JP2018504350A5 - - Google Patents
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- Publication number
- JP2018504350A5 JP2018504350A5 JP2017532163A JP2017532163A JP2018504350A5 JP 2018504350 A5 JP2018504350 A5 JP 2018504350A5 JP 2017532163 A JP2017532163 A JP 2017532163A JP 2017532163 A JP2017532163 A JP 2017532163A JP 2018504350 A5 JP2018504350 A5 JP 2018504350A5
- Authority
- JP
- Japan
- Prior art keywords
- plant
- alkyl
- fertilizer
- alkynyl
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 241000196324 Embryophyta Species 0.000 claims description 32
- 239000003337 fertilizer Substances 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000002689 soil Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 claims description 10
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims description 8
- 210000003608 fece Anatomy 0.000 claims description 6
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims description 4
- 125000000304 alkynyl group Chemical group 0.000 claims description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 239000002361 compost Substances 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000010871 livestock manure Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 244000003416 Asparagus officinalis Species 0.000 claims description 2
- 235000005340 Asparagus officinalis Nutrition 0.000 claims description 2
- 235000007319 Avena orientalis Nutrition 0.000 claims description 2
- 241000209763 Avena sativa Species 0.000 claims description 2
- 235000007558 Avena sp Nutrition 0.000 claims description 2
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims description 2
- 241001474374 Blennius Species 0.000 claims description 2
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 claims description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 claims description 2
- 240000000385 Brassica napus var. napus Species 0.000 claims description 2
- 240000007124 Brassica oleracea Species 0.000 claims description 2
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 claims description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 claims description 2
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 claims description 2
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 claims description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 244000068988 Glycine max Species 0.000 claims description 2
- 235000010469 Glycine max Nutrition 0.000 claims description 2
- 241000219146 Gossypium Species 0.000 claims description 2
- 244000020551 Helianthus annuus Species 0.000 claims description 2
- 235000003222 Helianthus annuus Nutrition 0.000 claims description 2
- 240000005979 Hordeum vulgare Species 0.000 claims description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 claims description 2
- 240000008415 Lactuca sativa Species 0.000 claims description 2
- 235000003228 Lactuca sativa Nutrition 0.000 claims description 2
- 241000361919 Metaphire sieboldi Species 0.000 claims description 2
- 150000001204 N-oxides Chemical class 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 240000000111 Saccharum officinarum Species 0.000 claims description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 2
- 244000061456 Solanum tuberosum Species 0.000 claims description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 2
- 240000006394 Sorghum bicolor Species 0.000 claims description 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 claims description 2
- 244000300264 Spinacia oleracea Species 0.000 claims description 2
- 235000009337 Spinacia oleracea Nutrition 0.000 claims description 2
- 235000021536 Sugar beet Nutrition 0.000 claims description 2
- 235000019714 Triticale Nutrition 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 244000098338 Triticum aestivum Species 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- PMUIBVMKQVKHBE-UHFFFAOYSA-N [S].NC(N)=O Chemical compound [S].NC(N)=O PMUIBVMKQVKHBE-UHFFFAOYSA-N 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- CSGLCWIAEFNDIL-UHFFFAOYSA-O azanium;urea;nitrate Chemical compound [NH4+].NC(N)=O.[O-][N+]([O-])=O CSGLCWIAEFNDIL-UHFFFAOYSA-O 0.000 claims description 2
- 235000005822 corn Nutrition 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002515 guano Substances 0.000 claims description 2
- 239000003895 organic fertilizer Substances 0.000 claims description 2
- 239000000575 pesticide Substances 0.000 claims description 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 241000228158 x Triticosecale Species 0.000 claims description 2
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims 5
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 claims 2
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims 2
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 claims 2
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 0 Cc1c(C)[n](*)nc1* Chemical compound Cc1c(C)[n](*)nc1* 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14198850 | 2014-12-18 | ||
| EP14198850.1 | 2014-12-18 | ||
| PCT/EP2015/080548 WO2016097318A1 (en) | 2014-12-18 | 2015-12-18 | Alkynylpyrazoles as nitrification inhibitors |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018504350A JP2018504350A (ja) | 2018-02-15 |
| JP2018504350A5 true JP2018504350A5 (enExample) | 2019-01-31 |
| JP6682538B2 JP6682538B2 (ja) | 2020-04-15 |
Family
ID=52338867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017532163A Active JP6682538B2 (ja) | 2014-12-18 | 2015-12-18 | 硝化阻害剤としてのアルキニルピラゾール |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10676408B2 (enExample) |
| EP (1) | EP3233761B1 (enExample) |
| JP (1) | JP6682538B2 (enExample) |
| CN (1) | CN107108386B (enExample) |
| AU (1) | AU2015366289B2 (enExample) |
| WO (1) | WO2016097318A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6743032B2 (ja) | 2015-02-06 | 2020-08-19 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 硝化抑制剤としてのピラゾール化合物 |
| WO2017025454A1 (en) | 2015-08-07 | 2017-02-16 | Basf Se | Control of pests in maize by ginkgolides and bilobalide |
| CN108368109B (zh) | 2015-11-19 | 2021-11-23 | 巴斯夫欧洲公司 | 用于制备聚氨酯的催化剂 |
| DE102017201608A1 (de) | 2017-02-01 | 2018-08-02 | Eurochem Agro Gmbh | 3,4-Dimethylpyrazol enthaltende Mischung und ihre Verwendung |
| ES3038032T3 (en) * | 2017-08-18 | 2025-10-08 | Basf Se | Process for preparing improved 3,4-dimethyl-1h-pyrazole phosphate formulations |
| CA3087313A1 (en) * | 2018-01-09 | 2019-08-01 | Basf Se | Silylethynyl hetaryl compounds as nitrification inhibitors |
| EP3758492A1 (en) * | 2018-02-28 | 2021-01-06 | Basf Se | Use of alkoxypyrazoles as nitrification inhibitors |
| US11578012B2 (en) * | 2018-02-28 | 2023-02-14 | Basf Se | Use of N-functionalized alkoxy pyrazole compounds as nitrification inhibitors |
| EP3758491A1 (en) * | 2018-02-28 | 2021-01-06 | Basf Se | Use of pyrazole propargyl ethers as nitrification inhibitors |
| US20220142161A1 (en) * | 2019-03-15 | 2022-05-12 | Basf Se | Method of improving the growth and/or the yield of plants grown on agriculturally or horticulturally utilized substrates by applying a nitrication inhibitor added to the irrigation system |
| CN111109034B (zh) * | 2019-12-27 | 2022-01-18 | 湖北格林凯尔农业科技有限公司 | 一种棉花免打顶营养配方及其使用方法 |
| CN111418461A (zh) * | 2020-04-17 | 2020-07-17 | 江西省红壤研究所 | 一种红壤稻田周年二种四收的种植方法 |
| US11236026B1 (en) * | 2020-10-15 | 2022-02-01 | Rosen's, Inc. | Fertigation process |
| WO2022106596A1 (en) | 2020-11-23 | 2022-05-27 | Wocklab Gmbh & Co. Kg | Composition comprising dmpp and phosphonate |
| CN112616586A (zh) * | 2020-12-19 | 2021-04-09 | 山东省农业科学院作物研究所 | 一种菠菜小麦玉米花生周年间套作种植方法及田间管理模式 |
| CN112868483B (zh) * | 2021-01-15 | 2022-03-22 | 山东棉花研究中心 | 一种减轻棉花蕾期雹灾损失的栽培方法 |
| CN117440946A (zh) * | 2021-05-21 | 2024-01-23 | 巴斯夫欧洲公司 | N-官能化的烷氧基吡唑化合物作为硝化抑制剂的用途 |
| CN115959945B (zh) * | 2023-03-17 | 2023-05-23 | 中化现代农业有限公司 | 一种解决葡萄果粒空心问题的营养增补剂及其应用 |
| CN116548260B (zh) * | 2023-05-09 | 2024-02-09 | 安徽农业大学 | 一种促进小白菜平展叶面转化为皱缩型叶面的方法 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE222471C (enExample) | ||||
| DE133088C (enExample) | ||||
| US3635690A (en) * | 1968-05-16 | 1972-01-18 | Dow Chemical Co | Soil treating method and composition for conserving nitrogen in soil by addition of a pyrazole thereto |
| DD133088A1 (de) * | 1977-09-07 | 1978-12-06 | Gerd Kaestner | Mittel zur hemmung bzw.regelung der nitrifikation von ammoniumstickstoff in kulturboeden |
| DD222471A3 (de) * | 1982-09-06 | 1985-05-15 | Piesteritz Stickstoff | Wirkstoffkombination zur hemmung bzw. regelung der nitrifikation von ammoniumstickstoff in kulturboeden |
| FR2598408A1 (fr) * | 1986-05-12 | 1987-11-13 | Rhone Poulenc Agrochimie | Derives propargyloxybenzenes : leur preparation et compositions fongicides les contenant |
| US4992091A (en) | 1986-07-11 | 1991-02-12 | The Dow Chemical Company | Substituted pyrazolo[1,5-a]pyrimidine-2-sulfonamides and compositions and methods of controlling undesired vegetation |
| DE4111922A1 (de) * | 1991-04-12 | 1992-10-15 | Basf Ag | Verfahren zur herstellung von 1-carbamoyl-pyrazolen |
| DE4419517A1 (de) * | 1994-06-03 | 1995-12-07 | Basf Ag | Substituierte 3-Phenylpyrazole |
| DE19503827A1 (de) * | 1995-02-06 | 1996-08-08 | Basf Ag | Verwendung von schwerflüchtigen Pyrazolderivaten mit hydrophilen Gruppen als Nitrifikationsinhibitoren |
| DE19631764A1 (de) * | 1996-08-06 | 1998-02-12 | Basf Ag | Neue Nitrifikationsinhibitoren sowie die Verwendung von Polysäuren zur Behandlung von Mineraldüngemitteln die einen Nitrifikationsinhibitor enthalten |
| JPH10265289A (ja) | 1997-03-27 | 1998-10-06 | Asahi Chem Ind Co Ltd | 被覆粒状肥料 |
| JPH10338582A (ja) | 1997-06-09 | 1998-12-22 | Sumitomo Chem Co Ltd | 施肥方法 |
| DE19958269A1 (de) * | 1999-12-03 | 2001-06-07 | Basf Ag | Düngemittelformulierungen die Polysulfonsäuren enthalten |
| DE10230593C1 (de) | 2002-07-06 | 2003-08-07 | Compo Gmbh & Co Kg | Bewässerungsdüngung von landwirtschaftlich oder gärtnerisch genutzten Substraten |
| DE10332288B4 (de) | 2003-07-16 | 2009-07-30 | Skw Stickstoffwerke Piesteritz Gmbh | Verwendung von 1,2,4-Thiadiazol-5-thioverbindungen und deren Derivate als Ureaseinhibitoren |
| DE102009034433A1 (de) | 2009-07-23 | 2011-01-27 | Skw Stickstoffwerke Piesteritz Gmbh | Zusammensetzungen, bestehend aus einem harnstoffbasierten Düngemittel und einem Ureaseinhibitor, sowie Verfahren zu dessen Herstellung |
| DE102009036229B4 (de) | 2009-08-05 | 2015-02-12 | Skw Stickstoffwerke Piesteritz Gmbh | Antibackmittel für harnstoffbasierte Düngemittel, Düngemittelformulierungen mit diesem Antibackmittel und Verfahren zu deren Herstellung |
| DE102011120098B4 (de) | 2011-12-02 | 2021-02-11 | Skw Stickstoffwerke Piesteritz Gmbh | N-(1H-Pyrazolyl-methyl)formamide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| WO2014053401A2 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Method of improving plant health |
| CN103588594B (zh) * | 2013-11-21 | 2015-12-02 | 成都新朝阳作物科学有限公司 | 肥料增效剂及其应用 |
| DE102013022031B3 (de) | 2013-12-19 | 2014-09-11 | Skw Stickstoffwerke Piesteritz Gmbh | Lösungsmittelsysteme für N-((3(5)-Methyl-1H-pyrazol-1-yl)methyl)acetamid und deren Verwendung zur Behandlung von harnstoffbasierten/ammoniumhaltigen Düngemitteln |
| WO2015104700A2 (en) | 2014-04-17 | 2015-07-16 | Basf Se | Combination of novel nitrification inhibitors and insecticides and/or nematicides as well as combination of (thio)phosphoric acid triamides and insecticides and/or nematicides |
| EA201692076A1 (ru) | 2014-04-17 | 2017-04-28 | Басф Се | Новые ингибиторы нитрификации |
| WO2015081349A2 (en) | 2014-04-17 | 2015-06-04 | Basf Se | Combination of novel nitrification inhibitors and herbicides as well as combination of (thio)phosphoric acid triamides and herbicides |
| WO2015104699A2 (en) | 2014-04-17 | 2015-07-16 | Basf Se | Combination of novel nitrification inhibitors and fungicides as well as combination of (thio)phosphoric acid triamides and fungicides |
| CA2955900C (en) | 2014-04-17 | 2022-10-18 | Basf Se | Combination of novel nitrification inhibitors and biopesticides as well as combination of (thio)phosphoric acid triamides and biopesticides |
| UA123897C2 (uk) | 2014-11-14 | 2021-06-23 | Басф Се | Бензилпропаргілові прості ефіри як інгібітори нітрифікації |
-
2015
- 2015-12-18 CN CN201580068786.3A patent/CN107108386B/zh active Active
- 2015-12-18 US US15/536,925 patent/US10676408B2/en active Active
- 2015-12-18 AU AU2015366289A patent/AU2015366289B2/en active Active
- 2015-12-18 EP EP15817271.8A patent/EP3233761B1/en active Active
- 2015-12-18 WO PCT/EP2015/080548 patent/WO2016097318A1/en not_active Ceased
- 2015-12-18 JP JP2017532163A patent/JP6682538B2/ja active Active
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