CN109316381A - Effectively control clean skin liquid and its preparation, clean skin method that micella penetrates into skin - Google Patents
Effectively control clean skin liquid and its preparation, clean skin method that micella penetrates into skin Download PDFInfo
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- CN109316381A CN109316381A CN201811237640.9A CN201811237640A CN109316381A CN 109316381 A CN109316381 A CN 109316381A CN 201811237640 A CN201811237640 A CN 201811237640A CN 109316381 A CN109316381 A CN 109316381A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to the clean skin liquid that a kind of effectively control micella penetrates into skin, component including following weight percentage: water, hydrophobically modified polymers, EDTA-2Na, butanediol, citric acid, hydrophobically modified polymers include PEG-6 caprylic/capric glyceride type, propylene glycol, PEG/PPG-25/30, low molecular weight HMP copolymer.It is a mild makeup removing aqua that a kind of effective control micella, which penetrates into the clean skin liquid of skin, milder than conventional makeup removal products, is the makeup removal products of leave, can quickly dissolve the dressings such as color make-up, foundation cream, BB frost；With salubrious, moisturizing skin sense；Extensive temperature range internal stability is good, and easy to use, performance is stablized, and is easy to save.
Description
Technical field
The present invention relates to cleansing cosmetic field, espespecially a kind of effectively control micella penetrates into the clean skin liquid and its system of skin
Preparation Method.
Background technique
With the improvement of people ' s living standards with the transformation of consumption idea, cosmetics are no longer luxury goods, then are become
Essential necessity in people's life.People more and more use the cosmetics such as BB frost, eye shadow, lipstick, if unclear
Except thorough, remaining cosmetics can cause the pore of skin to block, and lead to skin oil and fat dyssecretosis, so as to cause acne, powder
Thorn and blackhead etc. make us the skin problem of puzzlement.So the makeup removing link of skin is particularly significant, at this moment the selection of makeup removal products is shown
It obtains particularly important.
Makeup removal products are broadly divided into following several at present: makeup removing breast, make-up remover, makeup remover, makeup remover etc., the mechanism of makeup removing
It is substantially with the molten oil of oil or removes degreasing with surfactant emulsifies, solubilising etc..It is such as unloaded with the makeup removal products of the molten oily method of oil
Adornment oil, makeup removing are not thorough, and residual sense is stronger, needs to be cleaned one time with cleaning products such as facial cleanser, and it is complete to can be only achieved makeup removing.It adopts
With the makeup removal products of mode the effects of surfactant emulsifies, solubilising, decontamination, if surfactant collocation is unreasonable, to skin
Skin irritation is bigger, and especially skin is than more sensitive region, such as the skin around eyes.In addition, existing pierce skin
Swash the few makeup removal products needs of property just to stablize under low-temperature condition, thus office of travelling or go on business outside, carrying also need to consider such as
What is stored refrigerated.
Summary of the invention
To solve the above problems, the present invention provides a kind of clean skin liquid and its preparation side for effectively controlling micella and penetrating into skin
Method.
To achieve the above object, the present invention, which adopts the following technical scheme that, is: one kind effectively control micella penetrates into skin
Clean skin liquid, the component including following weight percentage: water, hydrophobically modified polymers, epoxy ethane-epoxy propane block are total
Polymers, EDTA-2Na, butanediol, citric acid, hydrophobically modified polymers be PEG-6 caprylic/capric glyceride type, propylene glycol,
The mixture of PEG/PPG-25/30, low molecular weight HMP.
Hydrophobically modified polymers are nonionic surfactant, by reducing the CMC point of single nonionic surfactant,
The biggish micella of volume is formed, so that remaining surfactant monomer concentration is low, it is difficult to penetrate into epidermal skin, to reach
To control micellar size, irritating use is reduced, product mild low-stimulation while with preferable makeup removing effect is made.Ring
Oxidative ethane-propylene oxide block copolymer exists in aqueous solution with the helical structure of similar crown ether, and the epoxy of low content
Oxide-propylene oxide block copolymer easily forms stable micellar structure in aqueous solution, in conjunction with hydrophobically modified polymers
After form biggish stable composition micella, the residual of free surfactant is considerably reduced, to make ethylene oxide-epoxy
The non-surface-active agent that propane block copolymer is formed with hydrophobically modified polymers has the function of as mild as a dove and can reduce
The irritation of surfactant.The effect of PGE is remaining free in surface of stability surfactant system in hydrophobically modified polymers
Micella is simultaneously allowed to milder.Since when low molecular weight HMP is present in composition, free micella is constituted as surface-active
The surfactant group of agent system irritation main contributor, thus PGE so that these free micellas is become the effect of milder can
So that entire cleaning system ratio PGE becomes obvious milder when not existing in composition.Butanediol can provide good guarantor
It is moist, so that skin achievees the effect that moisturizing is moistened, also there is good makeup removing ability, butanediol and epoxy second at the same time
Alkane-propylene oxide block copolymer and hydrophobically modified polymers have good intermiscibility, and as leave makeup removal products
Makeup removing effect is obvious.
Wherein, the water is deionized water.
Wherein, the pH value of the clean skin liquid is 5.5, more gets close to skin.
It wherein, further include the preservative of 0.005-0.5%.The effect of preservative is to prevent clean skin liquid from using and storing
Moldy metamorphism in journey.Preservative can be isothiazolinone (i.e. Kathon CG), sodium benzoate, hydantoins (i.e. DMDMH), diazoparaffins
One of base imidazoles urea (i.e. extremely beautiful), methylparaben and propylben or in which a variety of mixtures.
A kind of effective preparation method for controlling micella and penetrating into the clean skin liquid of skin, includes the following steps:
(1) EDTA-2Na, butanediol, citric acid and water are added in agitated kettle, are heated to 75-80 DEG C, stir evenly, it is complete
Fully dissolved；
(2) hydrophobically modified polymers are continuously added in step (1) described agitated kettle, stirs evenly, be completely dissolved, obtains
Mixture；
(3) mixture in step (2) described agitated kettle is cooled to 35-40 DEG C, epoxy ethane-epoxy propane block is total to
Polymers is added into mixture, stirs evenly, and is completely dissolved, and filtering obtains clean skin liquid.
A kind of effective three-dimensional clean skin method for controlling micella and penetrating into the clean skin liquid of skin, includes the following steps:
Step 1: wetting dissolution epidermis dirt: take clean skin liquid 2-3g in the palm of the hand, with soft gimmick Qing Rou face, clean skin
Liquid can make color make-up and the wetted dissolution of dirt particles；
Step 2: solubilising dispersion dirt: massage is reinforced at color make-up position, and hydrophobic grouping can make color make-up and dirt in clean skin liquid
Grain has charge, thus color make-up can be prevented to condense mutually with dirt particles, and the negatively charged and epidermis institute band of hydrophobic grouping institute is just
Electric forming electric double layer, electric double layer are stablized due to the balance of electrostatic force and extension, because charge is arranged between particle after formation electric double layer
Reprimand effect；
Step 3: package dirt: color make-up and dirt particles are wrapped to form hydrophilic polymer skeleton by PEG/PPG, effectively anti-
It is redeposited；
Step 4: cleaning dirt: after 20-30 seconds, with clear water or warm water cleaning face, hydrophilic polymer skeleton is rushed
It washes, PPG/PEG and each ingredient cooperate, and play the role of collaboration enhancing cleaning force, have constructed three-dimensional clean skin frame, maximum
Limit reduces cleaning monomer or small size micella penetrates into skin, and the irritation of makeup removal products can be greatly reduced to reach zero thorn
Swash, it is noninductive, releive it is red.
The beneficial effects of the present invention are: the present invention is a mild makeup removing aqua, is more heated than conventional makeup removal products
With assigning noninductive clean skin experience/all skin types can be applicable in, and delicate and general red muscle skin can also be used.Traditional clean skin produces
After product are except the barrier substance of skin surface, such as phosphatide, NMF ceramide, enzyme, it remains on the skin or inevitably penetrates into
Skin gap destroys skin texture, causes skin irritatin, causes as skin barrier is impaired, leather bag inflammation, oxidation, tight, cleaning
While cleaning skin, size is lesser to enter cuticula by aqueous gap, to cause skin for agent monomer and micella
Redness such as does, itches at the senses of discomfort.Void size about 2.0-5.6nm on cuticula.In general, in cleaning products, average micella is got over
Greatly, irritation is smaller, conversely, average micella is smaller, irritation is bigger.The present invention uses hydrophobically modified polymers for nonionic table
Face activating agent forms the biggish micella of volume, so that remaining table by reducing the CMC point of single nonionic surfactant
Face active agent monomer concentration is low, it is difficult to penetrate into epidermal skin, to reach control micellar size, reduce irritating make
With 2%-6% hydrophobically modified polymers can lay down basic grease；Additive amount can effectively lay down rapidly coloured silk 8% or more
Adornment；Under same additive amount in make up remover, the product of hydrophobically modified polymers preparation is close to zero stimulation, and irritation is than existing
There are makeup removal products weak very much, optimal additive amount is in 8%-12% or so.Ethylene oxide-propylene oxide block copolymer with it is hydrophobic
The non-surface-active agent of polymer-modified composition has the function of that the stimulation of surfactant can be reduced as mild as a dove and more preferably
Property, and stablize the clean skin liquid of preparation within the scope of 5 DEG C -50 DEG C.
The present invention can quickly dissolve the dressings such as color make-up, foundation cream, BB frost；With salubrious, moisturizing skin sense；Extensive temperature model
It is good to enclose internal stability, easy to use, performance is stablized, and is easy to save.With hydrophobically modified polymers and epoxy ethane-epoxy propane
The increase of block copolymer additive amount, makeup removing effect gradually increase, and skin irritation is fewer.Clean skin liquid of the present invention has preferably
Mild low-stimulation while makeup removing effect；With good compatibility, can be combined with various surfactants；With good
Dissolubility, it is very good in large temperature range stability inferior, for going on business, travelling for white collar, reduce the inconvenience of carrying.
Specific embodiment
The present invention penetrates into the clean skin liquid of skin, the group including following weight percentage about a kind of effectively control micella
Point: water, hydrophobically modified polymers, ethylene oxide-propylene oxide block copolymer, EDTA-2Na, butanediol, citric acid, it is hydrophobic
Polymer-modified is the mixture of PEG-6 caprylic/capric glyceride type, propylene glycol, PEG/PPG-25/30, low molecular weight HMP.
Hydrophobically modified polymers are nonionic surfactant, by reducing the CMC point of single nonionic surfactant,
The biggish micella of volume is formed, so that remaining surfactant monomer concentration is low, it is difficult to penetrate into epidermal skin, to reach
To control micellar size, irritating use is reduced, product mild low-stimulation while with preferable makeup removing effect is made.Ring
Oxidative ethane-propylene oxide block copolymer exists in aqueous solution with the helical structure of similar crown ether, and the epoxy of low content
Oxide-propylene oxide block copolymer easily forms stable micellar structure in aqueous solution, in conjunction with hydrophobically modified polymers
After form biggish stable composition micella, the residual of free surfactant is considerably reduced, to make ethylene oxide-epoxy
The non-surface-active agent that propane block copolymer is formed with hydrophobically modified polymers has the function of as mild as a dove and can reduce
The irritation of surfactant.The effect of PGE is remaining free in surface of stability surfactant system in hydrophobically modified polymers
Micella is simultaneously allowed to milder.Since when low molecular weight HMP is present in composition, free micella is constituted as surface-active
The surfactant group of agent system irritation main contributor, therefore PGE makes these free micellas become milder, may make whole
A cleaning system ratio PGE becomes obvious milder when not existing in composition.Butanediol can provide good moisture retention, make
It obtains skin and achievees the effect that moisturizing is moistened, also there is good makeup removing ability, butanediol and ethylene oxide-epoxy third at the same time
Alkane block copolymer and hydrophobically modified polymers have good intermiscibility, and obvious for makeup removing effect as clean skin liquid.
Wherein, the water is deionized water.
Wherein, the pH value of the clean skin liquid is 5.5, more gets close to skin.
It wherein, further include the preservative of 0.005-0.5%.The effect of preservative is to prevent clean skin liquid from using and storing
Moldy metamorphism in journey.Preservative can be isothiazolinone (i.e. Kathon CG), sodium benzoate, hydantoins (i.e. DMDMH), diazoparaffins
One of base imidazoles urea (i.e. extremely beautiful), methylparaben and propylben or in which a variety of mixtures.
A kind of effective preparation method for controlling micella and penetrating into the clean skin liquid of skin, includes the following steps:
(1) EDTA-2Na, butanediol, citric acid and water are added in agitated kettle, are heated to 75-80 DEG C, stir evenly, it is complete
Fully dissolved；
(2) hydrophobically modified polymers are continuously added in step (1) described agitated kettle, stirs evenly, be completely dissolved, obtains
Mixture；
(3) mixture in step (2) described agitated kettle is cooled to 35-40 DEG C, epoxy ethane-epoxy propane block is total to
Polymers is added into mixture, stirs evenly, and is completely dissolved, and filtering obtains clean skin liquid.
A kind of effective three-dimensional clean skin method for controlling micella and penetrating into the clean skin liquid of skin, includes the following steps:
Step 1: wetting dissolution epidermis dirt: take clean skin liquid 2-3g in the palm of the hand, with soft gimmick Qing Rou face, clean skin
Liquid can make color make-up and the wetted dissolution of dirt particles；
Step 2: solubilising dispersion dirt: massage is reinforced at color make-up position, and hydrophobic grouping can make color make-up and dirt in clean skin liquid
Grain has charge, thus color make-up can be prevented to condense mutually with dirt particles, and the negatively charged and epidermis institute band of hydrophobic grouping institute is just
Electric forming electric double layer, electric double layer are stablized due to the balance of electrostatic force and extension, because charge is arranged between particle after formation electric double layer
Reprimand effect；
Step 3: package dirt: color make-up and dirt particles are wrapped to form hydrophilic polymer skeleton by PEG/PPG, effectively anti-
It is redeposited；
Step 4: cleaning dirt: after 20-30 seconds, with clear water or warm water cleaning face, hydrophilic polymer skeleton is rushed
It washes, PPG/PEG and each ingredient cooperate, and play the role of collaboration enhancing cleaning force, have constructed three-dimensional clean skin frame, maximum
Limit reduces cleaning monomer or small size micella penetrates into skin, and the irritation of makeup removal products can be greatly reduced to reach zero thorn
Swash, it is noninductive, releive it is red.
The beneficial effects of the present invention are: the present invention is a mild makeup removing aqua, is more heated than conventional makeup removal products
With assigning noninductive clean skin experience/all skin types can be applicable in, and it is leave that delicate and general red muscle skin, which can also be used,
Makeup removal products can quickly dissolve the dressings such as color make-up, foundation cream, BB frost；With salubrious, moisturizing skin sense；Within the scope of extensive temperature
Stability is good, and easy to use, performance is stablized, and is easy to save.With the increase of hydrophobically modified polymers additive amount, makeup removing effect by
It is cumulative strong.2%-6% hydrophobically modified polymers can lay down basic grease；Additive amount can be unloaded effectively rapidly 8% or more
Fall color make-up；Under same additive amount in make up remover, the product of hydrophobically modified polymers preparation close to zero stimulation, want by irritation
It is weaker than existing makeup removal products very much, optimal additive amount is in 8%-12% or so；The clean skin liquid of hydrophobically modified polymers preparation is 5
Stablize within the temperature range of DEG C -10 DEG C.Clean skin liquid of the present invention mild low-stimulation while with preferable makeup removing effect；With good
Good compatibility, can combine with various surfactants；With good dissolubility, in large temperature range stability inferior
It is very good.
Embodiment of above be only preferred embodiments of the present invention will be described, not to the scope of the present invention into
Row limits, and without departing from the spirit of the design of the present invention, this field ordinary engineering and technical personnel is to technical side of the invention
The various changes and improvements that case is made, should fall within the scope of protection determined by the claims of the present invention.
Claims (5)
1. the clean skin liquid that a kind of effectively control micella penetrates into skin, it is characterised in that: the group including following weight percentage
Point: water, hydrophobically modified polymers, ethylene oxide-propylene oxide block copolymer, EDTA-2Na, butanediol, citric acid.
2. the clean skin liquid that a kind of effectively control micella according to claim 1 penetrates into skin, it is characterised in that: described to dredge
The polymer-modified mixing for PEG-6 caprylic/capric glyceride type, propylene glycol, PEG/PPG-25/30, low molecular weight HMP of water
Object.
3. the clean skin liquid that a kind of effectively control micella according to claim 1 penetrates into skin, it is characterised in that: further include
Preservative.
4. a kind of effectively control micella according to claim 1 penetrates into the preparation method of the clean skin liquid of skin, feature
It is: includes the following steps:
(1) EDTA-2Na, butanediol, citric acid and water are added in agitated kettle, are heated to 75-80 DEG C, stir evenly, it is completely molten
Solution；
(2) hydrophobically modified polymers are continuously added in step (1) described agitated kettle, stirs evenly, be completely dissolved, must mixes
Object；
(3) mixture in step (2) described agitated kettle is cooled to 35-40 DEG C, by ethylene oxide-propylene oxide block copolymer
It is added into mixture, stirs evenly, be completely dissolved, filter, obtain clean skin liquid.
5. a kind of effectively control micella according to claim 1 penetrates into the three-dimensional clean skin method of the clean skin liquid of skin,
It is characterized in that: including the following steps:
Step 1: wetting dissolution epidermis dirt: take clean skin liquid 2-3g in the palm of the hand, with soft gimmick Qing Rou face, clean skin liquid can
So that color make-up and the wetted dissolution of dirt particles；
Step 2: solubilising dispersion dirt: massage is reinforced at color make-up position, and hydrophobic grouping can make color make-up and dirt particles band in clean skin liquid
There is charge, thus color make-up can be prevented to condense mutually with dirt particles, the negatively charged positively charged shape of institute with epidermis of hydrophobic grouping institute
At electric double layer, electric double layer is stablized due to the balance of electrostatic force and extension, because electrical charge rejection is made between particle after formation electric double layer
With；
Step 3: package dirt: color make-up and dirt particles are wrapped to form hydrophilic polymer skeleton by PEG/PPG, effectively anti-to sink again
Product；
Step 4: cleaning dirt: after 20-30 seconds, with clear water or warm water cleaning face, being rinsed hydrophilic polymer skeleton,
PPG/PEG and each ingredient cooperate, and play the role of collaboration enhancing cleaning force, have constructed three-dimensional clean skin frame, maximum limit
Degree reduces cleaning monomer or small size micella penetrates into skin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811237640.9A CN109316381A (en) | 2018-10-23 | 2018-10-23 | Effectively control clean skin liquid and its preparation, clean skin method that micella penetrates into skin |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811237640.9A CN109316381A (en) | 2018-10-23 | 2018-10-23 | Effectively control clean skin liquid and its preparation, clean skin method that micella penetrates into skin |
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| CN109316381A true CN109316381A (en) | 2019-02-12 |
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| CN201811237640.9A Pending CN109316381A (en) | 2018-10-23 | 2018-10-23 | Effectively control clean skin liquid and its preparation, clean skin method that micella penetrates into skin |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111249217A (en) * | 2020-03-19 | 2020-06-09 | 西安润玉医疗科技有限公司 | Cleansing liquid for adjusting skin micro-ecological balance and preparation method thereof |
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2018
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| CN102552062A (en) * | 2010-12-21 | 2012-07-11 | 强生消费者公司 | Skin cleansing compositions with polyglycerol esters and hydrophobically modified polymers |
| CN105832572A (en) * | 2016-04-07 | 2016-08-10 | 广州宏度精细化工有限公司 | Amino acid facial cleanser and preparation method thereof |
| CN106361610A (en) * | 2016-10-19 | 2017-02-01 | 刘艺鹏 | Cleansing astringent containing shea butter |
| CN107260586A (en) * | 2017-06-27 | 2017-10-20 | 新时代健康产业（集团）有限公司 | A kind of makeup removing breast gel and preparation method thereof |
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Cited By (1)
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|---|---|---|---|---|
| CN111249217A (en) * | 2020-03-19 | 2020-06-09 | 西安润玉医疗科技有限公司 | Cleansing liquid for adjusting skin micro-ecological balance and preparation method thereof |
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Application publication date: 20190212 |