JP2020163358A - 被膜形成方法 - Google Patents
被膜形成方法 Download PDFInfo
- Publication number
- JP2020163358A JP2020163358A JP2019069480A JP2019069480A JP2020163358A JP 2020163358 A JP2020163358 A JP 2020163358A JP 2019069480 A JP2019069480 A JP 2019069480A JP 2019069480 A JP2019069480 A JP 2019069480A JP 2020163358 A JP2020163358 A JP 2020163358A
- Authority
- JP
- Japan
- Prior art keywords
- coating material
- weight
- coating
- resin
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 15
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 239000000463 material Substances 0.000 claims abstract description 147
- 239000011248 coating agent Substances 0.000 claims abstract description 122
- 238000000576 coating method Methods 0.000 claims abstract description 122
- 239000002904 solvent Substances 0.000 claims abstract description 59
- 229920005989 resin Polymers 0.000 claims abstract description 52
- 239000011347 resin Substances 0.000 claims abstract description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 22
- 238000005192 partition Methods 0.000 claims description 18
- 238000009826 distribution Methods 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 description 28
- 239000003822 epoxy resin Substances 0.000 description 26
- 229920000647 polyepoxide Polymers 0.000 description 26
- 239000000049 pigment Substances 0.000 description 22
- 150000001412 amines Chemical class 0.000 description 17
- 238000004040 coloring Methods 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- 238000010422 painting Methods 0.000 description 11
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 10
- 239000002518 antifoaming agent Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 9
- 229920003986 novolac Polymers 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 239000003208 petroleum Substances 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 5
- 229920000178 Acrylic resin Polymers 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
- -1 heterocyclic amines Chemical class 0.000 description 5
- 239000012046 mixed solvent Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004953 Aliphatic polyamide Substances 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000003915 air pollution Methods 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 229920003231 aliphatic polyamide Polymers 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000000805 composite resin Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N divinylbenzene Substances C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 231100001231 less toxic Toxicity 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 1
- XYKNTXVAUYWFFE-UHFFFAOYSA-N 1-(1-hexoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCCCOCC(C)OCC(C)O XYKNTXVAUYWFFE-UHFFFAOYSA-N 0.000 description 1
- QWOZZTWBWQMEPD-UHFFFAOYSA-N 1-(2-ethoxypropoxy)propan-2-ol Chemical compound CCOC(C)COCC(C)O QWOZZTWBWQMEPD-UHFFFAOYSA-N 0.000 description 1
- JKEHLQXXZMANPK-UHFFFAOYSA-N 1-[1-(1-propoxypropan-2-yloxy)propan-2-yloxy]propan-2-ol Chemical compound CCCOCC(C)OCC(C)OCC(C)O JKEHLQXXZMANPK-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- QXNPSEBOTQLKNZ-UHFFFAOYSA-N 1-cyclohexyloxypropan-2-ol Chemical compound CC(O)COC1CCCCC1 QXNPSEBOTQLKNZ-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- MQVBKQCAXKLACB-UHFFFAOYSA-N 1-pentoxypropan-2-ol Chemical compound CCCCCOCC(C)O MQVBKQCAXKLACB-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- QNYTUALIPGMUSK-UHFFFAOYSA-N 2-(2-cyclohexyloxyethoxy)ethanol Chemical compound OCCOCCOC1CCCCC1 QNYTUALIPGMUSK-UHFFFAOYSA-N 0.000 description 1
- ZQGCSCJWVDPFHX-UHFFFAOYSA-N 2-(2-cyclohexyloxypropoxy)propan-1-ol Chemical compound OCC(C)OCC(C)OC1CCCCC1 ZQGCSCJWVDPFHX-UHFFFAOYSA-N 0.000 description 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- PWTNRNHDJZLBCD-UHFFFAOYSA-N 2-(2-pentoxyethoxy)ethanol Chemical compound CCCCCOCCOCCO PWTNRNHDJZLBCD-UHFFFAOYSA-N 0.000 description 1
- QRLZJWCPSKLFKP-UHFFFAOYSA-N 2-(2-pentoxypropoxy)propan-1-ol Chemical compound CCCCCOC(C)COC(C)CO QRLZJWCPSKLFKP-UHFFFAOYSA-N 0.000 description 1
- ZUAURMBNZUCEAF-UHFFFAOYSA-N 2-(2-phenoxyethoxy)ethanol Chemical compound OCCOCCOC1=CC=CC=C1 ZUAURMBNZUCEAF-UHFFFAOYSA-N 0.000 description 1
- LCVQGUBLIVKPAI-UHFFFAOYSA-N 2-(2-phenoxypropoxy)propan-1-ol Chemical compound OCC(C)OCC(C)OC1=CC=CC=C1 LCVQGUBLIVKPAI-UHFFFAOYSA-N 0.000 description 1
- DJCYDDALXPHSHR-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethanol Chemical compound CCCOCCOCCO DJCYDDALXPHSHR-UHFFFAOYSA-N 0.000 description 1
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
- KESQFSZFUCZCEI-UHFFFAOYSA-N 2-(5-nitropyridin-2-yl)oxyethanol Chemical compound OCCOC1=CC=C([N+]([O-])=O)C=N1 KESQFSZFUCZCEI-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- JKJRAMLYRLVDGQ-UHFFFAOYSA-N 2-[2-(2-cyclohexyloxypropoxy)propoxy]propan-1-ol Chemical compound OCC(C)OCC(C)OCC(C)OC1CCCCC1 JKJRAMLYRLVDGQ-UHFFFAOYSA-N 0.000 description 1
- WFSMVVDJSNMRAR-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethanol Chemical compound CCOCCOCCOCCO WFSMVVDJSNMRAR-UHFFFAOYSA-N 0.000 description 1
- RGICCULPCWNRAB-UHFFFAOYSA-N 2-[2-(2-hexoxyethoxy)ethoxy]ethanol Chemical compound CCCCCCOCCOCCOCCO RGICCULPCWNRAB-UHFFFAOYSA-N 0.000 description 1
- ORUVRNUPHYNSLY-UHFFFAOYSA-N 2-[2-(2-hexoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCCCOC(C)COC(C)COC(C)CO ORUVRNUPHYNSLY-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- PLLUGRGSPQYBKB-UHFFFAOYSA-N 2-[2-(2-pentoxyethoxy)ethoxy]ethanol Chemical compound CCCCCOCCOCCOCCO PLLUGRGSPQYBKB-UHFFFAOYSA-N 0.000 description 1
- RPIUXDISLQFSAP-UHFFFAOYSA-N 2-[2-(2-pentoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCCOC(C)COC(C)COC(C)CO RPIUXDISLQFSAP-UHFFFAOYSA-N 0.000 description 1
- IDHKBOHEOJFNNS-UHFFFAOYSA-N 2-[2-(2-phenoxyethoxy)ethoxy]ethanol Chemical compound OCCOCCOCCOC1=CC=CC=C1 IDHKBOHEOJFNNS-UHFFFAOYSA-N 0.000 description 1
- XJCPAFGVHHFBSW-UHFFFAOYSA-N 2-[2-(2-phenoxypropoxy)propoxy]propan-1-ol Chemical compound OCC(C)OCC(C)OCC(C)OC1=CC=CC=C1 XJCPAFGVHHFBSW-UHFFFAOYSA-N 0.000 description 1
- KCBPVRDDYVJQHA-UHFFFAOYSA-N 2-[2-(2-propoxyethoxy)ethoxy]ethanol Chemical compound CCCOCCOCCOCCO KCBPVRDDYVJQHA-UHFFFAOYSA-N 0.000 description 1
- RFHPMEOKJKCEFR-UHFFFAOYSA-N 2-cyclohexyloxyethanol Chemical compound OCCOC1CCCCC1 RFHPMEOKJKCEFR-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- QVQDALFNSIKMBH-UHFFFAOYSA-N 2-pentoxyethanol Chemical compound CCCCCOCCO QVQDALFNSIKMBH-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- LDMRLRNXHLPZJN-UHFFFAOYSA-N 3-propoxypropan-1-ol Chemical compound CCCOCCCO LDMRLRNXHLPZJN-UHFFFAOYSA-N 0.000 description 1
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- GCJBLMDRJGAIDN-UHFFFAOYSA-N C(=C)C1=C(C=CC=C1)C=C.OC1=CC=CC2=CC=CC=C12 Chemical compound C(=C)C1=C(C=CC=C1)C=C.OC1=CC=CC2=CC=CC=C12 GCJBLMDRJGAIDN-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- KWORKYDIARWARF-UHFFFAOYSA-N N-(4-chloro-2-methylphenyl)-4-[(4-chloro-2-methylphenyl)diazenyl]-3-hydroxynaphthalene-2-carboxamide Chemical compound Cc1cc(Cl)ccc1NC(=O)c1cc2ccccc2c(N=Nc2ccc(Cl)cc2C)c1O KWORKYDIARWARF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BQCFCWXSRCETDO-UHFFFAOYSA-N [Fe].[Mn].[Cu] Chemical compound [Fe].[Mn].[Cu] BQCFCWXSRCETDO-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- MYONAGGJKCJOBT-UHFFFAOYSA-N benzimidazol-2-one Chemical compound C1=CC=CC2=NC(=O)N=C21 MYONAGGJKCJOBT-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000004842 bisphenol F epoxy resin Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- OCDXZFSOHJRGIL-UHFFFAOYSA-N cyclohexyloxycyclohexane Chemical compound C1CCCCC1OC1CCCCC1 OCDXZFSOHJRGIL-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- HEQBUZNAOJCRSL-UHFFFAOYSA-N iron(ii) chromite Chemical compound [O-2].[O-2].[O-2].[Cr+3].[Fe+3] HEQBUZNAOJCRSL-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical compound C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- 239000011850 water-based material Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Abstract
Description
1.基材に対し、第1被覆材を塗付した後、第2被覆材を塗付して被膜を形成する被膜形成方法であって、
上記第1被覆材は、樹脂成分、及び脂肪族炭化水素溶剤を含み、不揮発分が60重量%以下、不揮発分に対する樹脂成分比率が50重量%以上であり、
上記第2被覆材は、樹脂成分、水、及び分配係数3.0以下の溶剤を含み、粘度が2Pa・s以下である
ことを特徴とする被膜形成方法。
本発明では、第1被覆材の塗付・乾燥後に、第2被覆材を塗付する。第2被覆材としては、樹脂成分、水、及び分配係数3.0以下の溶剤を含み、粘度が2Pa・s以下であるものを使用する。このような第2被覆材は、水系上塗材として使用でき、塗装作業性が良好であり、薄く均一な被膜を形成することができる。
これに対し、本発明では、第2被覆材が特定分配係数の溶剤を含むため、第2被覆材の被膜が均一となり、仕上り良好な状態を安定的に得ることができる。
○第1被覆材1
エポキシ樹脂{フェノールノボラック型ビスフェノールAエポキシ樹脂溶液、固形分50重量%、エポキシ当量(固形分)800g/eq}、脂肪族炭化水素含有混合溶剤(ミネラルスピリット)、石油系溶剤(混合アニリン点14℃)、及び添加剤(増粘剤、分散剤、消泡剤)を含む主剤に、アミン硬化剤{脂肪族ポリアミドアミン、固形分70重量%、活性水素当量(固形分)120g/eq}を混合し、第1被覆材1を作製した。第1被覆材1の不揮発分は37重量%、不揮発分に対する樹脂比率は98重量%、溶剤総量に対する脂肪族炭化水素溶剤の比率は32重量%であった。
エポキシ樹脂(同上)、着色顔料(酸化チタン)、脂肪族炭化水素含有混合溶剤(同上)、石油系溶剤(同上)、及び添加剤(同上)を含む主剤に、アミン硬化剤(同上)を混合し、第1被覆材2を作製した。第1被覆材2の不揮発分は43重量%、不揮発分に対する樹脂比率は76重量%、溶剤総量に対する脂肪族炭化水素溶剤の比率は43重量%であった。
エポキシ樹脂(同上)、脂肪族炭化水素含有混合溶剤(同上)、石油系溶剤(同上)、及び添加剤(同上)を含む主剤に、アミン硬化剤(同上)を混合し、第1被覆材3を作製した。第1被覆材3の不揮発分は28重量%、不揮発分に対する樹脂比率は98重量%、溶剤総量に対する脂肪族炭化水素溶剤の比率は46重量%であった。
○第2被覆材1
樹脂エマルション(アクリルシリコン樹脂エマルション、固形分50重量%)200重量部に対し、着色顔料(酸化チタン)60重量部、溶剤1(ジエチレングリコールモノブチルエーテル、分配係数0.3)8重量部、増粘剤1重量部、消泡剤1重量部を均一に混合し、さらに水を加えて、粘度1.0Pa・s(測定温度5℃)の第2被覆材1を得た。
樹脂エマルション(同上)200重量部に対し、着色顔料(同上)60重量部、溶剤2(エチレングリコールモノブチルエーテル、分配係数0.8)8重量部、増粘剤1重量部、消泡剤1重量部を均一に混合し、さらに水を加えて、粘度1.0Pa・s(測定温度5℃)の第2被覆材2を得た。
樹脂エマルション(同上)200重量部に対し、着色顔料(同上)60重量部、溶剤3(ベンジルアルコール、分配係数1.1)8重量部、増粘剤1重量部、消泡剤1重量部を均一に混合し、さらに水を加えて、粘度1.0Pa・s(測定温度5℃)の第2被覆材3を得た。
樹脂エマルション(同上)200重量部に対し、着色顔料(同上)60重量部、溶剤4(トリプロピレングリコールモノブチルエーテル、分配係数1.5)8重量部、増粘剤1重量部、消泡剤1重量部を均一に混合し、さらに水を加えて、粘度1.0Pa・s(測定温度5℃)の第2被覆材4を得た。
樹脂エマルション(同上)200重量部に対し、着色顔料(同上)60重量部、溶剤5(2,2,4−トリメチル−1,3−ペンタンジオールモノイソブチレート、分配係数3.5)8重量部、増粘剤1重量部、消泡剤1重量部を均一に混合し、さらに水を加えて、粘度1.0Pa・s(測定温度5℃)の第2被覆材5を得た。
樹脂エマルション(同上)200重量部に対し、着色顔料(同上)60重量部、溶剤6(2,2,4−トリメチル−1,3−ペンタンジオールジイソブチレート、分配係数4.9)8重量部、増粘剤1重量部、消泡剤1重量部を均一に混合し、さらに水を加えて、粘度1.0Pa・s(測定温度5℃)の第2被覆材6を得た。
樹脂エマルション(同上)200重量部に対し、着色顔料(同上)60重量部、溶剤7(フタル酸ジブチル、分配係数4.7)8重量部、増粘剤1重量部、消泡剤1重量部を均一に混合し、さらに水を加えて、粘度1.0Pa・s(測定温度5℃)の第2被覆材7を得た。
アクリル樹脂の既存被膜を有するスレート板に対し、第1被覆材を塗付け量150g/m2にて刷毛塗りし、160分乾燥後、第2被覆材を塗付け量150g/m2にて刷毛塗りし、24時間乾燥させた。塗装及び乾燥は、全て5℃環境下にて行った。以上の方法で得られた試験体の外観を目視にて確認した。評価は、均一な被膜が形成されたものを「AA」、被膜が不均一となったものを「E」とする6段階(優:AA>A>B>C>D>E:劣)で行った。使用した第1被覆材と第2被覆材の組合せ、及び試験結果を表1に示す。
Claims (1)
- 基材に対し、第1被覆材を塗付した後、第2被覆材を塗付して被膜を形成する被膜形成方法であって、
上記第1被覆材は、樹脂成分、及び脂肪族炭化水素溶剤を含み、不揮発分が60重量%以下、不揮発分に対する樹脂成分比率が50重量%以上であり、
上記第2被覆材は、樹脂成分、水、及び分配係数3.0以下の溶剤を含み、粘度が2Pa・s以下である
ことを特徴とする被膜形成方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019069480A JP7281322B2 (ja) | 2019-03-30 | 2019-03-30 | 被膜形成方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019069480A JP7281322B2 (ja) | 2019-03-30 | 2019-03-30 | 被膜形成方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2020163358A true JP2020163358A (ja) | 2020-10-08 |
JP7281322B2 JP7281322B2 (ja) | 2023-05-25 |
Family
ID=72715462
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019069480A Active JP7281322B2 (ja) | 2019-03-30 | 2019-03-30 | 被膜形成方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP7281322B2 (ja) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012210605A (ja) * | 2011-03-31 | 2012-11-01 | Dainippon Toryo Co Ltd | 建造物外壁面の親水性防汚処理方法及び建造物 |
JP2015520785A (ja) * | 2012-04-30 | 2015-07-23 | ダウ グローバル テクノロジーズ エルエルシー | 水性塗装剤用低vocグリコールエーテル造膜助剤 |
JP2016163878A (ja) * | 2015-02-27 | 2016-09-08 | ベック株式会社 | 被膜形成方法 |
JP2017074578A (ja) * | 2015-03-04 | 2017-04-20 | ベック株式会社 | 被膜形成方法 |
-
2019
- 2019-03-30 JP JP2019069480A patent/JP7281322B2/ja active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012210605A (ja) * | 2011-03-31 | 2012-11-01 | Dainippon Toryo Co Ltd | 建造物外壁面の親水性防汚処理方法及び建造物 |
JP2015520785A (ja) * | 2012-04-30 | 2015-07-23 | ダウ グローバル テクノロジーズ エルエルシー | 水性塗装剤用低vocグリコールエーテル造膜助剤 |
JP2016163878A (ja) * | 2015-02-27 | 2016-09-08 | ベック株式会社 | 被膜形成方法 |
JP2017074578A (ja) * | 2015-03-04 | 2017-04-20 | ベック株式会社 | 被膜形成方法 |
Also Published As
Publication number | Publication date |
---|---|
JP7281322B2 (ja) | 2023-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5273752B1 (ja) | 水性エポキシ樹脂塗料組成物及びそれを用いた防食塗装方法 | |
KR101715825B1 (ko) | 무용제형 하도용 고방식 도료와 실란 함유 중상도용 고방식 도료 및 이를 이용한 이중도막 초내후성 강구조물 도장방법 | |
CN103865033B (zh) | 多羧基笼型倍半硅氧烷改性环氧树脂及其在涂料中的应用 | |
WO2013140953A1 (ja) | 水性エポキシ樹脂塗料組成物、防食塗装方法、及び塗装体 | |
KR101392471B1 (ko) | 친환경 기능성 2액형 프라이머 도료 조성물 및 이의 제조 방법 | |
JP4771717B2 (ja) | 水性塗料組成物 | |
JP5246977B1 (ja) | 水性防食塗装方法及び塗装体 | |
AU2015214291B2 (en) | Water-based epoxy formulations for applied fireproofing | |
KR101752385B1 (ko) | 습윤면용 경화성 도료조성물 및 이를 이용하여 구조물의 표면을 처리하는 방법 | |
JP6606112B2 (ja) | 被膜形成方法 | |
CN115433505B (zh) | 一种改性环氧树脂防水涂料组合物、改性环氧树脂防水涂料及其制备方法和应用 | |
JP7281322B2 (ja) | 被膜形成方法 | |
AU2015247667B2 (en) | Water-based epoxy formulations for applied fireproofing | |
JP6654496B2 (ja) | 被膜形成方法 | |
JP6706595B2 (ja) | 被膜形成方法 | |
JP6606016B2 (ja) | 被膜形成方法 | |
JP2021161184A (ja) | 被覆材 | |
JP6931381B2 (ja) | 被膜形成材 | |
TWI610988B (zh) | 具環氧羥基氨基甲酸酯之聚醚化合物及水性環氧樹脂組成物 | |
JP2001323212A (ja) | エポキシ樹脂系塗料組成物及びこれを用いた塗装工法 | |
Bernacki et al. | Enhancing the uv durability of epoxy coatings: waterborne acrylic-epoxy hybrid coatings for steel | |
KR20170092486A (ko) | 습윤면용 경화성 도료조성물 및 이를 이용하여 구조물의 표면을 처리하는 방법 | |
JP7428572B2 (ja) | 化粧方法 | |
JP7161425B2 (ja) | 被膜形成方法 | |
KR102182748B1 (ko) | 기능성 유성도료 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220228 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20221118 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20221122 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230113 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20230427 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20230515 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7281322 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |