JP2018131517A - 複合体 - Google Patents
複合体 Download PDFInfo
- Publication number
- JP2018131517A JP2018131517A JP2017025560A JP2017025560A JP2018131517A JP 2018131517 A JP2018131517 A JP 2018131517A JP 2017025560 A JP2017025560 A JP 2017025560A JP 2017025560 A JP2017025560 A JP 2017025560A JP 2018131517 A JP2018131517 A JP 2018131517A
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- Japan
- Prior art keywords
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- carbon
- general formula
- hydrocarbon group
- examples
- Prior art date
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- 239000002131 composite material Substances 0.000 title claims abstract description 26
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000002134 carbon nanofiber Substances 0.000 claims abstract description 54
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 43
- 150000001875 compounds Chemical class 0.000 claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 21
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- 239000000758 substrate Substances 0.000 claims abstract description 11
- 238000007639 printing Methods 0.000 claims abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 67
- 125000001931 aliphatic group Chemical group 0.000 claims description 23
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 21
- 239000002048 multi walled nanotube Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 12
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- 239000004744 fabric Substances 0.000 claims description 10
- 229910002804 graphite Inorganic materials 0.000 claims description 10
- 239000010439 graphite Substances 0.000 claims description 10
- 239000002109 single walled nanotube Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 125000006615 aromatic heterocyclic group Chemical group 0.000 claims description 5
- 125000000623 heterocyclic group Chemical group 0.000 claims description 5
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- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 abstract description 11
- 238000003860 storage Methods 0.000 abstract description 3
- 150000002894 organic compounds Chemical class 0.000 abstract description 2
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- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
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- 125000003342 alkenyl group Chemical group 0.000 description 8
- 229910021389 graphene Inorganic materials 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 229910017604 nitric acid Inorganic materials 0.000 description 8
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- 125000000217 alkyl group Chemical group 0.000 description 7
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- 239000002245 particle Substances 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
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- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 125000000304 alkynyl group Chemical group 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 6
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- 229920003986 novolac Polymers 0.000 description 6
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
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- 239000004917 carbon fiber Substances 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- 239000006232 furnace black Substances 0.000 description 5
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- 125000002950 monocyclic group Chemical group 0.000 description 5
- 239000002064 nanoplatelet Substances 0.000 description 5
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- 238000005160 1H NMR spectroscopy Methods 0.000 description 4
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
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- 239000011231 conductive filler Substances 0.000 description 4
- 229930003836 cresol Natural products 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000005457 ice water Substances 0.000 description 4
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 125000006040 2-hexenyl group Chemical group 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- DRUKNYVQGHETPO-UHFFFAOYSA-N Nonanedioic acid dimethyl ester Natural products COC(=O)CCCCCCCC(=O)OC DRUKNYVQGHETPO-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000006230 acetylene black Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
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- 238000003756 stirring Methods 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 2
- 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 description 2
- 125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 description 2
- 125000003682 3-furyl group Chemical group O1C([H])=C([*])C([H])=C1[H] 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical compound [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000006244 Medium Thermal Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
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- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 2
- 125000002078 anthracen-1-yl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C([*])=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 2
- 125000000748 anthracen-2-yl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C([H])=C([*])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 2
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- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
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- 230000006837 decompression Effects 0.000 description 2
- ALOUNLDAKADEEB-UHFFFAOYSA-N dimethyl sebacate Chemical compound COC(=O)CCCCCCCCC(=O)OC ALOUNLDAKADEEB-UHFFFAOYSA-N 0.000 description 2
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- 238000007922 dissolution test Methods 0.000 description 2
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- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
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- DEQUKPCANKRTPZ-UHFFFAOYSA-N (2,3-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1O DEQUKPCANKRTPZ-UHFFFAOYSA-N 0.000 description 1
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- 125000004973 1-butenyl group Chemical group C(=CCC)* 0.000 description 1
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- DUILGEYLVHGSEE-UHFFFAOYSA-N 2-(oxiran-2-ylmethyl)isoindole-1,3-dione Chemical compound O=C1C2=CC=CC=C2C(=O)N1CC1CO1 DUILGEYLVHGSEE-UHFFFAOYSA-N 0.000 description 1
- WTYYGFLRBWMFRY-UHFFFAOYSA-N 2-[6-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COCCCCCCOCC1CO1 WTYYGFLRBWMFRY-UHFFFAOYSA-N 0.000 description 1
- PRJQBLZFLQSJOM-UHFFFAOYSA-N 2-[[1,3-dibromo-2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C(C1CO1)OC(C(C)(C(OCC1CO1)Br)C)Br PRJQBLZFLQSJOM-UHFFFAOYSA-N 0.000 description 1
- OGRULRAOMCDCBO-UHFFFAOYSA-N 2-[[1-(oxiran-2-ylmethoxy)naphthalen-2-yl]oxymethyl]oxirane Chemical compound C1OC1COC1=CC=C2C=CC=CC2=C1OCC1CO1 OGRULRAOMCDCBO-UHFFFAOYSA-N 0.000 description 1
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 description 1
- GGIBUEPJJRWWNM-UHFFFAOYSA-N 2-[[2-[2-(oxiran-2-ylmethoxy)phenyl]phenoxy]methyl]oxirane Chemical compound C1OC1COC1=CC=CC=C1C1=CC=CC=C1OCC1CO1 GGIBUEPJJRWWNM-UHFFFAOYSA-N 0.000 description 1
- FSYPIGPPWAJCJG-UHFFFAOYSA-N 2-[[4-(oxiran-2-ylmethoxy)phenoxy]methyl]oxirane Chemical compound C1OC1COC(C=C1)=CC=C1OCC1CO1 FSYPIGPPWAJCJG-UHFFFAOYSA-N 0.000 description 1
- 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 1
- 125000000069 2-butynyl group Chemical group [H]C([H])([H])C#CC([H])([H])* 0.000 description 1
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
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- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000389 2-pyrrolyl group Chemical group [H]N1C([*])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000175 2-thienyl group Chemical group S1C([*])=C([H])C([H])=C1[H] 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- 125000000474 3-butynyl group Chemical group [H]C#CC([H])([H])C([H])([H])* 0.000 description 1
- 125000003349 3-pyridyl group Chemical group N1=C([H])C([*])=C([H])C([H])=C1[H] 0.000 description 1
- 125000001397 3-pyrrolyl group Chemical group [H]N1C([H])=C([*])C([H])=C1[H] 0.000 description 1
- 125000001541 3-thienyl group Chemical group S1C([H])=C([*])C([H])=C1[H] 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 125000000339 4-pyridyl group Chemical group N1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 1
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- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 238000007766 curtain coating Methods 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- MGRBBXBCQZNSIX-UHFFFAOYSA-N dimethyl octanedioate 2,2-dimethyloctanedioic acid Chemical compound COC(=O)CCCCCCC(=O)OC.OC(=O)C(C)(C)CCCCCC(O)=O MGRBBXBCQZNSIX-UHFFFAOYSA-N 0.000 description 1
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- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 239000003365 glass fiber Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000000593 indol-1-yl group Chemical group [H]C1=C([H])C([H])=C2N([*])C([H])=C([H])C2=C1[H] 0.000 description 1
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229940097364 magnesium acetate tetrahydrate Drugs 0.000 description 1
- XKPKPGCRSHFTKM-UHFFFAOYSA-L magnesium;diacetate;tetrahydrate Chemical compound O.O.O.O.[Mg+2].CC([O-])=O.CC([O-])=O XKPKPGCRSHFTKM-UHFFFAOYSA-L 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- KKQAVHGECIBFRQ-UHFFFAOYSA-N methyl propyl carbonate Chemical compound CCCOC(=O)OC KKQAVHGECIBFRQ-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004312 morpholin-2-yl group Chemical group [H]N1C([H])([H])C([H])([H])OC([H])(*)C1([H])[H] 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JAYXSROKFZAHRQ-UHFFFAOYSA-N n,n-bis(oxiran-2-ylmethyl)aniline Chemical compound C1OC1CN(C=1C=CC=CC=1)CC1CO1 JAYXSROKFZAHRQ-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002116 nanohorn Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 229920003050 poly-cycloolefin Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
一般式(1)
(式中、Xはn価の、脂肪族炭化水素基、脂環式炭化水素基、芳香族炭化水素基、脂肪族複素環基または芳香族複素環基を表し、nは2〜6の整数であり、
R1およびR2は、それぞれ独立に、水素原子、一般式(2)で表される基、脂肪族炭化水素基、脂環式炭化水素基または芳香族炭化水素基を表し、R1およびR2のうち、少なくとも1つは、一般式(2)で表される基である。)
一般式(2)
(式中、R3〜R6はそれぞれ独立に、水素原子または脂肪族炭化水素基を表す。)
トーカブラック#4300、#4400、#4500、及び#5500等の東海カーボン社製ファーネスブラック;
プリンテックスL等のデグサ社製ファーネスブラック;
Raven7000、5750、5250、5000ULTRAIII、5000ULTRA、Conductex SC ULTRA、975 ULTRA、PUER BLACK100、115、及び205等のコロンビヤン社製ファーネスブラック;
#2350、#2400B、#2600B、#3050B、#3030B、#3230B、#3350B、#3400B、及び#5400B等の三菱化学社製ファーネスブラック;
MONARCH1400、1300、900、VulcanXC−72R、及びBlackPearls2000等のキャボット社製ファーネスブラック;
Ensaco250G、Ensaco260G、Ensaco350G、及びSuperP−Li等のTIMCAL社製ファーネスブラック;
デンカブラック、デンカブラックHS−100、FX−35等のデンカ社製アセチレンブラック;
VGCF、VGCF−H、VGCF−X等の昭和電工社製カーボンナノチューブ;
xGnP−C−750、xGnP−M−5等のXGSciences社製グラフェンナノプレートレット;
EC1500、EC1000、EC500、EC300、EC100、PC−H、PC−10、PC−30等の伊藤黒鉛工業株式会社製黒鉛;
カイノール炭素繊維、カイノール活性炭繊維などの群栄化学工業社製炭素繊維;等が挙げられるが、これらに限定されるものではない。
アルコール類:メタノール、エタノール、プロパノール、及びイソプロパノールなど。
ケトン類:アセトン、メチルエチルケトン、及びメチルイソブチルケトンなど。
炭酸エステル類:プロピレンカーボネート、エチレンカーボネート、ビニレンカーボネート、及びメチルプロピルカーボネートなど。
エステル類:プロピオン酸エチル、γ−ブチロラクトン、γ−バレロラクトン、δ−バレロラクトン、メチルアセテート、及びエチルアセテート。
エーテル類:エチレングリコールジメチルエーテル、エチレングリコールジエチルエーテル、及びグリコールエーテルなど。
スルホキシド類:ジメチルスルホキシドなど。
(製造例1)[カーボンナノチューブ合成用触媒の製造]
酢酸コバルト・四水和物200部、酢酸マグネシウム・四水和物172部、七モリブデン酸六アンモニウム・四水和物3.5部をビーカーに量り取り、精製水を1488部加えて完全に溶解するまで攪拌した。耐熱性容器に移し替え、電気オーブンを用いて、雰囲気温度150±5℃の温度で60分間乾燥させ水分を蒸発させた後、乳鉢で粉砕して平均粒径(D50)20μmの触媒前駆体を得た。得られた触媒前駆体300部を耐熱容器に量り取り、マッフル炉にて、空気中450±5℃雰囲気下で60分間焼成した後、乳鉢で粉砕して平均粒径(D50)2μmの触媒を得た。
減圧が可能で、外部ヒーターで加熱可能な横型反応管の中央部に、製造例1で得られた触媒1.0gを散布した石英ガラス製耐熱皿を設置した。横型反応管中の空気を真空ポンプにて1×103Paまで減圧後、アルゴンガスを8×104Paまで注入し、再度真空ポンプにて1×103Paまで減圧する、を2回繰り返して、横型反応管中の酸素濃度を0.1体積%以下とした。1×103Paに保ちながら外部ヒーターにて加熱し、横型反応管の中心部が850℃まで加熱した。合成温度850±5℃ に保ち、ブタン/プロパン混合ガスを注入し、3×104Pa〜6×104Paに反応管内の圧力を維持しながら3時間反応させて多層カーボンナノチューブを製造した。合成終了後、反応管内のガスをアルゴンガスで置換し、200℃以下の温度で取り出し、多層カーボンナノチューブを得た。
攪拌機、温度計、滴下装置を備えた反応容器に、60%硝酸200部、濃硫酸800部、トーヨーカラー社製多層カーボンナノチューブ25部を入れ、60℃で8時間加熱攪拌した。その後、室温まで冷却し、10Lの氷水中に投入した。析出した多層カーボンナノチューブを吸引濾別し、さらに20Lのイオン交換水で洗浄して、19部のカルボキシル基を有するカーボンナノファイバー(1)を得た。
攪拌機、温度計、滴下装置を備えた反応容器に、60%硝酸100部、濃硫酸400部、アルドリッチ社製単層カーボンナノチューブ(CG100)10部を入れ、60℃で8時間加熱攪拌した。その後、室温まで冷却し、5Lの氷水中に投入した。析出した単層カーボンナノチューブを吸引濾別し、さらに10Lのイオン交換水で洗浄して、8部のカルボキシル基を有するカーボンナノファイバー(2)を得た。
攪拌機、温度計、滴下装置を備えた反応容器に、60%硝酸100部、濃硫酸400部、ケッチェンブラック(EC−600JD)5部を入れ、30℃で30分間攪拌した。その後、5Lの氷水中に投入した。析出したケッチェンブラックを吸引濾別し、さらに10Lのイオン交換水で洗浄して、3部のカルボキシル基を有するカーボンナノファイバー(3)を得た。
攪拌機、温度計、滴下装置を備えた反応容器に、60%硝酸100部、濃硫酸400部、黒鉛(EC1500)5部を入れ、80℃で8時間加熱攪拌した。その後、室温まで冷却し、5Lの氷水中に投入した。析出した黒鉛を吸引濾別し、さらに10Lのイオン交換水で洗浄して、5部のカルボキシル基を有するカーボンナノファイバー(4)を得た。
攪拌機、温度計、滴下装置、ディーンスターク管、還流冷却器、ガス導入管を備えた反応容器に、スベリン酸ジメチル(オクタン二酸ジメチル)225部、ジエタノールアミン234部、水酸化カリウム10部、トルエン300部を入れ、ディーンスターク管にはトルエンを満たし、窒素を吹き込みながら加熱還流させ、共沸によって生成する水を除去した。4時間後、トルエンをすべて除去し、1H−NMR測定、IR測定を行って目的物が生成していることを確認した。50℃まで降温した後、得られた均一な淡黄色透明の溶液を取り出した。
窒素雰囲気下、攪拌機、温度計、ディーンスターク管、還流冷却器、減圧装置を備えた反応容器に、アゼライン酸ジメチル(ノナン二酸ジメチル)1,000mmol(216.27g)、ジエタノールアミン2,000mmol(210.28g)、ナトリウムエトキシド50mmol(3.40g)を入れ、常圧状態で内温が90℃になるまで加熱攪拌した。内温が90℃に達したら、500hPaの減圧状態にし、100℃で2時間加熱攪拌し、生成するメタノールを留去しながら反応を進行させた。2時間後、200hPaの減圧状態でさらに1時間加熱攪拌し、残存するメタノールを全て留去した。1H−NMR測定、IR測定を行って目的物が生成していることを確認した。50℃まで降温した後、得られた均一な淡黄色透明の溶液を取り出した。
窒素雰囲気下、攪拌機、温度計、ディーンスターク管、還流冷却器、減圧装置を備えた反応容器に、セバシン酸ジメチル(デカン二酸ジメチル)1,000mmol(230.30g)、ジエタノールアミン2,000mmol(210.28g)、ジイソプロピルエチルアミン50mmol(6.46g)を入れ、常圧状態で内温が90℃になるまで加熱攪拌した。内温が90℃に達したら、500hPaの減圧状態で2時間加熱攪拌し、生成するメタノールを留去しながら反応を進行させた。2時間後、200hPaの減圧状態でさらに1時間加熱攪拌し、残存するメタノールを全て留去した。1H−NMR測定、IR測定を行って目的物が生成していることを確認した。50℃まで降温した後、得られた均一な淡黄色透明の溶液を取り出した。
カルボキシル基を有するカーボンナノファイバーと表1の化合物と基材からなる複合体を以下のように作製して、導電性試験、硬化試験、硬化膜強度試験を行った。
カルボキシル基を有するカーボンナノファイバー、架橋剤として表2に示す材料を用いた以外は、実施例1と同様に複合体を作製して、試験を行った。結果を表2に示す。
828:三菱化学株式会社製、ビスフェノールA型エポキシ化合物
EOCN−102S:日本化薬株式会社製、クレゾールノボラック型エポキシ樹脂
EPPN−201L:日本化薬株式会社製、フェノールノボラック型エポキシ樹脂
PVDF:ポリフッ化ビニリデン
カルボキシル基を有しないカーボンナノファイバーまたは架橋性の無い樹脂として、表2に示す材料を用いた以外は、実施例1と同様に複合体を作製して、試験を行った。ただし、架橋反応が見込めない場合でも一律に検討を行った。結果を表2に示す。
Claims (3)
- カルボキシル基を有するカーボンナノファイバーと、下記一般式(1)で表される化合物およびエポキシ基含有化合物からなる群より選ばれる少なくとも一種である架橋剤とを含む組成物を基材に塗布、含浸または印刷してなる複合体。
一般式(1)
R1およびR2は、それぞれ独立に、水素原子、一般式(2)で表される基、脂肪族炭化水素基、脂環式炭化水素基または芳香族炭化水素基を表し、R1およびR2のうち、少なくとも1つは、一般式(2)で表される基である。)
一般式(2)
- カルボキシル基を有するカーボンナノファイバーが、カルボキシル基を有する多層カーボンナノチューブ、カルボキシル基を有する単層カーボンナノチューブまたはカルボキシル基を有する黒鉛である請求項1記載の複合体。
- 基材が、紙、糸、布またはプラスチックフィルムである請求項1または2記載の複合体。
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