JP2020509925A - 合成ガスをアルコール類に転化するための触媒 - Google Patents

合成ガスをアルコール類に転化するための触媒 Download PDF

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JP2020509925A
JP2020509925A JP2019544884A JP2019544884A JP2020509925A JP 2020509925 A JP2020509925 A JP 2020509925A JP 2019544884 A JP2019544884 A JP 2019544884A JP 2019544884 A JP2019544884 A JP 2019544884A JP 2020509925 A JP2020509925 A JP 2020509925A
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catalyst
range
porous oxide
source
weight
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JP2020509925A5 (enExample
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ヤンケ,クリスティアン
シュヴァブ,エッケハルト
アー シュンク,シュテファン
アー シュンク,シュテファン
イェヴトヴィキ,イヴァナ
カイザー,ハリー
ロゾヴスキー,フランク
アルトヴァッサー,シュテファン
ベッテ,ヴィルジニー
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BASF SE
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023153134A1 (ja) * 2022-02-08 2023-08-17 日本碍子株式会社 リアクタ

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CN110773176B (zh) * 2019-11-08 2022-08-12 中国石油化工股份有限公司 用于降低石油焦硫含量的催化剂、其制备方法和应用
EP3903926A1 (en) * 2020-04-30 2021-11-03 Basf Se Catalytic material comprising ni supported on an oxidic support comprising zr and si

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001031602A (ja) * 1999-06-25 2001-02-06 Basf Ag 合成ガスからco2−オキシジェネートを製造するための方法および触媒
JP2008503440A (ja) * 2004-06-23 2008-02-07 ビーピー ピー・エル・シー・ 微孔質シリカゲルの合成および合成ガスからのc2酸素化物合成のための触媒の製造に対するその適用
WO2014097942A1 (ja) * 2012-12-20 2014-06-26 積水化学工業株式会社 アルコール合成用の触媒、アルコールの製造装置及びアルコールの製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2171925B (en) * 1985-02-02 1988-10-19 Agency Ind Science Techn Process for the manufacture of ethanol based, oxygen-containing carbon compounds
CN102218313B (zh) * 2010-04-15 2013-12-04 中国石油化工股份有限公司 合成气转化催化剂及其制备方法
CN103613483B (zh) * 2013-11-14 2015-07-29 中国科学院广州能源研究所 一种分层装填催化剂在合成气制备低碳醇中的应用

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001031602A (ja) * 1999-06-25 2001-02-06 Basf Ag 合成ガスからco2−オキシジェネートを製造するための方法および触媒
JP2008503440A (ja) * 2004-06-23 2008-02-07 ビーピー ピー・エル・シー・ 微孔質シリカゲルの合成および合成ガスからのc2酸素化物合成のための触媒の製造に対するその適用
WO2014097942A1 (ja) * 2012-12-20 2014-06-26 積水化学工業株式会社 アルコール合成用の触媒、アルコールの製造装置及びアルコールの製造方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023153134A1 (ja) * 2022-02-08 2023-08-17 日本碍子株式会社 リアクタ
JPWO2023153134A1 (enExample) * 2022-02-08 2023-08-17
JP7602672B2 (ja) 2022-02-08 2024-12-18 日本碍子株式会社 リアクタ
AU2023218076B2 (en) * 2022-02-08 2025-10-16 Ngk Insulators, Ltd. Reactor

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