JP2019500461A - 低結晶性ポリマー組成物 - Google Patents
低結晶性ポリマー組成物 Download PDFInfo
- Publication number
- JP2019500461A JP2019500461A JP2018531442A JP2018531442A JP2019500461A JP 2019500461 A JP2019500461 A JP 2019500461A JP 2018531442 A JP2018531442 A JP 2018531442A JP 2018531442 A JP2018531442 A JP 2018531442A JP 2019500461 A JP2019500461 A JP 2019500461A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- ethylene
- propylene
- less
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims description 109
- 239000000203 mixture Substances 0.000 title claims description 50
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000005977 Ethylene Substances 0.000 claims abstract description 36
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 32
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000178 monomer Substances 0.000 claims abstract description 23
- 238000003780 insertion Methods 0.000 claims abstract description 17
- 230000037431 insertion Effects 0.000 claims abstract description 17
- 230000009257 reactivity Effects 0.000 claims abstract description 14
- 239000004711 α-olefin Substances 0.000 claims abstract description 14
- 230000004927 fusion Effects 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 41
- 230000008569 process Effects 0.000 claims description 21
- -1 ethylene, propylene Chemical group 0.000 claims description 14
- 239000008188 pellet Substances 0.000 claims description 5
- 239000012968 metallocene catalyst Substances 0.000 claims description 4
- 239000002356 single layer Substances 0.000 claims description 3
- 150000001993 dienes Chemical class 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 description 56
- 239000010408 film Substances 0.000 description 50
- 239000003054 catalyst Substances 0.000 description 36
- 239000002904 solvent Substances 0.000 description 23
- 229920000573 polyethylene Polymers 0.000 description 20
- 238000006116 polymerization reaction Methods 0.000 description 20
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
- 229910052723 transition metal Inorganic materials 0.000 description 18
- 238000005227 gel permeation chromatography Methods 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 150000003624 transition metals Chemical class 0.000 description 17
- 239000003446 ligand Substances 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 239000012190 activator Substances 0.000 description 13
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 12
- 238000002844 melting Methods 0.000 description 11
- 230000008018 melting Effects 0.000 description 11
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 10
- 150000001450 anions Chemical class 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 239000002243 precursor Substances 0.000 description 10
- 238000001374 small-angle light scattering Methods 0.000 description 10
- 238000000149 argon plasma sintering Methods 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 7
- 235000013305 food Nutrition 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 6
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 229920006300 shrink film Polymers 0.000 description 6
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 6
- 238000005481 NMR spectroscopy Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229910052735 hafnium Inorganic materials 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000002516 radical scavenger Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229910000085 borane Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 238000012718 coordination polymerization Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 238000012552 review Methods 0.000 description 2
- 235000014102 seafood Nutrition 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- QVLAWKAXOMEXPM-DICFDUPASA-N 1,1,1,2-tetrachloro-2,2-dideuterioethane Chemical compound [2H]C([2H])(Cl)C(Cl)(Cl)Cl QVLAWKAXOMEXPM-DICFDUPASA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- ICSNLGPSRYBMBD-UHFFFAOYSA-N 2-aminopyridine Chemical compound NC1=CC=CC=N1 ICSNLGPSRYBMBD-UHFFFAOYSA-N 0.000 description 1
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 1
- BSBXLZYWGGAVHD-UHFFFAOYSA-N 2-phenyl-1h-indene Chemical compound C=1C2=CC=CC=C2CC=1C1=CC=CC=C1 BSBXLZYWGGAVHD-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- JXFPEFZGCIQGRZ-UHFFFAOYSA-N C[SiH](C)[Zr](C1C2=CC=CC=C2C=C1)(C1C2=CC=CC=C2C=C1)[SiH](C)C.Cl.Cl Chemical compound C[SiH](C)[Zr](C1C2=CC=CC=C2C=C1)(C1C2=CC=CC=C2C=C1)[SiH](C)C.Cl.Cl JXFPEFZGCIQGRZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 241000335574 Narayana Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 229920000034 Plastomer Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- OFHCOWSQAMBJIW-AVJTYSNKSA-N alfacalcidol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C OFHCOWSQAMBJIW-AVJTYSNKSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 235000015241 bacon Nutrition 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 235000012180 bread and bread product Nutrition 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013039 cover film Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000003936 heterocyclopentadienyl group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000008960 ketchup Nutrition 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229940127554 medical product Drugs 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 235000012771 pancakes Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000009512 pharmaceutical packaging Methods 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 235000013550 pizza Nutrition 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 235000013573 potato product Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000008476 powdered milk Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000001370 static light scattering Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000009460 vacuum skin packaging Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/327—Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
- B32B2553/02—Shock absorbing
- B32B2553/026—Bubble films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
Abstract
本発明で提供されるのは、約70重量%以上のエチレンに由来する単位、約30重量%以下のプロピレンに由来する単位および約5重量%未満のC4〜C20アルファオレフィンに由来する単位を含んでおり、以下の特性を有するポリマーである:エチレンに由来する結晶化度;約20〜約85J/gの融解熱;約2.5未満の多分散指数(Mw/Mn);約0.5〜約1.5の反応性比;0.5重量%未満の、13C NMRによって測定された、全てのプロピレン挿入基のうちプロピレンモノマーの2,1挿入に基いて逆挿入されたプロピレン単位の割合;および約0.5超の分枝指数。
【選択図】なし
Description
ヴァン・ホイベグヒェン、ダニー;ミッチェル、シンシア・エー;ヴァン・ルーン、アチエル・ジェイ・エム;ダーマラジャン、ナラヤナスワミ;ダッタ、サディン
関連出願の相互参照
本出願は、2015年12月16日に出願された米国特許仮出願第62/268,112号および2016年3月15日に出願された欧州特許出願第16160370.9号の優先権および利益を主張し、これらの内容は参照によってその全体が本明細書に組み込まれる。
技術分野
c=KDRIIDRI/(dn/dc)
この式で、KDRIはDRIを較正することによって決定される定数であり、(dn/dc)はその系の屈折率増分である。屈折率nは、145℃のTCBについてn=1.500であり、およびλ=690nmである。GPC−3D法についての本明細書の記載全体を通してのパラメーターの単位はたとえば、濃度はg/cm3で表され、分子量はg/モルで表され、および固有粘度はdL/gで表される。
LS検出器はWyatt Technology社製高温DAWN HELEOSである。クロマトグラムの各点でのポリマー分子量Mは、静的光散乱についての以下のZimmモデル(M.B.Huglin、「ポリマー溶液からの光散乱」、Academic Press社刊、1971年)を使用してLS出力を分析することによって決定される:
上記の式で、ΔR(θ)は散乱角θで測定された超過レーリー散乱強度であり、cはDRI分析から測定されたポリマー濃度であり、A2は第二ビリアル係数である。P(θ)は単分散ランダムコイルについての形状因子であり、Koは以下の式の系の光学定数である:
この式で、NAはアボガドロ数であり、(dn/dc)はその系の屈折率増分であり、これはDRI法から得られる値と同じ値をとる。屈折率nは、145℃のTCBについてn=1.500であり、およびλ=657nmである。
ηs=c[η]+0.3(c[η])2
この式で、cは濃度であり、DRIの出力から決定される。
分枝指数g’(g’vis)は、GPC−DRI−LS−VIS法の出力を使用して以下のように計算される。サンプルの平均固有粘度[η]avgは、以下の式によって計算され:
この式で、総和は積算限界間のクロマトグラフのスライスiにわたってされる。
分枝指数g’visは以下のように定義され:
この式で、Mvは、LS分析によって測定された分子量に基いた粘度平均分子量である。Z平均分枝指数(g’Zave)は、ポリマーピークのスライスiのポリマー濃度(Ci)にそのスライスの質量の2乗(Mi2)を乗じたものを使用して計算される。
「分枝指数」:本明細書に記載されるエチレンエラストマーは、好ましくは約0.5超の分枝指数を有する。エチレン、アルファオレフィン中の相対的な分枝の程度は、分枝指数因子(BI)を使用して決定される。この因子を計算するには、VerStrate、Gary、「エチレン−プロピレンエラストマー」、Encyclopedia of Polymer Science and Engineering、第6巻、第2版(1986年)に開示された溶液中のポリマー特性の一連の3個の実験室で得られる測定値が必要になる。これらの3個の実験室で得られる測定値は以下のとおりである:(i)ゲル透過クロマトグラフィー(GPC)と組み合された低角度レーザー光散乱検出器(LALLS)技術を使用して測定されたMw,GPC LALLS、重量平均分子量、(ii)GPCと組み合された示差屈折率(DRI)検出器を使用する重量平均分子量(MwDRI)および粘度平均分子量(MvDRI)、および(iii)135℃のデカリン中で測定された固有粘度(IV)。最初の2個の測定値(iおよびii)は、トリクロロベンゼン中のポリマーのろ過された稀薄溶液を使用してGPCで得られる。
BI=Mv,br×Mw,DRI/Mw,GPC LALLS×Mv,GPC DRI、ここで、Mv,br=(IV/k)1/a;および「a」はMark−Houwink定数(135℃のデカリン中のエチレン、プロピレンジエンエラストマーポリマーについてa=0.759)である。式(1)から、直鎖状ポリマーについての分枝指数は1.0であることになる。分枝状ポリマーの場合、分枝の程度は直鎖状ポリマーとの相対比として定義される。一定の数平均分子量Mnでは(MW)分枝>(MW)直鎖状であるので、分枝状ポリマーについてのBIは1.0未満であり、BI値が小さいほど分枝のレベルが高いことを示す。デカリン中のIVを測定する代わりに、DRIおよびLALLS検出器と連携した粘度検出器、いわゆるGPC−3D測定器を使用してIVを測定することも許容される。この場合、GPC溶媒に適した「k」値および「a」値が上記の式で使用されなければならない。
BI=Mv,br×Mw,DRI/Mw,GPC LALLS×Mv,GPC DRI、ここで、Mv,br=(IV/k)1/a;および「a」はMark−Houwink定数(135℃のデカリン中のエチレン、プロピレンジエンエラストマーポリマーについてa=0.759)である。式(1)から、直鎖状ポリマーについての分枝指数は1.0であることになる。分枝状ポリマーの場合、分枝の程度は直鎖状ポリマーとの相対比として定義される。一定の数平均分子量Mnでは(MW)分枝>(MW)直鎖状であるので、分枝状ポリマーについてのBIは1.0未満であり、BI値が小さいほど分枝のレベルが高いことを示す。デカリン中のIVを測定する代わりに、DRIおよびLALLS検出器と連携した粘度検出器、いわゆるGPC−3D測定器を使用してIVを測定することも許容される。この場合、GPC溶媒に適した「k」値および「a」値が上記の式で使用されなければならない。
上記の式中のピークの名前は、雑誌Rubber Chemistry and Technology、第44巻(1971年)、781頁中のCarmanらによる方法に従って付けられ、この式でIαδはαδ+第2級炭素ピークのピーク面積を表す。ピークの重なりのためにIαβ(構造(ii))からIαβ(構造(i))のピーク面積を分離するのは困難である。対応する面積を有する炭素ピークがそれに代わって使用されることができる。
エチレンポリマー
重合プロセス
重合触媒
特定の触媒
ポリマー組成物をつくるための好ましい手順
有用な物品
[実施例]
Claims (12)
- 約70重量%以上のエチレンに由来する単位、約30重量%以下のプロピレンに由来する単位および約5重量%未満のC4〜C20アルファオレフィンに由来する単位を含んでおり、以下の特性を有するポリマー:
a.エチレンに由来する結晶化度;
b.約20〜約85J/gの融解熱;
c.約2.5未満の多分散指数(Mw/Mn);
d.約0.5〜約1.5の反応性比;
e.0.5重量%未満の、13C NMRによって測定された、全てのプロピレン挿入基のうちプロピレンモノマーの2,1挿入に基いて逆挿入されたプロピレン単位の割合;および
f.約0.5超の分枝指数。 - 約85℃未満の溶解温度を有する、請求項1に記載のポリマー。
- 約0.01〜約5g/10分のメルトインデックス(190℃で2.16kgで測定されたもの)を有する、請求項1に記載のポリマー。
- 約77重量%〜約85重量%のエチレンに由来する単位を含んでいる、請求項1に記載のポリマー。
- 前記ポリマーが、メタロセン触媒を使用して調製される、請求項1に記載のポリマー。
- 前記ポリマーが、ジエンに由来する単位を実質的に含んでいない、請求項1に記載のポリマー。
- 前記ポリマーが、ペレットの形態をしている、請求項1に記載のポリマー。
- 請求項1に記載のポリマーを含んでいる物品であって、前記請求項1に記載のポリマーを含んでいるポリマー組成物が、約10重量%〜約70重量%の量で前記物品中に存在する、物品。
- 前記物品が、多層フィルムまたは単層フィルムである、請求項8に記載の物品。
- 前記物品がブローンフィルムである、請求項8に記載の物品。
- ポリマーを形成するプロセスであって、以下の工程を含むプロセス:
(a)エチレン、プロピレンおよび任意的なC4〜C20アルファオレフィンを重合して、ポリマーを形成する工程;および
(b)前記ポリマーを回収する工程であって、前記ポリマーが以下を有する工程;
a.エチレンに由来する結晶化度;
b.約70重量%以上のエチレンに由来する単位、約30重量%以下のプロピレンに由来する単位および任意的な約5重量%未満のC4〜C20アルファオレフィンに由来する単位
c.約20〜約85J/gの融解熱;
d.約2.5未満の多分散指数(Mw/Mn);
e.約0.5〜約1.5の反応性比;
f.0.5重量%未満の、13C NMRによって測定された、全てのプロピレン挿入基のうちプロピレンモノマーの2,1挿入に基いて逆挿入されたプロピレン単位の割合;および
g.約0.5超の分枝指数。 - 溶液プロセスで実施される、請求項11に記載のプロセス。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562268112P | 2015-12-16 | 2015-12-16 | |
US62/268,112 | 2015-12-16 | ||
EP16160370.9 | 2016-03-15 | ||
EP16160370 | 2016-03-15 | ||
PCT/US2016/057308 WO2017105614A1 (en) | 2015-12-16 | 2016-10-17 | Low crystalline polymer compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2019500461A true JP2019500461A (ja) | 2019-01-10 |
JP6694510B2 JP6694510B2 (ja) | 2020-05-13 |
Family
ID=55532195
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018531442A Active JP6694510B2 (ja) | 2015-12-16 | 2016-10-17 | 低結晶性ポリマー組成物 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP3390056B1 (ja) |
JP (1) | JP6694510B2 (ja) |
CN (1) | CN108290401B (ja) |
CA (1) | CA3004086C (ja) |
SG (1) | SG11201802756QA (ja) |
WO (1) | WO2017105614A1 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4219158A1 (en) | 2022-01-28 | 2023-08-02 | Dow Global Technologies LLC | Multilayer films comprising ethylene-based polymers |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07149833A (ja) * | 1993-10-06 | 1995-06-13 | Mitsui Petrochem Ind Ltd | プロピレン系エラストマー |
JPH09501184A (ja) * | 1994-04-06 | 1997-02-04 | モンテル テクノロジー カンパニー ビーブイ | メタロセン化合物及びオレフィンの重合用触媒への使用 |
JP2006045446A (ja) * | 2004-08-09 | 2006-02-16 | Japan Polypropylene Corp | 高剛性ポリプロピレン系組成物及び製造法 |
JP2007530738A (ja) * | 2004-03-24 | 2007-11-01 | エクソンモービル・ケミカル・パテンツ・インク | エチレン・インターポリマーの製造方法、該方法により製造されたインターポリマー、組成物、および該インターポリマーを含む電気デバイス |
JP2008523231A (ja) * | 2004-12-13 | 2008-07-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィン繊維 |
JP2009518507A (ja) * | 2005-12-06 | 2009-05-07 | エクソンモービル・ケミカル・パテンツ・インク | エチレンエラストマー組成物 |
JP2012525470A (ja) * | 2009-04-28 | 2012-10-22 | エクソンモービル・ケミカル・パテンツ・インク | エチレンをベースとするコポリマー、それらを含む潤滑油組成物及びそれらの製造方法 |
JP2015536368A (ja) * | 2013-06-28 | 2015-12-21 | エルジー・ケム・リミテッド | ジエンを含む三元系弾性共重合体およびその製造方法 |
JP2016540848A (ja) * | 2013-11-15 | 2016-12-28 | エクソンモービル ケミカル パテンツ インコーポレイテッド | ピリジルジアミド遷移金属錯体からポリマーを製造する方法及びその使用 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4522982A (en) | 1983-06-06 | 1985-06-11 | Exxon Research & Engineering Co. | Isotactic-stereoblock polymers of alpha-olefins and process for producing the same |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5391629A (en) | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
US5700896A (en) | 1988-07-30 | 1997-12-23 | Hoechst Aktiengesellschaft | Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts |
US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
ATE120768T1 (de) | 1989-10-30 | 1995-04-15 | Fina Technology | Herstellung von metallocenkatalysatoren für olefinpolymerisation. |
DE69026679T3 (de) | 1989-10-30 | 2005-10-06 | Fina Technology, Inc., Houston | Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators |
US5594080A (en) | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
WO1996020225A2 (en) | 1994-12-20 | 1996-07-04 | Montell Technology Company B.V. | Reactor blend polypropylene, process for the preparation thereof and process for preparing metallocene ligands |
US5747592A (en) | 1994-12-16 | 1998-05-05 | Exxon Chemical Patents, Inc. | Thermoplastic polymer compositions and their production and use |
US6265212B1 (en) | 1995-06-15 | 2001-07-24 | Introgene B.V. | Packaging systems for human recombinant adenovirus to be used in gene therapy |
TW479064B (en) | 1996-12-17 | 2002-03-11 | Advanced Elastomer Systems | Thermoplastic elastomeric compositions |
CA2292538A1 (en) | 1997-06-14 | 1998-12-23 | Charles L. Myers | Ethylene enhancement of processes for synthesis of high melting thermoplastic elastomeric .alpha.-olefin polymers (pre/epe effects) |
US6265512B1 (en) | 1997-10-23 | 2001-07-24 | 3M Innovative Company | Elastic polypropylenes and catalysts for their manufacture |
AU2801899A (en) | 1998-03-04 | 1999-09-20 | Exxon Chemical Patents Inc. | Noncoordinating anions for olefin polymerization |
CN1292014A (zh) | 1998-03-04 | 2001-04-18 | 埃克森化学专利公司 | 聚烯烃聚合物分散体产品及其制备方法 |
DE19816154A1 (de) | 1998-04-09 | 1999-10-21 | Bernhard Rieger | Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination |
ES2207183T3 (es) | 1998-05-07 | 2004-05-16 | Jowat Ag | Sistema de sustancias. |
WO2003040201A1 (en) | 2001-11-06 | 2003-05-15 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
WO2006138052A1 (en) | 2005-06-13 | 2006-12-28 | Exxonmobil Chemical Patents Inc. | Thermoplastic blend compositions |
US8052822B2 (en) * | 2008-02-15 | 2011-11-08 | Exxonmobil Chemical Patents Inc. | Blends of low crystallinity, low molecular weight propylene copolymers and styrenic block copolymers |
WO2010094450A1 (en) * | 2009-02-20 | 2010-08-26 | Basell Polyolefine Gmbh | Ethylene copolymers, catalyst system and process for preparing the same |
SG182320A1 (en) | 2010-01-22 | 2012-08-30 | Exxonmobil Chem Patents Inc | Ethylene copolymers, methods for their production, and use |
WO2014185996A1 (en) * | 2013-05-14 | 2014-11-20 | Exxonmobil Chemical Patents Inc. | Ethylene-based polymers and articles made therefrom |
-
2016
- 2016-10-17 SG SG11201802756QA patent/SG11201802756QA/en unknown
- 2016-10-17 CN CN201680067121.5A patent/CN108290401B/zh active Active
- 2016-10-17 JP JP2018531442A patent/JP6694510B2/ja active Active
- 2016-10-17 WO PCT/US2016/057308 patent/WO2017105614A1/en active Application Filing
- 2016-10-17 EP EP16788356.0A patent/EP3390056B1/en active Active
- 2016-10-17 CA CA3004086A patent/CA3004086C/en active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07149833A (ja) * | 1993-10-06 | 1995-06-13 | Mitsui Petrochem Ind Ltd | プロピレン系エラストマー |
JPH09501184A (ja) * | 1994-04-06 | 1997-02-04 | モンテル テクノロジー カンパニー ビーブイ | メタロセン化合物及びオレフィンの重合用触媒への使用 |
JP2007530738A (ja) * | 2004-03-24 | 2007-11-01 | エクソンモービル・ケミカル・パテンツ・インク | エチレン・インターポリマーの製造方法、該方法により製造されたインターポリマー、組成物、および該インターポリマーを含む電気デバイス |
JP2006045446A (ja) * | 2004-08-09 | 2006-02-16 | Japan Polypropylene Corp | 高剛性ポリプロピレン系組成物及び製造法 |
JP2008523231A (ja) * | 2004-12-13 | 2008-07-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィン繊維 |
JP2009518507A (ja) * | 2005-12-06 | 2009-05-07 | エクソンモービル・ケミカル・パテンツ・インク | エチレンエラストマー組成物 |
JP2012525470A (ja) * | 2009-04-28 | 2012-10-22 | エクソンモービル・ケミカル・パテンツ・インク | エチレンをベースとするコポリマー、それらを含む潤滑油組成物及びそれらの製造方法 |
JP2015536368A (ja) * | 2013-06-28 | 2015-12-21 | エルジー・ケム・リミテッド | ジエンを含む三元系弾性共重合体およびその製造方法 |
JP2016540848A (ja) * | 2013-11-15 | 2016-12-28 | エクソンモービル ケミカル パテンツ インコーポレイテッド | ピリジルジアミド遷移金属錯体からポリマーを製造する方法及びその使用 |
Also Published As
Publication number | Publication date |
---|---|
CA3004086A1 (en) | 2017-06-22 |
CN108290401A (zh) | 2018-07-17 |
CN108290401B (zh) | 2021-06-04 |
JP6694510B2 (ja) | 2020-05-13 |
WO2017105614A1 (en) | 2017-06-22 |
SG11201802756QA (en) | 2018-06-28 |
CA3004086C (en) | 2020-06-02 |
EP3390056A1 (en) | 2018-10-24 |
EP3390056B1 (en) | 2020-11-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110573538B (zh) | 多反应器溶液聚合 | |
US8288489B2 (en) | Use of a highly viscous largely amorphous polyolefin for the production of a film | |
CN111194327A (zh) | 提高使用均相和非均相催化剂配制物的乙烯互聚物的分子量和降低其密度的手段 | |
US20040152842A1 (en) | Metallocene-produced bery low density polyethylenes or linear low density polyethylenes as impact modifiers | |
CN108699269B (zh) | 聚乙烯膜 | |
US10894393B2 (en) | Multilayer films and methods of making the same | |
WO2018102091A1 (en) | Polyethylene films | |
CN101490116B (zh) | 包含乙烯类树脂或乙烯类树脂组合物的膜或叠层体 | |
CA3018952C (en) | Low crystalline polymer compositions prepared in a dual reactor | |
CN1196741A (zh) | 高阻透聚丙烯组合物及它们在包装应用中的使用 | |
JP6990661B2 (ja) | 2基リアクターで調製された低結晶性ポリマー組成物 | |
JP6694510B2 (ja) | 低結晶性ポリマー組成物 | |
US20200056004A1 (en) | Polyethylene Films | |
CN107001727A (zh) | 来自单位点催化的聚乙烯的收缩薄膜 | |
JP2004035730A (ja) | 樹脂組成物及びそれを成形して成るフィルム | |
US9771444B2 (en) | Low crystalline polymer compositions | |
WO2003040199A1 (en) | Heat-sealed easy-open packaging article containing highly branched homogeneous polyolefin | |
US20170283600A1 (en) | Low Crystalline Polymer Compositions Prepared in a Dual Reactor | |
JP5060828B2 (ja) | ヒートシール性積層体 | |
US20180126707A1 (en) | Multilayer Films and Methods of Making the Same | |
US20240002561A1 (en) | Low crystallinity ethylene-vinylcyclohexane copolymers | |
US20230416429A1 (en) | High crystallinity ethylene-vinylcyclohexane copolymers | |
CN117377700A (zh) | 具有快速结晶速率的塑性体 | |
WO2023227969A1 (en) | Polymer blend and multilayer film structure |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180813 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180813 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190628 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190709 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20191008 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20191209 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20200414 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20200417 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6694510 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |