JP2024538197A - Ｚｓｍ－５モレキュラーシーブ触媒、その調製方法およびその応用 - Google Patents

Ｚｓｍ－５モレキュラーシーブ触媒、その調製方法およびその応用 Download PDF

Info

Publication number
JP2024538197A
JP2024538197A JP2024523449A JP2024523449A JP2024538197A JP 2024538197 A JP2024538197 A JP 2024538197A JP 2024523449 A JP2024523449 A JP 2024523449A JP 2024523449 A JP2024523449 A JP 2024523449A JP 2024538197 A JP2024538197 A JP 2024538197A
Authority
JP
Japan
Prior art keywords
catalyst
hours
molecular sieve
zsm
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2024523449A
Other languages
English (en)
Japanese (ja)
Other versions
JP2024538197A5 (enExample
Inventor
滕加偉
任麗萍
趙国良
史静
謝在庫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Shanghai Research Institute of Petrochemical Technology
Original Assignee
Sinopec Shanghai Research Institute of Petrochemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sinopec Shanghai Research Institute of Petrochemical Technology filed Critical Sinopec Shanghai Research Institute of Petrochemical Technology
Publication of JP2024538197A publication Critical patent/JP2024538197A/ja
Publication of JP2024538197A5 publication Critical patent/JP2024538197A5/ja
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2024523449A 2021-10-19 2022-10-18 Ｚｓｍ－５モレキュラーシーブ触媒、その調製方法およびその応用 Pending JP2024538197A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN202111217885.7 2021-10-19
CN202111217885.7A CN115990508B (zh) 2021-10-19 2021-10-19 一种zsm-5分子筛催化剂及其制备方法和应用
PCT/CN2022/125833 WO2023066225A1 (zh) 2021-10-19 2022-10-18 一种zsm-5分子筛催化剂及其制备方法和应用

Publications (2)

Publication Number Publication Date
JP2024538197A true JP2024538197A (ja) 2024-10-18
JP2024538197A5 JP2024538197A5 (enExample) 2024-11-14

Family

ID=85992928

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2024523449A Pending JP2024538197A (ja) 2021-10-19 2022-10-18 Ｚｓｍ－５モレキュラーシーブ触媒、その調製方法およびその応用

Country Status (6)

Country Link
US (1) US20250235854A1 (enExample)
EP (1) EP4420780A4 (enExample)
JP (1) JP2024538197A (enExample)
KR (1) KR20240090507A (enExample)
CN (1) CN115990508B (enExample)
WO (1) WO2023066225A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119425772B (zh) * 2023-08-01 2025-10-31 中国石油化工股份有限公司 一种碳四烯烃裂解制丙烯乙烯的催化剂及制备方法和应用
CN119488946B (zh) * 2023-08-18 2026-02-10 中国石油化工股份有限公司 3d打印分子筛催化剂的制备方法及制备得到的3d打印分子筛催化剂与应用
CN117085730A (zh) * 2023-08-23 2023-11-21 安徽国星生物化学有限公司 一种丙烯醛、液氨合成3-甲基吡啶的催化剂的制备方法
CN119657212B (zh) * 2023-09-21 2025-11-25 中国石油化工股份有限公司 一种丁烯裂解制乙烯和丙烯催化剂及其制备方法和应用
CN117563658B (zh) * 2023-11-21 2025-12-12 中国石油大学(北京) 提高催化裂解产物中乙烯丙烯比的zsm-5分子筛改性方法及其所得的分子筛和应用
WO2025261370A1 (zh) * 2024-06-19 2025-12-26 中国石油化工股份有限公司 一种zsm-5分子筛、制备方法和轻质化的方法
CN119281236B (zh) * 2024-12-13 2025-03-18 延边大学 一种超薄片层反应釜及其快速合成亚微米zsm-5沸石的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104226360A (zh) * 2013-06-17 2014-12-24 中国石油化工股份有限公司 全结晶zsm-5分子筛催化剂及其制备方法和用途

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3372474D1 (en) 1982-11-10 1987-08-20 Montedipe Spa Process for converting olefins having 4 to 12 carbon atoms into propylene
JP3707607B2 (ja) 1998-08-25 2005-10-19 旭化成ケミカルズ株式会社 エチレンおよびプロピレンの製造方法
EP1508555A1 (en) * 2003-08-19 2005-02-23 Total Petrochemicals Research Feluy Production of olefins
JP5426983B2 (ja) * 2009-09-30 2014-02-26 旭化成ケミカルズ株式会社 Ｚｓｍ−５型ゼオライトの製造方法
CN103071522B (zh) * 2012-12-26 2018-01-05 宁夏大学 一种c4‑c6混合烃催化裂解增产丙烯和乙烯的催化剂及方法
CN104107709A (zh) * 2013-04-16 2014-10-22 中国石油化工股份有限公司 无粘结剂zsm-5分子筛催化剂及其制备方法和用途
CN104646047B (zh) * 2013-11-22 2017-04-05 中国石油天然气股份有限公司 一种多级孔复合分子筛及其制备和应用
CN112387303B (zh) * 2019-08-14 2024-04-26 国家能源投资集团有限责任公司 改性zsm-5分子筛及其制备方法和应用以及催化剂及其应用

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104226360A (zh) * 2013-06-17 2014-12-24 中国石油化工股份有限公司 全结晶zsm-5分子筛催化剂及其制备方法和用途

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"Conversion of methanol to propylene over hierarchical HZSM-5: the effect of Al spatial distributio", CHEMICAL COMMUNICATIONS, vol. 54, JPN6025039055, 2018, pages 6032 - 6035, ISSN: 0005829507 *
"Conversion of methanol to propylene over hierarchical HZSM-5: the effect of Al spatial distribution", CHEMICAL COMMUNICATIONS, JPN6025039056, 2018, ISSN: 0005829508 *

Also Published As

Publication number Publication date
EP4420780A4 (en) 2025-10-22
KR20240090507A (ko) 2024-06-21
EP4420780A1 (en) 2024-08-28
CN115990508B (zh) 2025-07-25
CN115990508A (zh) 2023-04-21
WO2023066225A1 (zh) 2023-04-27
US20250235854A1 (en) 2025-07-24

Similar Documents

Publication Publication Date Title
JP2024538197A (ja) Ｚｓｍ－５モレキュラーシーブ触媒、その調製方法およびその応用
CN108046288B (zh) 一种制备用于甲醇制丙烯的多级孔zsm-5分子筛的方法
CN101462071B (zh) 一种催化裂解生产丙烯的催化剂及其制备方法
CN108726535B (zh) 一种具有多级孔的磷改性zsm-5分子筛的制备方法
US9480975B2 (en) Catalyst for catalytic cracking in a fluidized bed
JP5588973B2 (ja) 結晶質メタロシリケートの製造方法
JP7467475B2 (ja) Ｃ４－ｃ７炭化水素から軽質オレフィンを製造するための触媒
JP2014024005A (ja) ゼオライト触媒、ゼオライト触媒の製造方法および低級オレフィンの製造方法
CN115990513B (zh) 烯烃催化裂解生产丙烯催化剂及其制备方法和应用
EP4596104A1 (en) Mfi molecular sieve catalyst, preparation method therefor and use thereof
CN101993091B (zh) 一种合成zsm-5沸石的方法
JP2014024006A (ja) ゼオライト触媒、ゼオライト触媒の製造方法および低級オレフィンの製造方法
CN115990506B (zh) 碳四混合烃共裂解的催化剂及其制备方法和应用
CN109665540A (zh) 一种zsm-5/zsm-48共晶分子筛及其制备方法与应用
RU2844805C2 (ru) Катализатор, содержащий молекулярное сито типа zsm-5, способ его получения и его применение
CN113042094A (zh) 含镧及含镍或/和锌的多级结构zsm-5分子筛及其制备方法和应用
CN113117729B (zh) 异构化催化剂及其制备方法
CN114479909B (zh) 一种烃转化的方法及催化剂和催化剂制法
CN112725023B (zh) 一种两段加氢裂化工艺
CN112121850B (zh) 流化床催化剂和二甲苯的生产方法
CN117654598B (zh) 催化汽油降烯烃芳构化催化剂及其制备方法和应用
RU2860434C2 (ru) Содержащий молекулярное сито mfi катализатор, способ его изготовления и его применение
JP6251788B2 (ja) ゼオライト触媒、ゼオライト触媒の製造方法および低級オレフィンの製造方法
CN119143148B (zh) 弱酸性mww分子筛及其制备方法与应用、芳烃化合物的制备方法
CN116199239B (zh) 一种低硅纳米片状sapo-34分子筛及其制备方法和应用

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20241106

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20241106

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20250917

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20250930

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20251225

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20260331