JP7217520B2 - Skin cosmetics - Google Patents

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JP7217520B2
JP7217520B2 JP2019044922A JP2019044922A JP7217520B2 JP 7217520 B2 JP7217520 B2 JP 7217520B2 JP 2019044922 A JP2019044922 A JP 2019044922A JP 2019044922 A JP2019044922 A JP 2019044922A JP 7217520 B2 JP7217520 B2 JP 7217520B2
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健仁 入合
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Dariya Co Ltd
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Description

本発明は、塗布後のみずみずしさ、吸い付き感、さらさら感、しっとり感があり、塗布中につっぱりがない皮膚用化粧料に関するものである。 TECHNICAL FIELD The present invention relates to a skin cosmetic that provides freshness, stickiness, smoothness, and moistness after application and does not cause tightness during application.

近年のスキンケア市場においては、様々な目的や効果を謳う化粧料が数多く上市されている。これらは、季節や流行りなどの影響を受けて、消費者の購入意欲を掻き立てるような内容に変化する。その中でも、一年を通して一定のニーズがあり、重きを置かれる重要な使用感の一つとして、しっとり感が挙げられる。 In the skin care market in recent years, a large number of cosmetics claiming various purposes and effects have been put on the market. These are influenced by the season, fashion, etc., and change to content that stimulates the consumer's desire to purchase. Among them, there is a certain need throughout the year, and one of the important feeling of use that is emphasized is moist feeling.

化粧料のしっとり感を向上させる技術は数多く存在し、比較的容易にしっとり感を向上させることができるものの、塗布中に皮膚がつっぱって不快であるという欠点がある。しっとり感を向上すればするほど、つっぱりも同時に強くなってしまうため、しっとり感とつっぱりのなさを同時に付与する化粧料が強く望まれている。また、これらの化粧料には、みずみずしさ、吸い付き感、さらさら感など、複合的な快適性も大いに求められる。なお、本発明における吸い付き感とは、化粧料を塗布した皮膚と、塗布していない皮膚を接触させた際の、あたかも両者が吸い付き合うような皮膚同士のなじみのよさを意味する。 There are many techniques for improving the moist feeling of cosmetics, and although it is possible to improve the moist feeling relatively easily, there is a drawback that the skin feels uncomfortable during application. The more the moist feeling is improved, the stronger the taut feeling is at the same time. Therefore, there is a strong demand for a cosmetic that simultaneously imparts a moist feeling and no taut feeling. In addition, complex comfort such as freshness, stickiness, and smoothness are also greatly required for these cosmetics. The sticking feeling in the present invention means the familiarity between the two skins when the cosmetic-applied skin and the non-coated skin are brought into contact with each other as if the two stick to each other.

しっとり感を付与する成分としては、一般的に、1,3-ブチレングリコール、グリセリン、ポリエチレングリコールなどの多価アルコールが例示される。これらの含有量を多く調製すれば、塗布後にしっとり感を十分に得ることができるが、塗布中は皮膚がつっぱるため、乾くまで不快感が続く。一方で、これらを少なく調製すれば、しっとり感を得にくくなり、消費者のニーズと合致しない化粧料になってしまう。以上より、従来技術においては両者を十分に満足することが困難であった。 Ingredients that impart a moist feeling are generally exemplified by polyhydric alcohols such as 1,3-butylene glycol, glycerin, and polyethylene glycol. If the content of these substances is increased, a sufficient moist feeling can be obtained after application, but the skin becomes taut during application, and discomfort continues until the skin dries. On the other hand, if they are prepared in a small amount, it becomes difficult to obtain a moist feeling, resulting in a cosmetic that does not meet consumer needs. As described above, it was difficult to fully satisfy both in the prior art.

特許文献1には、トリメチルグリシンなどの水溶性保湿剤と、スクワランなどの液状油を多く含有する、べたつきがなく皮膚にやわらかいハリ感を付与する水中油型乳化化粧料が開示されている。 Patent Document 1 discloses an oil-in-water emulsified cosmetic that contains a large amount of a water-soluble moisturizing agent such as trimethylglycine and a liquid oil such as squalane and imparts a soft and firm feeling to the skin without stickiness.

特許文献2には、トリメチルグリシンなどの電解質とアクリル酸・メタクリル酸アルキル共重合体を含有する、保存安定性と塗布時の使用感が良好な皮膚用化粧料が開示されている。 Patent Literature 2 discloses a skin cosmetic that contains an electrolyte such as trimethylglycine and an alkyl acrylic acid/methacrylate copolymer and has good storage stability and good feeling during application.

特開2015-59114号公報JP 2015-59114 A 特開2011-1297号公報JP 2011-1297 A

特許文献1に記載の技術は、しっとり感を強く得ることができるものの、ガム系水溶性高分子と乳化剤が同一系に含有されることにより、べたつきが生じる。また、塗布中における、つっぱりのなさに関しては検討されていない。 Although the technique described in Patent Document 1 can provide a strong moist feeling, stickiness occurs due to the inclusion of the gum-based water-soluble polymer and the emulsifier in the same system. In addition, no consideration has been given to the lack of tension during application.

特許文献2に記載の技術は、しっとり感を強く得ることができるものの、キサンタンガムと単糖類が同一系に含有されることにより、べたつきが生じる。また、塗布中における、つっぱりのなさに関しては検討されていない。 Although the technique described in Patent Document 2 can provide a strong moist feeling, stickiness occurs due to xanthan gum and monosaccharides contained in the same system. In addition, no consideration has been given to the lack of tension during application.

そこで、本発明の課題は、塗布後のみずみずしさ、吸い付き感、さらさら感、しっとり感があり、塗布中につっぱりがない皮膚用化粧料を提供することにある。 SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a skin cosmetic that provides freshness, stickiness, smoothness, and moistness after application, and that does not cause tension during application.

本発明者は、上記課題を解決するために鋭意検討した結果、成分(A)アクリル酸・メタクリル酸アルキル共重合体、成分(B)メチルグルセス-20およびメチルグルセス-10より選択される1種以上、成分(C)スクワラン、成分(D)トリメチルグリシンを含有する皮膚用化粧料を提供することによって、本発明に至った。 As a result of intensive studies to solve the above problems, the present inventors have found that one or more selected from component (A) an alkyl acrylate/methacrylate copolymer, component (B) methyl gluceth-20 and methyl gluceth-10, The present invention was accomplished by providing a skin cosmetic containing component (C) squalane and component (D) trimethylglycine.

本発明により、塗布後のみずみずしさ、吸い付き感、さらさら感、しっとり感があり、塗布中につっぱりがない皮膚用化粧料を提供する。 To provide a skin cosmetic that gives freshness, sticky feeling, smooth feeling and moist feeling after application, and does not cause tightness during application.

以下、本発明を詳細に説明する。なお、含有量を示す単位は、特に明記しない限り全て質量%である。 The present invention will be described in detail below. In addition, all the units which show content are the mass % unless otherwise specified.

本発明は、次の成分(A)~成分(D)を含有し、成分(C)と成分(D)の質量の含有比(C)/(D)が0.1~10であることを特徴とする、皮膚用化粧料である。
成分(A)アクリル酸・メタクリル酸アルキル共重合体
成分(B)メチルグルセス-20およびメチルグルセス-10より選択される1種以上
成分(C)スクワラン
成分(D)トリメチルグリシン
The present invention contains the following components (A) to (D), and the content ratio (C)/(D) of the mass of the component (C) and the component (D) is 0.1 to 10. It is characterized by skin cosmetics.
Component (A) Alkyl acrylate/methacrylate copolymer Component (B) One or more selected from methylgluceth-20 and methylgluceth-10 Component (C) Squalane Component (D) Trimethylglycine

本発明による皮膚用化粧料には、成分(A)アクリル酸・メタクリル酸アルキル共重合体(以下、成分(A)とする)を含有する。 The skin cosmetic composition according to the present invention contains component (A) an alkyl acrylic acid/methacrylate copolymer (hereinafter referred to as component (A)).

本発明に用いる成分(A)の含有量は、特に限定されるものではないが、塗布後のみずみずしさの観点から、0.1~1%が好ましい。成分(A)の含有量が0.1%を下回ると、経時安定性を得にくい恐れがあり、1%を上回っても、みずみずしさがそれ以上強くなる見込みが薄い。 The content of component (A) used in the present invention is not particularly limited, but is preferably 0.1 to 1% from the viewpoint of freshness after application. If the content of component (A) is less than 0.1%, it may be difficult to obtain stability over time.

本発明による皮膚用化粧料には、成分(B)メチルグルセス-20およびメチルグルセス-10より選択される1種以上(以下、成分(B)とする)を含有する。 The skin cosmetic composition according to the present invention contains component (B) one or more selected from methylgluceth-20 and methylgluceth-10 (hereinafter referred to as component (B)).

本発明に用いる成分(B)は、メチルグルセス-20、メチルグルセス-10が挙げられる。中でも塗布後の吸い付き感の観点から、メチルグルセス-20が好ましい。これらは1種以上を選択して含有されてもよい。 Component (B) used in the present invention includes methylgluceth-20 and methylgluceth-10. Among them, methyl gluceth-20 is preferable from the viewpoint of sticking feeling after application. One or more of these may be selected and contained.

本発明に用いる成分(B)の含有量は、特に限定されるものではないが、塗布後の吸い付き感の観点から、0.5~10%が好ましい。成分(B)の含有量が0.5%を下回ると、吸い付き感を得にくい恐れがあり、10%を上回ると、べたつき感を得る恐れがある。 The content of component (B) used in the present invention is not particularly limited, but is preferably 0.5 to 10% from the viewpoint of stickiness after application. If the content of component (B) is less than 0.5%, it may be difficult to obtain a sticky feeling, and if it exceeds 10%, a sticky feeling may be obtained.

本発明による皮膚用化粧料には、成分(C)スクワラン(以下、成分(C)とする)を含有する。 The skin cosmetic composition according to the present invention contains component (C) squalane (hereinafter referred to as component (C)).

本発明に用いる成分(C)の含有量は、塗布後のさらさら感の観点から、0.2~20%以上が好ましく、0.4~20%以上がより好ましく、2~20%以上がさらに好ましい。成分(C)の含有量が0.2%を下回ると、さらさら感を得られずきしみが生じ、好ましくない。また、成分(C)の含有量が20%を上回っても、さらさら感がそれ以上強くなる見込みが薄い。 The content of component (C) used in the present invention is preferably 0.2 to 20% or more, more preferably 0.4 to 20% or more, and further preferably 2 to 20% or more, from the viewpoint of smooth feeling after application. preferable. If the content of the component (C) is less than 0.2%, it is not preferable because the smooth feeling cannot be obtained and the skin feels squeaky. Moreover, even if the content of the component (C) exceeds 20%, it is unlikely that the silky feeling will become stronger.

本発明による皮膚用化粧料には、成分(D)トリメチルグリシン(以下、成分(D)とする)を含有する。 The skin cosmetic composition according to the present invention contains component (D) trimethylglycine (hereinafter referred to as component (D)).

本発明に用いる成分(D)の含有量は、塗布後のしっとり感の観点から、0.2~20%以上が好ましく、0.4~20%以上がより好ましく、1~20%以上がさらに好ましい。成分(D)の含有量が0.2%を下回ると、しっとり感を得られず好ましくない。また、成分(D)の含有量が20%を上回っても、しっとり感がそれ以上強くなる見込みが薄い。 The content of component (D) used in the present invention is preferably 0.2 to 20% or more, more preferably 0.4 to 20% or more, and further preferably 1 to 20% or more, from the viewpoint of moist feeling after application. preferable. If the content of component (D) is less than 0.2%, moist feeling cannot be obtained, which is not preferable. Also, even if the content of component (D) exceeds 20%, it is unlikely that the moist feeling will become stronger.

本発明に用いる成分(C)と成分(D)の含有比(C)/(D)は、塗布中のつっぱりのなさの観点から、0.1~10が好ましく、0.2~8がより好ましく、1~4がさらに好ましい。含有比(C)/(D)が0.1を下回ると、塗布中にべたつきが出て皮膚がつっぱり、10を上回ると、塗布中にきしみが出て皮膚がつっぱる。 The content ratio (C)/(D) of the component (C) and the component (D) used in the present invention is preferably 0.1 to 10, more preferably 0.2 to 8, from the viewpoint of lack of tension during application. 1 to 4 are more preferred. When the content ratio (C)/(D) is less than 0.1, stickiness occurs during application and the skin becomes taut, and when it exceeds 10, creaking occurs during application and the skin becomes taut.

本発明による皮膚用化粧料の剤形は、特に限定されるものではないが、液体、ジェル、水中油型エマルション等である。本発明による皮膚用化粧料の剤形がジェルまたは水中油型エマルションである場合、粘度は特に限定されるものではないが、50,000mPa・s以上であることが好ましい。粘度が50,000mPa・s未満の場合、経時安定性を損なう恐れがある。 Although the dosage form of the skin cosmetic according to the present invention is not particularly limited, it may be liquid, gel, oil-in-water emulsion, or the like. When the dosage form of the skin cosmetic according to the present invention is a gel or an oil-in-water emulsion, the viscosity is not particularly limited, but is preferably 50,000 mPa·s or more. If the viscosity is less than 50,000 mPa·s, the stability over time may be impaired.

本発明における粘度は、常法により調製した当該化粧料をサンプル瓶(食品140:第一硝子株式会社製)に120g充填し、25℃で24時間静置した後に、ヘリカルスタンド付B型粘度計(モデル:デジタル粘度計TVB-10M、東機産業株式会社製)により、M4号ローターを用いて25℃、6rpmで1分間回転させた後に測定したものである。 The viscosity in the present invention is measured by filling 120 g of the cosmetic prepared by a conventional method into a sample bottle (Food 140: manufactured by Daiichi Glass Co., Ltd.) and allowing it to stand at 25 ° C. for 24 hours. (model: digital viscometer TVB-10M, manufactured by Toki Sangyo Co., Ltd.), and measured after rotating at 25° C. and 6 rpm for 1 minute using an M4 rotor.

本発明による皮膚用化粧料は、本発明の効果を奏していれば、その他、水、油剤、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤、非イオン性界面活性剤、増粘剤、溶剤、保湿剤、ビタミン類、防腐剤、酸化防止剤、紫外線吸収剤、紫外線散乱剤、キレート剤、抽出液、発酵液、湿潤剤、着色剤、香料等を含有することができ、これらは1種以上含有してもよい。 The skin cosmetic composition according to the present invention may also contain water, an oil, an anionic surfactant, a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant as long as the effects of the present invention are exhibited. , thickeners, solvents, moisturizers, vitamins, preservatives, antioxidants, ultraviolet absorbers, ultraviolet scattering agents, chelating agents, extracts, fermentation liquids, wetting agents, coloring agents, fragrances, etc. , and one or more of these may be contained.

以下に実施例を挙げて本発明をさらに詳細に説明するが、これらは本発明を何ら限定するものではない。 EXAMPLES The present invention will be described in more detail below with reference to examples, but these are not intended to limit the present invention in any way.

表1~4に示される評価試験において、成分および含有量を種々変更しながら皮膚用化粧料を常法により調製した。 In the evaluation tests shown in Tables 1 to 4, skin cosmetics were prepared by a conventional method while changing the ingredients and contents.

(評価方法)
パネラー10名が皮膚用化粧料を使用し、各項目に関して官能評価を行った。パネラーが項目毎に5点(非常に良好)、4点(より良好)、3点(良好)、2点(不良)、1点(非常に不良)の5段階で評価して全員の平均点を算出した後、下記判定基準に従って判定した。
(Evaluation method)
Ten panelists used the skin cosmetics and performed a sensory evaluation for each item. Panelists evaluate each item on a 5-point scale of 5 points (very good), 4 points (better), 3 points (good), 2 points (bad), and 1 point (very bad), and the average score of all was calculated, and then determined according to the following criteria.

(平均点の判定基準)
4.0点以上 : 5
3.5点以上4.0点未満 : 4
3.0点以上3.5点未満 : 3
2.0点以上3.0点未満 : 2
2.0点未満 : 1
(Criteria for average score)
4.0 points or more: 5
3.5 points or more and less than 4.0 points: 4
3.0 points or more and less than 3.5 points: 3
2.0 points or more and less than 3.0 points: 2
Less than 2.0 points: 1

(第1評価試験)
第1評価試験において、成分(A)の含有量に関して皮膚用化粧料を評価した。表1に、皮膚用化粧料の成分とその含有量および評価結果を示す。
(First evaluation test)
In the first evaluation test, skin cosmetics were evaluated with respect to the content of component (A). Table 1 shows the components of the skin cosmetics, their contents, and the evaluation results.

Figure 0007217520000001
Figure 0007217520000001

表1に示す実施例1~4より、みずみずしさ、吸い付き感、さらさら感、しっとり感およびつっぱりのなさに関して良好な結果を得た。 From Examples 1 to 4 shown in Table 1, good results were obtained in terms of freshness, stickiness, dryness, moistness and lack of tightness.

(第2評価試験)
第2評価試験において、成分(B)の種類および含有量に関して皮膚用化粧料を評価した。表2に、皮膚用化粧料の成分とその含有量および評価結果を示す。
(Second evaluation test)
In the second evaluation test, skin cosmetics were evaluated with respect to the type and content of component (B). Table 2 shows the components of the skin cosmetics, their contents, and the evaluation results.

Figure 0007217520000002
Figure 0007217520000002

表2に示す実施例5~9より、みずみずしさ、吸い付き感、さらさら感、しっとり感およびつっぱりのなさに関して良好な結果を得た。 From Examples 5 to 9 shown in Table 2, good results were obtained with respect to freshness, stickiness, smoothness, moistness and lack of tightness.

(第3評価試験)
第3評価試験において、成分(C)の種類、含有量および成分(C)と成分(D)の含有比(C)/(D)に関して皮膚用化粧料を評価した。表3に、皮膚用化粧料の成分とその含有量および評価結果を示す。
(Third evaluation test)
In the third evaluation test, skin cosmetics were evaluated with respect to the type and content of component (C) and the content ratio (C)/(D) of component (C) and component (D). Table 3 shows the components of the skin cosmetics, their contents, and the evaluation results.

Figure 0007217520000003
Figure 0007217520000003

表3に示す実施例10~17より、みずみずしさ、吸い付き感、さらさら感、しっとり感およびつっぱりのなさに関して良好な結果を得た。 From Examples 10 to 17 shown in Table 3, good results were obtained with respect to freshness, stickiness, smoothness, moistness and lack of tightness.

(第4評価試験)
第4評価試験において、成分(D)の種類、含有量および成分(C)と成分(D)の含有比(C)/(D)に関して皮膚用化粧料を評価した。表4に、皮膚用化粧料の成分とその含有量および評価結果を示す。
(Fourth evaluation test)
In the fourth evaluation test, skin cosmetics were evaluated with respect to the type and content of component (D) and the content ratio (C)/(D) of component (C) and component (D). Table 4 shows the components of the skin cosmetics, their contents, and the evaluation results.

Figure 0007217520000004
Figure 0007217520000004

表4に示す実施例18~24より、みずみずしさ、吸い付き感、さらさら感、しっとり感およびつっぱりのなさに関して良好な結果を得た。 From Examples 18 to 24 shown in Table 4, good results were obtained in terms of freshness, stickiness, dryness, moistness and lack of tension.

以下に皮膚用化粧料の実施例25を記載する。 Example 25 of the skin cosmetic is described below.

実施例25により得られた皮膚用化粧料は、みずみずしさ、吸い付き感、さらさら感、しっとり感およびつっぱりのなさに関して良好な結果を得た。
The skin cosmetic obtained in Example 25 gave good results in terms of freshness, stickiness, smoothness, moistness and lack of tightness.

実施例25
成 分 含有量(%)
(A)アクリル酸・メタクリル酸アルキル共重合体 0.40
(B)メチルグルセス-20 2.00
(C)スクワラン 4.00
(D)トリメチルグリシン 2.00
EDTA-2Na 0.05
クエン酸 0.01
グリセリン 4.00
カルボマー 0.20
1,3-ブチレングリコール 10.00
キサンタンガム 0.10
ヒドロキシエチルセルロース 0.40
メチルパラベン 0.30
ジメチコン 2.00
パルミチン酸エチルヘキシル 2.00
アルギニン 0.60
ハマメリス葉エキス 0.10
ピリドキシン環状リン酸 0.10
サクシニルアテロコラーゲン 0.10
アスコルビルグルコシド 0.10
エクトイン 0.10
酵母エキス 0.10
水 残分
合 計 100.00
Example 25
Component content (%)
(A) Acrylic acid/alkyl methacrylate copolymer 0.40
(B) Methylgluceth-20 2.00
(C) Squalane 4.00
(D) Trimethylglycine 2.00
EDTA-2Na 0.05
Citric acid 0.01
Glycerin 4.00
Carbomer 0.20
1,3-butylene glycol 10.00
Xanthan gum 0.10
Hydroxyethyl cellulose 0.40
Methylparaben 0.30
Dimethicone 2.00
Ethylhexyl palmitate 2.00
Arginine 0.60
Hamamelis leaf extract 0.10
Pyridoxine cyclic phosphate 0.10
Succinyl atelocollagen 0.10
Ascorbyl glucoside 0.10
Ectoine 0.10
Yeast extract 0.10
Total water residue 100.00

本発明は、塗布後のみずみずしさ、吸い付き感、さらさら感、しっとり感があり、塗布中につっぱりがない皮膚用化粧料を提供できる。 INDUSTRIAL APPLICABILITY The present invention can provide a skin cosmetic that has freshness, stickiness, smoothness, and moistness after application, and does not cause tightness during application.

Claims (1)

次の成分(A)~成分(D)を含有し、成分(D)の含有量が1~2質量%であり、成分(C)と成分(D)の質量の含有比(C)/(D)が1~4であることを特徴とする、皮膚用化粧料。
成分(A)アクリル酸・メタクリル酸アルキル共重合体
成分(B)メチルグルセス-20
成分(C)スクワラン
成分(D)トリメチルグリシン
The following components (A) to (D) are contained, the content of component (D) is 1 to 2% by mass, and the content ratio of the mass of component (C) to component (D) (C) / ( A skin cosmetic, characterized in that D) is from 1 to 4 .
Component (A) Alkyl acrylic acid/methacrylate copolymer Component (B) Methyl gluceth-20
Component (C) Squalane Component (D) Trimethylglycine
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005179318A (en) 2003-12-24 2005-07-07 Pola Chem Ind Inc Anti-inflammatory quasi drug for skin external use

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5495632B2 (en) * 2009-06-18 2014-05-21 株式会社マンダム Skin cosmetics
JP2015067584A (en) * 2013-09-30 2015-04-13 株式会社マンダム Skin cosmetic kit
JP6517006B2 (en) * 2014-11-26 2019-05-22 株式会社ダリヤ Skin cosmetics

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005179318A (en) 2003-12-24 2005-07-07 Pola Chem Ind Inc Anti-inflammatory quasi drug for skin external use

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
FANCL, Japan, ID#3623853,Lotion,Mintel GNPD [online],2015年11月,[検索日2022.09.14],インターネット <URL:https://www.gnpd.com/sinatra/recordpage/>
NOEVIR, Japan,Face Lotion EX, ID#6009753,Mintel GNPD [online],2018年09月, [検索日 2022.09.14],インターネット <URL:https://www.gnpd.com/sinatra/recordpage/>

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