JP2018048371A - 電気化学反応装置 - Google Patents
電気化学反応装置 Download PDFInfo
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- JP2018048371A JP2018048371A JP2016184084A JP2016184084A JP2018048371A JP 2018048371 A JP2018048371 A JP 2018048371A JP 2016184084 A JP2016184084 A JP 2016184084A JP 2016184084 A JP2016184084 A JP 2016184084A JP 2018048371 A JP2018048371 A JP 2018048371A
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- electrode
- electrochemical reaction
- reaction device
- electrolytic solution
- conductive
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- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
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- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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Abstract
【解決手段】電気化学反応装置は、第1の収容部と、第2の収容部と、を備える電解液槽と、第1の収容部に配置された第1の電極と、第2の収容部に配置された第2の電極と、第1の電極および第2の電極に電気的に接続された電源と、を具備する。第1の電極は、空隙を有する多孔質導電体を備える。空隙は、多孔質導電体を貫通する。
【選択図】図1
Description
2H2O → 4H++O2+4e− ・・・(1)
2CO2+4H++4e− → 2CO+2H2O ・・・(2)
Claims (14)
- 二酸化炭素を含む第1の物質を含有する第1の電解液を収容するための第1の収容部と、第2の物質を含有する第2の電解液を収容するための第2の収容部と、を備える電解液槽と、
前記第1の収容部に配置された、前記第1の物質を還元するための第1の電極と、
前記第2の収容部に配置された、前記第2の物質を酸化するための第2の電極と、
前記第1の電極および前記第2の電極に電気的に接続された電源と、を具備し、
前記第1の電極は、空隙を有する多孔質導電体を備え、
前記空隙は、前記多孔質導電体を貫通する、電気化学反応装置。 - 前記多孔質導電体は、複数の導電性部材を有し、
前記空隙は、互いに隣り合う前記導電性部材の間に設けられ、
前記互いに隣り合う導電性部材の間隔の最大値は、0.01mm以上0.1mm以下である、請求項1に記載の電気化学反応装置。 - 前記導電性部材は、導電性繊維である、請求項2に記載の電気化学反応装置。
- 前記導電性繊維は、炭素繊維である、請求項3に記載の電気化学反応装置。
- 前記導電性繊維は、金属繊維である、請求項3に記載の電気化学反応装置。
- 前記金属繊維は、金、銀、白金、銅、亜鉛、およびニッケルから選ばれる少なくとも一つの元素を含む、請求項5に記載の電気化学反応装置。
- 前記第1の電極は、前記導電性部材の表面に接する金属層を有する、請求項2ないし請求項6のいずれか一項に記載の電気化学反応装置。
- 前記金属層は、金、銀、白金、銅、亜鉛、およびニッケルから選ばれる少なくとも一つの元素を含む、請求項7に記載の電気化学反応装置。
- 前記第1の電極は、前記導電性部材の表面または前記金属層の表面に結合された第4級カチオンを含む修飾有機分子を有する、請求項2ないし請求項8のいずれか一項に記載の電気化学反応装置。
- 前記第2の電極は、空隙を有する第2の多孔質導電体を備え、
前記第2の多孔質導電体の前記空隙は、前記第2の多孔質導電体を貫通する、請求項1ないし請求項9のいずれか一項に記載の電気化学反応装置。 - 前記電源は、前記第1の電極に電気的に接続された第1の面と前記第2の電極に電気的に接続された第2の面とを有する光電変換体を備える、請求項1ないし請求項10のいずれか一項に記載の電気化学反応装置。
- 前記第2の物質は、水を含む、請求項1ないし請求項11のいずれか一項に記載の電気化学反応装置。
- 前記電解液槽の一方向に沿って前記第2の収容部に配置された複数の前記第2の電極と、
前記一方向に沿って前記第1の収容部と前記電解液槽の外部とを接続する流路と、をさらに具備し、
前記多孔質導電体は、前記複数の第2の電極のそれぞれに重畳する、請求項1ないし請求項12のいずれか一項に記載の電気化学反応装置。 - 前記電解液槽は、前記一方向に沿って長さを有する円筒形状を有し、
前記複数の第2の電極は、それぞれ前記電解液槽の内周面に沿って配置され、
前記多孔質導電体は、前記複数の第2の電極よりも前記電解液槽の中心軸に近い、請求項13に記載の電気化学反応装置。
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