JP3817011B2 - 共役ジエンモノマーの重合方法 - Google Patents

共役ジエンモノマーの重合方法 Download PDF

Info

Publication number
JP3817011B2
JP3817011B2 JP06136097A JP6136097A JP3817011B2 JP 3817011 B2 JP3817011 B2 JP 3817011B2 JP 06136097 A JP06136097 A JP 06136097A JP 6136097 A JP6136097 A JP 6136097A JP 3817011 B2 JP3817011 B2 JP 3817011B2
Authority
JP
Japan
Prior art keywords
polymer
vinyl content
microstructure
conjugated diene
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP06136097A
Other languages
English (en)
Japanese (ja)
Other versions
JPH09328504A5 (enExample
JPH09328504A (ja
Inventor
アーサー・ロビンソン・ビーン・ジユニア
テーニス・フラーフラント
Original Assignee
シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー filed Critical シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー
Publication of JPH09328504A publication Critical patent/JPH09328504A/ja
Publication of JPH09328504A5 publication Critical patent/JPH09328504A5/ja
Application granted granted Critical
Publication of JP3817011B2 publication Critical patent/JP3817011B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP06136097A 1996-03-18 1997-03-14 共役ジエンモノマーの重合方法 Expired - Fee Related JP3817011B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US1354996P 1996-03-18 1996-03-18
US013549 1996-03-18

Publications (3)

Publication Number Publication Date
JPH09328504A JPH09328504A (ja) 1997-12-22
JPH09328504A5 JPH09328504A5 (enExample) 2004-10-14
JP3817011B2 true JP3817011B2 (ja) 2006-08-30

Family

ID=21760516

Family Applications (1)

Application Number Title Priority Date Filing Date
JP06136097A Expired - Fee Related JP3817011B2 (ja) 1996-03-18 1997-03-14 共役ジエンモノマーの重合方法

Country Status (11)

Country Link
US (1) US5795944A (enExample)
EP (1) EP0796871B1 (enExample)
JP (1) JP3817011B2 (enExample)
KR (1) KR100479887B1 (enExample)
CN (1) CN1130391C (enExample)
BR (1) BR9701296A (enExample)
CA (1) CA2200020A1 (enExample)
DE (1) DE69701296T2 (enExample)
ES (1) ES2142131T3 (enExample)
TW (1) TW425409B (enExample)
ZA (1) ZA972227B (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5795944A (en) * 1996-03-18 1998-08-18 Shell Oil Company Programmed addition of heavy ethers for microstructure control of diene polymers
USH1956H1 (en) * 1997-07-23 2001-04-03 Shell Oil Company Enhanced hydrogenation catalyst removal from block copolymers by reduction in polymer cement viscosity by increasing the vinyl content of the block copolymers
DE19801101A1 (de) * 1998-01-15 1999-07-22 Basf Ag Verfahren zur Herstellung von statistischen Styrol-Butadien-Copolymeren
JP5372309B2 (ja) * 2000-06-30 2013-12-18 クレイトン・ポリマーズ・リサーチ・ベー・ベー 両方とも硬いポリスチレンブロックおよび低ビニル含量ポリジエンブロックを含有するブロック共重合体
EP1381302B1 (en) * 2001-04-20 2008-06-18 Power Medical Interventions, Inc. Imaging device
US20030181584A1 (en) 2002-02-07 2003-09-25 Kraton Polymers U.S. Llc Elastomeric articles prepared from controlled distribution block copolymers
US6987142B2 (en) 2002-02-07 2006-01-17 Kraton Polymers U.S. Llc Adhesives and sealants from controlled distribution block copolymers
US7012118B2 (en) 2002-02-07 2006-03-14 Kraton Polymers U.S. Llc Photopolymerizable compositions and flexographic plates prepared from controlled distribution block copolymers
US6703449B1 (en) 2002-12-20 2004-03-09 Kraton Polymers U.S. Llc Block copolymers containing both polystyrene and low vinyl content polydiene hard blocks
US20040147686A1 (en) * 2002-12-31 2004-07-29 Kraton Polymers U.S. Llc Process for preparing hydrogenated conjugated diene block copolymers
US7125940B2 (en) * 2002-12-31 2006-10-24 Kraton Polymers U.S. Llc Conjugated diene polymers and copolymer blocks and process for preparing same
WO2005030821A1 (en) * 2003-09-24 2005-04-07 Kraton Polymers Research B.V. Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same
US7241540B2 (en) * 2004-04-27 2007-07-10 Kraton Polymers U.S. Llc Photocurable compositions and flexographic printing plates comprising the same
CN101628959A (zh) * 2008-07-15 2010-01-20 中国石油化工集团公司 一种可发泡苯乙烯属单体-二烯烃共聚物、其制备方法和用途
US11608404B2 (en) * 2020-05-22 2023-03-21 Kraton Corporation Block copolymers and polymer modified bitumen therefrom
DE202023001437U1 (de) 2022-07-15 2023-09-08 Kraton Polymers Nederland B.V. Silanfunktionalisiertes Styrol-Blockcopolymer

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5792014A (en) * 1980-11-27 1982-06-08 Sumitomo Rubber Ind Ltd Conjugated diene block polymer
GB8316052D0 (en) * 1983-06-13 1983-07-20 Shell Int Research Elastomeric copolymers
GB8407629D0 (en) * 1984-03-23 1984-05-02 Shell Int Research Preparation of polymers
US4748222A (en) * 1986-03-31 1988-05-31 The Dow Chemical Company Preparation of highly pure alpha-methylstyrene polymer
US5241008A (en) * 1991-09-03 1993-08-31 Bridgestone/Firestone, Inc. Process for producing continuously tapered polymers and copolymers and products produced thereby
US5276099A (en) * 1991-12-30 1994-01-04 Bridgestone Corporation (Vinyl sulfoxide)-capped elastomers and compositions containing them having reduced hysteresis properties
JP2611717B2 (ja) * 1992-06-10 1997-05-21 住友化学工業株式会社 ブタジエン系共重合体
US5329005A (en) * 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
US5332810A (en) * 1992-10-02 1994-07-26 Bridgestone Corporation Solubilized anionic polymerization initiator and preparation thereof
US5346962A (en) * 1993-11-03 1994-09-13 Bridgestone/Firestone, Inc. Elastomers having reduced hysteresis prepared with vinyl imidazole
US5795944A (en) * 1996-03-18 1998-08-18 Shell Oil Company Programmed addition of heavy ethers for microstructure control of diene polymers

Also Published As

Publication number Publication date
MX9701913A (es) 1998-05-31
CN1130391C (zh) 2003-12-10
ES2142131T3 (es) 2000-04-01
EP0796871B1 (en) 2000-02-16
CN1163277A (zh) 1997-10-29
JPH09328504A (ja) 1997-12-22
BR9701296A (pt) 1998-11-10
DE69701296D1 (de) 2000-03-23
EP0796871A2 (en) 1997-09-24
KR970065562A (ko) 1997-10-13
DE69701296T2 (de) 2000-07-27
CA2200020A1 (en) 1997-09-18
EP0796871A3 (en) 1998-04-15
US5795944A (en) 1998-08-18
ZA972227B (en) 1997-09-25
KR100479887B1 (ko) 2005-07-18
TW425409B (en) 2001-03-11

Similar Documents

Publication Publication Date Title
JP3817011B2 (ja) 共役ジエンモノマーの重合方法
US5296574A (en) Method of synthesis of block copolymers of vinyl aromatic hydrocarbons and polydimethylsiloxane
Quirk et al. Anionic synthesis of heteroarm, star-branched polymers. Scope and limitations
US3992483A (en) Promoters in the polymerization of monovinyl-aromatic compounds with primary lithium initiators
JPH03294318A (ja) テーパーブロックコポリマーの製造方法
US10889676B2 (en) Method for synthesizing a thermoplastic elastomer comprising at least one poly(α-methylstyrene) block
US5194530A (en) Termination of anionic polymerization using hydrocarbon terminating agents
RU2675525C1 (ru) Сополимеры сопряженных диенов и винилароматических мономеров и способ их получения. Резиновые смеси на основе указанных сополимеров
US3580895A (en) Production of copolymers in the presence of an organolithium compound and an orthoester
US5276095A (en) Star block copolymers of vinyl aromatic hydrocarbons and polydimethylsiloxane and method of synthesis
Liu et al. Synthesis and characterization of the well-defined polypentadiene via living anionic polymerization of (E)-1, 3-pentadiene
CN100509879C (zh) 含有环乙烯基单元的二烯高弹体及其制备工艺
EP0998502B1 (en) Enhanced hydrogenation catalyst removal from block copolymers by reduction in polymer cement viscosity by increasing the vinyl content of the block copolymers
US5914378A (en) Anionic copolymerization of conjugated dienes and vinyl arenes in the presence of alkyl ethers of tetrahydropyranyl methanol
US6107408A (en) Processes for improving linking efficiencies in the synthesis of star polymers
GB2112002A (en) Aromatic - diene - pivalolactone block copolymer
US4297451A (en) Dienyllithium initiated polymers
US5151475A (en) Termination of anionic polymerization
US4232137A (en) Cooling an alpha-methylstyrene polymerization mass
US6384164B2 (en) Process for the preparation of a branched diene elastomer via an anionic route
Adams et al. The Impact of Lithium Initiators on the Preparation of Synthetic Rubbers
MXPA97001913A (en) Process for the polymerization of monomeros dedieno conjug
JPH03134008A (ja) 星形に分枝したコポリマー、その水素化生成物およびリビングポリマー用のカプリング剤
RU2128669C1 (ru) Способ получения модифицированного полибутадиена
RU2141976C1 (ru) Способ получения термоэластопластов

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20051222

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20060110

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060405

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20060530

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20060609

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100616

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100616

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110616

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110616

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120616

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130616

Year of fee payment: 7

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees