JP2023155991A - Viscoelasticity enhancer and viscoelasticity enhancement method for gel-like cosmetics - Google Patents
Viscoelasticity enhancer and viscoelasticity enhancement method for gel-like cosmetics Download PDFInfo
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Abstract
Description
本発明は、容器からこぼれにくく良好な粘弾性を保つゲル状皮膚化粧料に関する。 The present invention relates to a gel-like skin cosmetic that does not easily spill from a container and maintains good viscoelasticity.
一般的に、増粘剤やゲル化剤を配合することで、とろみのあるローションやヘアスタイリング剤のような硬めのゲルを形成することができ、その種類や配合量は目的や用途に応じて調整している。近年では、微細繊維状セルロースがゲル状組成物における一成分として使用することが知られている。(例えば特許文献1~3)。 Generally, by adding thickeners and gelling agents, it is possible to form a hard gel like a thick lotion or hair styling agent, and the type and amount of addition depends on the purpose and use. I'm making adjustments. In recent years, it has been known that microfibrous cellulose can be used as a component in gel compositions. (For example, Patent Documents 1 to 3).
しかし、これらの化粧料は、増粘性に優れているものの、使用時に容器のフタを開ける際、または容器を傾けた時に容器からこぼれやすく使用性に改善の余地があった。 However, although these cosmetics have excellent thickening properties, they tend to spill out of the container when the lid is opened or when the container is tilted during use, leaving room for improvement in usability.
そこで、本発明は上記事情に鑑みてなされたもので、使用時に容器のフタを開ける際、または容器を傾けた時に容器からこぼれにくい良好な粘弾性を有するゲル状皮膚化粧料のための粘弾性増強剤を提供することにある。 Therefore, the present invention has been made in view of the above circumstances, and provides a viscoelasticity for a gel-like skin cosmetic that has good viscoelasticity and does not easily spill out of the container when the lid is opened or when the container is tilted during use. The purpose is to provide an enhancer.
本発明者らは、使用時に容器のフタを開ける際、または容器を傾けた時に化粧料が容器からこぼれ易い原因は、弾性優位の状態であるからであると考え、化粧料に粘性を加え適度な流体性をもつように鋭意検討した。 The present inventors believe that the reason why cosmetics tend to spill out of the container when the lid is opened or when the container is tilted during use is because the cosmetic is in an elastic state. We have made extensive efforts to ensure that it has a fluid property.
その結果、ゲル状皮膚化粧料に、リン酸化修飾セルロースナノファイバーと(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマー、カルボキシビニルポリマー、キサンタンガム、ヒドロキシエチルセルロースから選ばれる1種または2種以上と多価アルコールを組み合わせた組成物を含有することで、容器からこぼれにくい良好な粘弾性に加え、指取れ性も良好であることを見出し、本発明を完成した。 As a result, gel-like skin cosmetics contain phosphorylated modified cellulose nanofibers and one or more selected from the group consisting of (acrylates/alkyl acrylate (C10-30)) crosspolymer, carboxyvinyl polymer, xanthan gum, and hydroxyethylcellulose. The present invention was completed based on the discovery that by containing a composition containing a combination of polyhydric alcohols, in addition to having good viscoelasticity that prevents spillage from the container, it also has good finger retrieval properties.
すなわち、本願発明は、以下のとおりである。
[1]
下記(A)及び(B)を有効成分とすることを特徴とするゲル状皮膚化粧料のための粘弾性増強剤である。
(A)リン酸化修飾セルロースナノファイバーをゲル状皮膚化粧料全体質量中0.1質量%以上
(B)(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマー、カルボキシビニルポリマー、キサンタンガム、ヒドロキシエチルセルロースから選ばれる1種または2種以上をゲル状皮膚化粧料全体質量中0.01質量%以上
[2]
上記粘弾性増強剤及び下記(C)を含有するゲル状皮膚化粧料である。
(C)多価アルコール
[3]
ゲル状皮膚化粧料に下記(A)及び(B)を配合するゲル状皮膚化粧料の粘弾性向上方法である。
(A)リン酸化修飾セルロースナノファイバー
(B)(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマー、カルボキシビニルポリマー、キサンタンガム、ヒドロキシエチルセルロースから選ばれる1種または2種以上
That is, the present invention is as follows.
[1]
This is a viscoelasticity enhancer for gel-like skin cosmetics, characterized by containing the following (A) and (B) as active ingredients.
(A) 0.1% by mass or more of phosphorylated modified cellulose nanofibers in the total mass of gel skin cosmetics (B) (acrylates/alkyl acrylate (C10-30)) crosspolymer, carboxyvinyl polymer, xanthan gum, hydroxyethyl cellulose 0.01% by mass or more of one or more selected from the following in the total mass of the gel skin cosmetic [2]
This is a gel-like skin cosmetic containing the above-mentioned viscoelasticity enhancer and the following (C).
(C) Polyhydric alcohol
[3]
This is a method for improving the viscoelasticity of a gel-like skin cosmetic by blending the following (A) and (B) into the gel-like skin cosmetic.
(A) Phosphorylated modified cellulose nanofiber (B) (Acrylates/alkyl acrylate (C10-30)) One or more types selected from crosspolymer, carboxyvinyl polymer, xanthan gum, and hydroxyethyl cellulose
本発明のゲル状化粧料のための粘弾性増強剤は、容器からこぼれにくい良好な粘弾性を有する。さらに、指取れ性も良好である。 The viscoelasticity enhancer for gel cosmetics of the present invention has good viscoelasticity that prevents it from spilling out of the container. Furthermore, it has good finger removability.
以下、本発明のゲル状化粧料のための粘弾性増強剤について詳細に説明する。 Hereinafter, the viscoelasticity enhancer for gel cosmetics of the present invention will be explained in detail.
本明細書において、「容器からこぼれにくい」とは使用時に容器のフタを開ける際、または容器を傾けた時に内容物が垂れて落ちてこないことやことを意味する。「指取れ性」とは容器から内容物を指で取る際の密着感を意味する。また「ヨレ」とは擦るなど力を加えた時にゲル状組成物がポロポロと落ちることを意味する。 As used herein, "not easily spilled from the container" means that the contents do not drip when the lid of the container is opened during use or when the container is tilted. "Finger-removability" refers to the tightness when removing the contents from the container with fingers. In addition, "wrinkling" means that the gel-like composition falls off when force is applied such as rubbing.
本明細書において、「粘性」とは物質のねばり性であり流体が持つ性質のことを意味する。ゲル状組成物において粘性が不足すると、容器を傾けると内容物全体が一気に垂れ落ちる。一方、「弾性」とは応力を加えるとひずみが生じるが、応力をなくすと元に戻る性質のことを意味し、ゲル状組成物において弾性が不足すると、容器を傾けた時に徐々に内容物が垂れ落ちやすくなる。そして、「粘弾性」とは、粘性と弾性の両方を合わせた性質のことを意味し、ゲル状組成物において粘弾性が不足すると、容器を傾けるとすぐに内容物が垂れ落ちる。「シェアシニング性」とはせん断速度の増加とともに粘度が減少することを意味し、ゲル状組成物においてシェアシニング性が不足すると、密着感を得られず、内容物を指で少量しか取ることができない。 In this specification, "viscosity" refers to the stickiness of a substance and a property of a fluid. If the gel composition lacks viscosity, the entire contents will drip out at once when the container is tilted. On the other hand, "elasticity" refers to the property of causing distortion when stress is applied, but returning to its original state when the stress is removed.If the gel-like composition lacks elasticity, the contents will gradually collapse when the container is tilted. It will fall off easily. "Viscoelasticity" refers to a property that combines both viscosity and elasticity, and if a gel composition lacks viscoelasticity, the contents will drip as soon as the container is tilted. "Shear thinning property" means that the viscosity decreases as the shear rate increases, and if the gel composition lacks shear thinning property, it will not be possible to obtain a feeling of adhesion, and only a small amount of the content can be removed with fingers. I can't.
本願発明のゲル状皮膚化粧料のための粘弾性増強剤は、下記(A)及び(B)成分を含有し、好ましくは更に(C)成分を含有する。
(A)リン酸化修飾セルロースナノファイバー
(B)(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマー、カルボキシビニルポリマー、キサンタンガム、ヒドロキシエチルセルロースから選ばれる1種または2種以上
(C)多価アルコール
The viscoelasticity enhancer for gel skin cosmetics of the present invention contains the following components (A) and (B), and preferably further contains component (C).
(A) Phosphorylated modified cellulose nanofiber (B) One or more types selected from (acrylates/alkyl acrylate (C10-30)) crosspolymer, carboxyvinyl polymer, xanthan gum, hydroxyethyl cellulose (C) Polyhydric alcohol
<(A)成分>
本発明で用いる(A)成分はリン酸化修飾セルロースナノファイバーである。リン酸化修飾セルロースナノファイバーは、微細繊維状セルロースであり、繊維幅が1000nm以下、かつリン酸由来の置換基を0.1mmol/g以上3.0mmol/g 以下有する。
<(A) component>
Component (A) used in the present invention is phosphorylated modified cellulose nanofiber. The phosphorylated modified cellulose nanofiber is a fine fibrous cellulose, has a fiber width of 1000 nm or less, and has phosphoric acid-derived substituents of 0.1 mmol/g or more and 3.0 mmol/g or less.
(A)成分は市販されている化粧品原料として入手可能であり、例えばアウロ・ヴィスコCS(王子ホールディングス株式会社製)などが知られている。 Component (A) is available as a commercially available cosmetic raw material, and for example, Auro Visco CS (manufactured by Oji Holdings Co., Ltd.) is known.
(A)成分は、一般的に高い透明性・粘性・チキソトロピー性を付与する目的で用いられることが知られており、本発明では、(A)成分を使用することにより、粘弾性のある特徴的なゲル剤型に寄与していると考えられる。 It is known that component (A) is generally used for the purpose of imparting high transparency, viscosity, and thixotropy, and in the present invention, by using component (A), It is thought that this contributes to the gel formulation.
本発明のゲル状皮膚化粧料に用いる(A)成分の含有量は本発明の効果を発揮する限りにおいて特に限定されるものではないが、ゲル状皮膚化粧料全体に対して0.1~1.0質量%(以後、特別な記載のない限り質量%を表す)が好ましく、さらに好ましくは0.2~0.6%である。0.1%以上であれば、良好な粘弾性のあるゲルが得られ、1.0%以下であれば、塗布後の(A)成分由来のヨレを生じない。 The content of component (A) used in the gel skin cosmetic of the present invention is not particularly limited as long as it exhibits the effects of the present invention, but it is 0.1 to 1% based on the entire gel skin cosmetic. It is preferably 0.0% by mass (hereinafter expressed as % by mass unless otherwise specified), and more preferably 0.2 to 0.6%. If it is 0.1% or more, a gel with good viscoelasticity will be obtained, and if it is 1.0% or less, no wrinkling due to component (A) will occur after application.
<(B)成分>
本発明で用いる(B)成分は、(アクリレーツ/アクリル酸アルキル(C10-30)クロスポリマー、カルボキシビニルポリマー、キサンタンガム、ヒドロキシエチルセルロースから選ばれる1種または2種以上である。(B)成分は、水溶性の高分子であり、乳化安定剤や増粘剤の目的で使用される。
<(B) component>
Component (B) used in the present invention is one or more selected from (acrylates/alkyl acrylate (C10-30) crosspolymer, carboxyvinyl polymer, xanthan gum, and hydroxyethyl cellulose. Component (B) is: It is a water-soluble polymer and is used as an emulsion stabilizer and thickener.
(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマーとして市販されている原料としては、例えばAQUPEC HV-501ER、701EDR、801ERK、803ERK、703ER、705ER(住友精化株式会社製)、PEMULEN TR-1、TR-2、EZ-4U(日本ルーブリゾール株式会社製)などが挙げられる。 (Acrylates/alkyl acrylate (C10-30)) Commercially available raw materials as cross polymers include AQUPEC HV-501ER, 701EDR, 801ERK, 803ERK, 703ER, 705ER (manufactured by Sumitomo Seika Co., Ltd.), PEMULEN TR- 1, TR-2, and EZ-4U (manufactured by Japan Lubrizol Co., Ltd.).
カルボキシビニルポリマーとして市販されている原料としては、例えばAQUPEC HV-501E、801EG、805EG(住友精化株式会社製)、ハイビスワコー103、104、105(富士フィルム和光純薬株式会社製)などが挙げられる。 Examples of raw materials commercially available as carboxyvinyl polymers include AQUPEC HV-501E, 801EG, 805EG (manufactured by Sumitomo Seika Co., Ltd.), Hivis Wako 103, 104, 105 (manufactured by Fuji Film Wako Pure Chemical Industries, Ltd.), etc. It will be done.
キサンタンガムとして市販されている原料としては、例えばノムコートZ(日清オイリオグループ株式会社製)、ラボールガムGS-C(DSP五協フード&ケミカル株式会社製)などが挙げられる。 Examples of commercially available raw materials for xanthan gum include Nomcoat Z (manufactured by Nisshin Oillio Group Co., Ltd.) and Lavor Gum GS-C (manufactured by DSP Gokyo Food & Chemical Co., Ltd.).
ヒドロキシエチルセルロースとして市販されている原料としては、例えばHEC CF-G、CF-V、CF-W(住友精化株式会社製)、HECダイセルSE400、600、900(ダイセルミライズ株式会社製)などが挙げられる。 Examples of raw materials commercially available as hydroxyethyl cellulose include HEC CF-G, CF-V, CF-W (manufactured by Sumitomo Seika Co., Ltd.), HEC Daicel SE400, 600, and 900 (manufactured by Daicel Millize Co., Ltd.). It will be done.
本発明のゲル状皮膚化粧料に用いる(B)成分の配合量は、本発明の効果を発揮する限りにおいて特に限定されるものではないが、ゲル状皮膚化粧料全体に対して0.01~2.0%であり、好ましくは0.05~1.0%である。0.1%以上であれば、容器からこぼれにくく良好な粘弾性に優れ、2.0%以下であれば(B)成分由来のヨレを生じない。 The amount of component (B) used in the gel skin cosmetic of the present invention is not particularly limited as long as it exhibits the effects of the present invention, but it ranges from 0.01 to 0.01% of the total gel skin cosmetic. It is 2.0%, preferably 0.05 to 1.0%. If it is 0.1% or more, it will not easily spill out of the container and will have good viscoelasticity, and if it is 2.0% or less, no twisting will occur due to component (B).
本発明では、(A)成分と(B)成分を組み合わせることが必要である。両成分を組み合わせることにより、容器からこぼれにくい粘弾性になることに寄与していると考えられる。具体的には、(A)成分と(B)成分を組み合わせることで、弾性優位であった性状に粘性が加わり、適度な流体性を有した粘弾性になっているためと推測される。弾性に富むA成分に対し、粘性に富むB成分を加えることで、粘弾性が最適になったと推測される。 In the present invention, it is necessary to combine components (A) and (B). It is thought that the combination of both components contributes to the viscoelasticity that prevents spillage from the container. Specifically, it is presumed that this is because by combining the components (A) and (B), viscosity is added to the predominantly elastic properties, resulting in viscoelasticity with appropriate fluidity. It is presumed that the viscoelasticity was optimized by adding the B component, which is rich in viscosity, to the A component, which is rich in elasticity.
<(C)成分>
本発明で用いる(C)成分は、多価アルコールであり、ジグリセリン、ポリグリセリン、ソルビトール、マルチトール、ジプロピレングリコール、1,3-プロパンジオール、エチレングリコール、ジエチレングリコール、イソプレングリコールから選ばれる1種または2種以上である。
<(C) component>
Component (C) used in the present invention is a polyhydric alcohol, and is one selected from diglycerin, polyglycerin, sorbitol, maltitol, dipropylene glycol, 1,3-propanediol, ethylene glycol, diethylene glycol, and isoprene glycol. Or two or more types.
本発明では、(C)成分を使用することにより、良好な粘弾性の上に、さらに良好な指取れ性を得ることができる。具体的には、(A)成分と(B)成分と(C)成分を組み合わせることで、シェアシニング性が増加し、良好な粘弾性だけでなくさらに指取れ性も改善したと推測される。 In the present invention, by using the component (C), it is possible to obtain not only good viscoelasticity but also good finger removability. Specifically, it is presumed that by combining components (A), (B), and (C), shear thinning properties were increased, and not only good viscoelasticity but also finger removability was improved. .
本発明のゲル状皮膚化粧料で使用する(C)成分の含有量は、ゲル状皮膚化粧料全体に対して1.0~25.0%であり、好ましくは3.0~20.0%である。1%以上では、容器からこぼれにくく良好な指取れ性が得られ、20.0%以下であると、べたつき感を生じない。 The content of component (C) used in the gel skin cosmetic of the present invention is 1.0 to 25.0%, preferably 3.0 to 20.0%, based on the entire gel skin cosmetic. It is. When it is 1% or more, it is difficult to spill from the container and good finger removability is obtained, and when it is 20.0% or less, no sticky feeling is caused.
<その他成分>
本発明のゲル状皮膚化粧料は、上述した成分を必須の構成成分とするが、当該組成物には本発明の目的を損なわない範囲で、他の成分、例えば、陰イオン性界面活性剤、両性界面活性剤、非イオン性界面活性剤、油剤、高分子化合物、増粘剤、粉体(色素、樹脂、顔料)、防腐剤、香料、保湿剤、生理活性成分、塩類、溶媒、酸化防止剤、キレート剤、パール化剤、中和剤、pH調整剤、昆虫忌避剤、酵素等の成分を適宜配合することができる。
<Other ingredients>
The gel skin cosmetic of the present invention has the above-mentioned components as essential components, but the composition may include other components such as anionic surfactants, to the extent that the object of the present invention is not impaired. Amphoteric surfactants, nonionic surfactants, oils, polymer compounds, thickeners, powders (pigments, resins, pigments), preservatives, fragrances, humectants, physiologically active ingredients, salts, solvents, antioxidants Components such as agents, chelating agents, pearlizing agents, neutralizing agents, pH adjusting agents, insect repellents, and enzymes can be appropriately blended.
また、本発明のゲル状皮膚化粧料には、本発明の目的を損なわない範囲で、生理活性成分を適宜配合することができる。生理活性物質とは、皮膚に塗布した場合に皮膚に何らかの生理活性を与える物質であり、例えば、老化防止剤、ひきしめ剤、抗酸化剤、保湿剤、血行促進剤、抗菌剤、殺菌剤、乾燥剤、冷感剤、温感剤、ビタミン類、アミノ酸、創傷治癒促進剤、刺激緩和剤、鎮痛剤、細胞賦活剤、酵素成分等が挙げられる。 Further, the gel-like skin cosmetic of the present invention may appropriately contain physiologically active ingredients within a range that does not impair the purpose of the present invention. Physiologically active substances are substances that give some kind of physiological activity to the skin when applied to the skin, such as anti-aging agents, tightening agents, antioxidants, humectants, blood circulation promoters, antibacterial agents, bactericidal agents, drying agents, etc. agents, cooling agents, warming agents, vitamins, amino acids, wound healing promoters, irritation relievers, analgesics, cell activators, enzyme components, etc.
また、本発明のゲル状皮膚化粧料に配合することのできる生理活性成分は、特にその種類を制限されないが、植物の根・茎・葉・花・果実・種子由来の抽出物を用いることが好ましい。植物の根・茎・葉・花・果実・種子由来の抽出物の例として、例えばアシタバエキス、アボガドエキス、アマチャエキス、アルテアエキス、アルニカエキス、アロエエキス、イタドリエキス、ウイキョウ(フェンネル)エキス、エイジツエキス、オオムギエキス、オトギリソウエキス、カキエキス、カッコンエキス、カモミラエキス、カロットエキス、カンゾウエキス、キイチゴエキス、キウイエキス、キューカンバーエキス、キョウニンエキス、クインスシードエキス、黒糖エキス、コメヌカエキス、コメヌカ発酵エキス、サトウカエデエキス、サトウキビエキス、シソエキス、シャクヤクエキス、スイカズラエキス、セイヨウオトギリソウエキス、セイヨウサンザシエキス、セイヨウニワトコエキス、セージエキス、ダイズエキス、タイムエキス、チャエキス、ツバキエキス、ツボクサエキス、ドクダミエキス、トマトエキス、ノバラエキス、ハマメリス水、バラエキス、パリエタリアエキス、ビワエキス、ブドウエキス、ヘチマエキス、ボタンエキス、ホップエキス、ムクロジエキス、モモ葉エキス、ヤグルマギクエキス、ヨクイニンエキス、レモンエキス、ローズマリーエキス、ローマカミツレエキス等が挙げられる。 Furthermore, the types of physiologically active ingredients that can be incorporated into the gel skin cosmetic of the present invention are not particularly limited, but extracts derived from roots, stems, leaves, flowers, fruits, and seeds of plants can be used. preferable. Examples of extracts derived from roots, stems, leaves, flowers, fruits, and seeds of plants include Angelica extract, Avocado extract, Amacha extract, Althea extract, Arnica extract, Aloe extract, Japanese knotweed extract, Fennel extract, and Eizu extract. extract, barley extract, hypericum extract, persimmon extract, cuckoo extract, chamomilla extract, carot extract, licorice extract, raspberry extract, kiwi extract, cucumber extract, kyonin extract, quince seed extract, brown sugar extract, rice bran extract, rice bran fermentation extract, sugar maple extract, Sugarcane extract, perilla extract, peony extract, honeysuckle extract, hypericum perforatum extract, hawthorn extract, elderberry extract, sage extract, soybean extract, thyme extract, tea extract, camellia extract, asiatica extract, dokudami extract, tomato extract, wild rose extract, hamamelis water, Examples include rose extract, Parietaria extract, loquat extract, grape extract, loofah extract, button extract, hop extract, Sapindium extract, peach leaf extract, cornflower extract, Japanese cabbage extract, lemon extract, rosemary extract, Roman chamomile extract, and the like.
以下、本発明を実施例及び比較例を例示することにより具体的に説明するが、本発明はこれら実施例によりなんら限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 Hereinafter, the present invention will be specifically explained by illustrating Examples and Comparative Examples, but the present invention is not limited to these Examples in any way. Prior to the examples, the test methods and evaluation methods employed in each example will be explained.
[1]容器からのこぼれにくさの評価試験
(評価方法)
専門パネル5名について、本発明のゲル状皮膚化粧料をクリーム形状で20g容量の容器に15g充填し、容器を90度傾けてもらい何秒で全量が流れ落ちるかを、下記評価基準により判断した。
<評価基準>
5:容器を傾けて30秒以上要した
4:容器を傾けて20~30秒で流れ落ちた
3:容器を傾けて15~20秒で流れ落ちた
2:容器を傾けて10~15秒で流れ落ちた
1:容器を傾けて10秒以内で流れ落ちた
[1] Evaluation test for resistance to spillage from containers (evaluation method)
A panel of five experts filled 15 g of the gel skin cosmetic of the present invention in a 20 g container in the form of a cream, tilted the container 90 degrees, and judged how many seconds it would take for the entire amount to flow down, based on the following evaluation criteria.
<Evaluation criteria>
5: It took more than 30 seconds after tilting the container 4: It ran down within 20-30 seconds after tilting the container 3: It ran down within 15-20 seconds after tilting the container 2: It ran down within 10-15 seconds after tilting the container 1: Water flowed down within 10 seconds of tilting the container.
[2]指取れ性の評価試験
(評価方法)
専門パネル5名について、本発明のゲル状皮膚化粧料を上述の容器に充填し、人差し指と中指で取ったときの「密着感」を評価した。1~5点にて評価をしてもらい、その平均値を試験結果とした。
<評価基準>
5:指にしっかり密着し指上で保持される
4:指にややしっかり密着し指上で保持される
3:指にほぼ密着し指上で保持される
2:指に少し密着し指上で保持される
1:指にまったく密着せず指上で保持されない
[2] Evaluation test for finger removability (evaluation method)
Five expert panelists evaluated the "adherence" when the gel skin cosmetic of the present invention was filled into the above-mentioned container and taken with the index finger and middle finger. They were evaluated on a scale of 1 to 5 points, and the average value was used as the test result.
<Evaluation criteria>
5: Closely attached to the finger and held on the finger 4: Closely attached to the finger and held on the finger 3: Closely attached to the finger and held on the finger 2: Closely attached to the finger and held on the finger Retained 1: Does not adhere to the finger at all and is not held on the finger
<実施例1~10及び比較例1~4>
表1、2に示す実施例1~10および比較例1~4の各処方におけるゲル状皮膚化粧料を常法により調製し、各試験法により評価した。その結果を表1に併せて示す。
<Examples 1 to 10 and Comparative Examples 1 to 4>
Gel-like skin cosmetics according to the formulations of Examples 1 to 10 and Comparative Examples 1 to 4 shown in Tables 1 and 2 were prepared by conventional methods and evaluated by various test methods. The results are also shown in Table 1.
表1、2から明らかなように、本発明の成分を用いた実施例のゲル状皮膚化粧料はいずれも優れた性能を有していた。一方、必須成分のいずれかを欠いた比較例では、容器からこぼれにくい粘弾性、指取れ性のいずれかの面で劣っており、本発明の目的を達成できなかった。 As is clear from Tables 1 and 2, the gel skin cosmetics of Examples using the ingredients of the present invention all had excellent performance. On the other hand, comparative examples lacking any of the essential components were inferior in either viscoelasticity to prevent spillage from the container or finger removability, and could not achieve the object of the present invention.
以下、本発明のゲル状皮膚化粧料のその他の処方例を挙げる。なお、下記の処方例のゲル状皮膚化粧料についても、上記の容器からのこぼれにくさ、指取れ性について各項目を検討したところ、いずれにおいても実施例と同様に優れた特性を有しており、良好であった。 Other formulation examples of the gel skin cosmetic of the present invention are listed below. Regarding the gel skin cosmetics with the following formulation examples, we examined each item regarding the resistance to spillage from the containers mentioned above and ease of finger removal, and found that they had excellent properties in both cases, similar to those in the examples. It was in good condition.
処方例1 ゲル状皮膚化粧料
(1)ジグリセリン 0.5%
(2)ジプロピレングリコール 5.0%
(3)1,3-プロパンジオール 5.0%
(4)リン酸化修飾セルロースナノファイバー 0.4%
(5)(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマー、カルボキシビニルポリマー 0.2%
(6)キサンタンガム 0.1%
(7)ヒドロキシエチルセルロース 0.1%
(8)トリメチルグリシン 0.5%
(9)シクロヘキサン-1,4-ジカルボン酸ビスエトキシジグリコール0.5%
(10)PEG-60水添ヒマシ油 0.7%
(11)ポリソルベート20 0.3%
(12)メチルグルセス-20 0.5%
(13)クエン酸 適量
(14)クエン酸ナトリウム 適量
(15)メチルパラベン 0.5%
(16)フェノキシエタノール 0.5%
(17)ジメチルポリシロキサン 1.0%
(18)フィトステロール 0.08%
(19)トコフェロール 0.1%
(20)エタノール 8.0%
(21)エデト酸二ナトリウム 0.01%
(22)精製水 残余
Formulation example 1 Gel-like skin cosmetic (1) Diglycerin 0.5%
(2) Dipropylene glycol 5.0%
(3) 1,3-propanediol 5.0%
(4) Phosphorylated modified cellulose nanofiber 0.4%
(5) (Acrylates/alkyl acrylate (C10-30)) crosspolymer, carboxyvinyl polymer 0.2%
(6) Xanthan gum 0.1%
(7) Hydroxyethylcellulose 0.1%
(8) Trimethylglycine 0.5%
(9) Cyclohexane-1,4-dicarboxylic acid bisethoxydiglycol 0.5%
(10) PEG-60 hydrogenated castor oil 0.7%
(11) Polysorbate 20 0.3%
(12) Methylgluceth-20 0.5%
(13) Citric acid appropriate amount (14) Sodium citrate appropriate amount (15) Methylparaben 0.5%
(16) Phenoxyethanol 0.5%
(17) Dimethylpolysiloxane 1.0%
(18) Phytosterol 0.08%
(19) Tocopherol 0.1%
(20) Ethanol 8.0%
(21) Edetate disodium 0.01%
(22) Purified water remainder
(製法)(1)~(22)を常温にて均一溶解させゲル状皮膚化粧料を調製した。 (Production method) A gel-like skin cosmetic was prepared by uniformly dissolving (1) to (22) at room temperature.
Claims (3)
(A)リン酸化修飾セルロースナノファイバーをゲル状皮膚化粧料全体質量中0.1質量%以上
(B)(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマー、カルボキシビニルポリマー、キサンタンガム、ヒドロキシエチルセルロースから選ばれる1種または2種以上をゲル状皮膚化粧料全体質量中0.01質量%以上 A viscoelasticity enhancer for gel-like skin cosmetics, characterized by containing the following (A) and (B) as active ingredients.
(A) 0.1% by mass or more of phosphorylated modified cellulose nanofibers in the total mass of gel skin cosmetics (B) (acrylates/alkyl acrylate (C10-30)) crosspolymer, carboxyvinyl polymer, xanthan gum, hydroxyethyl cellulose 0.01% by mass or more of one or more selected from the following in the total mass of the gel skin cosmetic
(C)多価アルコール A gel skin cosmetic containing the viscoelasticity enhancer according to claim 1 and the following (C).
(C) Polyhydric alcohol
(A)リン酸化修飾セルロースナノファイバー
(B)(アクリレーツ/アクリル酸アルキル(C10-30))クロスポリマー、カルボキシビニルポリマー、キサンタンガム、ヒドロキシエチルセルロースから選ばれる1種または2種以上
A method for improving the viscoelasticity of a gel skin cosmetic by blending the following (A) and (B) into the gel skin cosmetic.
(A) Phosphorylated modified cellulose nanofiber (B) (Acrylates/alkyl acrylate (C10-30)) One or more types selected from crosspolymer, carboxyvinyl polymer, xanthan gum, and hydroxyethyl cellulose
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Publications (1)
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