CN107375017B - Cleansing composition and its preparation method and application - Google Patents
Cleansing composition and its preparation method and application Download PDFInfo
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- CN107375017B CN107375017B CN201710754576.0A CN201710754576A CN107375017B CN 107375017 B CN107375017 B CN 107375017B CN 201710754576 A CN201710754576 A CN 201710754576A CN 107375017 B CN107375017 B CN 107375017B
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- cleansing composition
- makeup remover
- makeup
- polyalcohol
- mixture
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a kind of cleansing compositions and its preparation method and application.The cleansing composition is made of surfactant and polyalcohol, the surfactant is nonionic surfactant, including a kind of ethoxylated glycerol ester and at least one ethylene oxide propylene oxide block copolymer, the polyalcohol is one or more in glycerine, propylene glycol, polyethylene glycol, butanediol, there is zero stimulation, disposable and very salubrious advantage using makeup remover prepared by cleansing composition of the present invention.
Description
Technical field
The present invention relates to cleansing cosmetic field, more particularly to a kind of cleansing composition and its preparation method and application.
Background technology
With the improvement of people ' s living standards with the transformation of consumption idea, cosmetics have no longer been luxury goods, then are become
Essential necessity in people's life.People more and more use the cosmetics such as BB frosts, eye shadow, lipstick, if unclear
Except thorough, remaining cosmetics can cause the pore of skin to block, and lead to skin oil and fat dyssecretosis, so as to cause acne, powder
Thorn and blackhead etc. make us the skin problem of puzzlement.So the makeup removing link of skin is particularly significant, at this moment the selection of makeup removal products is shown
It obtains particularly important.
Makeup removal products are broadly divided into following several at present：Makeup removing breast, make-up remover, makeup remover, makeup remover etc., the mechanism of makeup removing
It is substantially with the molten oil of oil or removes degreasing with surfactant emulsifies, solubilising etc..It is such as unloaded with the makeup removal products of the molten oily method of oil
Adornment oil, makeup removing are not thorough, and residual sense is stronger, needs to be cleaned one time with cleaning products such as facial cleanser, and it is complete to can be only achieved makeup removing.It adopts
With the makeup removal products of mode the effects that surfactant emulsifies, solubilising, decontamination, if surfactant collocation is unreasonable, to skin
Skin irritation is bigger, and especially skin is than more sensitive region, such as the skin around eyes.How to make a mildly has
The makeup removal products of effect are particularly important, and mild effective makeup removal products key is that mild makeup removing component is selected rationally to take
Match.
Invention content
Based on this, it is necessary to be directed to problem of the prior art, provide a kind of cleansing composition, which passes through glue
Shu Yuanli, which reaches, reduces the irritating effect of makeup remover, to meet the needs of stimulating makeup remover zero.
To achieve the above object, specific technical solution is as follows：
A kind of cleansing composition is made of the component a and b of following weight percentage：
A. at least one surfactant:50-80%；
B. at least one polyalcohol A:20-50%；
Wherein, the weight percentage summation of component a and b is 100%,
The surfactant is nonionic surfactant, including a kind of ethoxylated glycerol ester and at least one epoxy
Oxide-propylene oxide block copolymer；
The polyalcohol A is one or more in glycerine, propylene glycol, polyethylene glycol, butanediol, and preferably the third two
Alcohol.
Currently preferred technical solution is：
A kind of cleansing composition is made of a and b of following weight percentage：
A. at least one surfactant 50-60%；
B. at least one polyalcohol A 40-50%；
Wherein, the weight percentage summation of component a and b is 100%,
The surfactant is nonionic surfactant, including a kind of ethoxylated glycerol ester and at least one epoxy
Oxide-propylene oxide block copolymer；
The polyalcohol A is one or more in glycerine, propylene glycol, polyethylene glycol, butanediol, and preferably the third two
Alcohol.
In wherein some embodiments, the number-average molecular weight of the ethylene oxide-propylene oxide block copolymer is 1500-
15000, the number-average molecular weight of the ethylene oxide-propylene oxide block copolymer is preferably 2000-9000, ring of the present invention
Oxidative ethane-propylene oxide block copolymer is selected from the PE-64 and PE-78 of Rokopol 30P10 of PCC Exol, sanyo chemical
Deng.
In wherein some embodiments, the ethoxylated glycerol ester is selected from PEG-6 caprylic/caprics glyceride type or PEG-
7 glyceryl cocoate classes；The PEG-6 caprylic/caprics glyceride type is selected from the big Glycerox 767 of standing grain or wins woundGMC 6, the PEG-7 glyceryl cocoates class are selected from the big Glycerox HE of standing grain, BASFWhat HE and win were createdGC。
It is a further object of the present invention to provide a kind of preparation methods of above-mentioned cleansing composition.
A kind of preparation method of above-mentioned cleansing composition, includes the following steps：
(1) component of each weight percentage is taken, is mixed, is heated to 60-65 DEG C, stirs evenly, obtain mixture；
(2) said mixture is purified, refines, is cooled to room temperature, obtains cleansing composition.
Application it is a further object of the present invention to provide above-mentioned cleansing composition as makeup remover.
It is yet another object of the invention to provide a kind of makeup remover, the makeup remover contains above-mentioned cleansing composition, and should
Cleansing composition can obviously reduce the irritation of makeup remover.
A kind of makeup remover includes the component of water and following weight percentage：
In wherein some embodiments, the polyalcohol B in the makeup remover include glycerine, propylene glycol, polyethylene glycol and
It is one or more in butanediol.
In wherein some embodiments, the makeup remover further includes the preservative of 0.005-0.5%.
It is yet another object of the invention to provide a kind of preparation methods of above-mentioned makeup remover.
A kind of preparation method of makeup remover, includes the following steps：
(1) polyalcohol B, citric acid, sodium citrate, disodium ethylene diamine tetraacetate and water are added in agitated kettle, are heated to
It 75-80 DEG C, stirs evenly, is completely dissolved；
(2) cleansing composition is continuously added in step (1) described agitated kettle, stirs evenly, be completely dissolved, must mixes
Object；
(3) step (2) described mixture is cooled to 35-40 DEG C, preservative is added into mixture, is stirred evenly,
It is completely dissolved, filters, obtain makeup remover.
The principle of the present invention：
The present inventor is had found based on abundant experience and by a large amount of research：It is using number-average molecular weight
1500-15000 (preferably 2000-9000) ethylene oxide-propylene oxide block copolymer, in aqueous solution with similar crown ether
Helical structure exist, and the ethylene oxide-propylene oxide block copolymer of low content easily formed in aqueous solution it is stable
Micellar structure forms larger stable composition micella after being combined with ethoxylated glycerol ester, considerably reduce free surface work
Property agent residual, to the on-surface-active for making ethylene oxide-propylene oxide block copolymer and ethoxylated glycerol ester form
Agent has the function of as mild as a dove and can reduce the irritation of surfactant.Secondly, epoxy ethane-epoxy propane block is total
Polymers molecular weight is excessively high (being higher than 15000), and salubrious property is bad after leading to the makeup remover use of its composition, there is sticky feeling.This hair
When polyalcohol in the bright cleansing composition is propylene glycol, propylene glycol and ethoxylated glycerol ester and ethylene oxide-epoxy third
Alkane block copolymer has good intermiscibility, and apparent as leave makeup removal products makeup removing effect.
Compared with prior art, the present invention has the advantage that and effect is as follows：
Makeup remover prepared by cleansing composition of the present invention has zero stimulation, disposable and very salubrious advantage；In 5-50
In the range of DEG C, it can be stabilized without being precipitated.
Polyalcohol of the present invention can provide good moisture retention so that and skin achievees the effect that moisturizing is moistened, with
This also has good makeup removing ability simultaneously, wherein propylene glycol and ethoxylated glycerol ester and epoxy ethane-epoxy propane block
Copolymer has preferable intermiscibility, and apparent as leave makeup removal products makeup removing effect.
Description of the drawings
Fig. 1 is the lines drawn on arm using aqueous eyelashe cream；
Fig. 2 is the lines after being laid down on arm using makeup remover.
Specific implementation mode
Below in conjunction with specific embodiment, invention is further described in detail, but the present invention is not limited to these implementations
Example.
The cleansing composition of embodiment 1 and embodiment 2, by weight percentage, raw material as shown in Table 1 are prepared：
The formula table of the cleansing composition of 1 embodiment 1 of table and embodiment 2
The method for preparing above-described embodiment 1-2 cleansing compositions, includes the following steps：
(1) component of each weight percentage is taken, is mixed, is heated to 60 DEG C, stirs evenly, obtain mixture；
(2) said mixture is purified, refines, is cooled to room temperature, obtains cleansing composition.
The makeup remover of embodiment 3 and embodiment 4, by weight percentage, raw material as shown in Table 2 are prepared：
The formula table of the makeup remover of 2 embodiment 3 of table and embodiment 4
Comparative example 1：B phases and C phases are same as Example 4 in the formula of makeup remover, the difference is that, A phases are to account for makeup removing
The propylene glycol that water weight percent is 10%；
Comparative example 2：The formula of makeup remover is same as Example 4, the difference is that, A phases ethylene oxide-propylene oxide
Block copolymer is PEG/PPG-300/55 copolymers, number-average molecular weight 16400；
Comparative example 3：The formula of makeup remover is same as Example 4, the difference is that, A phases are 43% by weight percent
Propylene glycol and 57%PEG-6 caprylic/capric glyceride composition, and A phases account for that makeup remover weight percent is 10%.
The makeup remover of above example 3-4 and comparative example 1-3, preparation method includes the following steps：
(1) B is added in agitated kettle, is heated to 80 DEG C, stirs evenly, is completely dissolved；
(2) A is added in step (1) agitated kettle equipped with B phases, stirs evenly, be completely dissolved, must mixes
Object；
(3) step (2) described mixture is cooled to 35 DEG C, C is added into mixture, is stirred evenly, it is completely molten
Solution, filtering, obtains makeup remover.
5 physical and chemical testing of embodiment
Experimental method：
Conventional physical and chemical testing is carried out to the product of embodiment 3-4 and comparative example 1-3, data see the table below shown：
Experimental result：
The Physico-chemical tests result of table 3 embodiment 3-4 and comparative example 1-3 makeup removers
As shown in Table 3, the makeup remover of embodiment 3 and embodiment 4 is clear, it follows that being unloaded containing the present invention
The makeup remover of composition for cosmetics is all stable within the scope of 5-50 DEG C, will not be precipitated；Makeup remover is clear in comparative example 1
, main cause is to contain only propylene glycol in the makeup remover and be free of in nonionic surfactant；The makeup remover of comparative example 2 exists
28-35 DEG C is opaque, and nonionic surfactant has precipitation；The makeup remover of comparative example 3 is opaque at 28-35 DEG C
, nonionic surfactant has a precipitation, and main cause is can be by using single nonionic surfactant stability
The limitation of temperature.
The makeup removing power test of embodiment 6
One, experiment purpose
The makeup removing ability of testing example 4 (A), comparative example 1 (B), comparative example 2 (C) and comparative example 3 (D).
Two, experimental method
Test method：The lines for being about 2 centimetres are drawn on arm with aqueous eyelashe cream, are taken after waiting for 1 hour to be measured
0.1 gram of sample unloads lines position in cotton pads, and makeup removing effect is observed after wiping 5 times.
Three, experimental result
The test effect of Fig. 1 and Fig. 2 shows that the makeup remover makeup removing effect of embodiment 4 is best；The makeup remover of comparative example 1 is not
Containing nonionic surfactant, makeup removing is front and back not to have significant change, makeup removing effect poor；Epoxy contained by the makeup remover of comparative example 2
Oxide-propylene oxide block molecular weight of copolymer is excessive, causes the salubrious property of makeup remover poor and tacky, removes ornaments and formal dress front and back without apparent
Variation, makeup removing effect are poor；The makeup remover of comparative example 3 contains only single nonionic surfactant, removes ornaments and formal dress front and back without apparent
Variation, makeup removing effect are poor.
7 irritation of embodiment is tested
(1) irritation test 1
Test method：Embodiment 3-4 and comparative example the 1-3 makeup remover prepared are issued to 20 tests as test sample
Personnel (adult) test.Test sample is cleaned around eyes, and whether impression of opening eyes is irritant.
Test result：The results are shown in Table 4 for above-mentioned irritation test 1：
The test result of 4 irritation of table test 1
| Test sample | Apparent eye shouting pain | There is slight Eye irritation | It is non-stimulated |
| Embodiment 3 | 0 people | 0 people | 20 people |
| Embodiment 4 | 0 people | 0 people | 20 people |
| Comparative example 1 | 3 people | 4 people | 13 people |
| Comparative example 2 | 5 people | 7 people | 8 people |
| Comparative example 3 | 10 people | 6 people | 4 people |
(2) irritation test 2
Test name：Acute ocular irritant experiment
Test method：Sending Bao Hua inspection centers of Guangdong Province to carry out makeup remover prepared by embodiment 4, " acute eye irritation is real
Test ", experimental animal is new zealand rabbit, and experiment condition is to rinse for 30 seconds, and control sample is water.
Test result：According to Ministry of Health of the People's Republic of China《Cosmetics health specification》Version in 2007, the results are shown in Table 5：
5 tested material of table is to new zealand rabbit acute ocular irritant experiment appraisal result
By table 4 and table 5 it is found that the makeup remover of embodiment 3 and embodiment 4 can reach zero irritating effect；It uses
The makeup remover of comparative example 1 and comparative example 2 all can be irritant, and the makeup remover of comparative example 3 contains only single non-ionic surface and lives
Property agent, irritation are stronger.
8 moisture retention of embodiment is tested
Test method：
The moisture retention of makeup remover is tested using moisture of skin tester, is mainly tested person on probation and is used face after makeup remover
The moisture of portion and forehead, to indicate the moisture retention of makeup remover.
Embodiment 3-4 and comparative example the 1-3 makeup remover (sample) prepared are respectively issued to 50 testers to try out, tried out
Personnel use according to the conventional cosmetic method that unloads, and are maintained at 25 DEG C of room temperature, in the environment of relative humidity is 40%-60%,
The moisture of the forehead, left face and right face of test person on probation, records the water measured in 2 hours before makeup removing and after makeup removing
Divide content data, then calculate and remove ornaments and formal dress in latter two hour, moisture is relative to the value added before makeup removing.
Test result：
The front and back moisture value added test result (average value) of makeup remover makeup removing of 6 embodiment 3-4 of table and comparative example 1-3
Note：In table " after makeup removing 5min, 30min, 1 hour, 2 hours " indicate respectively 5min, 30min after makeup removing, 1 hour, 2
The moisture (%) of hour trier face or forehead is compared to the value added before makeup removing.
As seen from the results in Table 6, the makeup remover of embodiment 3 and embodiment 4 has apparent moistening effect to skin after makeup removing,
And the moistening effect of embodiment 4 is better than embodiment 3, i.e., the cleansing composition dosage containing embodiment 1 is bigger, and moisture retention is better；Separately
Outside, the makeup remover moisture retention of embodiment 3-4 is much better than comparative example 1-3.
By above-mentioned test result it is found that the makeup remover prepared containing cleansing composition of the present invention at 0-50 DEG C with good
Stability is not in cloud point；In addition cleansing composition to makeup removal products of the present invention, there is makeup removal products excellent moisturizing to imitate
Fruit, zero stimulation and mild product, makeup removing effect it is very good.
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (6)
1. a kind of cleansing composition, which is characterized in that be made of a and b of following weight percentage：
A. at least one surfactant 50-60%；
B. at least one polyalcohol A 40-50%；
Wherein, the weight percentage summation of component a and b is 100%,
The surfactant is nonionic surfactant, including a kind of ethoxylated glycerol ester and at least one epoxy second
Alkane-propylene oxide block copolymer；The number-average molecular weight of the ethylene oxide-propylene oxide block copolymer is 2000-9000；
The polyalcohol A is one or more in glycerine, propylene glycol, polyethylene glycol, butanediol.
2. cleansing composition according to claim 1, which is characterized in that it is pungent that the ethoxylated glycerol ester is selected from PEG-6
Acid/glycerol decanoate class or PEG-7 glyceryl cocoate classes.
3. a kind of preparation method of cleansing composition as claimed in claim 1 or 2, which is characterized in that include the following steps：
(1) component of each weight percentage is taken, is mixed, is heated to 60-65 DEG C, stirs evenly, obtain mixture；
(2) said mixture is purified, refines, is cooled to room temperature, obtains cleansing composition.
4. a kind of makeup remover, which is characterized in that the component including water and following weight percentage：
The polyalcohol B includes one or more in glycerine, propylene glycol, polyethylene glycol and butanediol.
5. makeup remover according to claim 4 further includes the preservative of 0.005-0.5%.
6. a kind of preparation method of the makeup remover as described in claim 4-5 is any, which is characterized in that include the following steps：
(1) polyalcohol B, citric acid, sodium citrate, disodium ethylene diamine tetraacetate and water are added in agitated kettle, are heated to 75-80
DEG C, it stirs evenly, is completely dissolved；
(2) cleansing composition is continuously added in step (1) described agitated kettle, stirs evenly, be completely dissolved, obtains mixture；
(3) step (2) described mixture is cooled to 35-40 DEG C, preservative is added into mixture, is stirred evenly, completely
Dissolving, filtering, obtains makeup remover.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710754576.0A CN107375017B (en) | 2017-08-29 | 2017-08-29 | Cleansing composition and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710754576.0A CN107375017B (en) | 2017-08-29 | 2017-08-29 | Cleansing composition and its preparation method and application |
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| CN107375017A CN107375017A (en) | 2017-11-24 |
| CN107375017B true CN107375017B (en) | 2018-07-13 |
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| CN201710754576.0A Active CN107375017B (en) | 2017-08-29 | 2017-08-29 | Cleansing composition and its preparation method and application |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109316381A (en) * | 2018-10-23 | 2019-02-12 | 张庆 | Effectively control clean skin liquid and its preparation, clean skin method that micella penetrates into skin |
| CN109846779A (en) * | 2019-03-06 | 2019-06-07 | 上海乐宝日化股份有限公司 | A kind of maintenance makeup remover and preparation method thereof containing vitamin B12 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1195520A (en) * | 1996-11-07 | 1998-10-14 | 莱雅公司 | Cosmetic composition in form of transparent foaming gel |
| CN106456516A (en) * | 2014-04-01 | 2017-02-22 | 莱雅公司 | Composition in the form of nano- or micro- emulsion |
-
2017
- 2017-08-29 CN CN201710754576.0A patent/CN107375017B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1195520A (en) * | 1996-11-07 | 1998-10-14 | 莱雅公司 | Cosmetic composition in form of transparent foaming gel |
| CN106456516A (en) * | 2014-04-01 | 2017-02-22 | 莱雅公司 | Composition in the form of nano- or micro- emulsion |
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