JP2019520969A5 - - Google Patents
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- Publication number
- JP2019520969A5 JP2019520969A5 JP2018559366A JP2018559366A JP2019520969A5 JP 2019520969 A5 JP2019520969 A5 JP 2019520969A5 JP 2018559366 A JP2018559366 A JP 2018559366A JP 2018559366 A JP2018559366 A JP 2018559366A JP 2019520969 A5 JP2019520969 A5 JP 2019520969A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- metal oxide
- mfi zeolite
- bed reactor
- zeolite catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims description 80
- 238000000034 method Methods 0.000 claims description 42
- 229910021536 Zeolite Inorganic materials 0.000 claims description 33
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 33
- 239000010457 zeolite Substances 0.000 claims description 33
- 229910044991 metal oxide Inorganic materials 0.000 claims description 16
- 239000012702 metal oxide precursor Substances 0.000 claims description 16
- 150000004706 metal oxides Chemical class 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 238000005336 cracking Methods 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical group 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052680 mordenite Inorganic materials 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 150000002910 rare earth metals Chemical class 0.000 claims description 4
- 229910052723 transition metal Inorganic materials 0.000 claims description 4
- 150000003624 transition metals Chemical class 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000005229 chemical vapour deposition Methods 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- GVHCUJZTWMCYJM-UHFFFAOYSA-N chromium(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GVHCUJZTWMCYJM-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- SXTLQDJHRPXDSB-UHFFFAOYSA-N copper;dinitrate;trihydrate Chemical compound O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SXTLQDJHRPXDSB-UHFFFAOYSA-N 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910001960 metal nitrate Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 238000005118 spray pyrolysis Methods 0.000 claims description 2
- 230000000476 thermogenic effect Effects 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 1
- -1 di Rukoniumu Chemical compound 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662335213P | 2016-05-12 | 2016-05-12 | |
| US62/335,213 | 2016-05-12 | ||
| PCT/US2017/031265 WO2017196660A1 (en) | 2016-05-12 | 2017-05-05 | Heat generating catalyst for hydrocarbons cracking |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019520969A JP2019520969A (ja) | 2019-07-25 |
| JP2019520969A5 true JP2019520969A5 (https=) | 2020-06-18 |
| JP7038670B2 JP7038670B2 (ja) | 2022-03-18 |
Family
ID=58745371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018559366A Active JP7038670B2 (ja) | 2016-05-12 | 2017-05-05 | 炭化水素クラッキングのための熱生成触媒 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10105689B2 (https=) |
| EP (1) | EP3454982B1 (https=) |
| JP (1) | JP7038670B2 (https=) |
| KR (1) | KR102407909B1 (https=) |
| CN (1) | CN109195702A (https=) |
| SA (1) | SA518400412B1 (https=) |
| SG (1) | SG11201809915XA (https=) |
| WO (1) | WO2017196660A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113423804B (zh) | 2018-11-27 | 2023-02-17 | 阿卜杜拉国王科技大学 | 用于将烃原料催化转化为石油化工产品的分区流化方法 |
| WO2021055184A1 (en) * | 2019-09-16 | 2021-03-25 | Chevron Phillips Chemical Company Lp | Chromium-based catalysts and processes for converting alkanes into higher and lower aliphatic hydrocarbons |
| KR102312917B1 (ko) * | 2020-01-20 | 2021-10-15 | 한국에너지기술연구원 | 촉매 화합물 및 촉매 화합물을 포함하는 연소 장치 |
| US20220017829A1 (en) * | 2020-07-20 | 2022-01-20 | Saudi Arabian Oil Company | Systems and processes for direct converting distillate fractions of crude oil to olefins |
| US11781074B1 (en) | 2022-07-11 | 2023-10-10 | Saudi Arabian Oil Company | Conversion of an aerosolized and charged hydrocarbon stream to lower boiling point hydrocarbons |
| US11692140B1 (en) | 2022-07-11 | 2023-07-04 | Saudi Arabian Oil Company | Conversion of an aerosolized hydrocarbon stream to lower boiling point hydrocarbons utilizing a fibrous filter |
| US11845901B1 (en) | 2022-07-11 | 2023-12-19 | Saudi Arabian Oil Company | Conversion of an aerosolized hydrocarbon stream to lower boiling point hydrocarbons |
| KR102822045B1 (ko) * | 2023-05-25 | 2025-06-19 | 한국화학연구원 | 천연가스의 열분해 반응장치 |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB315991A (en) | 1928-07-07 | 1929-07-25 | Ig Farbenindustrie Ag | Improvements in the conversion of hydrocarbons of high boiling point into others of low boiling point |
| US2476729A (en) | 1947-01-14 | 1949-07-19 | Phillips Petroleum Co | Catalytic oil cracking with air |
| US3013985A (en) * | 1958-09-24 | 1961-12-19 | Union Carbide Corp | Group ib metal catalysts |
| US3346328A (en) * | 1967-03-30 | 1967-10-10 | Francis J Sergeys | Method of treating exhaust gases |
| ZA801758B (en) * | 1979-04-04 | 1981-03-25 | Mobil Oil Corp | Steam-resistant zeolite catalyst |
| US4835127A (en) | 1983-11-16 | 1989-05-30 | Phillips Petroleum Company | Oxidative dehydrogenation and cracking of paraffins using a promoted cobalt catalyst |
| AU569971B2 (en) * | 1984-12-28 | 1988-02-25 | Mobil Oil Corp. | Hydrothermally stable zeolite with cu(i) |
| DE3872478T2 (de) * | 1987-10-07 | 1993-02-18 | Tosoh Corp | Verfahren zur herstellung eines kupfer enthaltenden zeoliths und methode fuer seine anwendung. |
| US5026936A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of propylene from higher hydrocarbons |
| JPH07106300B2 (ja) | 1989-12-08 | 1995-11-15 | 財団法人産業創造研究所 | 燃焼排ガス中の窒素酸化物除去法 |
| US5059738A (en) | 1990-03-07 | 1991-10-22 | Mobil Oil Corporation | Method for reactivating MTG process catalyst |
| US5384297A (en) * | 1991-05-08 | 1995-01-24 | Intevep, S.A. | Hydrocracking of feedstocks and catalyst therefor |
| US5997728A (en) | 1992-05-04 | 1999-12-07 | Mobil Oil Corporation | Catalyst system for maximizing light olefin yields in FCC |
| US5318692A (en) | 1992-11-30 | 1994-06-07 | Exxon Research And Engineering Company | FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds |
| US5318696A (en) | 1992-12-11 | 1994-06-07 | Mobil Oil Corporation | Catalytic conversion with improved catalyst catalytic cracking with a catalyst comprising a large-pore molecular sieve component and a ZSM-5 component |
| US5527979A (en) | 1993-08-27 | 1996-06-18 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| US5530171A (en) | 1993-08-27 | 1996-06-25 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| US5583081A (en) | 1993-08-31 | 1996-12-10 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Copper-containing zeolite catalysts |
| US5968466A (en) * | 1995-06-07 | 1999-10-19 | Asec Manufacturing | Copper-silver zeolite catalysts in exhaust gas treatment |
| US6046128A (en) * | 1996-11-27 | 2000-04-04 | Idemitsu Kosan Co., Ltd. | Method of manufacturing catalyst for purifying exhaust gas |
| EP0921175A1 (en) | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of olefins |
| US6579347B1 (en) * | 1998-04-28 | 2003-06-17 | Matsushita Electric Industrial Co., Ltd. | Method for removing sulfur compound present in city gas |
| US6888038B2 (en) | 2002-03-18 | 2005-05-03 | Equistar Chemicals, Lp | Enhanced production of light olefins |
| US7145051B2 (en) | 2002-03-22 | 2006-12-05 | Exxonmobil Chemical Patents Inc. | Combined oxydehydrogenation and cracking catalyst for production of olefins |
| CN1176020C (zh) | 2002-06-27 | 2004-11-17 | 中国石油化工股份有限公司 | 一种含磷和过渡金属的mfi结构分子筛 |
| CN1711135A (zh) | 2002-11-18 | 2005-12-21 | 株式会社Ict | 废气净化用催化剂与废气净化方法 |
| JP2004167306A (ja) | 2002-11-18 | 2004-06-17 | Ict:Kk | 排ガス浄化用触媒および排ガス浄化方法 |
| US7122492B2 (en) | 2003-02-05 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
| JP2006513843A (ja) | 2003-02-05 | 2006-04-27 | エクソンモービル・ケミカル・パテンツ・インク | 接触分解のための混合した分解及び選択的水素燃焼 |
| US7122493B2 (en) | 2003-02-05 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
| US7122494B2 (en) | 2003-02-05 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
| US7125817B2 (en) | 2003-02-20 | 2006-10-24 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
| TWI259106B (en) | 2003-06-30 | 2006-08-01 | China Petrochemical Technology | Catalyst conversion process for increasing yield of light olefins |
| JP5185816B2 (ja) | 2005-06-29 | 2013-04-17 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 流動接触ユニットにおける軽質オレフィン用ペンタシル触媒 |
| US7973207B2 (en) | 2005-09-02 | 2011-07-05 | Sud-Chemie Inc. | Endothermic hydrocarbon conversion process |
| US7622623B2 (en) | 2005-09-02 | 2009-11-24 | Sud-Chemie Inc. | Catalytically inactive heat generator and improved dehydrogenation process |
| CN102531821B (zh) | 2010-12-28 | 2015-03-25 | 中国科学院大连化学物理研究所 | 采用改性zsm-5分子筛催化剂催化甲醇耦合石脑油催化裂解反应的方法 |
| FR2977257B1 (fr) | 2011-06-30 | 2015-01-02 | Total Raffinage Marketing | Procede de craquage catalytique pour le traitement d'une coupe a faible carbone conradson. |
| WO2013032672A1 (en) | 2011-09-01 | 2013-03-07 | University Of Massachusetts | Method for producing fluid hydrocarbons |
| EP2814913A1 (en) | 2012-02-14 | 2014-12-24 | Reliance Industries Limited | A process for catalytic conversion of low value hydrocarbon streams to light olefins |
| US20150165427A1 (en) | 2013-12-13 | 2015-06-18 | King Fahd University Of Petroleum And Minerals | Metal-modified zeolite for catalytic cracking of heavy oils and process for producing light olefins |
| CN104194818B (zh) | 2014-06-11 | 2016-02-17 | 中国石油大学(华东) | 一种有机溶剂分散生物油和石油馏分共催化裂化的方法 |
-
2017
- 2017-05-02 US US15/584,585 patent/US10105689B2/en active Active
- 2017-05-05 SG SG11201809915XA patent/SG11201809915XA/en unknown
- 2017-05-05 EP EP17724982.8A patent/EP3454982B1/en active Active
- 2017-05-05 CN CN201780028936.7A patent/CN109195702A/zh active Pending
- 2017-05-05 KR KR1020187035918A patent/KR102407909B1/ko active Active
- 2017-05-05 JP JP2018559366A patent/JP7038670B2/ja active Active
- 2017-05-05 WO PCT/US2017/031265 patent/WO2017196660A1/en not_active Ceased
- 2017-09-29 US US15/720,185 patent/US10144003B2/en active Active
-
2018
- 2018-11-11 SA SA518400412A patent/SA518400412B1/ar unknown
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