JP2024534672A - エチレン-α-オレフィンコポリマー、その製造方法、及び使用、並びに組成物 - Google Patents

エチレン-α-オレフィンコポリマー、その製造方法、及び使用、並びに組成物 Download PDF

Info

Publication number
JP2024534672A
JP2024534672A JP2024519643A JP2024519643A JP2024534672A JP 2024534672 A JP2024534672 A JP 2024534672A JP 2024519643 A JP2024519643 A JP 2024519643A JP 2024519643 A JP2024519643 A JP 2024519643A JP 2024534672 A JP2024534672 A JP 2024534672A
Authority
JP
Japan
Prior art keywords
ethylene
olefin
mol
structural units
olefin copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2024519643A
Other languages
English (en)
Japanese (ja)
Other versions
JP2024534672A5 (https=
Inventor
呉長江
李娟�
侯莉萍
王偉
張韜毅
羅春霞
張龍貴
鄭俊鵬
鄭剛
杜文傑
盛建▲ファン▼
▲ガオ▼菲菲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Beijing Research Institute of Chemical Industry
Original Assignee
Sinopec Beijing Research Institute of Chemical Industry
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sinopec Beijing Research Institute of Chemical Industry filed Critical Sinopec Beijing Research Institute of Chemical Industry
Publication of JP2024534672A publication Critical patent/JP2024534672A/ja
Publication of JP2024534672A5 publication Critical patent/JP2024534672A5/ja
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/09Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/27Amount of comonomer in wt% or mol%
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2024519643A 2021-09-30 2022-09-28 エチレン-α-オレフィンコポリマー、その製造方法、及び使用、並びに組成物 Pending JP2024534672A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN202111156978.3A CN115894759B (zh) 2021-09-30 2021-09-30 乙烯-α-烯烃共聚物及其制备方法和应用以及组合物
CN202111156978.3 2021-09-30
PCT/CN2022/122018 WO2023051580A1 (zh) 2021-09-30 2022-09-28 乙烯-α-烯烃共聚物及其制备方法和应用以及组合物

Publications (2)

Publication Number Publication Date
JP2024534672A true JP2024534672A (ja) 2024-09-20
JP2024534672A5 JP2024534672A5 (https=) 2024-11-01

Family

ID=85733882

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2024519643A Pending JP2024534672A (ja) 2021-09-30 2022-09-28 エチレン-α-オレフィンコポリマー、その製造方法、及び使用、並びに組成物

Country Status (6)

Country Link
US (1) US20240400732A1 (https=)
EP (1) EP4400522A4 (https=)
JP (1) JP2024534672A (https=)
KR (1) KR20240055131A (https=)
CN (1) CN115894759B (https=)
WO (1) WO2023051580A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240392045A1 (en) * 2021-09-30 2024-11-28 China Petroleum & Chemical Corporation Catalyst composition and application thereof
CN117700593A (zh) * 2023-12-13 2024-03-15 海南贝欧亿科技有限公司 一种生物基高极性热塑性聚烯烃弹性体及其制备方法及光伏封装胶膜
CN119955040B (zh) * 2024-12-20 2025-10-17 浙江大学 一种共聚单体含量梯级分布的嵌段共聚物制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5924707A (ja) * 1982-07-09 1984-02-08 フイリツプス・ペトロリユ−ム・コンパニ− エチレン―ヘキセン―1コポリマー
JPH05239082A (ja) * 1991-07-23 1993-09-17 Phillips Petroleum Co フルオレニル含有メタロセンの製造方法
JPH08198909A (ja) * 1995-01-26 1996-08-06 Tosoh Corp オレフィン重合体製造用触媒、その製造方法及びそれを用いたオレフィン重合体の製造方法
WO1997010295A1 (en) * 1995-09-11 1997-03-20 Mitsui Petrochemical Industries, Ltd. Resin compositions and use thereof
JP2000234046A (ja) * 1998-12-18 2000-08-29 Mitsui Chemicals Inc 樹脂分散物、その調製方法、それを用いた樹脂塗工金属板及び積層板の製造方法
WO2008157243A1 (en) * 2007-06-13 2008-12-24 Dow Global Technology Inc. Interpolymers suitable for multilayer films
JP2011006674A (ja) * 2009-05-29 2011-01-13 Sumitomo Chemical Co Ltd エチレン−α−オレフィン共重合体、成形体、共重合用触媒およびエチレン−α−オレフィン共重合体の製造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5571880A (en) * 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
JPH1053619A (ja) * 1996-08-12 1998-02-24 Sumitomo Chem Co Ltd ポリオレフィン系樹脂組成物の製造方法
ES2200314T3 (es) * 1997-02-07 2004-03-01 Exxonmobil Chemical Patents Inc. Copolimeros de olefina de procesamiento mejorado.
KR100753478B1 (ko) * 2005-02-15 2007-08-31 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리에틸렌 공중합체의 제조방법
US7910669B2 (en) * 2009-03-17 2011-03-22 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US20120316310A1 (en) * 2009-12-15 2012-12-13 Sumitomo Chemical Company, Limited ETHYLENE-alpha-OLEFIN COPOLYMER
EP3127958B1 (en) * 2015-08-04 2021-09-01 FUJIFILM Business Innovation Corp. Resin composition, resin molded article, and method of preparing resin composition
KR102013170B1 (ko) * 2018-04-05 2019-08-22 대림산업 주식회사 폴리올레핀 수지 조성물 및 이의 제조방법
CN112661785B (zh) * 2019-10-15 2022-10-21 中国石油化工股份有限公司 一种萘氧基单茂过渡金属化合物、包含其的催化剂组合物与应用

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5924707A (ja) * 1982-07-09 1984-02-08 フイリツプス・ペトロリユ−ム・コンパニ− エチレン―ヘキセン―1コポリマー
JPH05239082A (ja) * 1991-07-23 1993-09-17 Phillips Petroleum Co フルオレニル含有メタロセンの製造方法
JPH08198909A (ja) * 1995-01-26 1996-08-06 Tosoh Corp オレフィン重合体製造用触媒、その製造方法及びそれを用いたオレフィン重合体の製造方法
WO1997010295A1 (en) * 1995-09-11 1997-03-20 Mitsui Petrochemical Industries, Ltd. Resin compositions and use thereof
JP2000234046A (ja) * 1998-12-18 2000-08-29 Mitsui Chemicals Inc 樹脂分散物、その調製方法、それを用いた樹脂塗工金属板及び積層板の製造方法
WO2008157243A1 (en) * 2007-06-13 2008-12-24 Dow Global Technology Inc. Interpolymers suitable for multilayer films
JP2011006674A (ja) * 2009-05-29 2011-01-13 Sumitomo Chemical Co Ltd エチレン−α−オレフィン共重合体、成形体、共重合用触媒およびエチレン−α−オレフィン共重合体の製造方法

Also Published As

Publication number Publication date
US20240400732A1 (en) 2024-12-05
KR20240055131A (ko) 2024-04-26
WO2023051580A1 (zh) 2023-04-06
EP4400522A4 (en) 2025-04-23
CN115894759A (zh) 2023-04-04
CN115894759B (zh) 2024-07-02
EP4400522A1 (en) 2024-07-17

Similar Documents

Publication Publication Date Title
RU2668075C2 (ru) Гетерофазный сополимер
JP7366013B2 (ja) オレフィン-オレフィンアルコール共重合体及びその製造方法
JP2024534672A (ja) エチレン-α-オレフィンコポリマー、その製造方法、及び使用、並びに組成物
US5874505A (en) Polypropylene composition
JP2007533786A (ja) メタロセン触媒系を使用した重合方法
KR101154508B1 (ko) 혼성 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한 폴리올레핀의 제조방법
US10870712B2 (en) Method for preparing polyolefin
RU2020116986A (ru) Полимер на основе этилена, обладающий превосходными характеристиками длительного сопротивления при сжатии, и труба, в которой он применяется
US20090270580A1 (en) Ethylene Polymer, and Thermoplastic Resin Composition Comprising the Same, and Molded Product Obtained Therefrom
CN114539478A (zh) 基于进料策略调控的梳状聚烯烃热塑性弹性体的制备方法
CN115894758A (zh) 乙烯-环烯烃共聚物及其制备方法
KR20260026089A (ko) 에틸렌/α-올레핀 공중합체 및 이의 응용
US20120071615A1 (en) Bi-Nuclear Metallocene Compound and the Preparation Method of Polyolefin Using the Same
CN106103502B (zh) 包含金属茂络合物和助催化剂的催化剂
KR102821274B1 (ko) 혼성 담지 촉매
JP2013204028A (ja) ポリエチレン系樹脂組成物およびその成形体
US7776974B2 (en) Olefin polymerization process
CN111116801B (zh) 一种烯烃-不饱和羧酸共聚物的制备方法
US20240132639A1 (en) Olefin-based polymer, film prepared therefrom, and preparation methods therefor
CN108290971B (zh) 金属茂负载型催化剂及使用该催化剂制备聚烯烃的方法
JP2020505480A (ja) オレフィン重合体、その製造方法、そしてこれを利用したフィルム
CN115894745A (zh) 催化剂组合物、烯烃聚合方法和应用
CN111116810B (zh) 一种烯烃-烯烃醇共聚物的制备方法
CN118994450A (zh) 超高分子量窄分布的聚α-烯烃的制备方法
CN117362817B (zh) 聚丙烯材料组合物、聚丙烯材料及其应用

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20241017

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20241017

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20250821

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20250909

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20251208

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20260217