JP2021511284A - 農業用途のための溶媒および殺虫剤製剤 - Google Patents
農業用途のための溶媒および殺虫剤製剤 Download PDFInfo
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- 239000002904 solvent Substances 0.000 title claims abstract description 63
- 239000003090 pesticide formulation Substances 0.000 title claims abstract description 53
- 239000000575 pesticide Substances 0.000 claims abstract description 69
- -1 ether ester Chemical class 0.000 claims abstract description 48
- 150000001408 amides Chemical class 0.000 claims abstract description 46
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 45
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 27
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 27
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
- 239000001257 hydrogen Substances 0.000 claims abstract description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 13
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 4
- 239000003995 emulsifying agent Substances 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 24
- 239000002917 insecticide Substances 0.000 claims description 19
- AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical group CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 claims description 15
- 238000009472 formulation Methods 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 13
- MBHINSULENHCMF-UHFFFAOYSA-N n,n-dimethylpropanamide Chemical compound CCC(=O)N(C)C MBHINSULENHCMF-UHFFFAOYSA-N 0.000 claims description 12
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 3
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 3
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 claims description 3
- 239000005660 Abamectin Substances 0.000 claims description 3
- 239000005874 Bifenthrin Substances 0.000 claims description 3
- 239000005885 Buprofezin Substances 0.000 claims description 3
- 239000005839 Tebuconazole Substances 0.000 claims description 3
- 229950008167 abamectin Drugs 0.000 claims description 3
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims description 3
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 claims description 3
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000010586 diagram Methods 0.000 abstract 1
- BHXIWUJLHYHGSJ-UHFFFAOYSA-N ethyl 3-ethoxypropanoate Chemical group CCOCCC(=O)OCC BHXIWUJLHYHGSJ-UHFFFAOYSA-N 0.000 description 18
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 16
- 239000004480 active ingredient Substances 0.000 description 13
- 150000002431 hydrogen Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229920001600 hydrophobic polymer Polymers 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 2
- 206010074268 Reproductive toxicity Diseases 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000007696 reproductive toxicity Effects 0.000 description 1
- 231100000372 reproductive toxicity Toxicity 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
R4−C(O)−NR5R6(式2)
式中、R4は、1〜4個の炭素原子を有するアルキル基であり、R5およびR6は、それぞれ独立して、1〜3個の炭素原子を有するアルキル基である、式2の極性アミドと、を含む、殺虫剤のための溶媒を提供する。
R4−C(O)−NR5R6(式2)
式中、R4は、1〜4個の炭素原子を有するアルキル基であり、R5およびR6は、それぞれ独立して、1〜3個の炭素原子を有するアルキル基である、式2の極性アミドと、から本質的になる、殺虫剤のための溶媒を提供する。
R4−C(O)−NR5R6(式2)
式中、R4は、1〜4個の炭素原子を有するアルキル基であり、R5およびR6は、それぞれ独立して、1〜3個の炭素原子を有するアルキル基である、式2の極性アミドと、を含む。いくつかの実施形態では、式2の極性アミドのR4は、メチル基またはエチル基である。極性アミドは、いくつかの実施形態では、N,N−ジエチルアセトアミドまたはN,N−ジメチルプロパンアミドである。いくつかの実施形態では、式1のエーテルエステルのR1およびR2は、エチル基であり、R3は、水素であり、nは、2である。いくつかの実施形態では、溶媒は、溶媒の総重量に基づいて、最大20重量パーセントのエーテルエステルを含む。
R4−C(O)−NR5R6(式2)
式中、R4が、1〜4個の炭素原子を有するアルキル基であり、R5およびR6が、それぞれ独立して、1〜3個の炭素原子を有するアルキル基である、式2の極性アミドと、から本質的になる。いくつかの実施形態では、式2の極性アミドのR4は、メチル基またはエチル基である。極性アミドは、いくつかの実施形態では、N,N−ジエチルアセトアミドまたはN,N−ジメチルプロパンアミドである。いくつかの実施形態では、式1のエーテルエステルのR1およびR2は、エチル基であり、R3は、水素であり、nは、2である。溶媒は、いくつかの実施形態では、溶媒の総重量に基づいて、最大20重量パーセントのエーテルエステルを含む。
本発明のいくつかの実施形態による殺虫剤のための溶媒は、(a)式1のエーテルエステルであって、
R4−C(O)−NR5R6(式2)
式中、R4は、1〜4個の炭素原子を有するアルキル基であり、R5およびR6は、それぞれ独立して、1〜3個の炭素原子を有するアルキル基である、式2の極性アミドと、を含む。
本発明の殺虫剤のための溶媒の第1の成分は、式1のエーテルエステルであって、
本発明の殺虫剤のための溶媒の第2の成分は、式2の極性アミドであって、
R4−C(O)−NR5R6(式2)
式中、R4は、1〜4個の炭素原子を有するアルキル基であり、R5およびR6は、それぞれ独立して、1〜3個の炭素原子を有するアルキル基である、式2の極性アミドからなるか、またはそれである。いくつかの実施形態では、式2の極性アミドのR4は、メチル基またはエチル基である。
いくつかの実施形態では、本発明の溶媒は、本発明の殺虫剤製剤を形成するのに有用である。本発明による殺虫剤製剤は、本明細書に開示される殺虫剤のための溶媒の実施形態のいずれかによる殺虫剤および溶媒を含む。これらの殺虫剤には、アバメクチン、テブコナゾール、ジフェノコナゾール、トリアゾロン、キザロホップ−p−エチル、ミクロブタニル、ジアフェンチウロン、ピラクロストロビン、ビフェントリン、ブプロフェジン、およびベータ−シペルメトリンのうちの1つ以上が含まれるが、これらに限定されない。
Claims (10)
- R4が、メチル基またはエチル基である、請求項1に記載の溶媒。
- 前記極性アミドが、N,N−ジエチルアセトアミドまたはN,N−ジメチルプロパンアミドである、請求項1または請求項2に記載の溶媒。
- R1およびR2が、エチル基であり、R3が、水素であり、nが、2である、請求項1〜3のいずれかに記載の溶媒。
- 前記溶媒が、前記溶媒の総重量に基づいて、最大20重量パーセントの前記エーテルエステルを含む、請求項1〜4のいずれかに記載の溶媒。
- 殺虫剤製剤であって、
請求項1〜6のいずれかに記載の溶媒と、
殺虫剤と、を含む、殺虫剤製剤。 - 乳化剤をさらに含む、請求項7に記載の殺虫剤製剤。
- 前記極性アミドが、前記製剤の30〜90重量パーセントを構成し、前記エーテルエステルが、前記製剤の5〜30重量パーセントを構成し、前記殺虫剤が、前記製剤の2〜70重量パーセントを構成し、前記乳化剤が、前記製剤の3〜20重量パーセントを構成する、請求項8に記載の殺虫剤製剤。
- 前記殺虫剤が、アバメクチン、テブコナゾール、ジフェノコナゾール、トリアゾロン、キザロホップ−p−エチル、ミクロブタニル、ジアフェンチウロン、ピラクロストロビン、ビフェントリン、ブプロフェジン、およびベータ−シペルメトリンのうちの1つ以上を含む、請求項3または請求項4に記載の殺虫剤製剤。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2017/109248 WO2019084896A1 (en) | 2017-11-03 | 2017-11-03 | Solvents for agricultural applications and pesticide formulations |
Publications (3)
Publication Number | Publication Date |
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JP2021511284A true JP2021511284A (ja) | 2021-05-06 |
JPWO2019084896A5 JPWO2019084896A5 (ja) | 2022-11-09 |
JP7231624B2 JP7231624B2 (ja) | 2023-03-01 |
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JP2020522818A Active JP7231624B2 (ja) | 2017-11-03 | 2017-11-03 | 農業用途のための溶媒および農薬製剤 |
Country Status (8)
Country | Link |
---|---|
US (1) | US11617366B2 (ja) |
EP (1) | EP3703495B1 (ja) |
JP (1) | JP7231624B2 (ja) |
CN (1) | CN111246737B (ja) |
BR (1) | BR112020008115B1 (ja) |
CA (1) | CA3079267A1 (ja) |
ES (1) | ES2969257T3 (ja) |
WO (1) | WO2019084896A1 (ja) |
Families Citing this family (1)
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BR112020008074A2 (pt) * | 2017-11-03 | 2020-10-06 | Dow Global Technologies Llc | solventes para aplicações agrícolas e formulações de pesticidas |
Citations (4)
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JPS5947268A (ja) * | 1982-09-10 | 1984-03-16 | Kashiwa Kagaku Kogyo:Kk | 可剥性フイルム形成エアゾ−ル製品 |
JPH03284651A (ja) * | 1990-03-30 | 1991-12-16 | Showa Denko Kk | 溶剤組成物 |
JPH11116994A (ja) * | 1997-10-17 | 1999-04-27 | Kyowa Yuka Kk | アルコキシ酪酸エステルからなる溶剤 |
JP2016535092A (ja) * | 2013-11-05 | 2016-11-10 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 農薬およびアミドを含んでなる組成物 |
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PL330717A1 (en) | 1996-06-28 | 1999-05-24 | Novartis Ag | Pesticidal compositions |
CN1223544A (zh) * | 1996-06-28 | 1999-07-21 | 诺瓦提斯公司 | 农药组合物 |
US7579017B2 (en) | 2003-06-18 | 2009-08-25 | Brook Chandler Murphy | Physical mode of action pesticide |
CA2651743C (en) | 2006-05-26 | 2016-08-16 | Huntsman Petrochemical Corporation | Low odor, low volatility solvent for agricultural chemicals |
BRPI0900019A2 (pt) * | 2009-01-12 | 2010-10-19 | Rotam Agrochem Int Co Ltd | suspoemulsões com base aquosa, processo de preparação e uso desta e método de tratamento de pragas indesejadas em um local |
CN101971824A (zh) | 2010-11-09 | 2011-02-16 | 上海生农生化制品有限公司 | 一种精噁唑禾草灵与麦草畏的组合物及其应用 |
CN102283195A (zh) | 2011-09-13 | 2011-12-21 | 广西田园生化股份有限公司 | 一种农药助剂及其制备方法 |
WO2013087416A1 (en) | 2011-12-14 | 2013-06-20 | Basf Se | Emulsifiable concentrate comprising pesticide, amide, carbonate and hydrocarbon |
US8971141B2 (en) | 2012-06-28 | 2015-03-03 | Sandisk Technologies Inc. | Compact high speed sense amplifier for non-volatile memory and hybrid lockout |
JP6131662B2 (ja) | 2013-03-22 | 2017-05-24 | セイコーエプソン株式会社 | 表示装置及び電子機器 |
US10375951B2 (en) * | 2015-04-20 | 2019-08-13 | Mitsui Chemicals Agro, Inc. | Fertilizer and agrochemical formulation |
EP3178320A1 (de) * | 2015-12-11 | 2017-06-14 | Bayer CropScience AG | Flüssige fungizid-haltige formulierungen |
-
2017
- 2017-11-03 JP JP2020522818A patent/JP7231624B2/ja active Active
- 2017-11-03 CA CA3079267A patent/CA3079267A1/en active Pending
- 2017-11-03 ES ES17930714T patent/ES2969257T3/es active Active
- 2017-11-03 WO PCT/CN2017/109248 patent/WO2019084896A1/en unknown
- 2017-11-03 US US16/638,418 patent/US11617366B2/en active Active
- 2017-11-03 EP EP17930714.5A patent/EP3703495B1/en active Active
- 2017-11-03 CN CN201780096148.1A patent/CN111246737B/zh active Active
- 2017-11-03 BR BR112020008115-9A patent/BR112020008115B1/pt active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5947268A (ja) * | 1982-09-10 | 1984-03-16 | Kashiwa Kagaku Kogyo:Kk | 可剥性フイルム形成エアゾ−ル製品 |
JPH03284651A (ja) * | 1990-03-30 | 1991-12-16 | Showa Denko Kk | 溶剤組成物 |
JPH11116994A (ja) * | 1997-10-17 | 1999-04-27 | Kyowa Yuka Kk | アルコキシ酪酸エステルからなる溶剤 |
JP2016535092A (ja) * | 2013-11-05 | 2016-11-10 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 農薬およびアミドを含んでなる組成物 |
Non-Patent Citations (1)
Title |
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JOURNAL OF ASTM INTERNATIONAL, vol. 6, no. 9, JPN6021036942, 2009, pages 69 - 81, ISSN: 0004840642 * |
Also Published As
Publication number | Publication date |
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EP3703495A1 (en) | 2020-09-09 |
WO2019084896A1 (en) | 2019-05-09 |
CN111246737A (zh) | 2020-06-05 |
BR112020008115B1 (pt) | 2023-04-11 |
US11617366B2 (en) | 2023-04-04 |
JP7231624B2 (ja) | 2023-03-01 |
BR112020008115A2 (pt) | 2020-11-03 |
ES2969257T3 (es) | 2024-05-17 |
EP3703495A4 (en) | 2021-06-16 |
CN111246737B (zh) | 2023-07-25 |
EP3703495B1 (en) | 2023-12-06 |
US20210378236A1 (en) | 2021-12-09 |
CA3079267A1 (en) | 2019-05-09 |
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