (ja) | 2006-01-26 | 2006-01-26 | 低密着性材料、樹脂成形型及び防汚性材料 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20080296532A1 (enExample) |
| EP (1) | EP1978005A4 (enExample) |
| JP (1) | JP3974152B2 (enExample) |
| KR (2) | KR20090082293A (enExample) |
| CN (1) | CN101238081A (enExample) |
| TW (1) | TW200730467A (enExample) |
| WO (1) | WO2007086228A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3996138B2 (ja) * | 2004-03-26 | 2007-10-24 | Towa株式会社 | 低密着性材料及び樹脂成形型 |
| JP4230492B2 (ja) | 2006-04-11 | 2009-02-25 | Towa株式会社 | 低密着性材料、樹脂成形型及び防汚性材料 |
| JP5554898B2 (ja) * | 2008-03-24 | 2014-07-23 | Towa株式会社 | 低密着性材料及びその製造方法、成形型及びその製造方法、並びに、防汚性材料及びその製造方法 |
| JP5561992B2 (ja) * | 2009-10-09 | 2014-07-30 | Towa株式会社 | 低密着性材料、防汚性材料、成形型、及び、それらの製造方法 |
| WO2016019418A1 (en) * | 2014-08-08 | 2016-02-11 | Pullman Espresso Accessories | Improved coffee tamper with step design |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1449899A (fr) * | 1965-07-09 | 1966-05-06 | Combustible Nucleaire | Matériau réfractaire résistant aux métaux liquides réactifs, tels que l'uranium |
| US4040845A (en) * | 1976-03-04 | 1977-08-09 | The Garrett Corporation | Ceramic composition and crucibles and molds formed therefrom |
| US4115134A (en) * | 1977-07-11 | 1978-09-19 | Gte Laboratories Incorporated | Transparent yttria ceramics and method for producing same |
| DE3683086D1 (de) * | 1985-06-06 | 1992-02-06 | Remet Corp | Giessen von reaktionsfaehigen metallen in keramische formen. |
| US4769353A (en) * | 1986-11-04 | 1988-09-06 | General Electric Company | Strontium-containing yttrium oxide ceramic body |
| US4761390A (en) * | 1987-02-02 | 1988-08-02 | Raytheon Company | Optically transparent yttrium oxide |
| JPH04164859A (ja) * | 1990-10-30 | 1992-06-10 | Onoda Cement Co Ltd | 軽希土類酸化物焼結体、その製造方法及びそれよりなるルツボ |
| US5494866A (en) * | 1991-06-17 | 1996-02-27 | Alliedsignal Inc. | Stress-rupture resistant sintered silicon nitride |
| JP2500631B2 (ja) * | 1993-07-23 | 1996-05-29 | 品川白煉瓦株式会社 | MgO部分安定化ZrO2焼結体製ダイス又はニップル |
| JP4240516B2 (ja) * | 1998-11-26 | 2009-03-18 | Toto株式会社 | 防汚性部材 |
| JP2005193610A (ja) * | 2004-01-09 | 2005-07-21 | Towa Corp | 複合材料及び樹脂成形型 |
| JP4518808B2 (ja) * | 2004-02-09 | 2010-08-04 | Towa株式会社 | 導電性多孔質材料、その材料からなる樹脂成形型、及びその材料の製造方法 |
| JP3996138B2 (ja) * | 2004-03-26 | 2007-10-24 | Towa株式会社 | 低密着性材料及び樹脂成形型 |
| JP2006131429A (ja) * | 2004-11-02 | 2006-05-25 | Towa Corp | 低密着性材料及び樹脂成形型 |
| DE102006027958A1 (de) * | 2006-06-14 | 2007-12-20 | Schott Ag | Optokeramiken, daraus hergestellte optische Elemente sowie Abbildungsoptiken |
-
2006
- 2006-01-26 JP JP2006017335A patent/JP3974152B2/ja not_active Expired - Fee Related
- 2006-12-27 KR KR1020097013884A patent/KR20090082293A/ko not_active Withdrawn
- 2006-12-27 CN CNA2006800290224A patent/CN101238081A/zh active Pending
- 2006-12-27 EP EP06843407A patent/EP1978005A4/en not_active Withdrawn
- 2006-12-27 US US11/920,421 patent/US20080296532A1/en not_active Abandoned
- 2006-12-27 KR KR1020077027278A patent/KR100961798B1/ko not_active Expired - Fee Related
- 2006-12-27 WO PCT/JP2006/326025 patent/WO2007086228A1/ja not_active Ceased
- 2006-12-29 TW TW095150108A patent/TW200730467A/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TW200730467A (en) | 2007-08-16 |
| US20080296532A1 (en) | 2008-12-04 |
| KR100961798B1 (ko) | 2010-06-08 |
| EP1978005A4 (en) | 2011-05-25 |
| JP2007197251A (ja) | 2007-08-09 |
| EP1978005A1 (en) | 2008-10-08 |
| KR20080015803A (ko) | 2008-02-20 |
| CN101238081A (zh) | 2008-08-06 |
| TWI339198B (enExample) | 2011-03-21 |
| WO2007086228A1 (ja) | 2007-08-02 |
| KR20090082293A (ko) | 2009-07-29 |
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