JP2017526604A - 装飾用ガラスパネル - Google Patents
装飾用ガラスパネル Download PDFInfo
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- JP2017526604A JP2017526604A JP2017504045A JP2017504045A JP2017526604A JP 2017526604 A JP2017526604 A JP 2017526604A JP 2017504045 A JP2017504045 A JP 2017504045A JP 2017504045 A JP2017504045 A JP 2017504045A JP 2017526604 A JP2017526604 A JP 2017526604A
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- 239000011521 glass Substances 0.000 title claims abstract description 29
- 239000010410 layer Substances 0.000 claims abstract description 144
- 239000002346 layers by function Substances 0.000 claims abstract description 64
- 238000000576 coating method Methods 0.000 claims abstract description 59
- 239000011248 coating agent Substances 0.000 claims abstract description 54
- 239000000758 substrate Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 29
- 230000031700 light absorption Effects 0.000 claims abstract description 20
- 230000003287 optical effect Effects 0.000 claims abstract description 18
- 238000005034 decoration Methods 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 239000000956 alloy Substances 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 14
- 230000007935 neutral effect Effects 0.000 claims description 13
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 11
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 238000013016 damping Methods 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 238000002834 transmittance Methods 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims 3
- 229910001120 nichrome Inorganic materials 0.000 claims 3
- 230000000694 effects Effects 0.000 abstract description 9
- 239000011651 chromium Substances 0.000 description 11
- 238000004544 sputter deposition Methods 0.000 description 11
- 210000003298 dental enamel Anatomy 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 150000004767 nitrides Chemical class 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 5
- 239000012300 argon atmosphere Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000001579 optical reflectometry Methods 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- 238000001429 visible spectrum Methods 0.000 description 4
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- 239000005361 soda-lime glass Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- -1 Si 3 N 4 Inorganic materials 0.000 description 2
- 229910006404 SnO 2 Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000002320 enamel (paints) Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000684 Cobalt-chrome Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910003087 TiOx Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910002065 alloy metal Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000010952 cobalt-chrome Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000016674 enamel mineralization Effects 0.000 description 1
- 238000004534 enameling Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- ZARVOZCHNMQIBL-UHFFFAOYSA-N oxygen(2-) titanium(4+) zirconium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4] ZARVOZCHNMQIBL-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3684—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used for decoration purposes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/251—Al, Cu, Mg or noble metals
- C03C2217/252—Al
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/257—Refractory metals
- C03C2217/258—Ti, Zr, Hf
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/268—Other specific metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/28—Other inorganic materials
- C03C2217/281—Nitrides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
- C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
本発明の分野は、不透明であり、または光透過率が非常に低く、装飾用被覆を有するガラス質材料でできた基材を含む装飾用ガラスパネルの分野である。
ほうろうの存在を回避するための解決策が見出されている。特許出願の国際公開第2012/013787 A2号パンフレットには、グレージング基材上に陰極スパッタリングによって形成された層のスタックが設けられたスパンドレルが記載されている。この文献には、ほうろう層を全く使用せずに建物のビジョンガラス領域と視覚的に適合するほぼ不透明のスパンドレルが開示されている。
本発明の目的の1つは、新規で快適な美的外観を有する装飾用パネルを提供することである。
本発明は、少なくとも1つの光吸収機能層および透明誘電体被覆を含み、光吸収機能層が誘電体被覆の間に挟まれる多層スタックを有するガラス質材料でできた基材を含むほぼ不透明の装飾用ガラスパネルであって、光吸収機能層が、15〜140nmの間で構成される幾何学的厚さ、少なくとも1.8の減衰係数k、および少なくとも91の減衰係数kとナノメートルの単位での厚さとの積を有することと、多層スタックが、さらに、1〜50nmの間で構成される厚さを有し、1を超える屈折率nおよび少なくとも0.5の減衰係数kを有する少なくとも1つの減衰層を含むことと、光学的厚さが30〜160nmの間で構成され屈折率nが1.5を超える透明誘電体被覆が、空気と接触しない場合に、光吸収機能層とは反対側で減衰層に隣接して配置されることとを特徴とする装飾用ガラスパネルに関する。
k×n×e>35、有利には>40,および好ましくは>60、
式中、kは前述の定義のような平均減衰係数であり、nは前述の定義のような平均屈折率であり、eはnmの単位で表される層の幾何学的厚さである。
これより、単なる例示として以下の代表的な実施形態を用いて本発明を説明する。
以下の表I中、本発明によらない最初の4つの例は、ただ1つの金属層と、2つの透明誘電体被覆、またはちょうど1つの透明誘電体被覆(たとえばC3の場合)のいずれかとを含んだ。対応する光学的性質を表Iに示している。%の単位の光透過率(TL)および%の単位の光反射率(RL)は、CIE標準光源D65、2°を用いて測定した。CIEのL*、a*、b*色座標は、光源D65、10°を用いて測定した。光反射率RLGおよびL* RG、a* RG、b* RG色座標は、基材側からの反射で観測した。
以下の表II中、本発明による実施例は、表Iの比較例と同じ方式に合わせられる。2つの比較例C5〜C8が示されている。層は、同じ条件下で、同じ技術、すなわちマグネトロン中の低圧マグネトロン陰極スパッタリングを用いて堆積した。NiCrW層の組成は、比較例と同じであった。Al、Cu、Cr、およびTiの金属層も、中性アルゴン雰囲気中、対応する材料でできた金属ターゲットを用いて堆積した。TiN、CrN、TaN、およびZrNの窒化物層は、対応する材料の金属ターゲットを用いて、反応性アルゴンおよび窒素雰囲気中で堆積した。TiO2酸化物層は、セラミックTiOxターゲットを用いて反応性アルゴンおよび酸素雰囲気中で堆積した。SiO2層は、4%のアルミニウムをドープしたシリコンターゲットを用いて酸化性反応性アルゴンおよび酸素雰囲気中で堆積した。SiON層は、わずかに酸素を含有する反応性アルゴンおよび窒素雰囲気中で堆積した。AZO層は、セラミックのアルミニウムドープ亜鉛酸化物ターゲットを用いて中性雰囲気中で堆積した。これらの多層スタックも厚さ4mmの通常の透明ソーダ石灰ガラス板上に堆積した。
実施例25は、両側から観察可能となること、したがって基材側または多層スタック側のいずれからも観察可能となることが意図された装飾用パネルに関するものであった。この場合、第1の減衰層に対して光吸収機能層の反対側に第2の減衰層が配置される。スタックの構造を表IVに示す。
表VIに示されるように、実施例26では、誘電体被覆はSnO2とNiCrの減衰層とから作製し、実施例27では、誘電体被覆はZn2SnO4とNiCrの減衰層とから作製した。
Claims (21)
- 少なくとも1つの光吸収機能層および透明誘電体被覆を含み、前記光吸収機能層が誘電体被覆の間に挟まれる多層スタックを有するガラス質材料でできた基材を含むほぼ不透明の装飾用ガラスパネルであって、前記光吸収機能層が、15〜140nmの間で構成される幾何学的厚さ、少なくとも1.8の減衰係数k、および少なくとも91の前記減衰係数kとナノメートルの単位での前記層厚さとの積を有することと、前記多層スタックが、さらに、1〜50nmの間で構成される厚さを有し、1を超える屈折率nおよび少なくとも0.5の減衰係数kを有する少なくとも1つの減衰層を含むことと、光学的厚さが30〜160nmの間で構成され屈折率nが1.5を超える透明誘電体被覆が、空気と接触しない場合に、前記光吸収機能層とは反対側で前記減衰層に隣接して配置されることとを特徴とする装飾用ガラスパネル。
- 前記光吸収機能層が金属特性の層であることを特徴とする請求項1に記載の装飾用パネル。
- 前記減衰層が金属特性の層であることを特徴とする請求項1または2のいずれか一項に記載の装飾用パネル。
- 前記減衰層が、透明誘電体被覆によって前記光吸収機能層から分離されることを特徴とする請求項1〜3のいずれか一項に記載の装飾用パネル。
- 前記光吸収機能層の前記幾何学的厚さが最大88nm、好ましくは最大80nmであることを特徴とする請求項1〜4のいずれか一項に記載の装飾用パネル。
- 前記光吸収機能層の前記幾何学的厚さが28nm以上、好ましくは31nm以上、有利には35nm以上であることを特徴とする請求項1〜5のいずれか一項に記載の装飾用パネル。
- 前記減衰層の幾何学的厚さが30nm以下、好ましくは20nm以下、有利には16nm以下であることを特徴とする請求項1〜6のいずれか一項に記載の装飾用パネル。
- 前記減衰層の前記減衰係数kと、前記屈折率nと、nmの単位で表される幾何学的厚さとの積が、35を超え、好ましくは40を超え、有利には60を超えることを特徴とする請求項1〜7のいずれか一項に記載の装飾用パネル。
- 前記光吸収機能層とは反対側で前記減衰層に隣接して配置される前記誘電体被覆の前記光学的厚さが50〜140nmの間、好ましくは60〜130nmの間、有利には70〜120nmの間で構成されることを特徴とする請求項1〜8のいずれか一項に記載の装飾用パネル。
- 前記光吸収機能層の前記幾何学的厚さが25〜70nmの間で構成され、前記減衰層の幾何学的厚さが1〜15nmの間で構成され、前記光吸収機能層とは反対側で前記減衰層に隣接して配置される前記誘電体被覆の前記光学的厚さが40〜160nmの間で構成されることを特徴とする請求項1〜9のいずれか一項に記載の装飾用パネル。
- 前記光吸収機能層および/または前記減衰層がNi、Cr、Zr、またはNiCrを主成分とする合金から形成されることを特徴とする請求項1〜10のいずれか一項に記載の装飾用パネル。
- 前記光吸収機能層および/または前記減衰層が、NiCr、NiCrW、NbZr、およびCrZrの群からの合金を主成分とすることを特徴とする請求項11に記載の装飾用パネル。
- 少なくとも、全体的にスタックに関して外側である前記透明誘電体被覆が、窒化アルミニウムまたは窒化ケイ素を主成分とすることを特徴とする請求項1〜12のいずれか一項に記載の装飾用パネル。
- 1〜50nmの間で構成される厚さを有し、1を超える屈折率および少なくとも0.5の減衰係数kを有する第2の減衰層と、光学的厚さが30〜160nmの間で構成され、空気と接触しない場合は屈折率nが1.5を超える追加の透明誘電体被覆とが、第1の減衰層に対して前記光吸収機能層の反対側に加えられ、それによってこの追加の透明誘電体被覆が、前記光吸収機能層に関して前記第2の減衰層の反対側に存在することを特徴とする請求項1〜13のいずれか一項に記載の装飾用パネル。
- 少なくとも1つの光吸収機能層および1つの減衰層を含み、これらの層に透明誘電体被覆が隣接する多層スタックを有するガラス質材料でできた基材を含むガラスパネルであって、2%以下、好ましくは1%以下の光透過率と、前記減衰層の側から観測して6.5%以下、好ましくは6%以下、有利には5.5%以下の光反射率と、同じ側から観測される反射における中性色相とを有することを特徴とするガラスパネル。
- 前記光吸収機能層および前記減衰層がNi、Cr、Zr、またはWを主成分とする合金から形成されることを特徴とする請求項15に記載のガラスパネル。
- 前記光吸収機能層および前記減衰層がNiCr、NiCrW、およびCrZrの群からの合金を主成分とすることを特徴とする請求項16に記載のガラスパネル。
- 前記透明誘電体被覆が窒化アルミニウムまたは窒化ケイ素を主成分とすることを特徴とする請求項15〜17のいずれか一項に記載のガラスパネル。
- 前記減衰層の側の反射で観測されるa*およびb*色座標の両方の絶対値が4未満、好ましくは3以下、有利には1以下であることを特徴とする請求項15〜18のいずれか一項に記載のガラスパネル。
- 前記パネルの少なくとも1つの側から観測される光反射率が5.2%以下、好ましくは5%以下であることを特徴とする請求項15〜19のいずれか一項に記載のガラスパネル。
- 接着性熱可塑性プラスチックによって別のガラス板が取り付けられた、請求項1〜13のいずれか一項に記載の装飾用パネルまたは請求項14〜19のいずれか一項に記載のガラスパネルを含む、積層パネル。
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Also Published As
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WO2016012325A1 (fr) | 2016-01-28 |
EP3172175A1 (fr) | 2017-05-31 |
US20170197874A1 (en) | 2017-07-13 |
JP6664377B2 (ja) | 2020-03-13 |
US10550034B2 (en) | 2020-02-04 |
EP3172175B1 (fr) | 2023-01-11 |
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