JP2019500530A - 織物素材を含む床用タイル及びその製造方法 - Google Patents
織物素材を含む床用タイル及びその製造方法 Download PDFInfo
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- JP2019500530A JP2019500530A JP2018550310A JP2018550310A JP2019500530A JP 2019500530 A JP2019500530 A JP 2019500530A JP 2018550310 A JP2018550310 A JP 2018550310A JP 2018550310 A JP2018550310 A JP 2018550310A JP 2019500530 A JP2019500530 A JP 2019500530A
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Abstract
Description
織物素材を含む床用タイルの製造
均衡層、第1の騒音防止層、伸縮防止層、第2の騒音防止層、機能性シート層、織物素材層を、150℃で、熱圧着工程によって接着させた後、織物素材層の上部に表面コーティング用液状原料のコーティングを施し、紫外線照射装置を用いて表面コーティング層を硬化させることで織物素材を含む床用タイルを製造した。各層に関する具体的な成分及び厚さは、下記の通りである。
均衡層は、厚さが1mmで、PVCを含み、PVC100重量部に対して、65重量部の充填剤を含み、下部面には複数の凸凹が形成されている。第1の騒音防止層は、PVCを含み、PVC100重量部に対して、炭酸カルシウム350重量部を含み、厚さは1.5mmである。伸縮防止層は、PVCが含浸されたガラス繊維であり、PVC100重量部に対して、充填剤55重量部を含み、厚さは1mmである。第2の騒音防止層は、PVCを含み、PVC100重量部に対して、炭酸カルシウム500重量部を含み、厚さは1.5mmである。機能性シート層は、PVC100重量部に対して、DOTP45重量部、Ca/Zn系安定剤4.5重量部、充填剤として炭酸カルシウム8重量部、及びその他の添加剤として酸化チタンが含まれた顔料5重量部を含み、厚さは0.2mmである。織物素材層は、PVC樹脂がコーティングされた熱可塑性ポリエステル樹脂で織られた織物素材であり、厚さは1.5mmである。表面コーティング層は、透明なウレタン樹脂であり、厚さは20μmである。
機能性シート層を有しない以外は、実施例1と同様にして織物素材を含む床用タイルを製造した。
機能性シート層の厚さを0.02mmとする以外は、実施例1と同様にして製造した。
織物素材層とシート層とを、熱圧着工程でなく、含浸法で製造する以外は、実施例1と同様にして製造した。含浸法は、液状状態であるPVC含浸層の配合を使用し、織物素材層の下部分を液状PVC含浸層の配合に浸漬させた後、オーブンで200℃の熱を加え、常温に冷却して固形化させた。PVC含浸層は、PVCを含み、PVC100重量部、DOTP70重量部、Ca/Zn系安定剤4.5重量部、充填剤としての炭酸カルシウム70重量部を含み、厚さは0.4mmである。
織物素材層の剥離現象発生の評価
実施例1、比較例1及び2の床用タイルを、KS M 3802:2014のテスト方法に基づいて実験を行い、剥離現象が発生する否かを確認した。その結果を表1に示す。
掃除容易性の評価
実施例1及び比較例1の床用タイルに、外部汚染物の一例としての砂を撒いた後、真空掃除機を用いて汚染物の除去程度を測定した。砂に代えて小麦粉及びほこりを使用して同様な実験を行った。その結果を表2、図4〜図7に示す。
製造方法に応じた機械物性の評価
実施例1及び比較例3の床用タイルを、KSM 3802のテスト方法に基づいて実験を行い、引張強度を測定した。その結果を表3に示す。
Claims (25)
- 床用タイルであって、
均衡層;
騒音防止層;
機能性シート層;
織物素材層;及び
表面コーティング層;
を含む、織物素材を含む床用タイル。 - 前記表面コーティング層の下部面に設けられる織物素材層;
前記織物素材層の下部面に設けられる機能性シート層;
前記機能性シート層の下部面に設けられる騒音防止層;及び
前記騒音防止層の下部面に設けられる均衡層;
を含む、請求項1に記載の織物素材を含む床用タイル。 - 前記騒音防止層は、単一の騒音防止層又は複数の騒音防止層である、請求項1に記載の織物素材を含む床用タイル。
- 前記表面コーティング層は、透明なウレタン又はアクリル系列樹脂を含む、請求項1に記載の織物素材を含む床用タイル。
- 前記織物素材層は、高分子樹脂でコーティングされた熱可塑性樹脂繊維を含む、請求項1に記載の織物素材を含む床用タイル。
- 前記高分子樹脂は、ポリエチレン樹脂、ポリプロピレン樹脂、ABS(アクリロニトリル−ブタジエン−スチレン)樹脂、ポリ塩化ビニル樹脂、アクリル樹脂、ポリエステル樹脂、ポリスチレン樹脂、ポリテトラフルオロエチレン、ゴム、エチレン酢酸ビニル共重合体、及びエチレンプロピレン共重合体からなる群から選択される1つ以上を含む、請求項5に記載の織物素材を含む床用タイル。
- 前記熱可塑性樹脂は、ポリオレフィン、ポリウレタン、アクリル樹脂、ポリエステル、ポリ塩化ビニル樹脂、ナイロン樹脂、及びこれらの混合樹脂からなる群から選択される1つ以上を含む、請求項5に記載の織物素材を含む床用タイル。
- 前記機能性シート層は、高分子樹脂、可塑剤、安定剤、充填剤、及び顔料を含む、請求項1に記載の織物素材を含む床用タイル。
- 前記機能性シート層は、高分子樹脂100重量部に対して、可塑剤5〜50重量部、安定剤3〜10重量部、充填剤0〜20重量部、及び顔料0.05〜15重量部を含む、請求項8に記載の織物素材を含む床用タイル。
- 前記高分子樹脂は、ポリエチレン樹脂、ポリプロピレン樹脂、ABS(アクリロニトリル−ブタジエン−スチレン)樹脂、ポリ塩化ビニル樹脂、アクリル樹脂、ポリエステル樹脂、ポリスチレン樹脂、ポリテトラフルオロエチレン、ゴム、エチレン酢酸ビニル共重合体、及びエチレンプロピレン共重合体からなる群から選択される1つ以上を含む、請求項8に記載の織物素材を含む床用タイル。
- 前記可塑剤は、ジオクチルフタレート(dioctyl phthalate:DOP)、ジイソノニルフタレート(diisononyl phthalate:DINP)、ジイソデシルフタレート(diisodecyl phthalate:DIDP)、ジウンデシルフタレート(diundecyl phthalate:DUP)、トリオクチルトリメリテート(trioctyl trimellitate:TOTM)、ジオクチルアジペート(dioctyl adipate:DOA)、ジオクチルテレフタレート(dioctyl terephthalate:DOTP)、1,2−シクロヘキサンジカルボン酸ジイソノニルエステル(1,2−cyclohexane dicarboxylic acid diisononyl ester:DINCH)、ジプロピルヘプチルフタレート(dipropylheptyl phthalate:DPHP)、アセチルトリブチルシトレート(acetyltributylcitrate:ATBC)、植物系の可塑剤、ベンゾエート(benzoate)からなる群から選択される1つ以上を含む、請求項8に記載の織物素材を含む床用タイル。
- 前記安定剤は、金属石鹸系安定剤、有機スズ複合安定剤、及びエポキシ系安定剤からなる群から選択される1つ以上を含む、請求項8に記載の織物素材を含む床用タイル。
- 前記充填剤は、炭酸カルシウム、シリカ、アルミナ、海泡石、タルク、酸化アンチモン、酸化アルミニウム、フライアッシュ、及び高炉スラグからなる群から選択される1つ以上を含む、請求項8に記載の織物素材を含む床用タイル。
- 前記顔料は、有機系顔料、無機系顔料、及びこれらの混合物からなる群から選択される1つ以上を含む、請求項8に記載の織物素材を含む床用タイル。
- 前記織物素材層のコーティング層及び前記機能性シート層は、同種類の高分子樹脂を含む、請求項1に記載の織物素材を含む床用タイル。
- 前記高分子樹脂は、ポリエチレン樹脂、ポリプロピレン樹脂、ABS(アクリロニトリル−ブタジエン−スチレン)樹脂、ポリ塩化ビニル樹脂、アクリル樹脂、ポリエステル樹脂、ポリスチレン樹脂、ポリテトラフルオロエチレン、ゴム、エチレン酢酸ビニル共重合体、及びエチレンプロピレン共重合体からなる群から選択される1つ以上を含む、請求項15に記載の織物素材を含む床用タイル。
- 前記床用タイルは、伸縮防止層をさらに含む、請求項1又は2に記載の織物素材を含む床用タイル。
- 前記伸縮防止層は、高分子樹脂を含むガラス繊維又は不織布であり、
前記高分子樹脂は、ポリエチレン樹脂、ポリプロピレン樹脂、ABS(アクリロニトリル−ブタジエン−スチレン)樹脂、ポリ塩化ビニル樹脂、アクリル樹脂、ポリエステル樹脂、ポリスチレン樹脂、ポリテトラフルオロエチレン、ゴム、エチレン酢酸ビニル共重合体、及びエチレンプロピレン共重合体からなる群から選択される1つ以上を含む、請求項17に記載の織物素材を含む床用タイル。 - 前記均衡層及び騒音防止層は、高分子樹脂、充填剤、及び添加剤を含む、請求項1に記載の織物素材を含む床用タイル。
- 前記高分子樹脂は、ポリエチレン樹脂、ポリプロピレン樹脂、ABS(アクリロニトリル−ブタジエン−スチレン)樹脂、ポリ塩化ビニル樹脂、アクリル樹脂、ポリエステル樹脂、ポリスチレン樹脂、ポリテトラフルオロエチレン、ゴム、エチレン酢酸ビニル共重合体、及びエチレンプロピレン共重合体からなる群から選択される1つ以上を含む、請求項19に記載の織物素材を含む床用タイル。
- 前記充填剤は、炭酸カルシウム、シリカ、アルミナ、海泡石、タルク、酸化アンチモン、酸化アルミニウム、フライアッシュ、硫酸バリウム、及び高炉スラグからなる群から選択される1つ以上を含む、請求項19に記載の織物素材を含む床用タイル。
- 前記添加剤は、可塑剤、安定剤、顔料、及び難燃剤からなる群から選択される1つ以上を含む、請求項19に記載の織物素材を含む床用タイル。
- 前記均衡層は、下部面に複数の凸凹を含む、請求項1に記載の織物素材を含む床用タイル。
- 請求項1に記載の織物素材を含む床用タイルは、均衡層、騒音防止層、機能性シート層、織物素材層を、熱圧着工程により製造した後、織物素材層の上部に表面コーティング用液状原料をコーティングし、紫外線照射装置を用いて硬化させることで、表面コーティング層を製造することを特徴とする、織物素材を含む床用タイルの製造方法。
- 前記床用タイルは、伸縮防止層及び騒音防止層をさらに含む、請求項24に記載の織物素材を含む床用タイルの製造方法。
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