JP2021507043A - 湿気硬化型組成物 - Google Patents
湿気硬化型組成物 Download PDFInfo
- Publication number
- JP2021507043A JP2021507043A JP2020533623A JP2020533623A JP2021507043A JP 2021507043 A JP2021507043 A JP 2021507043A JP 2020533623 A JP2020533623 A JP 2020533623A JP 2020533623 A JP2020533623 A JP 2020533623A JP 2021507043 A JP2021507043 A JP 2021507043A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- group
- alkoxysilane
- compound containing
- silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 63
- 229920000642 polymer Polymers 0.000 claims abstract description 74
- 150000001875 compounds Chemical class 0.000 claims abstract description 54
- 238000000034 method Methods 0.000 claims abstract description 37
- 239000004814 polyurethane Substances 0.000 claims abstract description 23
- 229920002635 polyurethane Polymers 0.000 claims abstract description 22
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 17
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 16
- 150000002602 lanthanoids Chemical class 0.000 claims abstract description 16
- 239000003446 ligand Substances 0.000 claims abstract description 13
- 230000003197 catalytic effect Effects 0.000 claims abstract description 10
- CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 claims abstract description 7
- -1 perfluoro-2-propoxypropionyl Chemical group 0.000 claims description 43
- 239000003054 catalyst Substances 0.000 claims description 29
- 239000000565 sealant Substances 0.000 claims description 23
- 230000001070 adhesive effect Effects 0.000 claims description 22
- 239000000853 adhesive Substances 0.000 claims description 21
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 15
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 15
- 230000000052 comparative effect Effects 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 7
- 238000012360 testing method Methods 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 4
- WVVLURYIQCXPIV-UHFFFAOYSA-N 4,4,4-trifluoro-1-naphthalen-2-ylbutane-1,3-dione Chemical compound C1=CC=CC2=CC(C(=O)CC(=O)C(F)(F)F)=CC=C21 WVVLURYIQCXPIV-UHFFFAOYSA-N 0.000 claims description 3
- NICYPDXBQUERJQ-UHFFFAOYSA-N 1,1,1,2,2,3,3,7,7,8,8,9,9,9-tetradecafluorononane-4,6-dione Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(=O)CC(=O)C(F)(F)C(F)(F)C(F)(F)F NICYPDXBQUERJQ-UHFFFAOYSA-N 0.000 claims description 2
- UIRWNAVHKJFQQG-UHFFFAOYSA-N 1,1,1,3,3,5,5,5-octafluoropentane-2,4-dione Chemical compound FC(F)(F)C(=O)C(F)(F)C(=O)C(F)(F)F UIRWNAVHKJFQQG-UHFFFAOYSA-N 0.000 claims description 2
- KPPVCIIQKVMPKM-UHFFFAOYSA-N 1,1,1-trifluoro-3-(furan-2-yl)propan-2-one Chemical compound FC(F)(F)C(=O)CC1=CC=CO1 KPPVCIIQKVMPKM-UHFFFAOYSA-N 0.000 claims description 2
- SHXHPUAKLCCLDV-UHFFFAOYSA-N 1,1,1-trifluoropentane-2,4-dione Chemical compound CC(=O)CC(=O)C(F)(F)F SHXHPUAKLCCLDV-UHFFFAOYSA-N 0.000 claims description 2
- KFODMJZTQLZQBN-UHFFFAOYSA-N 1,3-dipyridin-3-ylpropane-1,3-dione Chemical compound C=1C=CN=CC=1C(=O)CC(=O)C1=CC=CN=C1 KFODMJZTQLZQBN-UHFFFAOYSA-N 0.000 claims description 2
- RYEKDXOACFEXKG-UHFFFAOYSA-N 1,3-dithiophen-2-ylpropane-1,3-dione Chemical compound C=1C=CSC=1C(=O)CC(=O)C1=CC=CS1 RYEKDXOACFEXKG-UHFFFAOYSA-N 0.000 claims description 2
- WYECURVXVYPVAT-UHFFFAOYSA-N 1-(4-bromophenyl)ethanone Chemical compound CC(=O)C1=CC=C(Br)C=C1 WYECURVXVYPVAT-UHFFFAOYSA-N 0.000 claims description 2
- VYZCZHFSLXQIKL-UHFFFAOYSA-N 1-(furan-2-yl)-3-(4-methylphenyl)propane-1,3-dione Chemical compound C1=CC(C)=CC=C1C(=O)CC(=O)C1=CC=CO1 VYZCZHFSLXQIKL-UHFFFAOYSA-N 0.000 claims description 2
- CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 claims description 2
- UZICKDIYFALSHI-UHFFFAOYSA-N 2,2,6,6-tetramethyloctane-3,5-dione Chemical compound CCC(C)(C)C(=O)CC(=O)C(C)(C)C UZICKDIYFALSHI-UHFFFAOYSA-N 0.000 claims description 2
- KLKRGCUPZROPPO-UHFFFAOYSA-N 2,2,6-trimethylheptane-3,5-dione Chemical compound CC(C)C(=O)CC(=O)C(C)(C)C KLKRGCUPZROPPO-UHFFFAOYSA-N 0.000 claims description 2
- CEGGECULKVTYMM-UHFFFAOYSA-N 2,6-dimethylheptane-3,5-dione Chemical compound CC(C)C(=O)CC(=O)C(C)C CEGGECULKVTYMM-UHFFFAOYSA-N 0.000 claims description 2
- YIWTXSVNRCWBAC-UHFFFAOYSA-N 3-phenylpentane-2,4-dione Chemical compound CC(=O)C(C(C)=O)C1=CC=CC=C1 YIWTXSVNRCWBAC-UHFFFAOYSA-N 0.000 claims description 2
- VVXLFFIFNVKFBD-UHFFFAOYSA-N 4,4,4-trifluoro-1-phenylbutane-1,3-dione Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CC=C1 VVXLFFIFNVKFBD-UHFFFAOYSA-N 0.000 claims description 2
- SQNZLBOJCWQLGQ-UHFFFAOYSA-N 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyloctane-3,5-dione Chemical compound CC(C)(C)C(=O)CC(=O)C(F)(F)C(F)(F)C(F)(F)F SQNZLBOJCWQLGQ-UHFFFAOYSA-N 0.000 claims description 2
- IGMOYJSFRIASIE-UHFFFAOYSA-N 6-Methylheptan-2,4-dione Chemical compound CC(C)CC(=O)CC(C)=O IGMOYJSFRIASIE-UHFFFAOYSA-N 0.000 claims description 2
- 230000005595 deprotonation Effects 0.000 claims description 2
- 238000010537 deprotonation reaction Methods 0.000 claims description 2
- QAMFBRUWYYMMGJ-UHFFFAOYSA-N hexafluoroacetylacetone Chemical compound FC(F)(F)C(=O)CC(=O)C(F)(F)F QAMFBRUWYYMMGJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000005259 measurement Methods 0.000 claims description 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 2
- 125000004044 trifluoroacetyl group Chemical group FC(C(=O)*)(F)F 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- BVPKYBMUQDZTJH-UHFFFAOYSA-N 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dione Chemical compound CC(C)(C)C(=O)CC(=O)C(F)(F)F BVPKYBMUQDZTJH-UHFFFAOYSA-N 0.000 claims 2
- GYQLGOFXHBMNRM-UHFFFAOYSA-N 1,1,1,2,2,6,6,7,7,7-decafluoroheptane-3,5-dione Chemical compound FC(F)(F)C(F)(F)C(=O)CC(=O)C(F)(F)C(F)(F)F GYQLGOFXHBMNRM-UHFFFAOYSA-N 0.000 claims 1
- KEBPOWLGOOTMPK-UHFFFAOYSA-N 2,2,7-trimethyloctane-3,5-dione Chemical compound CC(C)CC(=O)CC(=O)C(C)(C)C KEBPOWLGOOTMPK-UHFFFAOYSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 42
- 229910000077 silane Inorganic materials 0.000 description 35
- 229920001002 functional polymer Polymers 0.000 description 26
- 229920000570 polyether Polymers 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 17
- 239000004721 Polyphenylene oxide Substances 0.000 description 14
- 125000004432 carbon atom Chemical group C* 0.000 description 14
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 11
- 125000005442 diisocyanate group Chemical group 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 150000003254 radicals Chemical class 0.000 description 9
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- 238000009472 formulation Methods 0.000 description 8
- 229920005862 polyol Polymers 0.000 description 8
- 150000003077 polyols Chemical class 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000002318 adhesion promoter Substances 0.000 description 5
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- 229920000573 polyethylene Polymers 0.000 description 5
- 150000004756 silanes Chemical class 0.000 description 5
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 4
- 125000005498 phthalate group Chemical class 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- BLBJEZPJTKVTAB-UHFFFAOYSA-N [Yb+3].CC(=O)CC(C)=O Chemical compound [Yb+3].CC(=O)CC(C)=O BLBJEZPJTKVTAB-UHFFFAOYSA-N 0.000 description 3
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- TXBBUSUXYMIVOS-UHFFFAOYSA-N thenoyltrifluoroacetone Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CS1 TXBBUSUXYMIVOS-UHFFFAOYSA-N 0.000 description 1
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- VPRMDTDSWWDQHO-UHFFFAOYSA-N tributoxy(3-isocyanatopropyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCCN=C=O VPRMDTDSWWDQHO-UHFFFAOYSA-N 0.000 description 1
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- FTWFPXOXERUJAH-UHFFFAOYSA-N triethoxy-(4-isocyanato-3-methylbutyl)silane Chemical compound N(=C=O)CC(CC[Si](OCC)(OCC)OCC)C FTWFPXOXERUJAH-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
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- XKCQNWLQCXDVOP-UHFFFAOYSA-N tris(2-chloropropan-2-yl) phosphate Chemical compound CC(C)(Cl)OP(=O)(OC(C)(C)Cl)OC(C)(C)Cl XKCQNWLQCXDVOP-UHFFFAOYSA-N 0.000 description 1
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
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- C—CHEMISTRY; METALLURGY
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Abstract
Description
市販のシラン末端ポリウレタンプレポリマーの製造は、NCO基とツェレビチノフ活性H原子との反応の触媒作用を含む。通常、ジブチルスズジラウレート(DBTL)がこれに使用される。ただし、DBTLの毒物学的特性により、代替の触媒が必要である。
R1は、1〜6個の炭素原子を有するアルキレンラジカルを表し、
R2は、メチルラジカルまたはエチルラジカルを表し、
mは、0または1または2を表す。
Xは、OまたはSまたはNR5を表し、式中、R5は、水素原子、または環状比率(cyclic proportion)を含んでもよく、アルコキシシリル基もしくは1つ以上のエーテル基もしくはカルボン酸エステル基を含んでもよい、1〜20個の炭素原子を有する炭化水素ラジカルを表し、
R3は、環状および/または芳香族比率(aromatic proportion)を含んでもよく、1つ以上のヘテロ原子を含んでもよい、1〜18個の炭素原子を有する二価の炭化水素ラジカルを表し、
R4は、エーテル基を含んでもよい、1〜5個の炭素原子を有するアルキルラジカルを表し、
nは、0または1または2を表す。
ここで、このラジカルは、Xがシクロヘキシル環に直接結合され、YがOまたはNR7を表し、R6およびR7が互いにそれぞれ独立して、エーテル酸素またはチオエーテル硫黄もしくは第三級アミン窒素の形でヘテロ原子を含み得るか、Y(またはN)とともに環、特にモルホリン環を形成し得る、1〜18個の炭素原子を有する一価の炭化水素ラジカルを表すように構成される。
・アリル含有ポリエーテルとヒドロシランとの、特にジイソシアネートによる鎖延長を伴ってもよい反応から得られるシラン含有ポリエーテル;
・アルキレンオキシドとエポキシシランとの、特にジイソシアネートによる鎖延長を伴ってもよい共重合から得られるシラン含有ポリエーテル;
・ポリエーテルポリオールとイソシアナトシランとの、ジイソシアネートによる鎖延長を伴ってもよい反応から得られるシラン含有ポリエーテル;および
・イソシアネート含有ウレタンポリエーテルとアミノシランまたはヒドロキシシランまたはメルカプトシランとの反応から得られるシラン含有ポリエーテルからなる群から選択される。
R8は、メチルラジカルまたはエチルラジカルを表し、
oは、0または1または2を表す。
R9は、メチルラジカルまたはエチルラジカルを表し、
pは、0または1または2を表し、
好ましくは0を表す。
a)10重量%〜50重量%のアルコキシシラン含有ポリマー;
b)イッテルビウム(III)アセチルアセトネート0.0001重量%〜0.1重量%;
c)スズまたはスズイオンも有機スズ化合物も含有しない化合物から選択される、シラン官能性ポリマーの架橋のための、0.001重量%〜3重量%の少なくとも1つの触媒;
d)助剤および添加物質。
・無機および有機フィラー、特に、脂肪酸、特にステアリン酸によって被覆されていてもよい天然、粉砕もしくは沈殿炭酸カルシウム、重晶石、タルク、石英粉、石英砂、ドロマイト、珪灰石、カオリン、焼成カオリン、雲母、モレキュラーシーブ、酸化アルミニウム、水酸化アルミニウム、水酸化マグネシウム、熱分解プロセスからの高分散シリカを含むシリカ、工業的に製造されたカーボンブラック、グラファイト、金属粉末、例えば、アルミニウム、銅、鉄、銀もしくは鋼、PVC粉末または無機もしくは有機材料の中空球。
・フィロシリケート、例えばベントナイト、ヒマシ油の誘導体、水素化ヒマシ油、ポリアミド、ポリウレタン、尿素化合物、焼成シリカ、セルロースエーテル、または疎水的に改質されたポリオキシエチレン。
・エチレン酢酸ビニルコポリマー(EVA)またはアタクチックポリ−α−オレフィン(APAO)。
(ショアA硬度(DIN 53505):比較ポリマーの90%以下(好ましくは85%以下、さらに好ましくは80%以下);
破断点伸びのパーセンテージ値(DIN EN 53504、引張速度:200mm/分、S2試験片):比較ポリマーのパーセンテージ値の101%以上(好ましくは105%以上、さらに好ましくは110%以上);
割線モジュラス(EN ISO 8339、100%伸び):比較ポリマーの90%以下(好ましくは85%以下、さらに好ましくは80%以下);)
比較ポリマーは、硬化したポリマーと同じ方法で製造したが、本明細書中上記に記載の方法の触媒成分中にランタノイドと少なくとも1つのβ−ジケトネート配位子との錯体の代わりに、同じモル量のジブチルスズジラウレートを用いて製造した。
・ガラス、ガラスセラミック、スクリーン印刷されたセラミック、コンクリート、モルタル、レンガ、タイル、石膏または天然石、例えば、花崗岩または大理石;
・金属もしくは合金、例えば、アルミニウム、鉄、鋼もしくは非鉄金属、または表面被覆された金属もしくは合金、例えば、亜鉛めっき金属もしくはクロムめっき金属;
・革、布、紙、木、樹脂、例えばフェノール樹脂、メラミン樹脂もしくはエポキシ樹脂により接合された木質系材料、樹脂−布複合材、または追加のいわゆるポリマー複合材;
・プラスチック、特に非可塑化もしくは可塑化PVC、ABS、ポリカーボネート(PC)、ポリアミド(PA)、ポリエステル、PMMA、エポキシ樹脂、PUR、POM、PO、PE、PP、EPMまたはEPDM(ここで、プラスチックは、プラズマ、コロナまたは火炎処理を使用して表面処理されていてもよい);
・繊維強化プラスチック、例えば、炭素繊維強化プラスチック(CFRP)、ガラス繊維強化プラスチック(GFRP)またはシート成形コンパウンド(SMC);
・被覆基材、例えば、粉末により被覆された金属または合金;
・塗料またはワニス、特に自動車用トップコート。
本発明は、実施例を参照して以下にさらに詳細に説明されるが、それらに限定されない。
ショア硬度、破断点伸び、引張強度、100%伸び時の引張応力および弾性の決定
カートリッジ内での製造から測定して7日間保存した後、ドクターブレードを使用してポリエチレンフィルムに湿気硬化性組成物を塗布して、2mmの均一な層厚を有する膜を得、23℃および相対湿度50%で14日間硬化させ、7日後に膜をフィルムから取り外し、裏返した。次に、得られた膜の特性を以下の方法により決定した。
[実施例1−1]
(発明)
OH価13のプロピレングリコール(Covestro Germany AG;Leverkusen DEのAcclaim(登録商標)Polyol 8200 N)1174.0gを、Mesamoll(登録商標)(Lanxess AG,Leverkusen,DE)147.2 gおよびイソホロンジイソシアネート63.5gと、60℃で80ppmのイッテルビウム(III)アセチルアセトネートを加え理論上のNCO含有量0.84%が達成されるまで予備重合した。次いで、ジエチルN−(3−トリメトキシシリルプロピル)アスパルテート(EP−A 596360、例5に従って製造)102.1gを迅速に滴下し、イソシアネートのバンドがIRスペクトルで見えなくなるまで混合物を撹拌した。アルコキシシラン末端基を含む得られたポリウレタンプレポリマーは、21100mPasの粘度を有した。
(比較例)
80ppmのイッテルビウム(III)アセチルアセトネートの代わりに40ppmのジブチルスズジラウレートを使用したことを除いて、実施例1に記載の手順を繰り返した。アルコキシシラン末端基を含む得られたポリウレタンプレポリマーは、23500mPasの粘度を有した。
(発明)
OH価4.9のポリプロピレングリコール(EP−A 0654302の例7に従って製造した)1200.0gを80℃で6時間真空乾燥した。60℃に冷却した後、3−イソシアナトプロピルトリメトキシシラン(Geniosil(登録商標)GF40、Wacker AG,Burghausen)24.36gおよび100ppmのイッテルビウム(III)アセチルアセトネートを加え、理論上のNCO含有量0.05%が達成されるまで反応を予備重合した。次いで、メタノール0.4gを加えて、過剰なNCO基を吸収させた。イソシアネートのバンドがIRスペクトルで見えなくなるまで、混合物を撹拌した。アルコキシシラン末端基を含む得られたポリウレタンプレポリマーは、69400mPas(23℃)の粘度を有した。
(比較例)
100ppmのイッテルビウム(III)アセチルアセトネートの代わりに50ppmのジブチルスズジラウレートを使用したことを除いて、実施例3に記載の手順を繰り返した。アルコキシシラン末端基を含む得られたポリウレタンプレポリマーは、62200mPasの粘度を有した。
(比較例)
100ppmのイッテルビウム(III)アセチルアセトネートの代わりに100ppmのK−Kat XK−614(スズを含まない、亜鉛ベースのウレタン化触媒、King Industries)を使用したことを除いて、実施例3に記載の手順を繰り返した。アルコキシシラン末端基を含む得られたポリウレタンプレポリマーは、70300mPasの粘度を有した。
以下の手順に従って、湿気硬化性組成物を製造した:バタフライスターラー(200回転/分)およびディゾルバーディスク(2500回転/分)を備えた実験室ディゾルバー内で、静的真空下および冷却下で15分間かけて、接着促進剤を除いて表1に列挙された全成分を分散させた。ここで、静的真空とは、装置が200mbar(動的真空)の圧力まで排気され、次いで真空ポンプへの接続が切断されることを意味すると理解されるべきである。製造全体を通じて65℃を超えないように冷却を選択した。次いで、接着促進剤を加え、混合物を静的真空下でさらに10分間分散させた。
Claims (15)
- 触媒成分の存在下で、
少なくとも1つのNCO基を含む化合物と、
少なくとも1つのツェレビチノフ活性H原子を含む化合物とを反応させて
(少なくとも1つのNCO基を含む前記化合物および/または少なくとも1つのツェレビチノフ活性H原子を含む前記化合物は、少なくとも1つのアルコキシシラン基を含む)、
アルコキシシラン含有ポリウレタンを得る
工程を含む、アルコキシシラン含有ポリウレタンの製造方法において、
前記触媒成分が、ランタノイドと少なくとも1つのβ−ジケトネート配位子との錯体を含有し、
前記触媒成分が有機スズ化合物を含まない
ことを特徴とする製造方法。 - 前記ランタノイドがイッテルビウム(III)であることを特徴とする、請求項1に記載の方法。
- 前記β−ジケトネート配位子が、hacac(アセチルアセトン)、hacac−F7(パーフルオロアセチルアセトン)、hbfa(ベンゾイル−2−フラノイルメタン)、hbpp(1,3−ビス(3−ピリジル)1,3−プロパンジオン)、Hbtfac(ベンゾイルトリフルオロアセトン)、hbzac(ベンゾイルアセトン)、hdbbm(ジ(4−ブロモ)ベンゾイルメタン)、hdcm(d,d−ジカンホリルメタン)、hdmbm(4,4’−ジメトキシジベンゾイルメタン)、hdmh(2,6−ジメチル−3,5−ヘプタンジオン)、hdnm(ジナフトイルメタン)、hdpm(ジピバロイルメタン)、hdppm(ジ(パーフルオロ−2−プロポキシプロピオニル)メタン)、hdtp(1,3−ジ(2−チエニル)−1,3−プロパンジオン)、hfacam(3−(トリフルオロアセチル)−d−カンファー)、hfdh(6,6,6−トリフルオロ−2,2−ジメチル−3,5−ヘキサンジオン)、hfhd(1,1,1,2,2,6,6,7,7,7−デカフルオロ−3,5−ヘプタンジオン)、hfod(6,6,7,7,8,8,8−ヘプタフルオロ−2,2−ジメチル−3,5−オクタンジオン)、hftac(2−フリルトリフルオロアセトン)、hhfac(ヘキサフルオロアセチルアセトン)、hhfbc(3−(ヘプタフルオロブチリル)−d−カンファー)、hhfth(4,4,5,5,6,6,6−ヘプタフルオロ−1−(2−チエニル)−1,3−ヘキサンジオン)、hmfa(4−メチルベンゾイル−2−フラノイルメタン)、hmhd(6−メチル−2,4−ヘプタンジオン)、hntac(2−ナフトイルトリフルオロアセトン)、hpop(3−(5−フェニル−1,3,4−オキサジアゾール−2−イル)−2,4−ペンタンジオン)、hppa(3−フェニル−2,4−ペンタンジオン)、hpta(=htpm)(ピバロイルトリフルオロアセトン)、hptp(1−フェニル−3−(2−チエニル)−1,3−プロパンジオン)、H(t−cam)(3−(tert−ブチルヒドロキシメチレン)−d−カンファー)、htfac(トリフルオロアセチルアセトン)、htfn(1,1,1,2,2,3,3,7,7,8,8,9,9,9−テトラデカフルオロ−4,6−ノナンジオン)、hthd(=hdpm、htmhd)(2,2,6,6−テトラメチル−3,5−ヘプタンジオン)、htnb(4,4,4−トリフルオロ−1−(2−ナフチル)−1,3−ブタンジオン)、htmod(2,2,6,6−テトラメチル−3,5−オクタンジオン)、htrimh(2,2,6−トリメチル−3,5−ヘプタンジオン)、htod(2,2,7−トリメチル−3,5−オクタンジオン)、htta(2−テノイルトリフルオロアセトン)またはそれらの任意の所望の混合物の脱プロトン化によって得ることができることを特徴とする、請求項1または2に記載の方法。
- ランタノイドと少なくとも1つのβ−ジケトネート配位子との前記錯体がYb(acac)3であることを特徴とする、請求項1から3のいずれか一項に記載の方法。
- 少なくとも1つのNCO基を含む前記化合物が少なくとも1つのアルコキシシラン基を含み、少なくとも1つのツェレビチノフ活性H原子を含む前記化合物がアルコキシシラン基を含まないことを特徴とする、請求項1から4のいずれか一項に記載の方法。
- 少なくとも1つのNCO基を含む前記化合物がアルコキシシラン基を含まず、少なくとも1つのツェレビチノフ活性H原子を含む前記化合物が少なくともアルコキシシラン基を含むことを特徴とする、請求項1から4のいずれか一項に記載の方法。
- 少なくとも1つのツェレビチノフ活性H原子を含む前記化合物が、少なくとも1つの第一級または第二級アミノ基を含むことを特徴とする、請求項6に記載の方法。
- ランタノイドと少なくとも1つのβ−ジケトネート配位子との錯体を含有し、有機スズ化合物を含まないことを特徴とするアルコキシシラン含有ポリマー。
- 請求項1から7のいずれか一項に記載の方法によって得ることができるポリウレタンであることを特徴とする、請求項8に記載のポリマー。
- 請求項8または9に記載のポリマーとシロキサン縮合触媒とを接触させる工程を含むことを特徴とする、硬化性ポリマーの製造方法。
- 前記ポリマーをさらに水と接触させることを特徴とする、請求項10に記載の方法。
- 請求項10または11に記載の方法によって得ることができることを特徴とする硬化性ポリマー。
- 請求項12に記載の硬化性ポリマーを硬化させることによって得ることができることを特徴とする硬化したポリマー。
- 前記硬化したポリマーが、比較ポリマーと比較して以下の特性のうちの少なくとも1つを有し、それぞれのサンプルが、測定前に23℃および相対湿度50%で14日間保存されており:
(ショアA硬度(DIN 53505):前記比較ポリマーの90%以下;
破断点伸びのパーセンテージ値(DIN EN 53504、引張速度:200mm/分、S2試験片):前記比較ポリマーのパーセンテージ値の101%以上;
割線モジュラス(EN ISO 8339、100%伸び):前記比較ポリマーの90%以下;)
前記比較ポリマーが、前記硬化したポリマーと同じ方法で製造されたが、請求項1から7のいずれか一項に記載の方法の前記触媒成分中の前記ランタノイドと少なくとも1つのβ−ジケトネート配位子との前記錯体の代わりに、同じモル量のジブチルスズジラウレートを用いて製造されたことを特徴とする、請求項13に記載の硬化したポリマー。 - シーラント、接着剤またはコーティング材料としての、請求項12に記載の硬化性ポリマーの使用および/または請求項13または14に記載の硬化したポリマーの使用。
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0931151A (ja) * | 1995-07-20 | 1997-02-04 | Rogers Corp | 金属アセチルアセトネートとアセチルアセトンとを含む触媒システムを利用したポリウレタン製造方法、及びその製品 |
JP2004339511A (ja) * | 2003-05-12 | 2004-12-02 | Bayer Materialscience Ag | 脂肪族オリゴカーボネートポリオールの調製用触媒としてのイッテルビウム(iii)アセチルアセトネート |
DE102004012876A1 (de) * | 2004-03-16 | 2005-10-06 | Bayer Materialscience Ag | Katalysatoren für die NCO/OH-Reaktion |
JP2008056849A (ja) * | 2006-09-01 | 2008-03-13 | Tosoh Corp | ポリウレタン樹脂製造用触媒組成物及びポリウレタン樹脂の製造方法 |
US20110034627A1 (en) * | 2008-04-25 | 2011-02-10 | Henkel Ag & Co. Kgaa | Curable compositions containing silylated polyurethanes |
JP2013513678A (ja) * | 2009-12-09 | 2013-04-22 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | ポリウレタンプレポリマー |
JP2015506917A (ja) * | 2011-12-12 | 2015-03-05 | ジーカ テクノロジー アクチェンゲゼルシャフト | ポリウレタン組成物のための触媒としての金属錯体化合物 |
JP2015513319A (ja) * | 2011-12-15 | 2015-05-07 | モーメンティブ・パフォーマンス・マテリアルズ・インク | 湿気硬化性オルガノポリシロキサン組成物 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3971751A (en) | 1975-06-09 | 1976-07-27 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Vulcanizable silylether terminated polymer |
DE4237468A1 (de) | 1992-11-06 | 1994-05-11 | Bayer Ag | Alkoxysilan- und Aminogruppen aufweisende Verbindungen |
US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
DE69821722T2 (de) | 1997-04-21 | 2004-12-02 | Asahi Glass Co., Ltd. | Bei raumtemperatur härtende zusammensetzungen |
DE102007023197A1 (de) * | 2007-05-22 | 2008-11-27 | Bayer Materialscience Ag | Polyester-Prepolymere |
FR2925515A1 (fr) * | 2007-12-20 | 2009-06-26 | Bluestar Silicones France Soc | Composition organopolysiloxanique vulcanisable a temperature ambiante en elastomere et nouveaux catalyseurs de polycondensation d'organopolysiloxanes. |
DE102009057584A1 (de) * | 2009-12-09 | 2011-06-16 | Bayer Materialscience Ag | Polyurethane-Prepolymere |
DE102009057597A1 (de) | 2009-12-09 | 2011-06-16 | Bayer Materialscience Ag | Polyrethan-Prepolymere |
CN104995235A (zh) | 2012-05-02 | 2015-10-21 | 莫门蒂夫性能材料股份有限公司 | 可湿固化的有机聚硅氧烷组合物 |
EP2813529A1 (de) * | 2013-06-11 | 2014-12-17 | Sika Technology AG | Härtbare Zusammensetzung auf Basis von Silangruppen-haltigen Polymeren und einem Zinkkatalysator |
US9156981B2 (en) * | 2013-07-24 | 2015-10-13 | Momentive Performance Materials Inc. | Moisture curable compositions with enhanced elongation and tear strength properties |
EP2952533A1 (de) | 2014-06-04 | 2015-12-09 | Sika Technology AG | Zinn- und Phthalat-freier Dichtstoff auf Basis von silanterminierten Polymeren |
-
2017
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Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0931151A (ja) * | 1995-07-20 | 1997-02-04 | Rogers Corp | 金属アセチルアセトネートとアセチルアセトンとを含む触媒システムを利用したポリウレタン製造方法、及びその製品 |
JP2004339511A (ja) * | 2003-05-12 | 2004-12-02 | Bayer Materialscience Ag | 脂肪族オリゴカーボネートポリオールの調製用触媒としてのイッテルビウム(iii)アセチルアセトネート |
DE102004012876A1 (de) * | 2004-03-16 | 2005-10-06 | Bayer Materialscience Ag | Katalysatoren für die NCO/OH-Reaktion |
JP2008056849A (ja) * | 2006-09-01 | 2008-03-13 | Tosoh Corp | ポリウレタン樹脂製造用触媒組成物及びポリウレタン樹脂の製造方法 |
US20110034627A1 (en) * | 2008-04-25 | 2011-02-10 | Henkel Ag & Co. Kgaa | Curable compositions containing silylated polyurethanes |
JP2013513678A (ja) * | 2009-12-09 | 2013-04-22 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | ポリウレタンプレポリマー |
JP2015506917A (ja) * | 2011-12-12 | 2015-03-05 | ジーカ テクノロジー アクチェンゲゼルシャフト | ポリウレタン組成物のための触媒としての金属錯体化合物 |
JP2015513319A (ja) * | 2011-12-15 | 2015-05-07 | モーメンティブ・パフォーマンス・マテリアルズ・インク | 湿気硬化性オルガノポリシロキサン組成物 |
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