KR970065562A - 공액 디엔 단량체의 중합 방법 - Google Patents
공액 디엔 단량체의 중합 방법 Download PDFInfo
- Publication number
- KR970065562A KR970065562A KR1019970008827A KR19970008827A KR970065562A KR 970065562 A KR970065562 A KR 970065562A KR 1019970008827 A KR1019970008827 A KR 1019970008827A KR 19970008827 A KR19970008827 A KR 19970008827A KR 970065562 A KR970065562 A KR 970065562A
- Authority
- KR
- South Korea
- Prior art keywords
- och
- added
- polymerization
- butoxy
- ethane
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
본 발명은 단량체를 음이온성 중합 개시제 및 수득된 중합체의 비닐 함량 조절용 미세구조 조절제의 존재하에서 음이온 중합하는 것을 포함하고, 조절제가 2 이상의 용량으로 또는 연속적으로 중합 혼합물에 부가되는 공액 디엔 단량체의 중합 방법을 제공한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (7)
- 단량체를 음이온성 중합 개시제 및 수득된 중합제의 비닐 함량 조절용 미세 구조 조절제의 존재하에서 음이온 중합하는 것을 포함하고, 조절제가 2 이상의 용량으로 또는 연속적으로 중합 혼합물에 부가되는 공액 디엔 단량체의 중합 방법.
- 제1항에 있어서, 중합이 제1단열 단계 및 제2동온 단계로 수행되고, 조절제가 중합 혼합물에 중합체의 비닐 함량을 비교적 일정하게 유지하기에 충분한양 및 횟수로 단열 단계동안 부가되는 방법.
- 제1항 또는 제2항에 있어서, 조절제가 1, 2-디에톡시-에탄, 1, 2-디에톡시-프로판, 1, 2-디-n-부톡시-에탄, 1-t-부톡시-2-n-부톡시-에탄, n-C4H9OCH2CH2O-n-C4H9, n-C4H9OCH2CH2OCH2OCH3,n-C4H9OCH2CH2OCHCH3OCH2OCH3,n-C4H9OCH2CH2O-t-C4H9및 n-C4H9OCH2CH2OCHCH3-O-i-C4H9로 이루어진 그룹 중에서 선택되는 방법.
- 제3항에 있어서, 조절제가 1, 2-디에톡시에탄 또는 1, 2-디에톡시프로판인 방법.
- 제1항 내지 4항 중 어는 한 항에 있어서, 조절제가 100내 300ppm의 양으로 사용되는 방법.
- 제1항 내지 5항 중 어느 한 항에 있어서, 조절제가 실질적으로 상이한 비닐 함량을 지닌 디엔 블럭이 생성될 정도의 양 및 횟수로 부가되는 방법.
- 제1항 내지 6항 중 어느 한 항에 있어서, 조절제가 중합 혼합물에 연속적을 부가되는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1354996P | 1996-03-18 | 1996-03-18 | |
US60/013549 | 1996-03-18 | ||
US60/013,549 | 1996-03-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970065562A true KR970065562A (ko) | 1997-10-13 |
KR100479887B1 KR100479887B1 (ko) | 2005-07-18 |
Family
ID=21760516
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019970008827A KR100479887B1 (ko) | 1996-03-18 | 1997-03-15 | 공액디엔단량체의중합방법 |
Country Status (11)
Country | Link |
---|---|
US (1) | US5795944A (ko) |
EP (1) | EP0796871B1 (ko) |
JP (1) | JP3817011B2 (ko) |
KR (1) | KR100479887B1 (ko) |
CN (1) | CN1130391C (ko) |
BR (1) | BR9701296A (ko) |
CA (1) | CA2200020A1 (ko) |
DE (1) | DE69701296T2 (ko) |
ES (1) | ES2142131T3 (ko) |
TW (1) | TW425409B (ko) |
ZA (1) | ZA972227B (ko) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5795944A (en) * | 1996-03-18 | 1998-08-18 | Shell Oil Company | Programmed addition of heavy ethers for microstructure control of diene polymers |
USH1956H1 (en) | 1997-07-23 | 2001-04-03 | Shell Oil Company | Enhanced hydrogenation catalyst removal from block copolymers by reduction in polymer cement viscosity by increasing the vinyl content of the block copolymers |
DE19801101A1 (de) * | 1998-01-15 | 1999-07-22 | Basf Ag | Verfahren zur Herstellung von statistischen Styrol-Butadien-Copolymeren |
US8262560B2 (en) * | 2001-04-20 | 2012-09-11 | Tyco Healthcare Group Lp | Imaging device for use with a surgical device |
BR0112058A (pt) * | 2000-06-30 | 2003-12-30 | Kraton Polymers Res Bv | Copolìmero em bloco, e, composto |
US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
US7012118B2 (en) | 2002-02-07 | 2006-03-14 | Kraton Polymers U.S. Llc | Photopolymerizable compositions and flexographic plates prepared from controlled distribution block copolymers |
US6759454B2 (en) | 2002-02-07 | 2004-07-06 | Kraton Polymers U.S. Llc | Polymer modified bitumen compositions |
US6703449B1 (en) | 2002-12-20 | 2004-03-09 | Kraton Polymers U.S. Llc | Block copolymers containing both polystyrene and low vinyl content polydiene hard blocks |
US20040147686A1 (en) * | 2002-12-31 | 2004-07-29 | Kraton Polymers U.S. Llc | Process for preparing hydrogenated conjugated diene block copolymers |
US7125940B2 (en) * | 2002-12-31 | 2006-10-24 | Kraton Polymers U.S. Llc | Conjugated diene polymers and copolymer blocks and process for preparing same |
US7166679B2 (en) * | 2003-09-24 | 2007-01-23 | Kraton Polymers Llc | Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same |
US7241540B2 (en) * | 2004-04-27 | 2007-07-10 | Kraton Polymers U.S. Llc | Photocurable compositions and flexographic printing plates comprising the same |
CN101628959A (zh) * | 2008-07-15 | 2010-01-20 | 中国石油化工集团公司 | 一种可发泡苯乙烯属单体-二烯烃共聚物、其制备方法和用途 |
US11608404B2 (en) * | 2020-05-22 | 2023-03-21 | Kraton Corporation | Block copolymers and polymer modified bitumen therefrom |
DE202023001437U1 (de) | 2022-07-15 | 2023-09-08 | Kraton Polymers Nederland B.V. | Silanfunktionalisiertes Styrol-Blockcopolymer |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5792014A (en) * | 1980-11-27 | 1982-06-08 | Sumitomo Rubber Ind Ltd | Conjugated diene block polymer |
GB8316052D0 (en) * | 1983-06-13 | 1983-07-20 | Shell Int Research | Elastomeric copolymers |
GB8407629D0 (en) * | 1984-03-23 | 1984-05-02 | Shell Int Research | Preparation of polymers |
US4748222A (en) * | 1986-03-31 | 1988-05-31 | The Dow Chemical Company | Preparation of highly pure alpha-methylstyrene polymer |
US5241008A (en) * | 1991-09-03 | 1993-08-31 | Bridgestone/Firestone, Inc. | Process for producing continuously tapered polymers and copolymers and products produced thereby |
US5276099A (en) * | 1991-12-30 | 1994-01-04 | Bridgestone Corporation | (Vinyl sulfoxide)-capped elastomers and compositions containing them having reduced hysteresis properties |
JP2611717B2 (ja) * | 1992-06-10 | 1997-05-21 | 住友化学工業株式会社 | ブタジエン系共重合体 |
US5329005A (en) * | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
US5332810A (en) * | 1992-10-02 | 1994-07-26 | Bridgestone Corporation | Solubilized anionic polymerization initiator and preparation thereof |
US5346962A (en) * | 1993-11-03 | 1994-09-13 | Bridgestone/Firestone, Inc. | Elastomers having reduced hysteresis prepared with vinyl imidazole |
US5795944A (en) * | 1996-03-18 | 1998-08-18 | Shell Oil Company | Programmed addition of heavy ethers for microstructure control of diene polymers |
-
1997
- 1997-03-12 US US08/820,404 patent/US5795944A/en not_active Expired - Lifetime
- 1997-03-14 ZA ZA9702227A patent/ZA972227B/xx unknown
- 1997-03-14 JP JP06136097A patent/JP3817011B2/ja not_active Expired - Fee Related
- 1997-03-14 CA CA002200020A patent/CA2200020A1/en not_active Abandoned
- 1997-03-14 BR BR9701296A patent/BR9701296A/pt active Search and Examination
- 1997-03-14 CN CN97109643A patent/CN1130391C/zh not_active Expired - Fee Related
- 1997-03-15 KR KR1019970008827A patent/KR100479887B1/ko not_active IP Right Cessation
- 1997-03-17 DE DE69701296T patent/DE69701296T2/de not_active Expired - Lifetime
- 1997-03-17 ES ES97200791T patent/ES2142131T3/es not_active Expired - Lifetime
- 1997-03-17 EP EP97200791A patent/EP0796871B1/en not_active Expired - Lifetime
- 1997-05-26 TW TW086107205A patent/TW425409B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US5795944A (en) | 1998-08-18 |
TW425409B (en) | 2001-03-11 |
EP0796871A2 (en) | 1997-09-24 |
ZA972227B (en) | 1997-09-25 |
JP3817011B2 (ja) | 2006-08-30 |
CN1130391C (zh) | 2003-12-10 |
ES2142131T3 (es) | 2000-04-01 |
CA2200020A1 (en) | 1997-09-18 |
DE69701296T2 (de) | 2000-07-27 |
JPH09328504A (ja) | 1997-12-22 |
MX9701913A (es) | 1998-05-31 |
BR9701296A (pt) | 1998-11-10 |
EP0796871B1 (en) | 2000-02-16 |
KR100479887B1 (ko) | 2005-07-18 |
CN1163277A (zh) | 1997-10-29 |
EP0796871A3 (en) | 1998-04-15 |
DE69701296D1 (de) | 2000-03-23 |
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