JP2021050420A - パラジウム系合金 - Google Patents
パラジウム系合金 Download PDFInfo
- Publication number
- JP2021050420A JP2021050420A JP2020218662A JP2020218662A JP2021050420A JP 2021050420 A JP2021050420 A JP 2021050420A JP 2020218662 A JP2020218662 A JP 2020218662A JP 2020218662 A JP2020218662 A JP 2020218662A JP 2021050420 A JP2021050420 A JP 2021050420A
- Authority
- JP
- Japan
- Prior art keywords
- palladium
- alloy
- rhodium
- based alloy
- platinum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 64
- 239000000956 alloy Substances 0.000 title claims abstract description 64
- 229910052763 palladium Inorganic materials 0.000 title claims abstract description 37
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 30
- 239000010948 rhodium Substances 0.000 claims abstract description 30
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 22
- 229910052709 silver Inorganic materials 0.000 claims abstract description 19
- 239000004332 silver Substances 0.000 claims abstract description 19
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 14
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 13
- 239000010936 titanium Substances 0.000 claims abstract description 13
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 12
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 12
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 9
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052702 rhenium Inorganic materials 0.000 claims abstract description 8
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims 3
- 238000002844 melting Methods 0.000 abstract description 6
- 230000008018 melting Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 229910001252 Pd alloy Inorganic materials 0.000 description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 238000005275 alloying Methods 0.000 description 7
- 229910001020 Au alloy Inorganic materials 0.000 description 5
- 238000000137 annealing Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 239000003353 gold alloy Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229910001260 Pt alloy Inorganic materials 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- -1 Platinum Metals Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 229910000923 precious metal alloy Inorganic materials 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- BBKFSSMUWOMYPI-UHFFFAOYSA-N gold palladium Chemical compound [Pd].[Au] BBKFSSMUWOMYPI-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001330 spinodal decomposition reaction Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/04—Alloys based on a platinum group metal
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C27/00—Making jewellery or other personal adornments
- A44C27/001—Materials for manufacturing jewellery
- A44C27/002—Metallic materials
- A44C27/003—Metallic alloys
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Adornments (AREA)
- Display Devices Of Pinball Game Machines (AREA)
Abstract
Description
焼きなましは、20〜30分間継続し、N2およびH2からなる還元雰囲気中、1000℃で行われる。各焼きなまし間の冷却は、水焼入れにより行う。
光源:D65
傾斜:10°
測定:SCI+SCE(正反射光含む+正反射光除去)
UV:100%
焦点距離:4mm
較正:黒体および白体
Claims (11)
- パラジウム系合金であって、重量で表して、
50%以上のパラジウム、
45%以上のロジウム、
量xの銀、ただし0%<x≦5%、
量Rの、イリジウム、ルテニウム、プラチナ、チタン、ジルコニウム、およびレニウムの中から選択される少なくとも1種の元素、ただし0%≦R<5%、及び
不可避的不純物
からなり、各元素の合計が100%である、パラジウム系合金。 - xは、2%以下であることを特徴とする、請求項1に記載のパラジウム系合金。
- 重量で表して、
50%以上のパラジウム、
47%以上のロジウム;
量xの銀、ただし0%<x≦2%、
量Rの、イリジウム、ルテニウム、プラチナ、チタン、ジルコニウム、およびレニウムの中から選択される少なくとも1種の元素、ただし0%≦R<3%、及び
不可避的不純物
からなり、各元素の合計が100%である、請求項1または2に記載のパラジウム系合金。 - Rは、1%以下であることを特徴とする、請求項1から3のいずれか1項に記載のパラジウム系合金。
- Rは、0.5%以下であることを特徴とする、請求項4に記載のパラジウム系合金。
- Rは、0.1%以下であることを特徴とする、請求項4に記載のパラジウム系合金。
- Rは、0であることを特徴とする、請求項1から6のいずれか1項に記載のパラジウム系合金。
- 請求項1から7のいずれか1項に記載のパラジウム系合金製の部品を少なくとも1つ含む、時計または宝飾品。
- 時計または宝飾品における、請求項1から7のいずれか1項に記載のパラジウム系合金の使用。
- 重量で、50%のパラジウム、45%のロジウム、5%の銀からなる請求項1に記載のパラジウム系合金。
- 重量で、50%のパラジウム、45%のロジウム、量xの銀、ただし0<x≦4%、量Rの、イリジウム、ルテニウム、プラチナ、チタン、ジルコニウム、およびレニウムの中から選択される少なくとも1種の元素、ただし1%≦R<5%、及び
不可避的不純物
からなり、各元素の合計が100%である、請求項1に記載のパラジウム系合金。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14193495.0A EP3020835B1 (fr) | 2014-11-17 | 2014-11-17 | Pièce d'horlogerie, de bijouterie ou de joaillerie comportant un composant réalisé dans un alliage à base de palladium |
EP14193495.0 | 2014-11-17 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017234867A Division JP2018090909A (ja) | 2014-11-17 | 2017-12-07 | パラジウム系合金 |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2021050420A true JP2021050420A (ja) | 2021-04-01 |
Family
ID=51900319
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015215461A Pending JP2016098437A (ja) | 2014-11-17 | 2015-11-02 | パラジウム系合金 |
JP2017234867A Pending JP2018090909A (ja) | 2014-11-17 | 2017-12-07 | パラジウム系合金 |
JP2020218662A Pending JP2021050420A (ja) | 2014-11-17 | 2020-12-28 | パラジウム系合金 |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015215461A Pending JP2016098437A (ja) | 2014-11-17 | 2015-11-02 | パラジウム系合金 |
JP2017234867A Pending JP2018090909A (ja) | 2014-11-17 | 2017-12-07 | パラジウム系合金 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20160138134A1 (ja) |
EP (1) | EP3020835B1 (ja) |
JP (3) | JP2016098437A (ja) |
CN (2) | CN108728684B (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3020835B1 (fr) * | 2014-11-17 | 2021-04-21 | Omega SA | Pièce d'horlogerie, de bijouterie ou de joaillerie comportant un composant réalisé dans un alliage à base de palladium |
EP3339455B1 (fr) * | 2016-12-20 | 2020-02-05 | Montres Breguet S.A. | Alliage d'or gris |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1086442B (de) * | 1957-03-29 | 1960-08-04 | Heraeus Gmbh W C | Verwendung einer Palladium-Legierung als Werkstoff fuer Spinnduesen |
GB1128136A (en) * | 1966-05-04 | 1968-09-25 | Tsurumi Soda Kk | Improvements in or relating to anodes for electrolytic cells |
JP2004059362A (ja) * | 2002-07-26 | 2004-02-26 | Tanaka Kikinzoku Kogyo Kk | ルツボ |
JP2005076085A (ja) * | 2003-09-01 | 2005-03-24 | Citizen Watch Co Ltd | 複色被膜を有する装飾品およびその製造方法 |
JP2016098437A (ja) * | 2014-11-17 | 2016-05-30 | オメガ・エス アー | パラジウム系合金 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2129721A (en) * | 1934-12-15 | 1938-09-13 | Int Nickel Co | Palladium-silver-platinum alloys |
GB556431A (en) * | 1941-02-11 | 1943-10-05 | Baker & Co | Improvements in or relating to electrical resistance wire |
US2303402A (en) * | 1941-07-09 | 1942-12-01 | Baker & Co Inc | Alloy |
DE1080785B (de) * | 1956-03-01 | 1960-04-28 | Heraeus Gmbh W C | Verwendung einer Palladium-Rhodium-Legierung als Werkstoff fuer elektrische Kontakte und Potentiometer |
FR2528285A1 (fr) * | 1982-06-09 | 1983-12-16 | Chugai Electric Ind Co Ltd | Articles de bijouterie et materiaux pour leur fabrication |
SE8206158L (sv) * | 1982-10-29 | 1984-04-30 | Hans G Wahlbeck | Forfarande och anordning for framstellning av allergifria edelmetallforemal |
US7494619B2 (en) * | 2003-12-23 | 2009-02-24 | General Electric Company | High temperature alloys, and articles made and repaired therewith |
ZA200703477B (en) * | 2004-09-02 | 2008-08-27 | Univ Cape Town | Hardening of metal alloys |
US7740720B2 (en) * | 2005-09-07 | 2010-06-22 | Fogel Kenneth D | Platinum-palladium alloy |
EP1875827A4 (en) * | 2006-03-01 | 2014-04-09 | Nakakura Sekikazu | PRECIOUS METAL JEWELRY AND METHOD FOR MANUFACTURING THE SAME |
JP4848912B2 (ja) * | 2006-09-28 | 2011-12-28 | 富士ゼロックス株式会社 | 真偽判定装置、真偽判定方法、真偽判定プログラム、非晶質合金部材の作製方法 |
EP2251444A1 (fr) | 2009-05-06 | 2010-11-17 | Rolex Sa | Alliage d'or gris sans nickel et sans cuivre |
EP2400354A1 (fr) * | 2010-06-22 | 2011-12-28 | The Swatch Group Research and Development Ltd. | Pieds de cadran de pièce d'horlogerie |
EP2420583B1 (de) | 2010-07-12 | 2016-11-02 | C. Hafner GmbH + Co. KG | Schmuckstück aus einer ideal-weiße, anlaufbeständigen Edelmetall-Legierung |
SE536911C2 (sv) * | 2011-02-09 | 2014-10-28 | Impact Coatings Ab | Material för att åstadkomma ett elektriskt ledande kontaktskikt, ett kontaktelement med sådant skikt, metod för att åstadkomma kontaktelementet, samt användning av materialet |
DK2546371T3 (en) | 2011-07-12 | 2017-04-03 | Cendres + Métaux Sa | 18 carat gray gold |
-
2014
- 2014-11-17 EP EP14193495.0A patent/EP3020835B1/fr active Active
-
2015
- 2015-10-26 US US14/922,264 patent/US20160138134A1/en active Pending
- 2015-11-02 JP JP2015215461A patent/JP2016098437A/ja active Pending
- 2015-11-16 CN CN201810787163.7A patent/CN108728684B/zh active Active
- 2015-11-16 CN CN201510783813.7A patent/CN105603241B/zh active Active
-
2017
- 2017-12-07 JP JP2017234867A patent/JP2018090909A/ja active Pending
-
2020
- 2020-12-28 JP JP2020218662A patent/JP2021050420A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1086442B (de) * | 1957-03-29 | 1960-08-04 | Heraeus Gmbh W C | Verwendung einer Palladium-Legierung als Werkstoff fuer Spinnduesen |
GB1128136A (en) * | 1966-05-04 | 1968-09-25 | Tsurumi Soda Kk | Improvements in or relating to anodes for electrolytic cells |
JP2004059362A (ja) * | 2002-07-26 | 2004-02-26 | Tanaka Kikinzoku Kogyo Kk | ルツボ |
JP2005076085A (ja) * | 2003-09-01 | 2005-03-24 | Citizen Watch Co Ltd | 複色被膜を有する装飾品およびその製造方法 |
JP2016098437A (ja) * | 2014-11-17 | 2016-05-30 | オメガ・エス アー | パラジウム系合金 |
JP2018090909A (ja) * | 2014-11-17 | 2018-06-14 | オメガ・エス アー | パラジウム系合金 |
Non-Patent Citations (1)
Title |
---|
THADDEUS B. MASSALSKI, "BINARY ALLOY PHASE DIAGRAMS, 2ND EDITION", vol. Vol.3,p.3038, JPN6016041740, December 1990 (1990-12-01), US, ISSN: 0004774022 * |
Also Published As
Publication number | Publication date |
---|---|
JP2018090909A (ja) | 2018-06-14 |
JP2016098437A (ja) | 2016-05-30 |
CN108728684B (zh) | 2020-08-04 |
CN105603241B (zh) | 2018-08-10 |
CN105603241A (zh) | 2016-05-25 |
CN108728684A (zh) | 2018-11-02 |
US20160138134A1 (en) | 2016-05-19 |
EP3020835B1 (fr) | 2021-04-21 |
EP3020835A1 (fr) | 2016-05-18 |
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