JP2018534781A - 紫外線発光素子及び発光素子パッケージ - Google Patents
紫外線発光素子及び発光素子パッケージ Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 claims abstract description 427
- 229910002704 AlGaN Inorganic materials 0.000 claims abstract description 278
- 238000005530 etching Methods 0.000 claims abstract description 120
- 230000000903 blocking effect Effects 0.000 claims abstract description 115
- 230000007480 spreading Effects 0.000 claims abstract description 108
- 238000003892 spreading Methods 0.000 claims abstract description 108
- 238000000605 extraction Methods 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims description 30
- 239000000758 substrate Substances 0.000 claims description 15
- 230000007423 decrease Effects 0.000 claims description 7
- 238000009792 diffusion process Methods 0.000 abstract description 20
- 238000000034 method Methods 0.000 abstract description 19
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 230000001939 inductive effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 691
- 230000000694 effects Effects 0.000 description 32
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 22
- 239000002019 doping agent Substances 0.000 description 21
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 19
- 229910052759 nickel Inorganic materials 0.000 description 19
- 229910052782 aluminium Inorganic materials 0.000 description 18
- 230000007547 defect Effects 0.000 description 17
- 229910052802 copper Inorganic materials 0.000 description 16
- 239000010949 copper Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 16
- 229910052697 platinum Inorganic materials 0.000 description 15
- 239000010936 titanium Substances 0.000 description 15
- 230000002265 prevention Effects 0.000 description 14
- 229910052721 tungsten Inorganic materials 0.000 description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 229910052804 chromium Inorganic materials 0.000 description 13
- 239000010931 gold Substances 0.000 description 13
- 229910052719 titanium Inorganic materials 0.000 description 13
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 12
- 229910052737 gold Inorganic materials 0.000 description 12
- 239000002356 single layer Substances 0.000 description 12
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 description 12
- 239000011787 zinc oxide Substances 0.000 description 12
- 229910052738 indium Inorganic materials 0.000 description 11
- 150000004767 nitrides Chemical class 0.000 description 10
- 230000003247 decreasing effect Effects 0.000 description 9
- 229910052750 molybdenum Inorganic materials 0.000 description 9
- 230000004888 barrier function Effects 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 229910052732 germanium Inorganic materials 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 229910052709 silver Inorganic materials 0.000 description 7
- 229910001887 tin oxide Inorganic materials 0.000 description 7
- 229910052720 vanadium Inorganic materials 0.000 description 7
- 229910052725 zinc Inorganic materials 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- 229960001296 zinc oxide Drugs 0.000 description 7
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 description 6
- 229910052733 gallium Inorganic materials 0.000 description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 6
- 229910052763 palladium Inorganic materials 0.000 description 6
- 229910052718 tin Inorganic materials 0.000 description 6
- 239000011135 tin Substances 0.000 description 6
- DZLPZFLXRVRDAE-UHFFFAOYSA-N [O--].[O--].[O--].[O--].[Al+3].[Zn++].[In+3] Chemical compound [O--].[O--].[O--].[O--].[Al+3].[Zn++].[In+3] DZLPZFLXRVRDAE-UHFFFAOYSA-N 0.000 description 5
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 5
- HRHKULZDDYWVBE-UHFFFAOYSA-N indium;oxozinc;tin Chemical compound [In].[Sn].[Zn]=O HRHKULZDDYWVBE-UHFFFAOYSA-N 0.000 description 5
- 229910019897 RuOx Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 229910052735 hafnium Inorganic materials 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 229910002601 GaN Inorganic materials 0.000 description 3
- 241001101998 Galium Species 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- 229910000530 Gallium indium arsenide Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- VRIVJOXICYMTAG-IYEMJOQQSA-L iron(ii) gluconate Chemical compound [Fe+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O VRIVJOXICYMTAG-IYEMJOQQSA-L 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910003465 moissanite Inorganic materials 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002096 quantum dot Substances 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 229910052712 strontium Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052714 tellurium Inorganic materials 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 241000408495 Iton Species 0.000 description 2
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- YZZNJYQZJKSEER-UHFFFAOYSA-N gallium tin Chemical compound [Ga].[Sn] YZZNJYQZJKSEER-UHFFFAOYSA-N 0.000 description 2
- 238000002248 hydride vapour-phase epitaxy Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000001451 molecular beam epitaxy Methods 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 2
- 229910017083 AlN Inorganic materials 0.000 description 1
- 229910018229 Al—Ga Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 description 1
- 229910005540 GaP Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052789 astatine Inorganic materials 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- SBYXRAKIOMOBFF-UHFFFAOYSA-N copper tungsten Chemical compound [Cu].[W] SBYXRAKIOMOBFF-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/0004—Devices characterised by their operation
- H01L33/002—Devices characterised by their operation having heterojunctions or graded gap
- H01L33/0025—Devices characterised by their operation having heterojunctions or graded gap comprising only AIIIBV compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/14—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/26—Materials of the light emitting region
- H01L33/30—Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table
- H01L33/32—Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table containing nitrogen
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/36—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
- H01L33/38—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
- H01L33/382—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape the electrode extending partially in or entirely through the semiconductor body
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/36—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
- H01L33/40—Materials therefor
- H01L33/405—Reflective materials
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
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- H01—ELECTRIC ELEMENTS
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/181—Encapsulation
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- H—ELECTRICITY
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- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/20—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
- H01L33/22—Roughened surfaces, e.g. at the interface between epitaxial layers
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Abstract
【選択図】図2
Description
Claims (15)
- 光抽出構造を有する第1導電型第1半導体層;
前記第1導電型第1半導体層上にエッチング遮断層;
前記エッチング遮断層上に第1導電型第2半導体層;
前記第1導電型第2半導体層上に活性層;
前記活性層上に第2導電型半導体層;及び
前記エッチング遮断層と前記活性層との間に配置された電流広がり層を含み、
前記電流広がり層は、アンドープAlN及び第1導電型AlGaN系の第2半導体層を含む紫外線発光素子。 - 前記第1導電型第1半導体層、第1導電型第2半導体層及び第2導電型半導体層は、AlGaN系で構成され、
前記電流広がり層は、前記エッチング遮断層上に配置された第1導電型AlGaN系の第1半導体層またはアンドープAlGaN系の第1半導体層;及び
前記第1導電型AlGaN系の第2半導体層上に配置されたアンドープAlGaN系の半導体層を含む、請求項1に記載の紫外線発光素子。 - 第1導電型AlGaN系の第1半導体層の厚さは、5nmないし20nmである、請求項2に記載の紫外線発光素子。
- 前記アンドープAlNの厚さは、0.5nmないし1.5nmである、請求項1に記載の紫外線発光素子。
- 前記第1導電型AlGaN系の第2半導体層は、AlbGa1−bN(0.25≦b≦0.35)の組成比を有し、Al組成は、前記アンドープAlGaN系の半導体層に行くほど徐々に低くなる、請求項2に記載の紫外線発光素子。
- 前記アンドープAlGaN系の半導体層の厚さは3nmないし10nmである、請求項2に記載の紫外線発光素子。
- 前記電流広がり層は、前記エッチング遮断層と直接接触される、請求項1に記載の紫外線発光素子。
- 前記第1導電型第1半導体層、第1導電型第2半導体層及び第2導電型半導体層は、GaN系で構成され、
前記電流広がり層は、前記エッチング遮断層上に配置された第1導電型GaN系の第1半導体層またはアンドープGaN系の第1半導体層;及び
前記第1導電型AlGaN系の第2半導体層上に配置されたアンドープAlGaN系の半導体層を含む、請求項1に記載の紫外線発光素子。 - 第1導電型GaN系の第1半導体層の厚さは、5nmないし20nmである、請求項8に記載の紫外線発光素子。
- 前記第1導電型AlGaN系の第2半導体層は、AldGa1−dN(0≦d≦0.35)の組成比を有し、Al組成は、前記アンドープGaN系の半導体層に行くほど徐々に低くなる、請求項8項に記載の紫外線発光素子。
- 前記アンドープGaN系の半導体層の厚さは、3nmないし10nmである、請求項8に記載の紫外線発光素子。
- 前記電流広がり層は、前記第1導電型第2半導体層と前記活性層との間に配置された、請求項8に記載の紫外線発光素子。
- 前記電流広がり層は、2ペアないし4ペア交互する、請求項1に記載の紫外線発光素子。
- 前記エッチング遮断層は、AlN及び第1導電型第3半導体層を含み、前記AlN及び第1導電型第3半導体層が5ペアないし15ペア交互する、請求項1に記載の紫外線発光素子。
- 請求項1ないし請求項14のうちいずれか一つの紫外線発光素子を含む発光素子パッケージ。
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KR1020150156638A KR102432015B1 (ko) | 2015-11-09 | 2015-11-09 | 자외선 발광소자 및 발광소자 패키지 |
KR10-2015-0156638 | 2015-11-09 | ||
PCT/KR2016/012852 WO2017082622A1 (ko) | 2015-11-09 | 2016-11-09 | 자외선 발광소자 및 발광소자 패키지 |
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KR (1) | KR102432015B1 (ja) |
CN (1) | CN108352426B (ja) |
WO (1) | WO2017082622A1 (ja) |
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JP4483513B2 (ja) * | 2004-10-08 | 2010-06-16 | 日立電線株式会社 | 半導体発光素子及び半導体発光素子用エピタキシャルウェハ |
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- 2016-11-09 JP JP2018523450A patent/JP6948494B2/ja active Active
- 2016-11-09 EP EP16864548.9A patent/EP3376546B1/en active Active
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US10971648B2 (en) | 2021-04-06 |
CN108352426A (zh) | 2018-07-31 |
JP6948494B2 (ja) | 2021-10-13 |
US20200259042A1 (en) | 2020-08-13 |
KR20170053998A (ko) | 2017-05-17 |
EP3376546A4 (en) | 2019-05-08 |
EP3376546A1 (en) | 2018-09-19 |
KR102432015B1 (ko) | 2022-08-12 |
EP3376546B1 (en) | 2021-02-17 |
CN108352426B (zh) | 2021-10-12 |
WO2017082622A1 (ko) | 2017-05-18 |
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